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Ag/石墨烯复合涂层的制备及抗菌性能 被引量:9
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作者 田惠博 张强 +4 位作者 闫岩 赵淑华 王丽丽 王欣 孙德烨 《吉林大学学报(理学版)》 CAS 北大核心 2020年第2期403-409,共7页
首先用改进的Hummers法制备氧化石墨烯(GO);其次用原位还原法将银氨溶液中的Ag纳米粒子通过还原剂葡萄糖和GO复合,获得Ag/GO胶体;最后在真空干燥条件下得到Ag/GO涂层,并用真空阶梯热还原技术制备Ag/还原氧化石墨烯(rGO)涂层。利用X射线... 首先用改进的Hummers法制备氧化石墨烯(GO);其次用原位还原法将银氨溶液中的Ag纳米粒子通过还原剂葡萄糖和GO复合,获得Ag/GO胶体;最后在真空干燥条件下得到Ag/GO涂层,并用真空阶梯热还原技术制备Ag/还原氧化石墨烯(rGO)涂层。利用X射线衍射、扫描电子显微镜、透射电子显微镜等方法对膜样品结构形貌进行表征,并用润湿角测量仪和抑菌环方法分别检测样品的亲/疏水性和抗菌性能。实验结果表明:石墨烯基膜材料与基底结合较好,Ag纳米粒子在石墨烯片层间呈球形均匀分布,粒径为20~50nm;纯GO和rGO膜表面未见菌落,大肠杆菌与金黄色葡萄球菌均未出现有效抑菌环;复合Ag纳米粒子后,涂层的抑菌效果得到显著提高;与Ag/GO复合膜相比,Ag/rGO复合膜呈更强的抗菌活性,即低温退火有助于提高石墨烯基复合涂层的抗菌性能。 展开更多
关键词 石墨涂层材料 /石墨抗菌涂层 阶梯热还原
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One-step electrodeposition to fabricate robust superhydrophobic silver/graphene coatings with excellent stability 被引量:2
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作者 De-xin CHEN Ye-qing HE +2 位作者 Qi-wei WANG Wei LI Zhi-xin KANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第10期3321-3333,共13页
A facile method was proposed to prepare stretchable silver-based composite coatings with excellent conductivity and stability for flexible electronics.Silver coating was firstly deposited on thermoplastic polyurethane... A facile method was proposed to prepare stretchable silver-based composite coatings with excellent conductivity and stability for flexible electronics.Silver coating was firstly deposited on thermoplastic polyurethane(TPU)elastomer rubber surface via two-component spraying technique,then the superhydrophobic surface was obtained by one-step electrodeposition of cerium compounds(CeM)and graphene nanosheets(GNS)to produce Ag/CeM/GNS composite coatings.The obtained Ag/CeM/GNS composite coatings maintained high conductivity after experiencing bending cycles and stretching cycles.Furthermore,the as-prepared Ag/CeM/GNS composite coatings showed excellent self-cleaning and anti-fouling properties,and the corrosion resistance has improved significantly compared to the original Ag coating.In addition,the Ag/CeM/GNS composite coatings could drive the circuit normally in the states of tensile,bending and twisting deformation,showing excellent mechanical stability and applicability.As a result,it is believed that the prepared Ag/CeM/GNS composite coatings with excellent conductivity and stability have promising applications for flexible electronics in harsh conditions. 展开更多
关键词 silver/graphene coating SUPERHYDROPHOBICITY one-step electrodeposition STABILITY
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