O713.2 2000010608甲酸钡单晶体理论形貌分析=Study of theoreticalhabit of Ba（HCOO）<sub>2</sub> crystal[刊,中]/黎军,郑吉民,车云霞（南开大学化学系.天津（300071））//人工晶体学报.—1998,27（3）.—251-256应用PB...O713.2 2000010608甲酸钡单晶体理论形貌分析=Study of theoreticalhabit of Ba（HCOO）<sub>2</sub> crystal[刊,中]/黎军,郑吉民,车云霞（南开大学化学系.天津（300071））//人工晶体学报.—1998,27（3）.—251-256应用PBC（Periodic Bond Chain）理论,结合晶体的结构数据,应用已给出的计算接触能(E<sub>att</sub>)公式,通过微机对离子型晶体甲酸钡的晶体形貌进行了分类。根据各接触能(E<sub>att</sub>)的计算,得出各晶面的重要性（呈现几率）与实际晶体测量相吻合。图5表4参6（于晓光）O721 20000010609吸收限附近非对称反射条件X射线的异常透射=Anomalous transmission of X-rays underasymmetrical reflection condition near absorp-展开更多
Balanced carrier transport is observed in acceptor-acceptor （A-A＇） type polymer for ambipolar organic thin-film transistors （OTFTs）. It is found that the incorporation of two electron-accepting moieties （BTz and...Balanced carrier transport is observed in acceptor-acceptor （A-A＇） type polymer for ambipolar organic thin-film transistors （OTFTs）. It is found that the incorporation of two electron-accepting moieties （BTz and IIG） into a polymer main chain to form A-A＇ polymer PIIG-BTz could lower highest occupied molecular orbital （HOMO） and lowest unoccupied molecular orbital （LUMO） levels and facilitate good molecular stacking of the polymer. Ambipolar transistor behaviour for PIIG-BTz, with the balanced hole and electron mobilities of 0.030 and 0.022 cm2 V 1 s-i was observed in OTFT devices, respectively. The study in this work reveals that the utilization of acceptor-acceptor （A-A＇） structure in polymer main chain can be a feasible strategy to develop ambipolar polymer semiconductors.展开更多
文摘O713.2 2000010608甲酸钡单晶体理论形貌分析=Study of theoreticalhabit of Ba（HCOO）<sub>2</sub> crystal[刊,中]/黎军,郑吉民,车云霞（南开大学化学系.天津（300071））//人工晶体学报.—1998,27（3）.—251-256应用PBC（Periodic Bond Chain）理论,结合晶体的结构数据,应用已给出的计算接触能(E<sub>att</sub>)公式,通过微机对离子型晶体甲酸钡的晶体形貌进行了分类。根据各接触能(E<sub>att</sub>)的计算,得出各晶面的重要性（呈现几率）与实际晶体测量相吻合。图5表4参6（于晓光）O721 20000010609吸收限附近非对称反射条件X射线的异常透射=Anomalous transmission of X-rays underasymmetrical reflection condition near absorp-
基金supported by the National Natural Science Foundation of China (51173055, 21504026, 51572094)the National Basic Research Program of China (2013CBA01600)the China Postdoctoral Science Foundation (2013M542009)
文摘Balanced carrier transport is observed in acceptor-acceptor （A-A＇） type polymer for ambipolar organic thin-film transistors （OTFTs）. It is found that the incorporation of two electron-accepting moieties （BTz and IIG） into a polymer main chain to form A-A＇ polymer PIIG-BTz could lower highest occupied molecular orbital （HOMO） and lowest unoccupied molecular orbital （LUMO） levels and facilitate good molecular stacking of the polymer. Ambipolar transistor behaviour for PIIG-BTz, with the balanced hole and electron mobilities of 0.030 and 0.022 cm2 V 1 s-i was observed in OTFT devices, respectively. The study in this work reveals that the utilization of acceptor-acceptor （A-A＇） structure in polymer main chain can be a feasible strategy to develop ambipolar polymer semiconductors.
