A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass ...A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass (Mr), conformation parameter (Rc) of peptides and electrophoretic condition parameter(A). The conformation parameter is introduced to characterize multifarious shapes owing to the complex conlormation and the various kinds of macromolecules, where Rc≥1/3. The parameters A and Rc can be obtained from experimental data. The times of migration of the nine standard peptides were measured in pH 2.5buffer on different electrophoretic conditions in CZE. The experimental results agreed well with the theoretical prediction.展开更多
We report a theoretical study on the rotational spectra of Ar-D232S. The intermolecular po- tential energy surface was transformed from our latest ab initio three-dimensional potential of Ar-H232S. The rotational ener...We report a theoretical study on the rotational spectra of Ar-D232S. The intermolecular po- tential energy surface was transformed from our latest ab initio three-dimensional potential of Ar-H232S. The rotational energy levels and wavefunctions of the complex were calcu- lated by using the radial discrete variable representation/angular finite basis representation method and the Lanczos algorithm. The calculated rotational transition frequencies and structural parameters were found to be in good agreement with the available experimental values.展开更多
The influence of parameters pertaining to the confinant structure on water hammer had been less studied than those relative to the fluid. One of them is the inner pipe-diameter, a basic structural-parameter that makes...The influence of parameters pertaining to the confinant structure on water hammer had been less studied than those relative to the fluid. One of them is the inner pipe-diameter, a basic structural-parameter that makes its influence in essential hydraulic topics such as head loss, in pipelines. In this paper, the objective is to analyze the inner-diameter influence on water hammer phenomenon. An analytical algorithm for solving the unsteady-one-dimensional water hammer model had been applied. It had allowed estimating the instantaneous head at any point of a single pipeline. The model was solved by mean of the Laplace＇s Transformed application and the anti-transforming procedure into the complex field. To determinate the influence of internal-diameter conduit on the pressure oscillation, four distinct inside-diameter values were introduced into the solution, successively. The first overpressure-peak at each case was tabulated along with the corresponding inner^liameter and a mathematical relation had been founded. The obtained results show a close dependence between both, over-pressure peaks and internal-pipe diameter. It was founded that this dependence is given in terms of a non-linear relation between them. It was further founded that the wave frequency is sensitive to the variation of the pipe-diameter.展开更多
文摘A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass (Mr), conformation parameter (Rc) of peptides and electrophoretic condition parameter(A). The conformation parameter is introduced to characterize multifarious shapes owing to the complex conlormation and the various kinds of macromolecules, where Rc≥1/3. The parameters A and Rc can be obtained from experimental data. The times of migration of the nine standard peptides were measured in pH 2.5buffer on different electrophoretic conditions in CZE. The experimental results agreed well with the theoretical prediction.
文摘We report a theoretical study on the rotational spectra of Ar-D232S. The intermolecular po- tential energy surface was transformed from our latest ab initio three-dimensional potential of Ar-H232S. The rotational energy levels and wavefunctions of the complex were calcu- lated by using the radial discrete variable representation/angular finite basis representation method and the Lanczos algorithm. The calculated rotational transition frequencies and structural parameters were found to be in good agreement with the available experimental values.
文摘The influence of parameters pertaining to the confinant structure on water hammer had been less studied than those relative to the fluid. One of them is the inner pipe-diameter, a basic structural-parameter that makes its influence in essential hydraulic topics such as head loss, in pipelines. In this paper, the objective is to analyze the inner-diameter influence on water hammer phenomenon. An analytical algorithm for solving the unsteady-one-dimensional water hammer model had been applied. It had allowed estimating the instantaneous head at any point of a single pipeline. The model was solved by mean of the Laplace＇s Transformed application and the anti-transforming procedure into the complex field. To determinate the influence of internal-diameter conduit on the pressure oscillation, four distinct inside-diameter values were introduced into the solution, successively. The first overpressure-peak at each case was tabulated along with the corresponding inner^liameter and a mathematical relation had been founded. The obtained results show a close dependence between both, over-pressure peaks and internal-pipe diameter. It was founded that this dependence is given in terms of a non-linear relation between them. It was further founded that the wave frequency is sensitive to the variation of the pipe-diameter.
