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RRLC-Q-TOF MS/MS法分析生晒参和大力参中的皂苷类成分 被引量:15
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作者 郝颖 于珊珊 +4 位作者 戴雨霖 张颖 钟薇 刘淑莹 越皓 《质谱学报》 EI CAS CSCD 北大核心 2014年第4期311-316,共6页
利用高分离度快速液相色谱与四极杆-飞行时间质谱(RRLC-Q-TOF MS/MS)联用,对生晒参和大力参中的人参皂苷类成分进行比较研究。基于人参皂苷Rd和Re、Rf和Rg1两组同分异构体在串联质谱中的裂解规律,以及mRd的串联质谱特征,通过标准品保留... 利用高分离度快速液相色谱与四极杆-飞行时间质谱(RRLC-Q-TOF MS/MS)联用,对生晒参和大力参中的人参皂苷类成分进行比较研究。基于人参皂苷Rd和Re、Rf和Rg1两组同分异构体在串联质谱中的裂解规律,以及mRd的串联质谱特征,通过标准品保留时间和精确分子质量鉴定了人参中的35种人参皂苷,进而比较了生晒参和大力参中人参皂苷的相对百分含量差异,并于大力参中检测到稀有人参皂苷,如人参皂苷Rg5、Rk1、F4、Rg6等。该方法对于大力参类传统中药炮制品的成分研究具有借鉴意义,研究结果能说明大力参区别于生晒参的物质基础,可以为大力参在临床上合理、有效地使用提供指导。 展开更多
关键词 生晒 大力参 皂苷 高分离度快速液相色谱-四极杆-飞行时间质谱(RRLC-Q-TOF MS MS)
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提高大力参加工质量的对比试验 被引量:1
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作者 姜喜同 高玉朋 +3 位作者 任跃英 李向高 官秀芝 贾洪森 《人参研究》 2004年第1期39-41,共3页
通过对大力参不同加工方法做对比试验 。
关键词 大力参 加工质量 加工方法 工艺流程
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中国 高丽 日本大力参化学成分的比较研究(Ⅰ)——人参皂甙含量的比较分析 被引量:1
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作者 李树殿 张永强 +1 位作者 鲁岐 邱春 《人参研究》 1989年第3期21-22,共2页
通过 CS——930型薄层扫描仪测定了中国、高丽和日本大力参,结果表明以中国大力参质量最好,人参总皂甙为2.607%,八种单体皂甙总计2.484%,其次是高丽大力参,人参总皂甙为2.405%,八种单体皂甙总计为2.262%,最次是日本大力参,人参总皂甙1.6... 通过 CS——930型薄层扫描仪测定了中国、高丽和日本大力参,结果表明以中国大力参质量最好,人参总皂甙为2.607%,八种单体皂甙总计2.484%,其次是高丽大力参,人参总皂甙为2.405%,八种单体皂甙总计为2.262%,最次是日本大力参,人参总皂甙1.662%,八种单体皂甙总和为1.578%。 展开更多
关键词 大力参 总皂甙 单体皂甙
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大力参急性毒性与遗传毒性试验研究 被引量:1
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作者 杨晓峰 陈文学 +1 位作者 陈志福 杨明 《中国中医药现代远程教育》 2014年第1期152-154,共3页
目的了解大力参急性毒性及遗传毒性,为大力参的食用安全性提供实验依据。方法采用小鼠及大鼠急性经口毒性试验;Ames试验(每皿分别加入8、40、200、1000、4000μg大力参)、小鼠骨髓细胞微核试验与小鼠精子畸形试验对大力参遗传毒性进行... 目的了解大力参急性毒性及遗传毒性,为大力参的食用安全性提供实验依据。方法采用小鼠及大鼠急性经口毒性试验;Ames试验(每皿分别加入8、40、200、1000、4000μg大力参)、小鼠骨髓细胞微核试验与小鼠精子畸形试验对大力参遗传毒性进行评价。结果大力参经口最大耐受剂量(MTD)均大于16.2g/kg。3项遗传毒性试验的结果均为阴性。结论在本实验条件下大力参对小鼠及大鼠经口急性毒性试验未见毒性反应,同时未见遗传毒性作用。 展开更多
关键词 大力参 急性毒性 遗传毒性
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大力参加工方法的改进 被引量:1
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作者 包玉清 许桂竹 +1 位作者 赵学艳 金东星 《农业与技术》 2001年第3期30-32,35,共4页
将大力参原加工法的关键──鲜参在沸水中烫一定时间,改为文武火各蒸30分钟, 结果成品物 理性状与原加工法几乎无差异,但提高了单位时间加工量、折干率和一等参率,从而增加了 经济效益。
关键词 大力参 加工方法 经济效益 改进措施 加工制品 文火时间 折干率 一等
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大力参炮制工艺及主要化学成分与颜色相关性分析
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作者 王艺霏 初奇 +4 位作者 孙佳莹 张译丹 罗健顺 胡亚男 高红梅 《药物评价研究》 CAS 2024年第11期2613-2626,共14页
目的优化大力参炮制工艺,并探究炮制过程中颜色与内在质量的相关性。方法采用高效液相色谱法(HPLC)建立8种人参皂苷的含量测定方法;采用紫外分光光度法(UV)建立人参总皂苷、人参多糖的含量测定方法。以人参皂苷Rg1、人参皂苷Rb_(1)、人... 目的优化大力参炮制工艺,并探究炮制过程中颜色与内在质量的相关性。方法采用高效液相色谱法(HPLC)建立8种人参皂苷的含量测定方法;采用紫外分光光度法(UV)建立人参总皂苷、人参多糖的含量测定方法。以人参皂苷Rg1、人参皂苷Rb_(1)、人参皂苷Re、人参多糖、人参总皂苷的含量及饮片外观性状评分作为指标,运用层次分析法(AHP)-熵权法结合响应面法考察料液比、参根直径和烫制时间对大力参炮制工艺的影响,得出最佳炮制工艺并进行验证。利用测色仪对不同炮制工艺的大力参样品粉末进行色度值测定,选择8种人参皂苷、人参多糖和人参总皂苷含量对大力参进行内在质量评价,对色度值和上述指标含量进行Pearson相关性分析、主成分分析(PCA)、层次聚类分析(HCA)和正交偏最小二乘法判别分析(OPLS-DA)。结果优选的大力参炮制工艺为料液比1∶10,参根直径范围为2.1~2.5 cm,烫制时间10 min。6次验证结果显示,最优炮制工艺的平均综合评分为80.55,与预测值的相对偏差为1.10%。相关性分析结果显示,人参多糖、人参总皂苷、人参皂苷Rg1、人参皂苷Rb_(1)、人参皂苷Rf、人参皂苷Rc、人参皂苷Rb_(2)、人参皂苷Rb3、人参皂苷Rd含量与明度值(L^(*) )、红绿色(a^(*) )、黄蓝色(b^(*) )以及总色度值(E^(*) )均呈显著正相关,人参皂苷Re与a^(*) 呈显著正相关,与L^(*) 、b^(*) 、E^(*) 无相关性。PCA及HCA结果显示,不同炮制工艺的大力参可聚为2类。OPLS-DA结果显示人参皂苷Rf、Rd、Rb_(1)含量是大力参炮制过程中的重要质量指标,a^(*) 是大力参炮制过程中的重要颜色指标。结论建立的大力参炮制工艺稳定可行,且大力参颜色与内在质量具有一定相关性。 展开更多
关键词 大力参 Box-Behnken响应面法 层次分析法-熵权法 炮制工艺 色度值 皂苷Rg1 皂苷Rb1 多糖
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基于近红外光谱技术的大力参含水量快速无损检测 被引量:5
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作者 曲正义 逄世峰 +4 位作者 王兆森 姚丽娜 郑培和 李亚丽 王英平 《时珍国医国药》 CAS CSCD 北大核心 2020年第11期2653-2655,共3页
目的采用近红外光谱技术结合化学计量学方法,对大力参中水分含量进行快速无损测定。方法利用手持式固体光纤探头采集大力参的近红外漫反射光谱,以烘干法测定的水分含量为实测值,结合偏最小二乘法(PLS)建大力参水分的定量分析模型,并用... 目的采用近红外光谱技术结合化学计量学方法,对大力参中水分含量进行快速无损测定。方法利用手持式固体光纤探头采集大力参的近红外漫反射光谱,以烘干法测定的水分含量为实测值,结合偏最小二乘法(PLS)建大力参水分的定量分析模型,并用未知样品对该模型进行外部验证。结果所建水分定量模型的校正集相关系数(R^(2))、内部交叉验证均方差(RMSECV)、校正均方差(RMSEC)分别为0.7643,0.516,0.49。验证集的相关系数(R^(2))与预测均方差(RMSEP)分别为0.8326和0.508,验证集NIR预测值与烘干法实测值的单因素方差分析结果为:在95%的置信区间,P(0.605)>0.05,差异无统计学意义。结论该方法操作简便,快速无损,结果准确,可用于大力参中水分含量的快速无损测定。 展开更多
关键词 大力参 含水量 近红外光谱法 偏最小二乘法 快速无损
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熏硫人参二氧化硫残留量分析测定 被引量:8
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作者 李月茹 孙晓秋 李树殿 《人参研究》 1995年第2期16-18,共3页
近年来,在人参商品上,有许多人片面地追求人参色泽,特别是生晒参、全须生晒参、大力参、白干参和保鲜参等加工品种,认为色越白越好,不看其实质,只追求色白。这种加工技术已经废止多年,又骤然兴起。
关键词 残留量分析 二氧化硫残留量 全须生晒 熏硫 产品质量监测 大力参 食品卫生国家标准 食品添加剂使用卫生标准 碘标准液
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中华人民共和国国家标准《人参加工产品分等质量标准》(一)对外观质量标准的研究与讨论
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作者 李树殿 赵秋萍 +2 位作者 汤美兰 初正云 徐绥绪 《人参研究》 1995年第2期24-27,共4页
人参加工产品分等质量标准(以下简称标准)是经过国家技术监督局立项、在国家中医药管理局主持下、从1991年开始筹备编写、1994年6月7日在哈尔滨召开审查会正式通过的国家标准。
关键词 分等质量标准 中华人民共和国国家标准 加工 全须生晒 外观质量 对外观 内在质量 白干 加工方法 大力参
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汤参加工工艺
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作者 车熙哲 《中国林副特产》 1989年第3期39-39,共1页
汤参又称烫参,大力参。具有色泽好,有效成份含量高,药性和缓,易贮藏的特点。近年来在香港、台湾、新加坡和日本等地深受欢迎,在市场上十分走俏,价格高于普通红参。此外,加工汤参的出货率高,经济效益显著,是一仲很有发展前途的商品参加... 汤参又称烫参,大力参。具有色泽好,有效成份含量高,药性和缓,易贮藏的特点。近年来在香港、台湾、新加坡和日本等地深受欢迎,在市场上十分走俏,价格高于普通红参。此外,加工汤参的出货率高,经济效益显著,是一仲很有发展前途的商品参加工品种,笔者在此介绍汤参的两种加工工艺。根据加工时对参根热处理方式的不同,加工汤参有两种方法。第一种方法的程序为: 展开更多
关键词 大力参 加工
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癃闭治验二则
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作者 许秀萍 《黔南民族医专学报》 1998年第2期71-72,共2页
癃闭以排尿困难,甚则小便不通为其特征,尤其是老年人常见。笔者在三十年的临床实践中,对本病的治疗积累了一些经验体会,现举治验病例二则,以作引玉之砖。1升清降浊 王某,男,64岁,患者素体亏虚,长期吐痰,咳嗽、气喘,活动困难。3天前突然... 癃闭以排尿困难,甚则小便不通为其特征,尤其是老年人常见。笔者在三十年的临床实践中,对本病的治疗积累了一些经验体会,现举治验病例二则,以作引玉之砖。1升清降浊 王某,男,64岁,患者素体亏虚,长期吐痰,咳嗽、气喘,活动困难。3天前突然小便点滴不通,无力排出,小腹胀痛,疼痛难忍,急送某医院,诊断为:尿潴留。经抗炎,导尿,对症治疗3天无效,准备手术治疗。因病人及亲属害怕手术,求治于余。诊视呈急性重病容,表情痛苦,呻吟不止,精神萎糜,语言低微,双手捧腹,下腹膨隆,压痛明显,面色晦暗,舌淡略紫,脉细弱。证属脾肺气虚,升降失常。治宜升清降浊,拟补中益气汤加味:大力参10g(即人参的一种)白术12g,陈皮9g、黄芪30g、升麻9g、柴胡6g。 展开更多
关键词 治验二则 癃闭 脾肺气虚 小便不通 小腹胀痛 手术治疗 大力参 老年人 益气汤 排尿困难
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Influence of enlarged section parameters on pressure transients of high-speed train passing through a tunnel 被引量:12
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作者 WANG Tian-tian LEE Chun-hian YANG Ming-zhi 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第11期2831-2840,共10页
The influence of enlarged section parameters on pressure transients of high-speed train passing through a tunnel was investigated by numerical simulation.The calculation results obtained by the structured and unstruct... The influence of enlarged section parameters on pressure transients of high-speed train passing through a tunnel was investigated by numerical simulation.The calculation results obtained by the structured and unstructured grid and the experimental results of smooth wall tunnel were verified.Numerical simulation studies were conducted on three tunnel enlarged section parameters,the enlarged section distribution along circumferential direction,the enlarged section area and the enlarged section distribution along tunnel length direction.The calculation results show that the influence of the different enlarged section distributions along tunnel circumferential direction on pressure transients in the tunnel is basically consistent.There is an optimal enlarged section area for the minimum value of the pressure variation amplitude and the average pressure variation in the tunnel.The law of the pressure variation amplitude and the average pressure variation of the enlarged section distribution along tunnel length direction are obtained. 展开更多
关键词 high-speed train enlarged section parameters TUNNEL pressure transients
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Application of Ambient Stress Parameters to Short-Term Prediction of the 2004, M_S5.0 Shuangbai, Yunnan Earthquake
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作者 Qian Xiaodong Qin Jiazheng 《Earthquake Research in China》 2007年第1期43-54,共12页
Based on the data recorded by the regional digital seismic network of Yunnan and using new methods, the short-term variations of the ambient stress field of Yunnan and its adjacent areas are monitored in real time. Wi... Based on the data recorded by the regional digital seismic network of Yunnan and using new methods, the short-term variations of the ambient stress field of Yunnan and its adjacent areas are monitored in real time. With the in-depth analyses of the spatial-temporal evolution of the ambient stress field prior to the 2004, Shuangbai M_S5.0 earthquake, concrete procedures for predicting the three elements of the earthquake are presented. 展开更多
关键词 Shuangbai earthquake Ambient stress parameter Short-term earthquake prediction
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Spectrum Correction in Study of Solvation Dynamics by Fluorescence Non-collinear Optical Parametric Amplification Spectroscopy
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作者 党伟 白晶晶 +1 位作者 张连水 翁羽翔 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2016年第1期147-150,I0003,共5页
Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spec- troscopy can extract the curve of spectral gain from its parametric superfluorescence. This unique spectrum correction method... Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spec- troscopy can extract the curve of spectral gain from its parametric superfluorescence. This unique spectrum correction method enables fluorescence non-collinear optical parametric amplification spectroscopy acquiring the genuine transient fluorescence spectrum of the studied system. In this work we employ fluorescence non-collinear optical parametric amplification spectroscopy technique to study the solvation dynamics of DCM dye in ethanol solution, and confirm that genuine solvation correlation function and shift of peak frequency can be derived from transient fluorescence spectra after the spectral gain correction. It demonstrates that fluorescence non-collinear optical parametric amplification spectroscopy can benefit the research fields, which focuses on both fluorescence intensity dynamics and fluorescence spectral shape evolution. 展开更多
关键词 Transient fluorescence spectrum Solvation dynamics Non-collinear optical parametric amplification Spectrum correction
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Theoretical Model of the Tropospheric Pressure Variation on the Height
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作者 Raul C. Perez 《Journal of Earth Science and Engineering》 2017年第3期175-180,共6页
In the study and the research of the troposphere, the knowledge about its pressure variation on the height is necessary and important. Of course, exist the sounding to make this work, but not always it is possible to ... In the study and the research of the troposphere, the knowledge about its pressure variation on the height is necessary and important. Of course, exist the sounding to make this work, but not always it is possible to access to sounding data when is necessary, so then, it is important to has others alternatives methods in order to replace it. The troposphere is basically a fluid, susceptible to be studied under the fluid mechanics and thermodynamics of the ideals gases without loss generalities. So, it is possible to study of the atmospheric air like as a continuous perfect gas. These facts are important questions to study the troposphere under the laws and beginning Physics, using its respective equations, in order to get a theoretical model to simulate the behavior of its thermodynamics variables and parameters. Working on this line, it was developed a model in order to simulate the tropospheric pressure variation on the height from its measure on surface data. 展开更多
关键词 Atmospherics pressure tropospheric pressure.
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Combustion characteristics of Daqing oil shale and oil shale semi-cokes 被引量:8
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作者 MIAO Zhen-yong WU Ouo-guang LI Ping ZHAO Na WANG Pan-cheng MENG Xian-liang 《Mining Science and Technology》 EI CAS 2009年第3期380-384,共5页
Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was stud... Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was studied.Prior pyrolysis affects the initial temperature of mass loss and the ignition temperature.The ignition temperature increases as the volatile content of the sample decreases.TG/DTG curves obtained at different heating rates show that heating rate has little effect on ignition temperature.But the peak of combustion shifts to higher temperatures as the heating rate is increased.The Coats-Redfern integration method was employed to find the combustion-reaction kinetic parameters for the burning of oil shale and oil shale semi-coke. 展开更多
关键词 oil shale SEMI-COKE combustion characteristics pyrolysis degree h-eating rate
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DETERMINATION OF THERMODYNAMIC AND KINETIC PARAMETERS OF LARGE SCALE CHROMATOGRAPHIC SEPARATION OF SUGAR AND REDUCING SUGAR
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作者 Li Zhong Shu Wenli +2 位作者 Liao Yongzhong Huang Peiquan Xu Qingcai 《Chinese Journal of Reactive Polymers》 1996年第1期84-91,共8页
The parameter identification model of largr scale chromatography separation process is proposed. The Phase equilibrium constants and lumped mass transfer coefficients of sugar and reducing sugar adsorption on D1, D2 a... The parameter identification model of largr scale chromatography separation process is proposed. The Phase equilibrium constants and lumped mass transfer coefficients of sugar and reducing sugar adsorption on D1, D2 and D3 resins as well as the axial dispersion coefficients of the fluid through packed columns are determined by means of the pulse-response experiment technique with an inert substance as a tracer and the chromatography measuring technique. The elution curve calculated from these parameters is good agreement with the experimental elution curve. The sensitivity analysis of these parameters is carried out, and the ressult shows that the elation curves of chromatography separation are more sensitive to the variations Of the Phase equilibrium relationship than to the variation of the axial dispersion as well as the lumped mass transfer coefficients. 展开更多
关键词 Chromatographic Separation RESINS Parameter Determination SUGAR Reducing sugar
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Role of NGOs in the National Significant Seismic Monitoring and Protection Regions
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作者 Wu Guochun Gao Mengtan 《Earthquake Research in China》 CSCD 2015年第1期21-29,共9页
In this paper,we analyzed the One Foundations relief and reconstruction activities after the Yaan earthquake.The analysis shows that the participation of NGOs in disaster relief activities has undergone different stag... In this paper,we analyzed the One Foundations relief and reconstruction activities after the Yaan earthquake.The analysis shows that the participation of NGOs in disaster relief activities has undergone different stages.In the Jiujiang earthquake,NGOs participation was in the rudimentary stage.In the Wenchuan earthquake,they became one of the active participants.In the Yaan earthquake,they played an active role through a cooperation mechanism.That means NGOs have had the capability of resource mobilization and cooperation with them will improve disaster management capacities,especially in the national significant seismic monitoring and protection regions. 展开更多
关键词 NGOs Cooperation mechanism Multiple cooperation Institutionalization Resilience
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向电影家族“夺权”!
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作者 曹晓峰 《大众电影》 2004年第21期24-24,共1页
不管大伙儿怎样高呼电影已经完蛋,电影圈倒一直是人人都想挤进去刨金的宝地。有才情的憧憬做导演,有相貌和表演欲的梦想当演员,都想在这个圈子里讨生活。事实是,电影也就这样由一拨拨人的“大力参与”逐渐朝前狂飙突进。 但在电影山头... 不管大伙儿怎样高呼电影已经完蛋,电影圈倒一直是人人都想挤进去刨金的宝地。有才情的憧憬做导演,有相貌和表演欲的梦想当演员,都想在这个圈子里讨生活。事实是,电影也就这样由一拨拨人的“大力参与”逐渐朝前狂飙突进。 但在电影山头上却盘踞着这样一种势力。 展开更多
关键词 电影圈 家族 资源有限 大力参 讨生活 当演员 人人都 导演 影视圈 其他人
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Influences of non-isothermal atmospheric backgrounds on variations of gravity wave parameters 被引量:8
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作者 LIU Xiao ZHOU QiHou +1 位作者 YUAN Wei XU JiYao 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第5期1251-1257,共7页
Because of the importance of gravity waves (GWs) in coupling different atmospheric regions, further studies are necessary to investigate the characteristics of GW propagation in a non-isothermal atmosphere. Using a ... Because of the importance of gravity waves (GWs) in coupling different atmospheric regions, further studies are necessary to investigate the characteristics of GW propagation in a non-isothermal atmosphere. Using a nonlinear numerical model, we simulate the propagation of small amplitude GWs with various wavelengths in different non-isothermal atmospheres. Our re- sults show that the GW vertical wavelength undergoes sharp changes above the stratopause and mesopause region. Specifically for a GW with an initial vertical wavelength of 5 km, the seasonal background temperature structure difference at 50° latitude can cause the vertical wavelength to vary by -2 krn in the mesosphere and by as large as -4.5 km in the lower thermosphere. In addition, the GW paths exhibit great divergence in the height range of -65-110 kin. Our results also show that the variations of GW path, vertical wavelength and horizontal phase velocity are not synchronized in a non-isothermal atmosphere as in an isothermal atmosphere. Despite the fact that all GWs change their characteristics as they propagate upward in a non-isothermal atmosphere, the variations relative to the initial parameters at a reference height are similar for different initial vertical wavelengths. Our results indicate that the changing characteristics of a gravity wave in a non-isothermal atmosphere need to be considered when investigating the relationship of GWs at two different heights. 展开更多
关键词 gravity wave non-isothermal atmosphere atmospheric coupling
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