双功能梯度石墨烯片增强金属-陶瓷基圆柱壳的行波振动分析

采用Halpin-Tsai微观力学模型和传递矩阵方法,开展了旋转态双功能梯度石墨烯片增强复合材料圆柱壳体的行波振动特性研究。描述了金属-陶瓷功能梯度基体和5种石墨烯片分布模式的材料属性,基于Love壳理论和传递矩阵方法,考虑转速影响推导了任一截面状态向量的常微分方程和整体传递矩阵关系。以固支-自由(悬臂)边界条件为主,对动力学微分方程进行求解计算,验证了分析方法的合理性。结果表明:低阶模态以轴向半波数为1和周向模态的振动为主,转速引起的科氏力使行波曲线出现分离现象;行波频率随着石墨烯质量分数的增加而增大,分布模式对振型顺序的影响较小,基体体积分数指数对振动特性的影响较大,而石墨烯片层数对振动特性的影响很小,不同倍频激励对共振特性的影响不同。

铜—钨基金属陶瓷导板的研制

采用粉末冶金方法研制出铜—钨基金属陶瓷导板 ,介绍了导板材料的化学成分、试制工艺及对比试验情况 ,试验结果表明 ,这种铜—钨基金属陶瓷材料具有优良的高温耐磨性、热强性、热稳定性及抗氧化性能 ,适用于作优质导卫板。

Effect of VC/Cr_3C_2 on microstructure and mechanical properties of Ti(C,N)-based cermets

Effects of VC/Cr3C2 on the microstructure and mechanical properties of Ti（C,N）-based cermets were studied. The microstructure was investigated by means of optical microscopy, X-ray diffractometry as well as scanning electron microscopy in combination with energy dispersive spectrometry. Mechanical properties, such as transverse rupture strength, hardness and fracture toughness, were measured. The results show that there are black core-grey rim structure and white core-grey rim structure in the microstructure. The grains become fine due to the VC/Cr3C2, and the grains of cermet added with 0.75VC/0.25Cr3C2 are refined most remarkably. The black core becomes finer with the increase of VC addition and rim phase becomes thicker with the decrease of Cr3C2 addition. The porosity increases with the increase of VC addition in VC/Cr3C2. Compared with the cermet free of VC/Cr3C2, the transverse rupture strength and hardness of cermets with VC/Cr3C2 are both improved, and the maximum values are both found for the cermet with 0.25VC/0.75Cr3C2. The fracture toughness can be effectively promoted by adding VC/Cr3C2 with an appropriate ratio of VC to Cr3C2, and the maximum value is found for the cermet with 0.5VC/0.5Cr3C2.

Effect of sintering atmosphere on corrosion resistance of Ni/(NiFe_2O_4-10NiO) cermet inert anode for aluminum electrolysis

A comparative study on the corrosion resistance of 17Ni/（NiFe2O4-10NiO） cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 （volume fraction） are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer （about 50 μm） is thicker than that （about 30 μm） formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe（II） in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.

Hydrogen Permeation Performance of Ni-BaZr0.1Ce0.7Y0.2O3-δ Metal-Ceramic Hollow Fiber Membrane

Acknowledgment： This work was supported by the National Natural Science Foundation of China （No.21076204） and the Basic Research Foundation

Effect of sintering atmosphere on microstructure and properties of TiC based cermets

The effect of the sintering atmospheres (vacuum, N_2, Ar) on the microstructures and properties of the TiC based cermets was studied using XRD, SEM/BSE and energy dispersive spectrometer. Compared with the alloy sintered in vacuum, the carbon content of the specimen sintered in N_2 and Ar is lower by 0.5%; and the nitrogen content is higher by 0.3% when sintered in nitrogen. The central part of the ring structure may be carbide with either a high W or Ti content. The ring structures are (Ti, W, Ta, Mo, Co, Ni)C solid solutions with different metallic elements and distributions. The composition of the binder phase is (Co, Ni) solid solution with different Ti, W, Ta, Mo, C contents. The structures are uniform for the cermets sintered in vacuum and the properties are the best. When sintered in Ar or N2, the O_2 and N2 in the atmosphere take part in the sintering reaction to break the carbon balance in the cermets to form a shell structure and defects, which results in poor density, microhardness (HV) and transverse rupture strength (TRS).

Processing and mechanical properties of network ceramic/steel composites by pressureless infiltration

A new style Ni-containing alumina ceramic foam based continuous three-dimensional interconnected skeleton was prepared by impregnating a polymeric sponge with aqueous ceramic slurry.Subsequently,alumina ceramic foam/steel metal matrix composites(MMCs) were prepared successfully by sand mold casting technique.The microstructure and mechanical properties of MMCs were investigated by SEM,EDS and compressive test.The results show that the depth of infiltration is about 40 μm to the bonding interface of ceramic/steel and the fracture strength σmax and plastic strain limit εp of composite are 520 MPa and 11.2%,respectively.The fretting wear mechanism of MMCs is mainly performed at the oxidative wear mode with lower load/friction frequency and the predominant oxidation wear together with slight adhesive wear and abrasive wear multiple mode with higher load/ friction frequency.Moreover,the infiltration bonding and continuous three-dimensional interconnected ceramic skeleton play a vital role in the stability of the bonding interface and excellent mechanical properties.