In order to investigate the atmospheric oxidation processes and the formation of secondary organic aerosol （SOA）, an indoor environmental reaction smog chamber are constructed and characterized. The system consists ...In order to investigate the atmospheric oxidation processes and the formation of secondary organic aerosol （SOA）, an indoor environmental reaction smog chamber are constructed and characterized. The system consists of the collapsible ～830 L FEP Teflon film main reactor, in which the atmospheric chemical reactions take place and the formation of SOA occurs under the simulated atmospheric conditions, and the diverse on-line gas- and particle-phase instrumentation, such as the proton transfer reaction mass spectrometer, the synchrotron radiation photoionization mass spectrometer, the aerosol laser time-of-flight mass spectrometer, and other traditional commercial instruments. The initial characterization experiments are described, concerning the temperature and ultraviolet light intensity, the reactivity of the pure air, the wall loss rates of gaseous compounds and particulate matter. And the initial evaluation experiments for SOA yields from the ozonolysis of α-pinene and for mass spectra of the products resulting from the photooxidation of OH initiated isoprene are also presented, which indicate the applicability of this facility on the studies of gas-phase chemical mechanisms as well as the formation of SOA expected in the atmosphere.展开更多
One quarter scale experiment device of a typical L-shape architecture structure including a burning room and an adjacent hallway is established to carry out the research.The smoke characteristics at the sampling point...One quarter scale experiment device of a typical L-shape architecture structure including a burning room and an adjacent hallway is established to carry out the research.The smoke characteristics at the sampling points below the ceiling of the burning compartment and the roof of the hallway are studied systematically to find out the effects of different ceilings on the local fire origin compartment and the smoke transportation to a remote area.A series of tests is reported and the smoke residence time,the concentration peak and the concentration build up rate are investigated as functions of the type of the ceiling.The smoke residence time,the most important factor concerning smoke toxicity,is described by a novel concept,wavelength,in this study.Furthermore,it is worth emphasizing that the PVC ceiling exhibits a phenomenon of frequent collapse during the fire developing period.The single heat action is conducted to judge the smoke and the heat effect on the fire risk.展开更多
The heat transfer performance of a mist/air jet impingement on a constant-heat flux surface was experimentally investigated.Two objectives were outlined in the current study.The first objective is to assess the effect...The heat transfer performance of a mist/air jet impingement on a constant-heat flux surface was experimentally investigated.Two objectives were outlined in the current study.The first objective is to assess the effects of mist/air volumetric flow rate ratio,impinging mode and heat flux on the heat transfer characteristics of free mist/air jet impingement.The second objective is to assess the effect of swirl flow induced by the spinning grinding wheel on the mist/air jet impingement,simulating the heat transfer process on a grinding work-piece surface subjected to the mist/air jet impingement.The results show that the addition of dilute water droplets to air flow results in significant heat transfer enhancement.Once the mist/air ratio is increased to a certain value,the increase of heat transfer with the mist/air ratio becomes slow.For a given mist/air ratio,as the increase of heat flux,the contribution of droplet evaporation to the overall heat transfer is weakened relatively,resulting in a decrease of heat transfer enhancement in comparison to the lower heat flux case.The heat transfer coefficient in the stagnation region for the oblique jet is much lower than the normal mist/air jet impingement,while in the region away from the stagnation,the local heat transfer coefficient for the oblique jet is higher than the normal jet.As regards as the mist/air jet impingement in the vicinity of grinding zone is concerned,when the jet impinging direction is consistent with the rotating direction of rotating disk,the swirl flow induced by the rotating disk could entrain more droplets to enter the jet impinging stagnation zone,which is beneficial to convective heat transfer enhancement.Furthermore,as the rotational speed of disk increases,the temperature deceases in impinging jet stagnation zone.展开更多
基金This work was supported by the Natural Science Foundation of Anhui Province, China （No.1208085MD59）, the National Natural Science Foundation of China （No.U1232209, No.41175121, and No.21307137）, the Presidential Foundation of Hefei Institutes of Physical Science, Chinese Academy of Sciences, China （No.YZJJ201302）, and the Knowledge Innovation Foundation of the Chinese Academy of Sciences （No.KJCX2-YW-N24）.
文摘In order to investigate the atmospheric oxidation processes and the formation of secondary organic aerosol （SOA）, an indoor environmental reaction smog chamber are constructed and characterized. The system consists of the collapsible ～830 L FEP Teflon film main reactor, in which the atmospheric chemical reactions take place and the formation of SOA occurs under the simulated atmospheric conditions, and the diverse on-line gas- and particle-phase instrumentation, such as the proton transfer reaction mass spectrometer, the synchrotron radiation photoionization mass spectrometer, the aerosol laser time-of-flight mass spectrometer, and other traditional commercial instruments. The initial characterization experiments are described, concerning the temperature and ultraviolet light intensity, the reactivity of the pure air, the wall loss rates of gaseous compounds and particulate matter. And the initial evaluation experiments for SOA yields from the ozonolysis of α-pinene and for mass spectra of the products resulting from the photooxidation of OH initiated isoprene are also presented, which indicate the applicability of this facility on the studies of gas-phase chemical mechanisms as well as the formation of SOA expected in the atmosphere.
文摘One quarter scale experiment device of a typical L-shape architecture structure including a burning room and an adjacent hallway is established to carry out the research.The smoke characteristics at the sampling points below the ceiling of the burning compartment and the roof of the hallway are studied systematically to find out the effects of different ceilings on the local fire origin compartment and the smoke transportation to a remote area.A series of tests is reported and the smoke residence time,the concentration peak and the concentration build up rate are investigated as functions of the type of the ceiling.The smoke residence time,the most important factor concerning smoke toxicity,is described by a novel concept,wavelength,in this study.Furthermore,it is worth emphasizing that the PVC ceiling exhibits a phenomenon of frequent collapse during the fire developing period.The single heat action is conducted to judge the smoke and the heat effect on the fire risk.
基金supported by the National Natural Science Foundation of China(Grant No.51076063)
文摘The heat transfer performance of a mist/air jet impingement on a constant-heat flux surface was experimentally investigated.Two objectives were outlined in the current study.The first objective is to assess the effects of mist/air volumetric flow rate ratio,impinging mode and heat flux on the heat transfer characteristics of free mist/air jet impingement.The second objective is to assess the effect of swirl flow induced by the spinning grinding wheel on the mist/air jet impingement,simulating the heat transfer process on a grinding work-piece surface subjected to the mist/air jet impingement.The results show that the addition of dilute water droplets to air flow results in significant heat transfer enhancement.Once the mist/air ratio is increased to a certain value,the increase of heat transfer with the mist/air ratio becomes slow.For a given mist/air ratio,as the increase of heat flux,the contribution of droplet evaporation to the overall heat transfer is weakened relatively,resulting in a decrease of heat transfer enhancement in comparison to the lower heat flux case.The heat transfer coefficient in the stagnation region for the oblique jet is much lower than the normal mist/air jet impingement,while in the region away from the stagnation,the local heat transfer coefficient for the oblique jet is higher than the normal jet.As regards as the mist/air jet impingement in the vicinity of grinding zone is concerned,when the jet impinging direction is consistent with the rotating direction of rotating disk,the swirl flow induced by the rotating disk could entrain more droplets to enter the jet impinging stagnation zone,which is beneficial to convective heat transfer enhancement.Furthermore,as the rotational speed of disk increases,the temperature deceases in impinging jet stagnation zone.
