The launderability of wool fabrics treated by nano finoshing agent influences directly the functional endurance of he treated wool fabric. In order to investigate the effect of wool fibers surface modification on the ...The launderability of wool fabrics treated by nano finoshing agent influences directly the functional endurance of he treated wool fabric. In order to investigate the effect of wool fibers surface modification on the functional erdurance of nano finishinp wool fibers, in this paper, for the first time wool fibers were chemically modified by using NaClO aqueous and KMnO4 aqueous, and then chemically modified wool fibers and native wool fibers were treated using nano ZnO finishing agent, respectively. The launderability of wool fibers treated by nano finishing agent was investigated. The experimental results show that the chemically modified wool fibers have a good launderaility after being treated by nano ZnO finishing agent treating. The surface morphologies of wool fibers were observed by using SEM. It is got that there is a strong adbesion between nano ZnO and wool surface through XPS analysis.展开更多
Most Zn hydrometallurgy factories adopt Cu2SO4 as a dechlorination reagent from zinc solution nowadays, thus much CuCl residue is produced. The existing process of treating this residue is washing with water or sodium...Most Zn hydrometallurgy factories adopt Cu2SO4 as a dechlorination reagent from zinc solution nowadays, thus much CuCl residue is produced. The existing process of treating this residue is washing with water or sodium carbonate solution, which would cause a lot of troubles to water treatment and waste discharge. A method of microwave roasting was adopted for dechlorination of CuCl residue. A 1.5 kW microwave roasting equipment with dust collection and tail gas adsorption systems was set up and applied during the experiment. By investigating the effect of temperature, heat preservation time, moisture content of raw material and grain size of samples on the dechlorination, the optimal experimental condition is obtained. When the samples with 2% moisture and <150 μm grain size are microwave roasted at 400 °C for 2 h, the Cl content turns from 14.27% to 1.35% and the dechlorination rate is as high as 90%, while that with conventional heating is only 60%-80%. The phase change of the roasting process investigated with X-ray diffraction verifies that CuCl in CuCl residue is removed by being transformed into CuO.展开更多
文摘The launderability of wool fabrics treated by nano finoshing agent influences directly the functional endurance of he treated wool fabric. In order to investigate the effect of wool fibers surface modification on the functional erdurance of nano finishinp wool fibers, in this paper, for the first time wool fibers were chemically modified by using NaClO aqueous and KMnO4 aqueous, and then chemically modified wool fibers and native wool fibers were treated using nano ZnO finishing agent, respectively. The launderability of wool fibers treated by nano finishing agent was investigated. The experimental results show that the chemically modified wool fibers have a good launderaility after being treated by nano ZnO finishing agent treating. The surface morphologies of wool fibers were observed by using SEM. It is got that there is a strong adbesion between nano ZnO and wool surface through XPS analysis.
基金Project(51104073)supported by the National Natural Science Foundation of China
文摘Most Zn hydrometallurgy factories adopt Cu2SO4 as a dechlorination reagent from zinc solution nowadays, thus much CuCl residue is produced. The existing process of treating this residue is washing with water or sodium carbonate solution, which would cause a lot of troubles to water treatment and waste discharge. A method of microwave roasting was adopted for dechlorination of CuCl residue. A 1.5 kW microwave roasting equipment with dust collection and tail gas adsorption systems was set up and applied during the experiment. By investigating the effect of temperature, heat preservation time, moisture content of raw material and grain size of samples on the dechlorination, the optimal experimental condition is obtained. When the samples with 2% moisture and <150 μm grain size are microwave roasted at 400 °C for 2 h, the Cl content turns from 14.27% to 1.35% and the dechlorination rate is as high as 90%, while that with conventional heating is only 60%-80%. The phase change of the roasting process investigated with X-ray diffraction verifies that CuCl in CuCl residue is removed by being transformed into CuO.
