A huge gypsum miarolitic cavity has been found locatedin an antimony mineralized layer. It is an interformational bleb. Four crystallization steps are recognized for mineral crystals in the miarolitic cavity. Gypsum c...A huge gypsum miarolitic cavity has been found locatedin an antimony mineralized layer. It is an interformational bleb. Four crystallization steps are recognized for mineral crystals in the miarolitic cavity. Gypsum crystals seem to have been formed through two forms of crystallization. The data on fluid inclusions and hydrogen isotopes.show that this cavity is the product of hypergenic process, the orebeariug solution is derived from meteorie water, and the compositional material comes from the oxidized ore zone. During the formation of the miarolitic cayity, the pH-value was within the range of 4--5, i.e., weakly acidic solution, and the formation temperature less than 50℃. It can be clearly seen from the crystallization behaviour of gypsum cyrstals and mineral association that there have taken place significant changes in the pH-value of mineralization solution.展开更多
The potential energies, volumes and electronic structures of characteristic atoms coordinated by neighboring configurations were obtained from the experimental heats of formation and lattice parameters of disordered A...The potential energies, volumes and electronic structures of characteristic atoms coordinated by neighboring configurations were obtained from the experimental heats of formation and lattice parameters of disordered Au1-xCux alloys. From characteristic atom occupation （CAO） patterns of L12-Au3Cu, L12-AuCu3 and Llo-AuCu compounds, their electronic structures, volumetric and energetic properties were calculated. The CAO pattern of Johasson-Linde（J-L） model shows that the transition AuCuI→AuCulI is an exothermic and volume contraction reaction, which is opposite from experimental phenomena. According to CAO pattern of Guymont-Feutelais-Legendre（G-F-L） model, the AuCulI cell consists of two periodic antidirection （PAD） AuCuI regions and two PAD boundary regions. The equations derived from CAO pattern of G-F-L model can be used to calculate energetic properties, volumetric properties and ordering degrees of the PAD AuCuI region and PAD boundary region, as well as corresponding average properties of the AuCulI phase. The results are consistent with experimental phenomena.展开更多
文摘A huge gypsum miarolitic cavity has been found locatedin an antimony mineralized layer. It is an interformational bleb. Four crystallization steps are recognized for mineral crystals in the miarolitic cavity. Gypsum crystals seem to have been formed through two forms of crystallization. The data on fluid inclusions and hydrogen isotopes.show that this cavity is the product of hypergenic process, the orebeariug solution is derived from meteorie water, and the compositional material comes from the oxidized ore zone. During the formation of the miarolitic cayity, the pH-value was within the range of 4--5, i.e., weakly acidic solution, and the formation temperature less than 50℃. It can be clearly seen from the crystallization behaviour of gypsum cyrstals and mineral association that there have taken place significant changes in the pH-value of mineralization solution.
基金Project (50711181) supported by the National Natural Science Foundation of China Project (2009FJ4016) supported by Natural Science Foundation of Hunan Province,China
文摘The potential energies, volumes and electronic structures of characteristic atoms coordinated by neighboring configurations were obtained from the experimental heats of formation and lattice parameters of disordered Au1-xCux alloys. From characteristic atom occupation （CAO） patterns of L12-Au3Cu, L12-AuCu3 and Llo-AuCu compounds, their electronic structures, volumetric and energetic properties were calculated. The CAO pattern of Johasson-Linde（J-L） model shows that the transition AuCuI→AuCulI is an exothermic and volume contraction reaction, which is opposite from experimental phenomena. According to CAO pattern of Guymont-Feutelais-Legendre（G-F-L） model, the AuCulI cell consists of two periodic antidirection （PAD） AuCuI regions and two PAD boundary regions. The equations derived from CAO pattern of G-F-L model can be used to calculate energetic properties, volumetric properties and ordering degrees of the PAD AuCuI region and PAD boundary region, as well as corresponding average properties of the AuCulI phase. The results are consistent with experimental phenomena.
