Trans-sobrerol （Sob） and 8-p-menthen-1,2-diol （Limo-diol） are the primary products in the atmospheric oxidation of α-pinene and limonene, respectively. Because of their low volatility, they associate more likely ...Trans-sobrerol （Sob） and 8-p-menthen-1,2-diol （Limo-diol） are the primary products in the atmospheric oxidation of α-pinene and limonene, respectively. Because of their low volatility, they associate more likely to the liquid particles in the atmosphere, where they are subject to the aqueous phase oxidation by the atmospheric oxidants. In this work, through experimental and theoretical study, we first provide the rate constants of Sob and Limo-diol reacting with hydroxyl radical （.OH） in aqueous solution at room temperature of 3044-3 K and 1 atm pressure, which are （3.05±0.5）×10 9 and （4.57±0.2）×10 9 L/（mol.s）, respectively. Quantum chemistry calculations have also been employed to demonstrate the solvent effect on the rate constants in aqueous phase and the calculated results agree well with the measurements. Some reaction products have been identified based on liquid chromatography combined with mass spectroscopy and theoretical calculations.展开更多
CFG pile has been widely applied as one of the common ground treatment techniques. As a concealed work, the construction quality of pile foundation not only relates to the success of the project, but also concerns the...CFG pile has been widely applied as one of the common ground treatment techniques. As a concealed work, the construction quality of pile foundation not only relates to the success of the project, but also concerns the benefits of thousands of hot, seholds. Only strengthening the supervision and management during the construction and strictly designing and specifying CFG pile can ensure the construction quality of CFG pile. But most researches focus on operating mechanism and theoretical analysis, and there are fewer researches about the construction of CFG pile. The real construction of CFG pile has no specified operation and lacks of the construction guidance, which not only causes great problems and has great influence on the intensity of CFG pile, but also makes the real pile body have great difference from the design requirements. Therefore, the study on construction of CFG pile in the paper has great significance.展开更多
基金This work was supported by the National Natural Science Foundation of China （No.21177041 and No.21107026）, the Fundamental Research Funds for the Central Universities （No.2013ZZ0073）, and the Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry.
文摘Trans-sobrerol （Sob） and 8-p-menthen-1,2-diol （Limo-diol） are the primary products in the atmospheric oxidation of α-pinene and limonene, respectively. Because of their low volatility, they associate more likely to the liquid particles in the atmosphere, where they are subject to the aqueous phase oxidation by the atmospheric oxidants. In this work, through experimental and theoretical study, we first provide the rate constants of Sob and Limo-diol reacting with hydroxyl radical （.OH） in aqueous solution at room temperature of 3044-3 K and 1 atm pressure, which are （3.05±0.5）×10 9 and （4.57±0.2）×10 9 L/（mol.s）, respectively. Quantum chemistry calculations have also been employed to demonstrate the solvent effect on the rate constants in aqueous phase and the calculated results agree well with the measurements. Some reaction products have been identified based on liquid chromatography combined with mass spectroscopy and theoretical calculations.
文摘CFG pile has been widely applied as one of the common ground treatment techniques. As a concealed work, the construction quality of pile foundation not only relates to the success of the project, but also concerns the benefits of thousands of hot, seholds. Only strengthening the supervision and management during the construction and strictly designing and specifying CFG pile can ensure the construction quality of CFG pile. But most researches focus on operating mechanism and theoretical analysis, and there are fewer researches about the construction of CFG pile. The real construction of CFG pile has no specified operation and lacks of the construction guidance, which not only causes great problems and has great influence on the intensity of CFG pile, but also makes the real pile body have great difference from the design requirements. Therefore, the study on construction of CFG pile in the paper has great significance.
