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α-溴代邻氯苯乙酸的拆分及自消旋研究
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作者 何佺 蒋岚 彭阳峰 《化工科技》 CAS 2004年第4期19-21,共3页
以α 苯乙胺(PEA)为拆分剂,拆分α 溴代邻氯苯乙酸(BrA)的实验过程中,光学活性的α 溴代邻氯苯乙酸(R BrA或S BrA)容易发生自消旋,笔者对BrA和BrA·PEA盐在溶液中和固体状态下的消旋作用进行了研究。
关键词 α-溴代邻氯苯乙酸 Α-苯乙胺 拆分 光学活性 自消旋 分泌抑制剂 血液凝固阻止剂
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α-溴代邻氯苯乙酸拆分过程中的自消旋现象研究
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作者 何佺 彭阳峰 《合成化学》 CAS CSCD 2004年第4期399-401,J005,共4页
以S (- ) α 苯乙胺 [S (- ) PEA]为拆分剂 ,对消旋的α 溴代邻氯苯乙酸 (BrA)进行拆分 ,在实验过程中发现 ,R BrA或S BrA容易发生自消旋。
关键词 α-溴代邻氯苯乙酸 Α-苯乙胺 拆分 消旋 自消旋
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α-溴代邻氯苯乙酸的拆分及自消旋研究
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《医药化工》 2004年第8期42-43,共2页
α-溴代邻氯苯乙酸[2-Bromo-(2-chloro)-Phenyl acetic acid,简称BrA]是十分重要的农药和医药中间体,可用于合成分泌抑制剂.最近用于制备新型血液凝固阻止剂(Clopidogrel),市场前景十分看好。然而实际应用时只有右旋的S型对映体才... α-溴代邻氯苯乙酸[2-Bromo-(2-chloro)-Phenyl acetic acid,简称BrA]是十分重要的农药和医药中间体,可用于合成分泌抑制剂.最近用于制备新型血液凝固阻止剂(Clopidogrel),市场前景十分看好。然而实际应用时只有右旋的S型对映体才具有应用价值.故对化学合成得到的外消旋体需要进一步拆分才能使用。 展开更多
关键词 α-溴代邻氯苯乙酸 拆分 自消旋 化学合成
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Simulation of Decoherence by Averaged Semiquantum Method for Spin-Boson Model
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作者 WANG Zhuo 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第11期881-887,共7页
We investigate the dynamics of a system coupled to an environment by averaged semiquantum method. The theory origins from the time-dependent variational principle (TDVP) formulation and contains nondiagonal matrix e... We investigate the dynamics of a system coupled to an environment by averaged semiquantum method. The theory origins from the time-dependent variational principle (TDVP) formulation and contains nondiagonal matrix elements. So it can be applied to study dissipation, measurement, and decoherence problems in the model (H= hs+hE+ht ). In the calculation, the influence of the environment govern by differential dynamical equation is incorporated through a mean field. We have performed averaged semiquantum method for a spin-boson model, which reproduce the results from stochastic Schrodinger equation method and Hierarchical approach quite accurately. The problems, dynamics in nonequilibrium environments, have also been studied by our method. 展开更多
关键词 ENVIRONMENT semiquantum method DECOHERENCE spin-boson
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Numerical simulation of direct shear tests on mechanical properties of talus deposits based on self-adaptive PCNN digital image processing 被引量:5
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作者 王盛年 徐卫亚 +1 位作者 石崇 张强 《Journal of Central South University》 SCIE EI CAS 2014年第7期2904-2914,共11页
The macro mechanical properties of materials with characteristics of large scale and complicated structural composition can be analyzed through its reconstructed meso-structures.In this work,the meso-structures of tal... The macro mechanical properties of materials with characteristics of large scale and complicated structural composition can be analyzed through its reconstructed meso-structures.In this work,the meso-structures of talus deposits that widely exist in the hydro-power engineering in the southwest of China were first reconstructed by small particles according to the in-situ photographs based on the self-adaptive PCNN digital image processing,and then numerical direct shear tests were carried out for studying the mechanical properties of talus deposits.Results indicate that the reconstructed meso-structures of talus deposits are more consistent with the actual situation because the self-adaptive PCNN digital image processing has a higher discrimination in the details of soil-rock segmentation.The existence and random distribution of rock blocks make the initial shear stiffness,the peak strength and the residual strength higher than those of the "pure soil" with particle size less than 1.25 cm apparently,but reduce the displacements required for the talus deposits reaching its peak shear strength.The increase of rock proportion causes a significant improvement in the internal friction angle of talus deposit,which to a certain degree leads to the characteristics of shear stress-displacement curves having a changing trend from the plastic strain softening deformation to the nonlinear strain hardening deformation,while an unconspicuous increase in cohesion.The uncertainty and heterogeneity of rock distributions cause the differences of rock proportion within shear zone,leading to a relatively strong fluctuation in peak strengths during the shear process,while movement features of rock blocks,such as translation,rotation and crossing,expand the scope of shear zone,increase the required shear force,and also directly lead to the misjudgment that the lower shear strength is obtained from the samples with high rock proportion.That,however,just explains the reason why the shear strength gained from a small amount of indoor test data is not consistent with engineering practice. 展开更多
关键词 talus deposits digital image processing pulse coupled neural networks(PCNN) direct shear test mechanical property granular discrete element method
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Effect of decoherence from a spin environment on the entanglement dynamics of two-qutrit states 被引量:4
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作者 MA XiaoSan REN MingFan +1 位作者 ZHAO GuangXing WANG AnMin 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第10期1833-1838,共6页
The entanglement dynamics of a two-qutrit system under decoherence from a spin environment is investigated by using negativityas entanglement measure. Our results imply that the entanglement evolution depends not only... The entanglement dynamics of a two-qutrit system under decoherence from a spin environment is investigated by using negativityas entanglement measure. Our results imply that the entanglement evolution depends not only on the coupling strength and thetunneling elements of the environment but also on the number of the freedom degrees and the initial state of the environment. 展开更多
关键词 entanglement dynamics quantum decoherence a spin environment
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Robust Quantum Computing in Decoherence-Free Subspaces with Double-Dot Spin Qubits
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作者 冯志波 张春丽 周运清 《Communications in Theoretical Physics》 SCIE CAS CSCD 2014年第2期181-186,共6页
We present a scheme for implementing robust quantum gates in decoherence-free subspaces(DFSs) with double-dot spin qubits. Through the resonator-assisted interaction, the controllable interqubit couplings can be achie... We present a scheme for implementing robust quantum gates in decoherence-free subspaces(DFSs) with double-dot spin qubits. Through the resonator-assisted interaction, the controllable interqubit couplings can be achieved only by adjusting the qubit transition frequencies. We construct a set of logic gates on the DFS-encoded qubits to eliminate the collective noise effects, and thus the gate fidelities can be enhanced remarkably. This proposal may offer a potential approach to realize the robust quantum computing with spin qubits. 展开更多
关键词 decoherence-free subspace double-dot spin qubit transmission line resonator
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