The separation of Eu^3 ＋is studied with a dispersion combined liquid membrane（DCLM）,in which polyvinylidene fluoride membrane（PVDF）is used as the liquid membrane support,dispersion solution containing HCl solutio...The separation of Eu^3 ＋is studied with a dispersion combined liquid membrane（DCLM）,in which polyvinylidene fluoride membrane（PVDF）is used as the liquid membrane support,dispersion solution containing HCl solution as the stripping solution,and 2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester（P507）dissolved in kerosene as the membrane solution.The effects of pH value,initial concentration of Eu3 ＋and different ionic strength in the feed phase,volume ratio of membrane solution to stripping solution,concentration of HCl solution, concentration of carrier,different stripping agents in the dispersion phase on the separation are investigated.The optimum condition for separation of Eu3 ＋is that concentration of HCl solution is 4.0 mol·L 1,concentration of carrier is 0.16 mol·L 1,and volume ratio of membrane solution to stripping solution is 30︰30 in the dispersion phase, and pH value is 4.2 in the feed phase.The ionic strength has no significant effect on separation of Eu3 ＋.Under the optimum condition,when the initial concentration of Eu3 ＋is 0.8×10 4mol·L 1,the separation percentage of Eu 3＋is 95.3%during the separation time of 130 min.The kinetic equation is developed in terms of the law of mass diffusion and the theory of interface chemistry.The diffusion coefficient of Eu3 ＋in the membrane and the thickness of diffusion layer between feed phase and membrane phase are obtained and their values are 1.48×10 7m 2·s 1and 36.6μm,respectively.The results obtained are in good agreement with literature data.展开更多
One way for reducing tar is oxidative and thermal cracking by partial combustion of the biomass producer gas in the gas reformer. Cracking and polymerization of the tar occur simultaneously at the proximity of inverse...One way for reducing tar is oxidative and thermal cracking by partial combustion of the biomass producer gas in the gas reformer. Cracking and polymerization of the tar occur simultaneously at the proximity of inverse diffusion flame. Experimental study has been performed to clarify the effect of hydrogen concentration on soot formation and the growth of polycyclic aromatic hydrocarbons. In the present study, hydrogen concentration is controlled by the small amount of hydrogen addition to the oxidizer. The main results are as follows. Soot formation is suppressed by the small amount of hydrogen addition. The suppression of soot formation is caused by higher concentration of hydrogen. Carbon yield increases by hydrogen addition since carbon content in the undetectable components by the integrated gas chromatograph decreases. In addition, the increase in carbon yield is caused mainly by the increase in carbon monoxide stemmed from reforming of high-boiling components.展开更多
Purpose： to evaluate the in vitro influence of Copaiferalangsdorffii essential oil on the antinecrotic activity in macrophages, and on the antiapoptotic activity in macrophages and lymphocytes of Swiss mice. Methods...Purpose： to evaluate the in vitro influence of Copaiferalangsdorffii essential oil on the antinecrotic activity in macrophages, and on the antiapoptotic activity in macrophages and lymphocytes of Swiss mice. Methods： lymphocytes and macrophages were obtained from ten 60-day-old male mice weighing 42-45 g, and then cultured in 24-well plates. Cells were treated with concentrations of 2%, 5%, 10% and 20% of oil from Copaiferalangsdorffii before or after induction of apoptosis with ultraviolet light. We used positive and negative controls. Hoechst staining was performed, and then images of cells under fluorescence microscope were captured and digitalized. We used Image J_1.46o to quantify the fluorescence intensity/brightness of condensation of the chromatin ofapoptotic cells. We used one-way ANOVA with Bonferroni＇s and Tukey＇s multiple comparison tests. Results are expressed as the means of relative densities after adjustment and 95% confidence intervals; P 〈 0.05 was considered statistically significant. Results： oil from Copaiferalangsdorffii at different concentrations has decreased necrosis and apoptosis of both lymphocytes and macrophages from mice, when compared to C＋ （all P 〈 0.05）. Discussion： Copaiferalangsdorffii is typically Brazilian and found in the Amazon region, with anti-inflammatory, antioxidant and antineoplastic effects due to its oil compounds, such as xyloglucans and kaurenoic acid. Its potential therapeutical usage was demonstrated in a national study. The present study showed that its oil has significant in vitro antiapoptotic and antinecrotic activity and it should be tested experimentally in vivo.展开更多
基金Supported by the National Natural Science Foundation of China（90401009） the Foundation for Planning Project of West Action of Chinese Academy of Sciences（KZCX2-XB2-13） the Research Fund for Excellent Doctoral Thesis of Xi’an University of Technology（602-210805）
文摘The separation of Eu^3 ＋is studied with a dispersion combined liquid membrane（DCLM）,in which polyvinylidene fluoride membrane（PVDF）is used as the liquid membrane support,dispersion solution containing HCl solution as the stripping solution,and 2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester（P507）dissolved in kerosene as the membrane solution.The effects of pH value,initial concentration of Eu3 ＋and different ionic strength in the feed phase,volume ratio of membrane solution to stripping solution,concentration of HCl solution, concentration of carrier,different stripping agents in the dispersion phase on the separation are investigated.The optimum condition for separation of Eu3 ＋is that concentration of HCl solution is 4.0 mol·L 1,concentration of carrier is 0.16 mol·L 1,and volume ratio of membrane solution to stripping solution is 30︰30 in the dispersion phase, and pH value is 4.2 in the feed phase.The ionic strength has no significant effect on separation of Eu3 ＋.Under the optimum condition,when the initial concentration of Eu3 ＋is 0.8×10 4mol·L 1,the separation percentage of Eu 3＋is 95.3%during the separation time of 130 min.The kinetic equation is developed in terms of the law of mass diffusion and the theory of interface chemistry.The diffusion coefficient of Eu3 ＋in the membrane and the thickness of diffusion layer between feed phase and membrane phase are obtained and their values are 1.48×10 7m 2·s 1and 36.6μm,respectively.The results obtained are in good agreement with literature data.
文摘One way for reducing tar is oxidative and thermal cracking by partial combustion of the biomass producer gas in the gas reformer. Cracking and polymerization of the tar occur simultaneously at the proximity of inverse diffusion flame. Experimental study has been performed to clarify the effect of hydrogen concentration on soot formation and the growth of polycyclic aromatic hydrocarbons. In the present study, hydrogen concentration is controlled by the small amount of hydrogen addition to the oxidizer. The main results are as follows. Soot formation is suppressed by the small amount of hydrogen addition. The suppression of soot formation is caused by higher concentration of hydrogen. Carbon yield increases by hydrogen addition since carbon content in the undetectable components by the integrated gas chromatograph decreases. In addition, the increase in carbon yield is caused mainly by the increase in carbon monoxide stemmed from reforming of high-boiling components.
文摘Purpose： to evaluate the in vitro influence of Copaiferalangsdorffii essential oil on the antinecrotic activity in macrophages, and on the antiapoptotic activity in macrophages and lymphocytes of Swiss mice. Methods： lymphocytes and macrophages were obtained from ten 60-day-old male mice weighing 42-45 g, and then cultured in 24-well plates. Cells were treated with concentrations of 2%, 5%, 10% and 20% of oil from Copaiferalangsdorffii before or after induction of apoptosis with ultraviolet light. We used positive and negative controls. Hoechst staining was performed, and then images of cells under fluorescence microscope were captured and digitalized. We used Image J_1.46o to quantify the fluorescence intensity/brightness of condensation of the chromatin ofapoptotic cells. We used one-way ANOVA with Bonferroni＇s and Tukey＇s multiple comparison tests. Results are expressed as the means of relative densities after adjustment and 95% confidence intervals; P 〈 0.05 was considered statistically significant. Results： oil from Copaiferalangsdorffii at different concentrations has decreased necrosis and apoptosis of both lymphocytes and macrophages from mice, when compared to C＋ （all P 〈 0.05）. Discussion： Copaiferalangsdorffii is typically Brazilian and found in the Amazon region, with anti-inflammatory, antioxidant and antineoplastic effects due to its oil compounds, such as xyloglucans and kaurenoic acid. Its potential therapeutical usage was demonstrated in a national study. The present study showed that its oil has significant in vitro antiapoptotic and antinecrotic activity and it should be tested experimentally in vivo.
