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DSC法与流变学法在测定HTPB基PBX代料固化动力学参数中的应用对比
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作者 王泓 王天翔 尹艳华 《兵工学报》 EI CAS CSCD 北大核心 2024年第10期3596-3607,共12页
为优化高聚物黏结炸药(Polymer Bonded Explosive,PBX)制备工艺并深入理解其性能,探寻适用于研究PBX炸药固化动力学的最佳方法,分别采用非等温差示扫描量热(Differential Scanning Calorimetry,DSC)法、流变学等温法及流变学非等温法对H... 为优化高聚物黏结炸药(Polymer Bonded Explosive,PBX)制备工艺并深入理解其性能,探寻适用于研究PBX炸药固化动力学的最佳方法,分别采用非等温差示扫描量热(Differential Scanning Calorimetry,DSC)法、流变学等温法及流变学非等温法对HTPB/TDI/Na_(2)SO_(4)/Al体系的固化反应动力学进行深入研究,得到在这3种测试条件下的固化反应动力学方程。同时,针对目前广泛使用的流变学非等温法进行合理优化。实验结果表明:HTPB与TDI间的固化反应遵循自催化模型;使用Kissinger法和Ozawa法获得的固化反应活化能相近,二者相差不超过3%;PBX代料体系的恒温固化表现为起始温度423.29 K,峰值温度440.23 K,终止温度444.49 K;流变学研究固化动力学过程中,需考虑温度对储能模量的影响,不能仅用测量值表征固化度,需要对数据进行修正;DSC法与流变学法各有优劣,若仅需获得固化动力学参数,DSC法是一个更好的选择,但欲了解固化过程中药浆内部结构变化,必须借助流变学法。 展开更多
关键词 高聚物黏结炸药 非等温差示扫描量热 流变学法 固化反应动力学
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流变学法研究部分水解聚丙烯酰胺/Cr(Ⅲ)交联反应 Ⅰ.浓度的影响 被引量:10
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作者 段洪东 侯万国 +3 位作者 孙德军 刘尚营 汪庐山 李伯耿 《化学学报》 SCIE CAS CSCD 北大核心 2002年第4期580-584,共5页
采用流变学法系统地考察了部分水解聚丙烯酰胺 (HPAM) /Cr(Ⅲ )交联体系的反应动力学 .HPAM溶液的粘性模量G″大于弹性模量G′ ,且其数值随时间不发生变化 ,体系为粘性溶液 .而HPAM/Cr(Ⅲ )体系的G′和G″的数值都随时间变化 ,G″在反... 采用流变学法系统地考察了部分水解聚丙烯酰胺 (HPAM) /Cr(Ⅲ )交联体系的反应动力学 .HPAM溶液的粘性模量G″大于弹性模量G′ ,且其数值随时间不发生变化 ,体系为粘性溶液 .而HPAM/Cr(Ⅲ )体系的G′和G″的数值都随时间变化 ,G″在反应开始阶段大于G′ ,当反应进行一段时间后 ,G′超过G″占据主要地位 ,体系成为弹性体系 .交联过程可分为三个阶段 :第一上升阶段 ,平缓上升阶段和第二上升阶段 .利用G′~t曲线可以推测反应机理 .实验发现成胶速率随反应物HPAM和Cr(Ⅲ )的浓度的增加而增加 ,而成胶时间缩短 .在羧基浓度过量的情况下 ,交联反应对Cr(Ⅲ )浓度的反应级数是 1.凝胶的有效弹性交联密度随聚合物浓度的增加而增加 ,且随凝胶反应的进行而增加 .凝胶的交联点间的链平均分子量随Cr(Ⅲ )浓度的增加和交联反应的进行而下降 . 展开更多
关键词 流变学法 部分水解聚丙烯酰胺 铬(Ⅲ) 浓度 油田 化学驱油 凝胶 动力学 交联反应
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化痰逐瘀法对Ⅱ度酒精性股骨头坏死患者血液流变学及血脂水平的影响 被引量:9
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作者 孙云保 刘诗荣 +2 位作者 安建原 邹如政 仲兆富 《中医正骨》 2006年第4期5-5,7,共2页
为探讨化痰逐瘀中药萌生丸治疗酒精性股骨头坏死的疗效机理,选择Ⅱ期酒精性股骨头坏死患者60例,采用萌生丸治疗3个月,检测患者治疗前后血液流变学及血脂的变化,结果治疗后患者全血比黏度、血浆比黏度、红细胞压积、红细胞电泳时间、血... 为探讨化痰逐瘀中药萌生丸治疗酒精性股骨头坏死的疗效机理,选择Ⅱ期酒精性股骨头坏死患者60例,采用萌生丸治疗3个月,检测患者治疗前后血液流变学及血脂的变化,结果治疗后患者全血比黏度、血浆比黏度、红细胞压积、红细胞电泳时间、血清总胆固醇、三酰甘油及低密度脂蛋白均明显降低,而高密度脂蛋白则明显增高,与治疗前比较有明显差异(P<0.05)。表明化痰逐瘀的中药萌生丸可改善Ⅱ期酒精性股骨头坏死病理变化中的血液流学及血清学的水平,促进坏死股骨头的修复。 展开更多
关键词 酒精性股骨头坏死/中医药疗化痰农瘀/药效学血液流变学血清学 临床研究
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部分水解聚丙烯酰胺/Cr(Ⅲ)交联作用的研究方法 被引量:4
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作者 段洪东 侯万国 +2 位作者 汪庐山 李希明 李伯耿 《高分子通报》 CAS CSCD 2002年第2期49-55,共7页
部分水解聚丙烯酰胺 (HPAM) Cr(Ⅲ )凝胶已在油田广泛应用 ,是一类有效的调剖堵水剂 ,对于调整吸水剖面和提高原油采收率起到重要作用。本文简要概述HPAM Cr(Ⅲ )交联反应机理的研究方法 ,如粘度法、紫外 可见吸光光度法、原子力显微镜... 部分水解聚丙烯酰胺 (HPAM) Cr(Ⅲ )凝胶已在油田广泛应用 ,是一类有效的调剖堵水剂 ,对于调整吸水剖面和提高原油采收率起到重要作用。本文简要概述HPAM Cr(Ⅲ )交联反应机理的研究方法 ,如粘度法、紫外 可见吸光光度法、原子力显微镜 (AFM)、激光光散射法、原子吸收法等 。 展开更多
关键词 凝胶反应 流变学法 分光光度 油田 调剂堵水剂 部分水解 聚丙烯酰胺 Cr(Ⅲ) 铬(Ⅲ) 交联作用 反应机理
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表面活性剂对渣油沥青质体系分散性质的影响 被引量:11
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作者 李传 崔敏 +2 位作者 王继乾 石斌 阙国和 《应用化学》 CAS CSCD 北大核心 2008年第1期85-89,共5页
通过流变学参数法研究十二烷基磺酸钠(SDS)、十六烷基-三甲基溴化铵(CTAB)、油酸(OA)和椰子胺(CA)对轮古常渣(LGAR甲)-苯溶液中沥青质分散性质的影响。结果表明,LGAR甲-苯溶液中,沥青质存在形态为流体力学意义上的球形,表面活性剂能促... 通过流变学参数法研究十二烷基磺酸钠(SDS)、十六烷基-三甲基溴化铵(CTAB)、油酸(OA)和椰子胺(CA)对轮古常渣(LGAR甲)-苯溶液中沥青质分散性质的影响。结果表明,LGAR甲-苯溶液中,沥青质存在形态为流体力学意义上的球形,表面活性剂能促进沥青质溶剂化,使沥青质颗粒不规则程度增大。表面活性剂促进沥青质溶剂化能力大小顺序为CA>OA>SDS>CTAB;SDS、OA和CA具有沥青质解缔作用,且解缔能力大小顺序为CA>OA>SDS,而CTAB则在一定程度上促进沥青质缔合。 展开更多
关键词 渣油 表面活性剂 流变学参数 沥青质 分散性质
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INVESTIGATION ON MECHANICAL PROPERTIES OF ZN-AL/SIC PARTICULATE COMPOSITES
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作者 陶杰 肖军 +2 位作者 崔益华 李顺林 沃丁柱 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 1995年第1期23-29,共7页
In order to improve the properties of ZA 27 and ZA4-3 zinc alloys and broaden their application ranges,SiC particlj1Ale composites, prepared by means of rheological casting technology, are investigated individually on... In order to improve the properties of ZA 27 and ZA4-3 zinc alloys and broaden their application ranges,SiC particlj1Ale composites, prepared by means of rheological casting technology, are investigated individually on their rT..t'llanical properties. The results of ne-cural strength, impact strensttl, compressive strength, hardness values and wear rate of the composites show that the addition of SiCp, leads to the increase of the compressive strength and hardness values at both room and higher temperature, and wear resistance of the materials, accompanying with the slight decrease of the fie-cural strength and sharp reduction of the impacttoughness. The factors affecting the mechanical properties of the composites are discussed in the paper. 展开更多
关键词 metal matrix composite zinc alloy SiC particle rheological casting technology mechanical properties
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A stability study of goaf based on mechanical properties degradation of rock caused by rheological and disturbing loads 被引量:11
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作者 Xiao Chao Zheng Huaichang +1 位作者 Hou Xiaolin Zhang Xiaojun 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2015年第5期741-747,共7页
Based on the classical static theory and static numerical simulation,the static method could not accurately reflect the stability of goaf where the rocks on the pillar and roof are influenced by Theological and blasti... Based on the classical static theory and static numerical simulation,the static method could not accurately reflect the stability of goaf where the rocks on the pillar and roof are influenced by Theological and blasting disturbance for a long time.According to the test from the site,an experimental study was made in Theological and dynamic disturbance.After that,on the basis of variable rock mechanics parameters from the experimental data,numerical simulation was used to analyze the vertical stress distribution of goaf,vertical displacement and plastic area of roof in the "deterioration" caused by Theological and blasting,which shows that the mechanics properties of the rock were greatly influenced by Theological,and dynamic disturbance.The results of the experimental study and numerical simulation show that the mechanics properties of rock are greatly influenced by Theological and dynamic disturbance.As a result,the stability of goaf is greatly reduced.Finally,by comparing golf monitoring results with the analysis of theoretical calculation,it was found that the results were approximately the same,which testifies the reliability of the method.This method provides a new way of studying the stability of goaf as well as laying a basic foundation for future safety management. 展开更多
关键词 Stability of goaf Rheological disturbance experiment Rock mechanics parameters Numerical simulation
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Research on rheological properties of micro-fine grouting cement 被引量:3
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作者 管学茂 王雨利 杨雷 《Journal of Coal Science & Engineering(China)》 2003年第1期67-72,共6页
This article studies the influence of the fineness of cement, fly ash(FA), its composite admixture and the amount and way mixed with superplasticizer on the rheological properties of micro fine cement(MC). By means of... This article studies the influence of the fineness of cement, fly ash(FA), its composite admixture and the amount and way mixed with superplasticizer on the rheological properties of micro fine cement(MC). By means of modern instruments and technologies (such as XRD, SEM, laser granulometer and superficial potential apparatus etc.), the article studies the mineral compositions, the appearance character of grains, particle size distribution and superficial potential of FA and its composite materials. And through that, the reducing mechanism of FA is thoroughly analyzed. The study shows that FA and its composite admixture are excellent components which can effectively improve the rheological properties of micro fine cement, and that the superplasticizer has a saturation point and the mixing way of it has a great influence on the rheological properties. 展开更多
关键词 micro fine cement rheological properties grouting materials
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Particle characteristics and rheological constitutive relations of high concentration red mud 被引量:10
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作者 WANG Xing QU Yuan-yuan +3 位作者 HU Wei-wei CHEN Jie ZHAO Xue-yi WU Miao 《Journal of China University of Mining and Technology》 EI 2008年第2期266-270,共5页
Red mud has relatively small solid particles (d50= 13.02 μm) and will flow in paste form under high pressure during pipeline transport. Red mud belongs to a two-phase flow of materials with high viscosity and a hig... Red mud has relatively small solid particles (d50= 13.02 μm) and will flow in paste form under high pressure during pipeline transport. Red mud belongs to a two-phase flow of materials with high viscosity and a high concentration of non-sedimentation, homogeneous solid-liquids. It is difficult to test its rheological properties under atmospheric pressure. Measurements such as rotational viscometry can not reflect the real state of the material when it is flowing in a pipe. Tested rheological parameters are somewhat higher than the actual values. In our investigation, grain shape, distinctive modality and grain size distribution of red mud were tested. Based on the principle of tube measurement, rheological experiments on red mud at different concentrations were carried out by using our independently developed tube-type pressure theology test facility, and obtained constitutive equations. We conclude that red mud behaves as non-Newtonian pseudo-plastic fluid in pipe flows. Its consistency and power-law indices vary considerably with different concentrations. 展开更多
关键词 high concentration non-Newtonian fluid rheological constitutive relations red mud tube-pipe flow method tube-type pressure rheology test facility
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EFFECT OF ACUPUNCTURE TREATMENT ON CELLULAR HEMORHEOLOGY, CHOLESTEROL AND TRIGLYCERIDE OF SIMPLE OBESITY PATIENTS
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作者 赵宁侠 郭瑞林 +2 位作者 任秦有 张周良 史恒军 《World Journal of Acupuncture-Moxibustion》 2004年第3期24-27,共4页
Objective: To observe the effect of acupuncture on simple obesity and cellular hemorheology. Methods: Thirty-two cases of simple obesity patients were enrolled into this study. Acupoints of the Stomach Meridian and Sp... Objective: To observe the effect of acupuncture on simple obesity and cellular hemorheology. Methods: Thirty-two cases of simple obesity patients were enrolled into this study. Acupoints of the Stomach Meridian and Spleen Meridian as Zhongwan (中脘 CV 12), Liangmen (梁门 ST 21), Tianshu (天枢 ST 25), Guayuan (关元 CV 4), etc. were punctured, once daily in the first 5 days, and once every other day afterwards, with 10 sessions being a therapeutic course. Before treatment and after 3 courses of treatment, the body weight, waistline, weight index, seam cholesterol (CH), triglyceride and aggregation index of red blood cell (RBC) were detected. Results: After acupuncture treatment, all the indexes of body weight, waistline, weight index, serum CH, triglyceride and aggregation index of RBC decreased significantly in comparison with those of pre-treatment(P< 0.05). Conclusion: Acupuncture can apparently improve cellular hemorheology, reduce body weight, serum cholesterol and TG levels in simple obesity patients. 展开更多
关键词 Simple obesity Serum cholesterol Triglyceride Cellular hemorheology Acupuncture therapy
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Topology optimization of magnetorheological smart materials included PnCs for tunable wide bandgap design 被引量:1
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作者 Kuan Liang Jingjie He +1 位作者 Zhiyuan Jia Xiaopeng Zhang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2022年第3期94-106,I0003,共14页
Design and application of tunable phononic crystals(PnCs)are attracting increasing interest due to their promising capabilities to manipulate acoustic and elastic waves effectively.This paper investigates topology opt... Design and application of tunable phononic crystals(PnCs)are attracting increasing interest due to their promising capabilities to manipulate acoustic and elastic waves effectively.This paper investigates topology optimization of the magnetorheological(MR)materials including PnCs for opening the tunable and wide bandgaps.Therein,the bandgap tunability of the PnCs is achieved by shear modulus variation of MR materials under a continuously changing applied magnetic field.The pseudo elemental densities representing the bi-material distribution inside the PnC unit cell are taken as design variables and interpolated with an artificial MR penalization model.An aggregated bandgap index for enveloping the extreme values ofbandgap width and tunable range of the MR included smart PnCs is proposed as the objective function.In this context,the sensitivity analysis scheme is derived,and the optimization problem is solved with the gradient-based mathematical programming method.The effectiveness of the proposed optimization method is demonstrated by numerical examples,where the optimized solutions present tunable and stably wide bandgap characteristics under different magnetic fields.The tunable optimized PnCs based device that can provide a wider tunable bandgap range is also explored. 展开更多
关键词 Topology optimization Tunable bandgap Phononic crystals Magnetorheological material
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Study on the critical diameter of the subway tunnel based on the pressure variation 被引量:4
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作者 SUN ZhenXu YANG GuoWei ZHU Lan 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第10期2037-2043,共7页
When the subway train operates at a speed higher than 100 km/h,the corresponding aerodynamic issue becomes severe.To meet the future requirement for the speedup of subway trains,a research on the critical diameters of... When the subway train operates at a speed higher than 100 km/h,the corresponding aerodynamic issue becomes severe.To meet the future requirement for the speedup of subway trains,a research on the critical diameters of the subway tunnel for trains operating at 120 and 140 km/h has been performed based on passengers’aural discomfort caused by rail tunnel pressure variation.A three-dimensional computational fluid dynamic approach has been adopted for analysis.Meanwhile,trains with different airtight indices are considered and the pressure variations inside and outside the trains are both under investigation.Based on the corresponding criteria for different airtight indices,critical tunnel diameters for trains running at different speeds have been determined.This study would aid in the tunnel section design for future high-speed subway trains. 展开更多
关键词 tunnel pressure waves airtight index aural discomfort blockage ratio
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