用偶合反应-流动注射化学发光法测定食品和水中痕量亚硝酸根

基于在酸性介质下，ＮＯ２－与Ｉ－快速反应产生Ｉ２，和Ｉ２氧化Ｌｕｍｉｎｏｌ产生化学发光反应，建立了Ｌｕｍｉｎｏｌ－Ｉ－－ＮＯ２－偶合发光体系测定痕量 ＮＯ２－的方法。本法测定 ＮＯ２－线性范围：８．０×１０－９～１．０×１０－６ｇ／ｍＬ；检出限１．６×１０－９ｇ／ｍＬ；对１．０×１０－８ｇ／ｍＬＮＯ２连续１１次测定的相对标准偏差为１．５％。用于食品及水中亚硝酸根的测定，结果满意。

流动注射氢化物发生原子吸收光谱法测定人发中痕量汞

目的 建立测定人发中痕量汞的新方法。方法 用自制的电热恒温石英管为吸收池 ,用流动注射氢化物发生原子吸收光谱法联合技术进行测定。结果 选定了最佳工作条件 ,提高了方法的精密度、准确度。检出限为 0 1ng/ g ,线性范围0 0 0 0～ 2 5 2 0 μg/ g ,r=0 9996 ,回收率为 92 %～ 98% ,相对标准偏差为 1 4%～ 3 4%。结论 该方法精密度高 ,准确度好 ,适用于人发中痕量汞的测定。

Flow Behaviors of Gas-Solid Injector by 3D Simulation with Kinetic Theory of Granular Flow

A computational study on the flow behavior of a gas-solid injector by Eulerian approach was carried out. The gas phase was modeled with k-ε turbulent model and the particle phase was modeled with kinetic theory of granular flow. The simulations by Eulerian two-fluid model （TFM） were compared with the corresponding results by discrete element method （DEM） and experiments. It was showed that TFM simulated results were in reasonable agreement with the experimental and DEM simulated results. Based on TFM simulations, gas-solid flow pattern, gas velocity, particle velocity and the static pressure under different driving jet velocity, backpressure and convergent section angle were obtained. The results showed that the time average axial gas velocity sharply decreased and then slightly increased to a constant value in the horizontal conveying pipe. The time average axial particle velocity increased initially and then decreased, but in the outlet region of the convergent section the particle velocity remarkably increased once more to the maximal value. As a whole, the static pressure distribution change trends were found to be independent on driving gas velocity, backpressure and convergent section angle. However, the static pressure increased with increase of convergent section angle and gas jet velocities. The difference of static pressure to backpressure increased with increasing backpressure.

Flame Structure of a Jet Flame with Penetration of Side Micro-jets

In this paper, an innovative jet lifted flame with side micro-jets has been proposed and its effects on the flame structure have also been investigated. Due to the changes of the initial combustion conditions, mixing and aerodynamics which resulted from the perturbation of the side micro-jets, such a lifted jet flame has different flame structure compared with the common premixed flame. Results demonstrate that use of the micro-jets can control, to a certain extent, the flame structure, including the flame length, lift-off distance and blow-off limit. With the same fuel and air flow rate, the flame length with the side micro-jets will decrease about 5%-40% as the air volume ratio a increases from 58%-76%. Compared with the common diffusion flame, the jet flame with the side micro-jets demonstrates to be easier to be a momentum-dominated flame. The flame length with 2 micro-jets is about 5% less than with 6 micro-jets under the same fuel and air flow rate. With the same a, the fewer number of the controlled jets lead to the flame with relatively shorter length, not easier to be blown off and higher NOx emission. With certain fuel flow rate, the critical air volume ratio is largest for the flame with 3 micro-jets, which is more difficult to be blown off than the cases with 2, 4 or 6 micro-jets.

Fluid flow characteristics of single inclined circular jet impingement for ultra-fast cooling

The fluid flow characteristics of the single bunch inclined jet impingement were investigated with different jet flow velocities,nozzle diameters,jet angles and jet-to-target distances for ultra-fast cooling technology.The results show that the peak pressure varying significantly from nearly 0.5 to above 13.4 kPa locates at the stagnation point with different jet diameters,and the radius of impact pressure affected zone is small promoted from 46 to 81 mm in transverse direction,and 50 to 91 mm in longitude direction when the jet flow velocity changes from 5 to 20 m/s.However,the fluid flow velocity is relatively smaller near the stagnation point,and increases gradually along the radius outwards,then declines.There is an obvious anisotropic characteristic that the flow velocity component along the jet direction is about twice of the contrary one where the jet anlge is 60°,jet diameter is 5 mm,jet length is 8 mm and jet height is 50 mm.

MHD three dimensional flow of viscoelastic fluid with thermal radiation and variable thermal conductivity

The objective of the present work is to model the magnetohydrodynamic(MHD) three dimensional flow of viscoelastic fluid passing a stretching surface. Heat transfer analysis is carried out in the presence of variable thermal conductivity and thermal radiation. Arising nonlinear analysis for velocity and temperature is computed. Discussion to importantly involved parameters through plots is presented. Comparison between present and previous limiting solutions is shown. Numerical values of local Nusselt number are computed and analyzed. It can be observed that the effects of viscoelastic parameter and Hartman number on the temperature profile are similar in a qualitative way. The variations in temperature are more pronounced for viscoelastic parameter K in comparison to the Hartman number M. The parameters N and ε give rise to the temperature. It is interesting to note that values of local Nusselt number are smaller for the larger values of ε.

Two-dimensional semiconductors with possible high room temperature mobility

We have calculated the longitudinal acoustic phonon limited electron mobility of 14 twvo-dimensional semiconductors with composition of MX2, where M （= Mo, W, Sn, Hf, Zr and Pt） is the transition metal, and X is S, Se and Te. We treated the scattering matrix by the deformation potential approximation. We found that out of 14 compounds, MoTe2, HfSe2 and ZrSe2 are promising regarding to their possible high mobility and finite band gap. The phonon limited mobility can be above 2,500 cm^2·V^-1·s^-1 at room temperature.

Upshot of Chemical Species and Nonlinear Thermal Radiation on Oldroyd-B Nanofluid Flow Past a Bi-directional Stretched Surface with Heat Generation/Absorption in a Porous Media

A three-dimensional mathematical model is developed to examine the flow of nonlinear thermal radiation Oldroyd-B nanofluid past a bidirectional linearly stretched surface in a porous medium. The flow is induced by temperature dependent thermal conductivity, chemical reaction and convective heat and mass conditions. Novel characteristics of Brownian motion and thermophoresis are accompanied by magnetohydrodynamic and heat generation/absorption.Self-similar transformations are employed to convert the system of nonlinear partial differential equations to a system of ordinary differential equations with high nonlinearity and are solved by strong analytic technique named as Homotopy Analysis method(HAM). Effects of varied arising parameters on involved distributions are reflected through graphical illustrations. From this study, it is perceived that strong magnetic field hinders the fluid's motion and leads to rise in temperature that eventually lowers heat transfer rate from the surface. Further, decrease in heat transfer rate is also observed for enhanced values of thermal radiation parameter. To validate our results, a comparison with already published paper in limiting case is also given and results are found in excellent oncurrence; hence reliable results are being presented.

Flow Characteristics of Rectangular Underexpanded Impinging Jets

In this paper, the flow fields of underexpanded impinging jet issued from rectangular nozzles of aspect ratio 1, 3 and 5 are numerically and experimentally studied. Two dimensional temperature and pressure distributions are measured by using infrared camera and the combination of a pressure scanning device and a stepping motor, respectively. The variation of the stagnation pressure on the impinging plate reveals that a hysteretic phenomenon exists during the increasing and decreasing of the pressure ratio for the aspect ratio of 3.0 and 5.0. It is also found that the nozzle of aspect ratio 1.0 caused the largest total pressure loss Pc /p0= 0.27 at the pressure ratio of Po /p0 = 6.5, where Pc is the stagnation center pressure on the wall, P0 the upstream stagnation pressure, Pb the ambient pressure. The other two nozzles showed that the pressure loss Pc / P0 =0.52 and 0.55 were achieved by the nozzles of the aspect ratio 3,0 and 5.0, respectively. The comparison between the calculations and experiments is fairly good, showing the three dimensional streamlines and structures of the shock waves in the jets. However, the hysteresis of the pressure variations observed in the experiments between the pressure ratio of 3.5 and 4.5 cannot be confirmed in the calculations.

Experimental study on heat transfer characteristics of synthetic jet driven by piston actuator

Experimental investigation was conducted to investigate the impingement heat transfer performance of a synthetic jet driven by piston actuator on a constant heat flux surface. Effects of jet formation frequency, nozzle-to-surface spacing ratio and con- jugation of cross flow were considered. The synthetic jet is of stronger penetration and heat transfer capacity when the piston reciprocates at relatively high frequency. Similar to the continuous jet impingement, nozzle-to-surface spacing ratio plays an important role in the heat transfer enhancement of synthetic jet. The optimum nozzle-to-surface spacing ratio corresponding to maximum heat transfer enhancement is considerably high in the synthetic jet, as compared to that in a continuous jet, which indicates that the synthetic jet introduces a stronger entrainment and more vigorous penetration in the surrounding fluid. The convective heat transfer capacity is enhanced significantly under the conjugate action of a synthetic jet and cross flow in com- narison with their individual action.

Influence of Non-linear Radiation Heat Flux on Rotating Maxwell Fluid over a Deformable Surface: A Numerical Study

Mathematical model for Maxwell fluid flow in rotating frame induced by an isothermal stretching wall is explored numerically. Scale analysis based boundary layer approximations are applied to simplify the conservation relations which are later converted to similar forms via appropriate substitutions. A numerical approach is utilized to derive similarity solutions for broad range of Deborah number. The results predict that velocity distributions are inversely proportional to the stress relaxation time. This outcome is different from that observed for the elastic parameter of second grade fluid. Unlike non-rotating frame, the solution curves are oscillatory decaying functions of similarity variable. As angular velocity enlarges, temperature rises and significant drop in the heat transfer coefficient occurs. We note that the wall slope of temperature has an asymptotically decaying profile against the wall to ambient ratio parameter. From the qualitative view point, temperature ratio parameter and radiation parameter have similar effect on the thermal boundary layer. Furthermore, radiation parameter has a definite role in improving the cooling process of the stretching boundary.A comparative study of current numerical computations and those from the existing studies is also presented in a limiting case. To our knowledge, the phenomenon of non-linear radiation in rotating viscoelastic flow due to linearly stretched plate is just modeled here.

Global existence and stability of a stationary Mach reflection

We prove the global existence and stability of a wave structure containing a stationary Mach con- figuration, which occurs when an incident shock front hits a wall with a large incident angle. Our result shows that tile data of the upstream flow and the pressure at downstream part jointly determine the whole flow, as well a the wave structure. Particularly, we show that the height of the Mach stem depends not only on the data of upstream flow, but also on the pressure at downstream flow. The flow with the assigned wave structure is governed by a free boundary value problem for the Euler system. In the problem the location of the triple point, the shock fronts and the contact discontinuity are all unknown, they are finally determined together with the solution.

Numerical Simulation of 2-D Radiation-Drive Ignition Implosion Process

A Lagrangian compatible radiation hydrodynamic algorithm and the nuclear dynamics computing module are developed and implemented in the LARED Integration code, which is a radiation hydrodynamic code based on the 2-D cylindrical coordinates for the numerical simulation of the indirect-drive Inertial Confined Fusion. A number of 1-D and 2-D ignition implosion numerical simulations by using the improved LARED Integration code (ILARED) are presented which show that the 1-D numerical results are consistent with those computed by the 1-D radiation hydrodynamic code RDMG, while the simulation results of the 2-D low-mode radiative asymmetry and hydrodynamic instability growth,according to the physical analysis and anticipation, are satisfactory. The capsules driven by the sources from SGII experiments are also simulated by ILARED, and the fuel shapes agree well with the experimental results. The numerical simulations demonstrate that ILARED can be used in the simulation of the 1-D and 2-D ignition capsule implosion using the multi-group diffusion model for radiation.

Aero-Thermal Performances of Leakage Flows Injection from the Endwall Slot in Linear Cascade of High-Pressure Turbine

The existence of a gap between combustor and turbine endwall in the real gas turbine induces to the leakages phenomenon. However, the leakages could be used as a coolant to protect the endwaU surfaces from the hot gas since it could not be completely prevented. Thus, present study investigated the potential of leakage flows as a function of film cooling. In present study, the flow field at the downstream of high-pressure turbine blade has been investigated by 5-holes pitot tube. This is to reveal the aerodynamic performances under the influenced of leakage flows while the temperature measurement was conducted by thermoehromic liquid crystal （TLC）. Expe- rimental has significantly captured theaerodynamics effect of leakage flows near the blade downstream. Further- more, TLC measurement illustrated that the film cooling effectiveness contours were strongly influenced by the secondary flows behavior on the endwall region. Aero-thermal results were validated by the numerical simulation adopted by commercial sottware, ANSYS CFX 13. Both experimental and numerical simulation indicated almost similar trendinaero and also thermal behavior as the amount of leakage flows increases.

Global Solutions of Shock Reflection by Wedges for the Nonlinear Wave Equation

When a plane shock hits a wedge head on, it experiences a reflection-diffraction process and then a self-similar reflected shock moves outward as the original shock moves forward in time. In this paper, shock reflection by large-angle wedges for compressible flow modeled by the nonlinear wave equation is studied and a global theory of existence, stability and regularity is established. Moreover, C^0,1 is the optimal regularity for the solutions across the degenerate sonic boundary.

Electrogravitational stability of streaming compound jets

The electrohydrodynamic stability of a self-gravitating streaming compound jet has been investigated for all modes of perturbation. The jets are immersed in a dielectric motionless tenuous medium pervaded by varying electric field. A second-order integrodifferential equation of Mathieu type has been derived and some reported works are recovered as limiting cases from it.

Flow effects on jet energy loss with detailed balance

In the presence of collective flow a new model potential describing the interaction of the hard jet with scattering centers is derived based on the static color-screened Yukawa potential.The flow effect on jet quenching with detailed balance is investigated in pQCD.It turns out,considering the collective flow with velocity vzalong the jet direction,the collective flow decreases the LPM destructive interference comparing to that in the static medium.The gluon absorption plays a more important role in the moving medium.The collective flow increases the energy gain from gluon absorption,however,decreases the energy loss from gluon radiation,which is(1-vz)times as that in the static medium to the first order of opacity.In the presence of collective flow,the second order in opacity correction is relatively small compared to the first order.So that the total effective energy loss is decreased.The flow dependence of the energy loss will affect the suppression of high pThadron spectrum and anisotropy parameter v2in high-energy heavy-ion collisions.