High soda content in fine alumina trihydrate（ATH） limits its application and increases the soda consumption. The variation of soda content in the fine ATH by seeded precipitation was determined by detection of elect...High soda content in fine alumina trihydrate（ATH） limits its application and increases the soda consumption. The variation of soda content in the fine ATH by seeded precipitation was determined by detection of electric conductivity of solution, soda content in ATH, measurement of particle size distribution and microscopic analysis. The results show that high concentration of sodium aluminate solution, ground circulative seed, low temperature or fast initial precipitation rate increases the soda content in ATH. Soda mainly exists in lattice soda and less soda in desilication product （DSP） exists in the fine ATH precipitated from sodium aluminate solution with concentration of Al2O3 （ρAl2O3） more than 160 g/L and mass ratio of alumina to silica （μSiO2） of 400, and lattice soda decreases with increasing initial precipitation temperature, aging seed, and low precipitation rate and precipitation time. Results also imply that -＋ 4）Na Al（OH ion-pair influences lattice soda content in ATH on the basis of electric conductivity variation.展开更多
Mechanical activation was used to improve the extraction of chromium in molten NaOH.It is observed that the extraction ratio reaches 97% after leaching for 200 min when chromite ore is mechanically activated for 10 mi...Mechanical activation was used to improve the extraction of chromium in molten NaOH.It is observed that the extraction ratio reaches 97% after leaching for 200 min when chromite ore is mechanically activated for 10 min,but only 34% if not activated.Mechanical activation can decrease the particle size,increase the surface area,and enhance the lattice distortion.Further,the mechanisms for mechanical activation were exposed.The results show that the mechanical activation mainly focuses on chromite ore particle size decrease and the lattice distortion.The formation of aggregation weakens the strengthening effect of mechanical activation for releasing high surface energy.展开更多
基金Project(51274242)supported by the National Natural Science Foundation of China
文摘High soda content in fine alumina trihydrate（ATH） limits its application and increases the soda consumption. The variation of soda content in the fine ATH by seeded precipitation was determined by detection of electric conductivity of solution, soda content in ATH, measurement of particle size distribution and microscopic analysis. The results show that high concentration of sodium aluminate solution, ground circulative seed, low temperature or fast initial precipitation rate increases the soda content in ATH. Soda mainly exists in lattice soda and less soda in desilication product （DSP） exists in the fine ATH precipitated from sodium aluminate solution with concentration of Al2O3 （ρAl2O3） more than 160 g/L and mass ratio of alumina to silica （μSiO2） of 400, and lattice soda decreases with increasing initial precipitation temperature, aging seed, and low precipitation rate and precipitation time. Results also imply that -＋ 4）Na Al（OH ion-pair influences lattice soda content in ATH on the basis of electric conductivity variation.
基金Project(2009AA06XK1485430) supported by the National Hi-tech Research and Development Program of ChinaProject(2007CB613501) supported by the National Basic Research Program of China
文摘Mechanical activation was used to improve the extraction of chromium in molten NaOH.It is observed that the extraction ratio reaches 97% after leaching for 200 min when chromite ore is mechanically activated for 10 min,but only 34% if not activated.Mechanical activation can decrease the particle size,increase the surface area,and enhance the lattice distortion.Further,the mechanisms for mechanical activation were exposed.The results show that the mechanical activation mainly focuses on chromite ore particle size decrease and the lattice distortion.The formation of aggregation weakens the strengthening effect of mechanical activation for releasing high surface energy.
