The evolution of nanoporous structure with dealloying condition was investigated, thus, the mechanism of porous structure evolution was uncovered. The Gasar Cu-Mn alloy was dealloyed by room and elevated temperature c...The evolution of nanoporous structure with dealloying condition was investigated, thus, the mechanism of porous structure evolution was uncovered. The Gasar Cu-Mn alloy was dealloyed by room and elevated temperature chemical corrosion, low and high current level electrochemical corrosion, four types of porous structures, including uneven corrosion pits, hybrid porous, haystack type and bicontinuous model were prepared by chemically and electrochemically dealloying the porous Cu-34.6%Mn alloy made by the Gasar process. Then, the surface diffusion coefficient(DS) and the diffusion frequency(kD) of Cu atom, as well as the dissolution frequency(kE) of Mn atom were calculated with dealloying condition. The dealloyed morphologies for room temperature chemical corrosion and low current level electrochemical corrosion were similar due to the same DS. While the dealloyed structures changed from bulk hybrid porous structure to bicontinuous porous film with decreasing kD/kE.展开更多
基金Project(51371104)supported by the National Natural Science Foundation of China
文摘The evolution of nanoporous structure with dealloying condition was investigated, thus, the mechanism of porous structure evolution was uncovered. The Gasar Cu-Mn alloy was dealloyed by room and elevated temperature chemical corrosion, low and high current level electrochemical corrosion, four types of porous structures, including uneven corrosion pits, hybrid porous, haystack type and bicontinuous model were prepared by chemically and electrochemically dealloying the porous Cu-34.6%Mn alloy made by the Gasar process. Then, the surface diffusion coefficient(DS) and the diffusion frequency(kD) of Cu atom, as well as the dissolution frequency(kE) of Mn atom were calculated with dealloying condition. The dealloyed morphologies for room temperature chemical corrosion and low current level electrochemical corrosion were similar due to the same DS. While the dealloyed structures changed from bulk hybrid porous structure to bicontinuous porous film with decreasing kD/kE.
