Lutein was nano-encapsuled with hydroxypropylmethyl cellulose phthalate （HPMCP） to maintain its bioactivity and to avoid thermal/light degradation. Supercritical antisolvent precipitation was applied to prepare lute...Lutein was nano-encapsuled with hydroxypropylmethyl cellulose phthalate （HPMCP） to maintain its bioactivity and to avoid thermal/light degradation. Supercritical antisolvent precipitation was applied to prepare lutein/HPMCP nano-capsule. The effects of several operating parameters on the yield, lutein loading, encapsulation efficiency, particle size and particle size distribution of the nanocapsule were investigated. The mean diameter of nanocapsules ranged from 163 nm to 219 nm under appropriate experimental conditions. The result of scanning electron microscope showed that the nanocapsules were nearly spherical. The highest yield reached 95.35% when the initial concentration of lutein was saturated. The highest lutein loading of 15.80% and encapsulation efficiency of 88,41% were obtained under the conditions of 11 MPa, 40℃ and CHPMCP： Clutein= 5：1. The results may promote the application of lutein in food industry.展开更多
Catechol adsorbed on TiO_(2)is one of the simplest models to explore the relevant properties of dye-sensitized solar cells.However,the effects of water and defects on the electronic levels and the excitonic properties...Catechol adsorbed on TiO_(2)is one of the simplest models to explore the relevant properties of dye-sensitized solar cells.However,the effects of water and defects on the electronic levels and the excitonic properties of the catechol/TiO_(2)interface have been rarely explored.Here,we investigate four catechol/TiO_(2)interfaces aiming to study the influence of coverage,water,and defects on the electronic levels and the excitonic properties of the catechol/TiO_(2)interface through the first-principles many-body Green’s function theory.We find that the adsorption of catechol on the rutile(110)surface increases the energies of both the TiO_(2)valence band maximum and conduction band minimum by approximately 0.7 eV.The increasing coverage and the presence of water can reduce the optical absorption of charge-transfer excitons with maximum oscillator strength.Regarding the reduced hydroxylated TiO_(2)substrate,the conduction band minimum decreases greatly,resulting in a sub-bandgap of 2.51 eV.The exciton distributions in the four investigated interfaces can spread across several unit cells,especially for the hydroxylated TiO2substrate.Although the hydroxylated TiO_(2)substrate leads to a lower open-circuit voltage,it may increase the separation between photogenerated electrons and holes and may therefore be beneficial for improving the photovoltaic efficiency by controlling its concentration.Our results may provide guidance for the design of highly efficient solar cells in future.展开更多
Using the wave model WAVEWATCH III(WW3), we simulated the generation and propagation of typhoon waves in the South China Sea and adjacent areas during the passage of typhoon Nesat(2011). In the domain 100°–145&#...Using the wave model WAVEWATCH III(WW3), we simulated the generation and propagation of typhoon waves in the South China Sea and adjacent areas during the passage of typhoon Nesat(2011). In the domain 100°–145°E and 0°–35°N, the model was forced by the cross-calibrated multi-platform(CCMP) wind fi elds of September 15 to October 5, 2011. We then validated the simulation results against wave radar data observed from an oil platform and altimeter data from the Jason-2 satellite. The simulated waves were characterized by fi ve points along track using the Spectrum Integration Method(SIM) and the Spectrum Partitioning Method(SPM), by which wind sea and swell components of the 1D and 2D wave spectra are separated. There was reasonable agreement between the model results and observations, although the WW3 wave model may underestimate swell wave height. Signifi cant wave heights are large along the typhoon track and are noticeably greater on the right of the track than on the left. Swells from the east are largely unable to enter the South China Sea because of the obstruction due to the Philippine Islands. During the initial stage and later period of the typhoon, swells at the fi ve points were generated by the propagation of waves that were created by typhoons Haitang and Nalgae. Of the two methods, the 2D SPM method is more accurate than the 1D SIM which overestimates the separation frequency under low winds, but the SIM method is more convenient because it does not require wind speed and wave direction. When the typhoon left the area, the wind sea fractions decreased rapidly. Under similar wind conditions, the points located in the South China Sea are affected less than those points situated in the open sea because of the infl uence of the complex internal topography of the South China Sea. The results reveal the characteristic wind sea and swell features of the South China Sea and adjacent areas in response to typhoon Nesat, and provide a reference for swell forecasting and offshore structural designs.展开更多
Let A be a j x d (0,1) matrix. It is known that if j = 2k - 1 is odd, then det(AAT) ≤ (j+1)((j+1)d/4j)j; if j is even, then det(AAT) ≤ (j+1)((j+2)d/4(j+1))j. A is called a regular D-optimal matrix if it satisfies th...Let A be a j x d (0,1) matrix. It is known that if j = 2k - 1 is odd, then det(AAT) ≤ (j+1)((j+1)d/4j)j; if j is even, then det(AAT) ≤ (j+1)((j+2)d/4(j+1))j. A is called a regular D-optimal matrix if it satisfies the equality of the above bounds. In this note, it is proved that if j = 2k - 1 is odd, then A is a regular D-optimal matrix if and only if A is the adjacent matrix of a (2k - 1, k, (j + l)d/4j)-BIBD; if j = 2k is even, then A is a regular D-optimal matrix if and only if A can be obtained from the adjacent matrix B of a (2k + 1,k + 1,(j + 2)d/4(j +1))-BIBD by deleting any one row from B. Three 21 x 42 regular D-optimal matrices, which were unknown in [11], are also provided.展开更多
基金香港中文大学科大卫(David Faure)主持的CCKF资助课题"The conversion of chieftains-territorial godschieftain lineages and the retention of indigenous identity in bord"阶段性成果
基金Supported by the National High Technology Research and Development Program of China(2007AA10Z350)
文摘Lutein was nano-encapsuled with hydroxypropylmethyl cellulose phthalate （HPMCP） to maintain its bioactivity and to avoid thermal/light degradation. Supercritical antisolvent precipitation was applied to prepare lutein/HPMCP nano-capsule. The effects of several operating parameters on the yield, lutein loading, encapsulation efficiency, particle size and particle size distribution of the nanocapsule were investigated. The mean diameter of nanocapsules ranged from 163 nm to 219 nm under appropriate experimental conditions. The result of scanning electron microscope showed that the nanocapsules were nearly spherical. The highest yield reached 95.35% when the initial concentration of lutein was saturated. The highest lutein loading of 15.80% and encapsulation efficiency of 88,41% were obtained under the conditions of 11 MPa, 40℃ and CHPMCP： Clutein= 5：1. The results may promote the application of lutein in food industry.
基金supported by the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2020L0609 and No.2020L0556)the Doctoral research funds of Jinzhong University(jzxybsjjxm2019005)the Basic Research Program in Shanxi Province under the Grant No.20210302124345。
文摘Catechol adsorbed on TiO_(2)is one of the simplest models to explore the relevant properties of dye-sensitized solar cells.However,the effects of water and defects on the electronic levels and the excitonic properties of the catechol/TiO_(2)interface have been rarely explored.Here,we investigate four catechol/TiO_(2)interfaces aiming to study the influence of coverage,water,and defects on the electronic levels and the excitonic properties of the catechol/TiO_(2)interface through the first-principles many-body Green’s function theory.We find that the adsorption of catechol on the rutile(110)surface increases the energies of both the TiO_(2)valence band maximum and conduction band minimum by approximately 0.7 eV.The increasing coverage and the presence of water can reduce the optical absorption of charge-transfer excitons with maximum oscillator strength.Regarding the reduced hydroxylated TiO_(2)substrate,the conduction band minimum decreases greatly,resulting in a sub-bandgap of 2.51 eV.The exciton distributions in the four investigated interfaces can spread across several unit cells,especially for the hydroxylated TiO2substrate.Although the hydroxylated TiO_(2)substrate leads to a lower open-circuit voltage,it may increase the separation between photogenerated electrons and holes and may therefore be beneficial for improving the photovoltaic efficiency by controlling its concentration.Our results may provide guidance for the design of highly efficient solar cells in future.
基金Supported by the National High Technology Research and Development Program of China(863 Program)(No.2013AA122803)the Special Funds for Marine Commonweal Research(No.201305032)the ESA-MOST Dragon 3 Cooperation Program(No.10466)
文摘Using the wave model WAVEWATCH III(WW3), we simulated the generation and propagation of typhoon waves in the South China Sea and adjacent areas during the passage of typhoon Nesat(2011). In the domain 100°–145°E and 0°–35°N, the model was forced by the cross-calibrated multi-platform(CCMP) wind fi elds of September 15 to October 5, 2011. We then validated the simulation results against wave radar data observed from an oil platform and altimeter data from the Jason-2 satellite. The simulated waves were characterized by fi ve points along track using the Spectrum Integration Method(SIM) and the Spectrum Partitioning Method(SPM), by which wind sea and swell components of the 1D and 2D wave spectra are separated. There was reasonable agreement between the model results and observations, although the WW3 wave model may underestimate swell wave height. Signifi cant wave heights are large along the typhoon track and are noticeably greater on the right of the track than on the left. Swells from the east are largely unable to enter the South China Sea because of the obstruction due to the Philippine Islands. During the initial stage and later period of the typhoon, swells at the fi ve points were generated by the propagation of waves that were created by typhoons Haitang and Nalgae. Of the two methods, the 2D SPM method is more accurate than the 1D SIM which overestimates the separation frequency under low winds, but the SIM method is more convenient because it does not require wind speed and wave direction. When the typhoon left the area, the wind sea fractions decreased rapidly. Under similar wind conditions, the points located in the South China Sea are affected less than those points situated in the open sea because of the infl uence of the complex internal topography of the South China Sea. The results reveal the characteristic wind sea and swell features of the South China Sea and adjacent areas in response to typhoon Nesat, and provide a reference for swell forecasting and offshore structural designs.
基金Project supported by the Science Foundation of China for Postdoctors (No.5(2001)).
文摘Let A be a j x d (0,1) matrix. It is known that if j = 2k - 1 is odd, then det(AAT) ≤ (j+1)((j+1)d/4j)j; if j is even, then det(AAT) ≤ (j+1)((j+2)d/4(j+1))j. A is called a regular D-optimal matrix if it satisfies the equality of the above bounds. In this note, it is proved that if j = 2k - 1 is odd, then A is a regular D-optimal matrix if and only if A is the adjacent matrix of a (2k - 1, k, (j + l)d/4j)-BIBD; if j = 2k is even, then A is a regular D-optimal matrix if and only if A can be obtained from the adjacent matrix B of a (2k + 1,k + 1,(j + 2)d/4(j +1))-BIBD by deleting any one row from B. Three 21 x 42 regular D-optimal matrices, which were unknown in [11], are also provided.
