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玻璃纤维布/聚偏氟乙烯复合膜的制备与性能研究 被引量:1
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作者 罗少伶 陈建 +2 位作者 何刚 聂松 代祖洋 《化工新型材料》 CAS CSCD 北大核心 2016年第12期94-96,共3页
通过在玻璃纤维布表面涂覆聚偏氟乙烯/硅烷偶联剂(PVDF/KH550)(质量比9∶1)粘接剂,将无机玻璃纤维与有机PVDF纤维进行复合,制得玻璃纤维/PVDF复合膜。将不同浓度(8%(wt,质量分数,下同)、10%、12%、14%)的涂覆液分别制备复合膜,表征复合... 通过在玻璃纤维布表面涂覆聚偏氟乙烯/硅烷偶联剂(PVDF/KH550)(质量比9∶1)粘接剂,将无机玻璃纤维与有机PVDF纤维进行复合,制得玻璃纤维/PVDF复合膜。将不同浓度(8%(wt,质量分数,下同)、10%、12%、14%)的涂覆液分别制备复合膜,表征复合膜表面形貌、抗拉强度、吸液率、孔隙率和离子电导率、电化学稳定性和锂电池放电比容量。对比得出最佳涂覆液浓度10%,此时抗拉强度为35.70MPa,吸液率为177.65%,孔隙率为45.07%,锂离子传导率为0.2mS/cm。首次放电比容量为136mAh/g,在5C下复合膜的放电比容量比商用隔膜Celgard 2400高出47.3%。 展开更多
关键词 玻璃纤维/聚偏氟乙烯复合膜 隔膜 静电纺丝 锂电池
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酯交换抑制剂对玻璃纤维增强PC/PBT合金性能的影响的探究
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作者 张传鑫 陈晓东 +1 位作者 范金辰 徐群杰 《塑料工业》 CAS CSCD 北大核心 2021年第8期112-118,共7页
在聚碳酸酯/聚对苯二甲酸丁二醇酯/玻璃纤维/增韧剂(PC/PBT/30GF/5PTW)复合材料体系中分别添加磷酸二氢钠和亚磷酸三苯酯两种酯交换抑制剂,研究了酯交换抑制剂含量在0.5%-2%变化下对复合材料力学性能、结晶性能、热稳定性、熔体流动性... 在聚碳酸酯/聚对苯二甲酸丁二醇酯/玻璃纤维/增韧剂(PC/PBT/30GF/5PTW)复合材料体系中分别添加磷酸二氢钠和亚磷酸三苯酯两种酯交换抑制剂,研究了酯交换抑制剂含量在0.5%-2%变化下对复合材料力学性能、结晶性能、热稳定性、熔体流动性、耐热性的影响。通过对比不同含量的酯交换抑制剂的复合材料性能差异性,优选出玻璃纤维增强PC/PBT合金中适量的酯交换抑制剂。我们发现分别添加0.5%NaH_(2) PO_(4)和TPPI与未添加相比复合材料的弯曲模量明显提高,刚性增大,其他力学性能保持接近。当酯交换抑制剂含量超过1%时,添加TPPI的复合材料的强度急剧下滑,而添加NaH_(2) PO_(4)的复合材料的强度趋于稳定。通过热重分析得出酯交换抑制剂的添加有利于提高复合材料的热稳定性,分别添加1.5%、2%TPPI复合材料起始分解温度分别提高了110.2、140.4℃,最大分解速率温度分别提高了130、130.8℃,有效地减缓了复合材料在高温下的热失重行为。 展开更多
关键词 酯交换抑制剂 热稳定性 力学性能 相容性 玻璃纤维增强碳酸酯/聚对苯二甲酸丁二醇酯合金
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新型纳米生物活性接骨螺钉固定犬股骨髁间骨折 被引量:1
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作者 苏保 李吉东 +3 位作者 蒋电明 李玉宝 邬均 李军 《第三军医大学学报》 CAS CSCD 北大核心 2012年第17期1745-1749,共5页
目的评估纳米羟基磷灰石(nano-hydroxyapatite,n-HA)/聚酰胺66(PA66)/玻璃纤维(glass fiber,GF)新型生物活性螺钉固定犬髁间骨折的效果。方法制备n-HA/PA66/GF生物活性螺钉。取24只成年中华田园犬,按随机数字表法分为2组:生物螺钉实验... 目的评估纳米羟基磷灰石(nano-hydroxyapatite,n-HA)/聚酰胺66(PA66)/玻璃纤维(glass fiber,GF)新型生物活性螺钉固定犬髁间骨折的效果。方法制备n-HA/PA66/GF生物活性螺钉。取24只成年中华田园犬,按随机数字表法分为2组:生物螺钉实验组和金属螺钉对照组。使用电锯将动物股骨外侧髁锯断造股骨髁间骨折,分别使用生物螺钉及金属螺钉固定骨折。术后4、8、12、24周行大体观察、组织学、CT片、生物力学及血常规、生化检测,术后24周行肝、肾、脾组织学检测。结果 2种螺钉均能有效固定犬髁间骨折。术后2组动物均活动正常,切口愈合良好。术后12周CT显示2组动物髁间骨折均已骨性愈合。组织学检测发现n-HA/PA66/GF螺钉表面被新生骨覆盖,新生骨不断钙化、成熟,骨-钉界面结合紧密。金属螺钉与骨之间存在较大间隙,螺钉周围骨组织被1层纤维组织包裹。生物力学测试证实2组最大推出载荷在术后4、8、12周无统计学差异(P>0.05),但在术后24周有统计学差异(P<0.05),推出生物螺钉所需的最大载荷比金属螺钉对照组大。生物螺钉实验组术后24周碱性磷酸酶水平升高[(58.8±14.49)U/L],2组其余外血常规、生化均正常。2组肝、脾、肾HE染色未见异常。结论 n-HA/PA66/GF生物活性螺钉具有良好的内固定性能和体内相容性。 展开更多
关键词 接骨螺钉 纳米羟基磷灰石/聚酰胺66/玻璃纤维 生物活性假体 应力遮挡
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用于大型公共交通的热塑性复合夹芯板结构设计与制造
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作者 Haibin Ning Gregg M. Janowski +1 位作者 Uday K. Vaidya George Husman 《钢结构》 2008年第2期74-74,共1页
轻质运输工具可以提高燃料的燃烧效率、降低运行费用,在大型公共交通系统中更为明显。轻质复合材料,如玻璃纤维增强聚合物,被用来替代传统的钢材和铝合金。介绍了采用热塑性复合材料的大型公共汽车侧板的设计、分析研究和制造。设计了... 轻质运输工具可以提高燃料的燃烧效率、降低运行费用,在大型公共交通系统中更为明显。轻质复合材料,如玻璃纤维增强聚合物,被用来替代传统的钢材和铝合金。介绍了采用热塑性复合材料的大型公共汽车侧板的设计、分析研究和制造。设计了一种由E-玻璃纤维/聚丙烯表面覆盖和聚丙烯蜂窝核心构成的复合夹芯板,具有轻质,高强和良好的吸能性能。夹芯板的设计和分析采用Pro/E、Hy-permesh、ANSYS等软件进行。单一的膜结构用于制造玻璃纤维/聚丙烯表面覆盖,表面覆盖的微结构分析证明此过程可以保证很好的固结。表面覆盖与核心材料被牢固地结合起来并经过了模型测试。荷载达到11.7kN时由于粘结失效导致夹芯板破坏。夹芯板的静载能力已满足美国公共运输协会(AP-TA)的要求。与传统的铝面钢结构卡车相比,热塑性复合材料制造的夹芯板减轻了55%的重量。 展开更多
关键词 热塑性复合材料 夹芯板结构 玻璃纤维/聚 乙烯 大型交通系统 膜结构
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Bond strength improvement of GFRP rebars with different rib geometries 被引量:12
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作者 HAO Qing-duo WANG Yan-lei +1 位作者 ZHANG Zhi-chun OU Jin-ping 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第9期1356-1365,共10页
Based on the Canadian Standards Association (CSA) criteria,105 pullout specimens were tested to investigate the effect of different rib geometries on bond strength of glass fiber reinforced polymer (GFRP) rebars embed... Based on the Canadian Standards Association (CSA) criteria,105 pullout specimens were tested to investigate the effect of different rib geometries on bond strength of glass fiber reinforced polymer (GFRP) rebars embedded in concrete. Two kinds of conventional reinforcing rebars were also studied for comparison. Each rebar was embedded in a 150 mm concrete cube,with the embedded length being four times the rebar diameter. The experimental parameters were the rebar type,rebar component,rebar diameter,rebar surface texture,rib height,rib spacing and rib width. Theoretical analysis was also carried out to explain the experimental phenomena and results. The experimental and theoretical results indicated that the bond strength of GFRP rebars was about 13%~35% lower than that of steel rebars. The bond strength and bond-slip behavior of the specially machined rebars varied with the rebar type,rebar diameter,rebar surface texture,rib height,rib spacing and rib width. Using the results,design recom-mendations were made concerning optimum rib geometries of GFRP ribbed rebars with superior bond-slip characteristics,which concluded that the optimal rib spacing of ribbed rebars is the same as the rebar diameter,and that the optimal rib height is 6% of the rebar diameter. 展开更多
关键词 GFRP rebars CONCRETE Pullout test Bond strength Rib geometries Optimal surface configuration
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Strengthening reinforced concrete beams using prestressed glass fiber-reinforced polymer-Part I: Experimental study 被引量:11
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作者 WU Jong-hwei YEN Tsong +1 位作者 HUNG Chien-hsing LIN Yiching 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第3期166-174,共9页
This work is aimed at studying the strengthening of reinforced concrete (R. C.) beams using prestressed glass fi- ber-reinforced polymer (PGFRP). Carbon fiber-reinforced polymer (CFRP) has recently become popular for ... This work is aimed at studying the strengthening of reinforced concrete (R. C.) beams using prestressed glass fi- ber-reinforced polymer (PGFRP). Carbon fiber-reinforced polymer (CFRP) has recently become popular for use as repair or rehabilitation material for deteriorated R. C. structures, but because CFRP material is very stiff, the difference in CFRP sheet and concrete material properties is not favorable for transferring the prestress from CFRP sheets to R. C. members. Glass fi- ber-reinforced polymer (GFRP) sheets with Modulus of Elasticity quite close to that of concrete was chosen in this study. The load-carrying capacities (ultimate loads) and the deflections of strengthened R. C. beams using GFRP and PGFRP sheets were tested and compared. T- and ⊥-shaped beams were used as the under-strengthened and over-strengthened beams. The GFRP sheets were prestressed to one-half their tensile capacities before being bonded to the T- and ⊥-shaped R. C. beams. The prestressed tension in the PGFRP sheets caused cambers in the R. C. beams without cracks on the tensile faces. The PGFRP sheets also enhanced the load-carrying capacity. The test results indicated that T-shaped beams with GFRP sheets increased in load-carrying capacity by 55% while the same beams with PGFRP sheets could increase load-carrying capacity by 100%. The ⊥-shaped beams with GFRP sheets could increase load-carrying capacity by 97% while the same beams with PGFRP sheets could increase the loading-carrying capacity by 117%. Under the same external loads, beams with GFRP sheets underwent larger deflections than beams with PGFRP sheets. While GFRP sheets strengthen R. C. beams, PGFRP sheets decrease the beams’ ductility, especially for the over-strengthened beams (⊥-shaped beams). 展开更多
关键词 Strengthening Prestressed glass fiber reinforcement polymer Modulus of Elasticity R. C. beams
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Applications of Glass and Glass Fiber Retrofit Polymer in Modern Footbridges 被引量:1
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作者 Beata Stankiewicz MarcinTatara 《Journal of Civil Engineering and Architecture》 2015年第7期791-797,共7页
The architecture of footbridge design takes the form of a number of submissions from leading architects and engineers, each setting out their views on bridge design--present and future. It looks at the functions of a ... The architecture of footbridge design takes the form of a number of submissions from leading architects and engineers, each setting out their views on bridge design--present and future. It looks at the functions of a bridge, defining purpose of place and context, the spirit of creativity and the reasoned progression of an idea. It also explores the exploitation of materials technology and construction innovation and the tension between lightness and mass and between sculpture and scale. Present parameters of tempered and laminated glass create possibility of modern architecture of footbridges which are being full of transparency and light reflex effects. Four projects, using glass panels designed by Santiago Calatrava, have been presented in this paper. GFRP (glass fiber retrofit polymer) makes new horizon in material technology, helps to enrich new conception of structure with longer durability, low weight of deck and new creation of architecture line. The paper has described a few results of FEM (finite element method) analysis of footbridge with modular bridge GFRP deck system. The footbridge was excited by impact and human-induced vibrations. Composite material consists of glass fibers and polymer matrix is a promising alternative against traditional materials. New architecture and modern material engineering are looking for fresh possibilities of form and shape of structure, long durability and extraordinary technical parameters of building elements. 展开更多
关键词 Transparent bridge deck parameters of glass GFRP deck pultruded material FEM of bridge deck fiberline technology.
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Strengthening reinforced concrete beams using prestressed glass fiber-reinforced polymer-Part II:Analytical study 被引量:2
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作者 HUNG Chien-hsing YEN Tsong WU Jong-hwei 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第8期844-852,共9页
Strengthening reinforced concrete (R. C.) beams using prestressed glass fiber-reinforced polymer (PGFRP) was studied experimentally as described in Part I of this paper (Huang et al., 2005). In that paper, R. C. beams... Strengthening reinforced concrete (R. C.) beams using prestressed glass fiber-reinforced polymer (PGFRP) was studied experimentally as described in Part I of this paper (Huang et al., 2005). In that paper, R. C. beams, R. C. beams with GFRP (glass fiber-reinforced polymer) sheets, and R. C. beams with PGFRP sheets were tested in both under-strengthened and over-strengthened cases. The test results showed that the load-carrying capacities (ultimate loads) of the beams with GFRP sheets were greater than those of the beams without polymer sheets. The load-carrying capacities of beams with PGFRP sheets were greater than those of beams with GFRP sheets. The objective of this work is to develop an analytical method to compute all of these load-carrying capacities. This analytical method is independent of the experiments and based only on the traditional R. C. and P. C. (prestressed concrete) theory. The analytical results accorded with the test results. It is suggested that this analytical method be used for analyzing and designing R. C. beams strengthened using GFRP or PGFRP sheets. 展开更多
关键词 Analytical analysis Glass fiber-reinforced polymer Prestressed glass fiber-reinforced polymer R. C. beams
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Experimental Analysis on Local Buckling of GFRP?Foam Sandwich Pipe Under Axial Compressive Loading
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作者 CHEN Li CHEN Li +2 位作者 PAN Darong ZHAO Qilin NIU Longlong 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2020年第1期129-142,共14页
To find out the local buckling behaviors of glass fiber reinforced plastic(GFRP)-foam sandwich pipe suffering axial loading,a series of quasi-static axial compression tests are carried out in the laboratory.Comparing ... To find out the local buckling behaviors of glass fiber reinforced plastic(GFRP)-foam sandwich pipe suffering axial loading,a series of quasi-static axial compression tests are carried out in the laboratory.Comparing with the test data,systematic numerical analysis on the local buckling behavior of this sandwich pipe is also conducted,and the buckling failure mechanism is revealed.The influences of the key parameters on bearing capacity of the sandwich structure are discussed.Test and numerical results show that the local buckling failure of the GFRPfoam sandwich pipe is dominated basically by two typical modes,i.e.,the conjoint buckling and the layered buckling.Local buckling at the end,shear failure at the end and interface peeling failure are less efficient than the local buckling failure at the middle height,and ought to be restrained by appropriate structural measures.The local buckling bearing capacity increases linearly with the core density of the sandwich pipe structure.When the core density is relatively high(higher than 0.05 g/cm3),the effect of increasing the core density on improving the bearing efficiency is less on the specimens with a large ratio of the wall thickness to the radius than on those with a small one.Local layered buckling is another failure mode with lower bearing efficiency than the local conjoint buckling,and it can be restrained by increasing the core density to ensure the cooperation of the inner and the outer GFRP surface layer.The bearing capacity of the GFRP-foam sandwich pipe increases with the height-diameter ratio;however,the bearing efficiency decreases with this parameter. 展开更多
关键词 sandwich pipe polyurethane foam glass fiber reinforced plastic(GFRP) local buckling axial compression
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Comparative Life-cycle Assessment of Sheet Molding Compound Reinforced by Natural Fiber vs. Glass Fiber
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作者 Jinwu Wang Sheldon Qiang Shi Kaiwen Liang 《Journal of Agricultural Science and Technology(B)》 2013年第7期493-502,共10页
We present comparative life-cycle assessments of three fiber-reinforced sheet molding compounds (SMCs) using kenaf fiber, glass fiber and soy protein resin. Sheet molding compounds for automotive applications are ty... We present comparative life-cycle assessments of three fiber-reinforced sheet molding compounds (SMCs) using kenaf fiber, glass fiber and soy protein resin. Sheet molding compounds for automotive applications are typically made of unsaturated polyester and glass fibers. Replacing these with kenaf fiber or soy protein offers potential environmental benefits. A soy-based resin, maleated acrylated epoxidized soy oil (MAESO), was synthesized from refined soybean oil. Kenaf fiber and polyester resins were used to make SMC 1 composites, while SMC2 composites were made from kenaf fiber and a resin blend of 20% MASEO and 80% unsaturated polyester. Both exhibited good physical and mechanical properties, though neither was as strong as glass fiber reinforced polyester SMC. The functional unit was defined as mass to achieve equal stiffness and stability for the manufacture of interior parts for automobiles. The life-cycle assessments were done on SMCI, SMC2 and glass fiber reinforced SMC. The material and energy balances from producing one functional unit of three composites were collected from lab experiments and the literature. Key environmental measures were computed using SimaPro software. Kenaf fiber-reinforced SMC composites (SMC1 and SMC2) performed better than glass fiber-reinforced SMC in every environmental category. The global warming potentials of kenaf fiber-reinforced SMC (SMCI) and kenaf soy resin-based SMC (SMC2) were 45% and 58%, respectively, of glass fiber-reinforced SMC. Thus, we have demonstrated significant ecological benefit from replacing glass fiber reinforced SMC with soy-based resin and natural fiber. 展开更多
关键词 Natural fiber reinforced composites sheet molding compound life-cycle assessment.
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Influence of additives on strength enhancement and greenhouse gas emissions of pre-cast lime-based construction products
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作者 F.J.O’Flaherty F.J.Khalaf V.Starinieri 《Low-carbon Materials and Green Construction》 2023年第1期347-364,共18页
Strength properties of laboratory scale lime-based samples enhanced with additives such as nanomaterials(nanofibrillated cellulose,nanosilica,nanoclay,expanded graphite),hemp&glass fibres,hemp shiv and polyvinyl a... Strength properties of laboratory scale lime-based samples enhanced with additives such as nanomaterials(nanofibrillated cellulose,nanosilica,nanoclay,expanded graphite),hemp&glass fibres,hemp shiv and polyvinyl acetate(PVAc)are determined.Samples were cured for 26 days in air at 20℃/60%RH after casting before being oven dried for a further two days at 50℃(28 days total).Results show that the nanomaterials on their own had a mixed effect on the strength although nSiO_(2) as a solo additive performed exceptionally well.The combination of fibres in conjunction with PVAc also greatly enhanced the strength due to increased bond between the fibres and the matrix.In addition,Greenhouse Gas emissions(GHG,kgCO_(2)eq)of an arbitrary block was determined for all composites and compared to the GHG of a commonly used lightweight aerated concrete block.Comparison of the normalised compressive strengths to the different loading conditions as outlined in BS EN 8103 shows that a more widespread use of pre-cast lime composites is possible and without unduly increasing GHG emissions. 展开更多
关键词 Hempcrete NANOMATERIALS Hemp shiv&fibre PVAC Glass fibre Greenhouse gas
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新型生物活性接骨螺钉材料对成骨细胞生物学行为影响的体外研究
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作者 苏保 蒋电明 +3 位作者 李吉东 安洪 邬均 祁小桐 《中华创伤杂志》 CAS CSCD 北大核心 2014年第10期1055-1060,共6页
目的,研究用于制备新型生物活性接骨螺钉的纳米羟基磷灰石/聚酰胺66/玻璃纤维(nano—hydroxyapatite/polyamide66/glassfiber,n-HA/PA66/GF)对成骨细胞生物学行为的影响,为生物螺钉后期临床应用提供实验依据。方法,制备圆片状... 目的,研究用于制备新型生物活性接骨螺钉的纳米羟基磷灰石/聚酰胺66/玻璃纤维(nano—hydroxyapatite/polyamide66/glassfiber,n-HA/PA66/GF)对成骨细胞生物学行为的影响,为生物螺钉后期临床应用提供实验依据。方法,制备圆片状n-HA/PA66/GF及其浸提液;取小鼠成骨细胞与n-HA/PA66/GF浸提液共培养,采用直接接触实验观察细胞生长变化情况;MTT实验检测细胞增殖情况;流式细胞仪检测细胞凋亡率;ELISA法测定细胞骨钙素含量;Tran-swell小室实验观察细胞迁移能力;扫描电镜观察细胞黏附和生长情况;细胞免疫荧光检查细胞骨架及肌动蛋白纤维表达。结果,直接接触实验表明,n-HA/PA66/GF对成骨细胞无明显细胞毒性。MTT检测n-HA/PA66/GF浸提液与成骨细胞共培养2,4,6d后,吸光度(A)值分别为0.96±0.14,1.54±0.15,2.39±0.27。结果显示,成骨细胞数量随着培养时间延长而增多(P〈0.05)。流式细胞检测结果证实,n-HA/PA66/GF能使更多成骨细胞进入S期而对细胞凋亡率无明显影响,成骨细胞骨钙素分泌随着共培养时间延长而增多。Transwell实验显示,含浸提液和FBS的α-MEM培养基小室穿过半透膜的细胞数分别为(8.73±3.26)个/视野、(9.47±3.29)个/视野,差异无统计学意义(P〉0.05)。扫描电镜观察n-HA/PA66/GF表面的成骨细胞形态规整,紧紧黏附在材料表面,逐渐呈现复层生长。免疫荧光结果表明,材料浸提液对细胞骨架及肌动蛋白纤维的分布无明显影响。结论,新型生物螺钉n-HA/PA66/GF具有良好的成骨细胞相容性,对细胞生长、增殖、分泌、黏附、周期和骨钙素分泌等均有一定调节作用。 展开更多
关键词 细胞生物学 成骨细胞 纳米羟基磷灰石/聚酰胺66/玻璃纤维
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