基于电离种子的发射药燃烧生成等离子体研究

针对发射药燃气温度难以满足等离子体生成条件的问题,通过添加电离种子的方法提高燃气生成等离子体含量。基于气体平衡方程推导了发射药添加电离种子后的燃气电子密度计算公式,分析了电子密度随温度的变化规律,通过不同类型发射药的燃烧对比实验及双基药添加电离种子实验进行了验证。结果表明:电子密度随燃气温度的增加而增加,且添加电离种子能在现有发射药的基础上进一步提高燃气电子密度。研究成果为下一步等离子体在火炮发射过程中的应用提供理论依据。

电离种子对发射药电离特性影响研究

为探究电离种子对发射药电离特性的影响规律,构建了火炮发射药热电离模型,数值模拟了电离种子类型和含量等因素对发射药燃气中电子密度的影响规律。数值模拟结果表明:针对不同类型的电离种子,发射药燃气中电子密度从高到低依次为CsNO_(3)、KNO_(3)、NaNO_(3);针对同一种电离种子,电离种子含量越高,火药燃气中电子密度越大,但随着电离种子含量的增加,电子密度增加的幅度变缓。

火炮膛内火药燃气温度控制仿真研究

为了解决火炮常规装药参数下膛内温度不满足燃气热电离条件的问题,基于内弹道理论建立火炮发射内弹道模型,推导了含电离种子的燃气电导率方程,并以某型炮发射过程为仿真算例,通过Matlab对内弹道微分方程组进行编程,采用四阶龙格-库塔法进行求解,获得了常规装药条件下的内弹道规律曲线,计算分析了添加电离种子后的燃气电导率。仿真结果表明,电离种子能在燃气温度不足的情况下,有效提高燃气电导率,从而使燃气具有导电性,为下一步磁化等离子的可行性提供理论依据。

Continuous changes in electrical conductivity of sodium aluminate solution in seeded precipitation

The mechanism of seeded precipitation of sodium aluminate solution was studied by measuring the seeded-precipitation rate and electrical conductivity online, as well as calculating the activity and fraction of ion pair. The results show that the electrical conductivity of sodium aluminate slurry linearly decreases with increasing aluminum hydroxide addition. Moreover, both the electrical conductivity of slurry and the difference in electrical conductivity between sodium aluminate solution and slurry remarkably decline in the first 60 min before gradually increasing in the preliminary 10 h and finally reaching almost the same level after 10 h. In low Na2 O concentration solution the activities of Na OH and Na Al（OH）4 in seeded precipitation are high, which can enlarge the difference in conductivity between slurry and solution. Additionally, more ion pairs exist in solution in preliminary seeded precipitation, and the adsorption of Na＋Al（OH）4- on seed surface is likely to break the equilibrium of ion pair formation and to decrease the difference in conductivity in preliminary seeded precipitation.

Synthesis of Ni^2+cation modified TS-1 molecular sieve nanosheets as effective photocatalysts for alcohol oxidation and pollutant degradation

lmprovement of the charge separation of titanosilicate molecular sieves is critical to their use asphotocatalysts for oxidative organic transformations.In this work,MFI TS-1 molecular sievenanosheets(TS-1 NS)were synthesized by a low-temperature hydrothermal method using a tai-lored diquaternary ammonium surfactant as the structure-directing agent.Introducing Ni^2+cationsat the ion-exchange sites of the TS-1 NS framework significantly enhanced its photoactivity in aero-bic alcohol oxidation.The optimized Ni cation-functionalized TS-1 NS(Ni/TS-1 NS)provide impres-sive photoactivity,with a benzyl alcohol(BA)conversion of 78.9%and benzyl aldehyde(BAD)se-lectivity of 98.8%using O as the only oxidant under full light irradiation;this BAD yield is approx-imately six times greater than that obtained for bulk TS-1,and is maintained for five runs.The ex-cellent photoactivity of Ni/TS-1 NS is attributed to the significantly enlarged surface area of thetwo-dimensional morphology TS-1 NS,extra mesopores,and greatly improved charge separation.Compared with bulk TS-1,Ni/TS-1 NS has a much shorter charge transfer distance.Theas-introduced Ni species could capture the photoelectrons to further improve the charge separa-tion.This work opens the way to a class of highly selective,robust,and low-cost titanosilicate mo-lecular sieve-based photocatalysts with industrial potential for selective oxidative transformationsand pollutant degradation.

Highly Dispersed Pt Species with Excellent Stability and Catalytic Performance by Reducing a Perovskite-Type Oxide Precursor for CO Oxidation

A new scheme for the preparation of highly dispersed precious metal catalysts is proposed in this work. Samples of LaCol-xPtxO3/SiO2 （x = 0.03, 0.05, 0.07, 0.09, and 0.10） were prepared through a simple method of citrate acid complexa-tion combined with impregnation. In a nanocrystallite of LaCOl-xPtxO3, ions of lanthanum, cobalt, and platinum are evenly mixed at the atomic level and confined within the nanocrystallite. In the reduction process, platinum ions were reduced and migrated onto the surface of the nanocrystallite, and the platinum should be highly dispersed owing to the even mixing of the platinum ions in the precursor. When x = 0.05 or lower, the highest dispersion of Pt could be achieved. The highly dispersed Pt is stable, because of the strong interaction between Pt atoms and the support. The catalysts were characterized by BET surface area, temperature-programmed reduction, X-ray diffraction, transmission electron microscopy, CO temperature-programmed desorption, and turnover frequency. Compared with general precious metal Pt catalysts, the LaCo0.95Pt0.05O3/ SiO2 catalyst exhibited better activity for CO oxidation, and it maintained stability at a high temperature of 400 ℃ for 250 h with complete CO conversion.

Effect of Electrolyte on the Dissolution of Aluminum from Acid Soils and the Distribution of Aluminum Forms inSoil Solution

KCl, CaCl2, NH4Cl, NaCl, K2SO4 and KF solutions were used for studying the effects of canons and anions on the dissolution of aluminum and the distribution of aluminum forms respectively. Power of exchanging and releasing aluminum of four kinds of canons was in the decreasing order Ca2+ >K+ >NH+4 >Na+.The dissolution of aluminum increased with the canon concentration. The adsorption affinity of various soils for aluminum was different. The aluminum in the soil with a stronger adsorption affinity was difficult to be exchanged and released by canons. The Al-F complexes were main species of inorganic aluminum at a low concentration of canons, while Al3+ became major species of inorganic aluminum at a high concentration of canons. The results on the effect of anions indicated that the concentrations of total aluminum, three kinds of inorganic aluminum (Al3+, Al-F and Al-OH complexes) and organic aluminum complexes (Al-OM)when SO2-4 was added into soil suspension were lower than those when Cl- was added. The dissolution of aluminum from soils and the distribution of aluminum forms in solution were edicted by the adsorption of Fon the soil. For soils with strong affinty for F- , the concentrations of the three inorganic aluminum species in soil solution after addition of F- were lower than those after addition of Cl-; but for soils with weak affinity for F- , the concentrations of Al3+ and Al-OM were lower and the concentrations of Al-F complexes and total inorganic aluminum after addition of F- were higher than those after addition of Cl-. The increase of F- concentration in soil solution accelerated the dissolution of aluminum from soils.

Charge Breeding Simulations in a Hollow Electron Beam

Charge breeding technique is used for RIB （radioactive ion beam） production in order of optimizing the re-acceleration of the radioactive isotopes produced by a primary beam in a thick target. Charge breeding is achieved by means of a device capable of increasing the ion charge state from 1＋ to a desired value n＋. In some experiments, a continuous RIB of a given energy may be required. To reach this goal, a charge breeding device based on a hollow gun EBIS （electron beam ion source） has been proposed by the author recently. That EBIS, in principle, can be capable to realize a CW （continuous wave） operation. A sufficiently high focusing magnetic field could reduce to zero the hole radius in the EBIS electron beam. However, a smaller efficiency in the ion charge state increase should be expected. A code developed for studying the ion selective containment in a EBIS has been modified and used to simulate the ion charge state breeding. The effects of the hollow electron beam on the breeding rate have been studied.

Electrostatic Waves in Weakly Magnetized Quantum Plasmas

By using the quantum magnetohydrodynamic model, the electrostatic waves in weakly magnetized quantum plasmas are investigated. The electrons are treated as a quantum and magnetized species, while the ions are classical unmagnetized ones. The general dispersion relations are derived. It is shown that, both the high frequency electron waves （Langmuire wave and upper-hybrid wave） and the low frequency ion acoustic wave can propagate when the plasmas are cold.

Numerical simulation on magnetohydrodynamic power generation channel of scramjet

The reverse magnetohydrodynamic(MHD)energy bypass technology is a promising energy redis⁃tribution technology in the scramjet system,in augmented with a power generation equipment to supply the neces⁃sary long-distance flight airframe power.In this paper,a computational model of the scramjet magnetohydrody⁃namic channel is developed and verified by using the commercial software Fluent.It is found that when the mag⁃netic induction intensity is 1,2,3,4 T,the power generation efficiency is 22.5%,22.3%,22.0%,21.5%,and decreases with the increase of the magnetic induction intensity,and the enthalpy extraction rate is 0.026%,0.1%,0.21%,0.34%,and increases with the increase of the magnetic induction intensity.The deceleration ef⁃fect of electromagnetic action on the airflow in the power channel increases with the increase of magnetic induc⁃tion intensity.The stronger the magnetic field intensity,the more obvious the decreasing effect of fluid Mach num⁃ber in the channel.The power generation efficiency decreases as the magnetic induction intensity increases and the enthalpy extraction rate is reversed.As the local currents gathering at inlet and outlet of the power generation area,total temperature and enthalpy along the flow direction do not vary linearly,and there are maximum and minimum values at inlet and outlet.Increasing the number of electrodes can effectively regulate the percentage of Joule heat dissipation,which can improve the power generation efficiency.