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Sb(Ⅲ)与腐殖酸络合特征 被引量:2
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作者 鄢元波 孙福红 +4 位作者 吴丰昌 吴珊 林樱 朱元荣 谢理 《环境科学研究》 EI CAS CSCD 北大核心 2013年第3期307-312,共6页
采用平衡透析法和Dom(浓度分配系数)研究土壤提取的HA(腐殖酸)与Sb(Ⅲ)的络合特征及作用机理.结果表明:在Sb(Ⅲ)与HA络合过程中,4 h左右透析管内外ρ〔Sb(Ⅲ)〕达到物理平衡,72 h左右达到络合平衡状态.当pH为4.0时,Dom最大达7.33 Lg,... 采用平衡透析法和Dom(浓度分配系数)研究土壤提取的HA(腐殖酸)与Sb(Ⅲ)的络合特征及作用机理.结果表明:在Sb(Ⅲ)与HA络合过程中,4 h左右透析管内外ρ〔Sb(Ⅲ)〕达到物理平衡,72 h左右达到络合平衡状态.当pH为4.0时,Dom最大达7.33 Lg,Sb(Ⅲ)与HA络合能力最强;当pH为2.0~4.0时,Sb(Ⅲ)与HA的络合能力几乎不受pH影响;当pH为5.0~8.0时,Sb(Ⅲ)与HA的络合能力随着pH的增大而显著减小;当pH为4.0时,Sb(Ⅲ)与HA之间的络合能力随着HA溶液中ρ(DOC)的增加而加强.红外光谱表征反应物的研究结果证明,HA与Sb(Ⅲ)的结合点主要发生在羧基和酚羟基之间. 展开更多
关键词 Sb(Ⅲ) 腐殖酸(HA) 络合作用 平衡透析法 浓度分配系数
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Investigation of condition-induced bubble size and distribution in electroflotation using a high-speed camera 被引量:2
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作者 Ren Liuyi Zhang Yimin +3 位作者 Qin Wenqing Bao Shenxu Wang Peipei Yang Congren 《International Journal of Mining Science and Technology》 SCIE EI 2014年第1期7-12,共6页
In the flotation process, bubble is a key factor in studying bubble-particle interaction and fine particle flo- tation. Knowledge on size distribution of bubbles in a flotation system is highly important. In this stud... In the flotation process, bubble is a key factor in studying bubble-particle interaction and fine particle flo- tation. Knowledge on size distribution of bubbles in a flotation system is highly important. In this study, bubble distributions in different reagent concentrations, electrolyte concentrations, cathode apertures, and current densities in electroflotation are determined using a high-speed camera. Average bubble sizes under different conditions are calculated using Image-Pro@ Plus (Media Cybernetics@, MD, USA) and SigmaScan@ Pro (Systat Software, CA, USA) software. Results indicate that the average sizes of bubbles, which were generated through 38, 50, 74, 150, 250, 420, and 1000 μm cathode apertures, are 20.2, 29.5, 44.6, 59.2, 68.7, 78.5, and 88.8 μm, respectively. The optimal current density in electroflotation is 20 A/m2. Reagent and electrolyte concentrations, current density, and cathode aperture are important factors in controlling bubble size and nucleation. These factors also contribute to the control of fine- Particle flotation. 展开更多
关键词 High-speed camera Bubble Electroflotation Fine particle Bubble production and control
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Zinc Redistribution in a Soil Developed from Limestone During Pedogenesis
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作者 C. LAVEUF S. CORNU +5 位作者 D. BAIZE M. HARDY O. JOSIERE S. DROUIN A. BRUAND F. JUILLOT 《Pedosphere》 SCIE CAS CSCD 2009年第3期292-304,共13页
The long-term redistribution of Zn in a naturally Zn-enriched soil during pedogenesis was quantified based on mass balance calculations. According to their fate, parent limestones comprised three Zn pools: bound to ca... The long-term redistribution of Zn in a naturally Zn-enriched soil during pedogenesis was quantified based on mass balance calculations. According to their fate, parent limestones comprised three Zn pools: bound to calcite and pyritesphalerite grains, bound to phyllosilicates and bound to goethite in the inherited phosphate nodules. Four pedological processes, i.e., carbonate dissolution, two stages of redox processes and eluviation, redistributed Zn during pedogenesis. The carbonate dissolution of limestones released Zn bound to calcite into soil solution. Due to residual enrichment, Zn concentrations in the soil are higher than those in parent limestones. Birnessite, ferrihydrite and goethite dispersed in soil horizon trapped high quantities of Zn during their formation. Afterwards, primary redox conditions induced the release of Zn and Fe into soil solution, and the subsequent individualization of Fe and Mn into Zn-rich concretions. Both processes and subsequent aging of the concretions formed induced significant exportation of Zn through the bottom water table. Secondary redox conditions promoted the weathering of Fe and Mn oxides in cements and concretions. This process caused other losses of Zn through lateral exportation in an upper water table. Concomitantly, eluviation occurred at the top of the solum. The lateral exportation of eluviated minerals through the upper water table limited illuviation. Eluviation was also responsible for Zn loss, but this Zn bound to phyllosilicates was not bioavailable. 展开更多
关键词 carbonate dissolution eluviation long-term redox SPECIATION
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Variation in carbon,nitrogen and phosphorus partitioning between above-and belowground biomass along a precipitation gradient at Tibetan Plateau 被引量:4
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作者 HONG Jiang-tao WANG Xiao-dan WU Jian-bo 《Journal of Mountain Science》 SCIE CSCD 2016年第4期661-671,共11页
Precipitation is a potential factor that significantly affects plant nutrient pools by influencing biomass sizes and nutrient concentrations. However, few studies have explicitly dissected carbon(C), nitrogen(N) and p... Precipitation is a potential factor that significantly affects plant nutrient pools by influencing biomass sizes and nutrient concentrations. However, few studies have explicitly dissected carbon(C), nitrogen(N) and phosphorus(P) pools between above- and belowground biomass at the community level along a precipitation gradient. We conducted a transect(approx. 1300 km long) study of Stipa purpurea community in alpine steppe on the Tibet Plateau of China to test the variation of N pool of aboveground biomass/N pool of belowground biomass(AB/BB N) and P pool of aboveground biomass/P pool of belowground biomass(AB/BB P) along a precipitation gradient. The proportion of aboveground biomass decreased significantly from mesic to drier sites. Along the belt transect, the plant N concentration was relatively stable; thus, AB/BB N increased with moisture due to the major influences by above- and belowground biomass allocation. However, P concentration of aboveground biomass decreased significantly with increasing precipitation and AB/BB P did not vary with aridity because of the offset effect of the P concentration and biomass allocation. Precipitation gradients do decouple the N and P pool of a S. purpurea community along a precipitation gradient in alpine steppe. The decreasing of N:P in aboveground biomass in drier regions may indicate much stronger N limitation in more arid area. 展开更多
关键词 Biomass allocation Nutrient concentration Qinghai-Tibetan Plateau Alpine steppe Stipa purpurea
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A New Method for Analyzing VOCs Emission from Dry Materials 被引量:4
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作者 ZHANG Tao JIA Li 《Journal of Thermal Science》 SCIE EI CAS CSCD 2008年第3期228-232,共5页
An approximate integral method for volatile compounds emission from plate is presented in this paper. The gas-phase mass transfer resistance was neglected for simplifying computation. Compared to Laplace Transformatio... An approximate integral method for volatile compounds emission from plate is presented in this paper. The gas-phase mass transfer resistance was neglected for simplifying computation. Compared to Laplace Transformation Method, the method suggested is simple, and emission flux, chamber concentration of volatile compounds and concentration distribution of volatile compounds in the material can be determined conveniently. Results of the present method show good agreement with experimental data. The influence of CO, D, K and N on concentration of total volatile organic compounds (TVOC) in the air is also calculated. 展开更多
关键词 approximate integral method emission flux concentration distribution
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