Lanthanum alginate bead is a new, highly active adsorbent. In the present study, we investigated its ad- sorption performance and its adsorption mechanism. The adsorption isotherm for fluoride onto lanthanum alginate ...Lanthanum alginate bead is a new, highly active adsorbent. In the present study, we investigated its ad- sorption performance and its adsorption mechanism. The adsorption isotherm for fluoride onto lanthanum alginate b ead fits the Langmuir model well, and the maximum adsorption capacity is 197.2 mg·g-1. X-ray diffraction shows the amorphous nature of lanthanum alginate bead, which allows for better accessibility to fluoride and thus better activity. Infrared spectra of lanthanum alginate bead before and after adsorption confirm its stable skeletal structure. Scanning electron microscopy shows that the dense surface structure of the adsorbent appear cracks after adsorption. T he adsorption mechanism of lanthanum alginate bead is considered as an ion exchange between F- and Cl- or OH-, as verified from the adsorbent and the solution by pH effect, energy dispersive X-ray, and ion chromatography.展开更多
The spatial variation and diurnal fluctuation of sea surface wind over the Qiongzhou Strait were described using verified datasets from automatic weather stations on board a ferry, buoys, and on the coast. Results are...The spatial variation and diurnal fluctuation of sea surface wind over the Qiongzhou Strait were described using verified datasets from automatic weather stations on board a ferry, buoys, and on the coast. Results are as follows： （1） On average, sea surface wind speed is 34 m/s larger over the Qiongzhou Strait than in the coastal area. Sea surface wind speeds of 8.0 rrds or above （on Beaufort scale five） in the coastal area are associated with speeds 5-6 m/s greater over the surface of the Qiongzhou Strait. （2） Gust coefficients for the Qiongzhou Strait decrease along with increasing wind speeds. When coastal wind speed is less than scale five, the average gust coefficient over the sea surface is between 1.4 and 1.5; when wind speed is equal to scale five or above, the average gust coefficient is about 1.35. （3） In autumn and winter, the diurnal differences of average wind speed and wind consistency over the strait are less than those in the coastal area; when wind speed is 10.8 m/s （scale six） or above, the diurnal difference of average wind speed decreases while wind consistency increases for both the strait and the coast.展开更多
In-situ transmission electron microscopy(TEM)has been demonstrated to be a powerful method in resolving challenging problems such as interactions among various defects.To take advantage of the atomic resolution of adv...In-situ transmission electron microscopy(TEM)has been demonstrated to be a powerful method in resolving challenging problems such as interactions among various defects.To take advantage of the atomic resolution of advanced TEMs,a compact five-degree-of-freedom nanomanipulator was integrated with an indenter that was made of nanotwinned diamonds,for both the in-situ mechanical testing and double tilting of TEM samples.As a demonstration,in-situ bending tests were performed on the?111?,?110?and?100?single-crystal diamond needles.The tests revealed the{111}cleavage to be the dominant failure mode.The in-situ indentation on a diamond nanoplate led to curved cracks consisting of nanometer-scale steps,which were identified to be atomic flat{111}facets.The atomic-scale observation of the deformation and failure of diamonds demonstrated the stability of the entire system and the durability of the indenter.We expect that more delicate research can be carried out by means of this holder in the near future,including in-situ stimulation,atomic characterization,and tomography.展开更多
A fully flattened carbon nanotube （FNT）, a graphene nanoribbon （GNR） analogue, provides a hollow space at edges for endohedral doping. Due to the unique shape of the hollow space of FNTs, novel types of low-dimens...A fully flattened carbon nanotube （FNT）, a graphene nanoribbon （GNR） analogue, provides a hollow space at edges for endohedral doping. Due to the unique shape of the hollow space of FNTs, novel types of low-dimensional arrangements of atoms and molecules can be obtained through endohedral doping into FNTs, which provides a new type of nanopeapods. FNT-based nanopeapods have been synthesized through endohedral doping of C60, and their structural characterization with transmission electron microscopy （TEM） performed. The doping of C60 into the inner hollow space of FNTs has been carried out via the gas-phase filling method, where open-ended FNTs are sealed in a glass ampoule and heated at 723-773 K for two days. TEM observations show that most of the encapsulated C60 molecules align as single molecular chains along the edges of FNTs and that some of the C60 forms two-dimensional close-packed structures inside FNTs.展开更多
基金Supported by the Major National Science and Technology Special Project on Treatment and Control of Water Pollution(2009ZX07425-006)State Key Laboratory of Environmental Simulation and Pollution Control (09K04ESPCT)
文摘Lanthanum alginate bead is a new, highly active adsorbent. In the present study, we investigated its ad- sorption performance and its adsorption mechanism. The adsorption isotherm for fluoride onto lanthanum alginate b ead fits the Langmuir model well, and the maximum adsorption capacity is 197.2 mg·g-1. X-ray diffraction shows the amorphous nature of lanthanum alginate bead, which allows for better accessibility to fluoride and thus better activity. Infrared spectra of lanthanum alginate bead before and after adsorption confirm its stable skeletal structure. Scanning electron microscopy shows that the dense surface structure of the adsorbent appear cracks after adsorption. T he adsorption mechanism of lanthanum alginate bead is considered as an ion exchange between F- and Cl- or OH-, as verified from the adsorbent and the solution by pH effect, energy dispersive X-ray, and ion chromatography.
基金Research on the Pattern of gales over the Qiongzhou Strait and Forecasting Methods, a project of Natural Science Foundation of China (40765002)Forecasting System of Gales over the Qiongzhou Strait, a key science project for Hainan province (070302)
文摘The spatial variation and diurnal fluctuation of sea surface wind over the Qiongzhou Strait were described using verified datasets from automatic weather stations on board a ferry, buoys, and on the coast. Results are as follows： （1） On average, sea surface wind speed is 34 m/s larger over the Qiongzhou Strait than in the coastal area. Sea surface wind speeds of 8.0 rrds or above （on Beaufort scale five） in the coastal area are associated with speeds 5-6 m/s greater over the surface of the Qiongzhou Strait. （2） Gust coefficients for the Qiongzhou Strait decrease along with increasing wind speeds. When coastal wind speed is less than scale five, the average gust coefficient over the sea surface is between 1.4 and 1.5; when wind speed is equal to scale five or above, the average gust coefficient is about 1.35. （3） In autumn and winter, the diurnal differences of average wind speed and wind consistency over the strait are less than those in the coastal area; when wind speed is 10.8 m/s （scale six） or above, the diurnal difference of average wind speed decreases while wind consistency increases for both the strait and the coast.
基金supported by the National Natural Science Foundation of China(11725210,11672355 and 11702165)the National Key R&D Program of China(2018YFA0703400)。
文摘In-situ transmission electron microscopy(TEM)has been demonstrated to be a powerful method in resolving challenging problems such as interactions among various defects.To take advantage of the atomic resolution of advanced TEMs,a compact five-degree-of-freedom nanomanipulator was integrated with an indenter that was made of nanotwinned diamonds,for both the in-situ mechanical testing and double tilting of TEM samples.As a demonstration,in-situ bending tests were performed on the?111?,?110?and?100?single-crystal diamond needles.The tests revealed the{111}cleavage to be the dominant failure mode.The in-situ indentation on a diamond nanoplate led to curved cracks consisting of nanometer-scale steps,which were identified to be atomic flat{111}facets.The atomic-scale observation of the deformation and failure of diamonds demonstrated the stability of the entire system and the durability of the indenter.We expect that more delicate research can be carried out by means of this holder in the near future,including in-situ stimulation,atomic characterization,and tomography.
文摘A fully flattened carbon nanotube （FNT）, a graphene nanoribbon （GNR） analogue, provides a hollow space at edges for endohedral doping. Due to the unique shape of the hollow space of FNTs, novel types of low-dimensional arrangements of atoms and molecules can be obtained through endohedral doping into FNTs, which provides a new type of nanopeapods. FNT-based nanopeapods have been synthesized through endohedral doping of C60, and their structural characterization with transmission electron microscopy （TEM） performed. The doping of C60 into the inner hollow space of FNTs has been carried out via the gas-phase filling method, where open-ended FNTs are sealed in a glass ampoule and heated at 723-773 K for two days. TEM observations show that most of the encapsulated C60 molecules align as single molecular chains along the edges of FNTs and that some of the C60 forms two-dimensional close-packed structures inside FNTs.
