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农田沟道土壤中锰氨氧化(Mn-ANAMMOX)过程的探究 被引量:3
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作者 陈湜 李正魁 +2 位作者 覃云斌 丁帮璟 陈志浩 《环境科学》 EI CAS CSCD 北大核心 2019年第6期2948-2953,共6页
二氧化锰介导的厌氧氨氧化(锰氨氧化)是最近发现的一种新型微生物脱氮途径,然而很少有研究报道农田沟道中的锰氨氧化过程和反应过程中主要微生物群落锰还原菌.本研究经过340 d锰还原菌富集培养实验,采用同位素示踪技术和高通量测序技术... 二氧化锰介导的厌氧氨氧化(锰氨氧化)是最近发现的一种新型微生物脱氮途径,然而很少有研究报道农田沟道中的锰氨氧化过程和反应过程中主要微生物群落锰还原菌.本研究经过340 d锰还原菌富集培养实验,采用同位素示踪技术和高通量测序技术,证实了锰氨氧化在农田沟道土壤中的存在.结果表明,在锰氨氧化过程中可以观察到氨氮的氧化和MnO_2的还原,以及NO_2^-、NO_3^-、^(30)N_2和Mn^(2+)的产生,锰氨氧化平均速率为2. 88 mg·(kg·d)^(-1),氨氮平均去除率为20%,总氮去除率平均可达15%.另外,高通量测序结果表明,经过340 d富集培养实验,在门水平上锰还原菌丰度从原来的27%增加到了70%,其主要的锰还原菌为不动杆菌(Acinetobacter)和地发菌属(Geothrix),相对丰度分别为26. 63%和4. 07%.实验结果证实了农田沟道中存在二氧化锰介导的厌氧氨氧化过程,可以认为锰氨氧化是微生物脱氮过程的一条重要路径. 展开更多
关键词 锰氨氧化 还原菌 同位素标记 高通量测序 氮去除
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Understanding the roles of Brønsted/Lewis acid sites on manganese oxide-zeolite hybrid catalysts for low-temperature NH_(3)-SCR
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作者 Hyun Sub Kim Hwangho Lee +2 位作者 Hongbeom Park Inhak Song Do Heui Kim 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第10期79-88,共10页
Although metal oxide-zeolite hybrid materials have long been known to achieve enhanced catalytic activity and selectivity in NO_(x)removal reactions through the inter-particle diffusion of intermediate species,their s... Although metal oxide-zeolite hybrid materials have long been known to achieve enhanced catalytic activity and selectivity in NO_(x)removal reactions through the inter-particle diffusion of intermediate species,their subsequent reaction mechanism on acid sites is still unclear and requires investigation.In this study,the distribution of Brønsted/Lewis acid sites in the hybrid materials was precisely adjusted by introducing potassium ions,which not only selectively bind to Brønsted acid sites but also potentially affect the formation and diffusion of activated NO species.Systematic in situ diffuse reflectance infrared Fourier transform spectroscopy analyses coupled with selective catalytic reduction of NO_(x)with NH_(3)(NH_(3)-SCR)reaction demonstrate that the Lewis acid sites over MnO_(x)are more active for NO reduction but have lower selectivity to N_(2)than Brønsted acids sites.Brønsted acid sites primarily produce N_(2),whereas Lewis acid sites primarily produce N_(2)O,contributing to unfavorable N_(2)selectivity.The Brønsted acid sites present in Y zeolite,which are stronger than those on MnO_(x),accelerate the NH_(3)-SCR reaction in which the nitrite/nitrate species diffused from the MnO_(x)particles rapidly convert into the N_(2).Therefore,it is important to design the catalyst so that the activated NO species formed in MnO_(x)diffuse to and are selectively decomposed on the Brønsted acid sites of H-Y zeolite rather than that of MnO_(x)particle.For the physically mixed H-MnO_(x)+H-Y sample,the abundant Brønsted/Lewis acid sites in H-MnO_(x)give rise to significant consumption of activated NO species before their inter-particle diffusion,thereby hindering the enhancement of the synergistic effects.Furthermore,we found that the intercalated K+in K-MnO_(x)has an unexpected favorable role in the NO reduction rate,probably owing to faster diffusion of the activated NO species on K-MnO_(x)than H-MnO_(x).This study will help to design promising metal oxide-zeolite hybrid catalysts by identifying the role of the acid sites in two different constituents. 展开更多
关键词 Hybrid metal oxide-zeolite The role of acid sites Manganese oxides Physical mixing Selective catalytic reduction of NOx with NH3
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铁/锰矿基人工湿地脱氮除磷性能及机理 被引量:3
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作者 卓亿元 刘草葱 +8 位作者 姜蕾 马江森 马锐 程麟凇 毛圆翔 沈秋实 赵刘伟 许晓毅 吉芳英 《环境工程学报》 CAS CSCD 北大核心 2023年第5期1441-1450,共10页
铁氧化物和锰氧化物均可在缺氧条件下介导氨氮(NH_(4)^(+)-N)的氧化去除,这2项技术被称为铁氨氧化(Feammox)和锰氨氧化(Mnammox)。此外,金属氧化物对总磷(TP)也有去除能力,因此,在人工湿地中具有良好的应用前景。为比较铁矿基和锰矿基... 铁氧化物和锰氧化物均可在缺氧条件下介导氨氮(NH_(4)^(+)-N)的氧化去除,这2项技术被称为铁氨氧化(Feammox)和锰氨氧化(Mnammox)。此外,金属氧化物对总磷(TP)也有去除能力,因此,在人工湿地中具有良好的应用前景。为比较铁矿基和锰矿基人工湿地的脱氮除磷效果,本研究建立了铁矿基人工湿地(CW-Fe)、锰矿基人工湿地(CW-Mn)和砾石对照组人工湿地(CW-C)3组人工湿地。结果表明,CW-Fe和CW-Mn的脱氮除磷性能均优于CW-C。尽管锰矿对NH_(4)^(+)-N的吸附作用最强,但CW-Fe却表现出了更优越的NH_(4)^(+)-N长期去除性能。在基质对NH_(4)^(+)-N的吸附饱和后,CW-Fe对NH_(4)^(+)-N的去除率仍有39.93%~62.4%,而CW-Mn只有29.15%~35.4%。由于铁矿和锰矿溶出的金属离子能与磷酸盐结合形成稳定的沉淀,从而有效去除TP,CW-Fe和CW-Mn均有优异的TP去除性能。CW-Mn的TP去除率最高,为95.26%,其次是CW-Fe,为79.97%。在微生物方面,具有还原铁氧化物和氧化NH_(4)^(+)-N潜力的Bacillus和Exiguobacterium在CW-Fe中均得到了显著富集。结合水质数据及脱氮相关功能菌的分析,推测出Feammox中可能更倾向于将NH_(4)^(+)-N直接氧化为N_(2),而Mnammox则是更倾向于先将NH_(4)^(+)-N氧化为NO_(x)^(-)-N。本研究可为探索同步脱氮除磷的低能耗污水处理工艺及人工湿地中基质的选择提供案例参考。 展开更多
关键词 人工湿地 氧化 锰氨氧化 营养物质去除
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Product selectivity controlled by manganese oxide crystals in catalytic ammoxidation 被引量:1
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作者 Hai Wang Qingsong Luo +4 位作者 Liang Wang Yu Hui Yucai Qin Lijuan Song Feng-Shou Xiao 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第12期2164-2172,共9页
The performances of heterogeneous catalysts can be effectively tuned by changing the catalyst structures.Here we report a controllable nitrile synthesis from alcohol ammoxidation,where the nitrile hydration side react... The performances of heterogeneous catalysts can be effectively tuned by changing the catalyst structures.Here we report a controllable nitrile synthesis from alcohol ammoxidation,where the nitrile hydration side reaction could be efficiently prevented by changing the manganese oxide catalysts.α-Mn_(2)O_(3)based catalysts are highly selective for nitrile synthesis,but MnO_(2)-based catalysts includingα,β,γ,andδphases favour the amide production from tandem ammoxidation and hydration steps.Multiple structural,kinetic,and spectroscopic investigations reveal that water decomposition is hindered onα-Mn2O3,thus to switch off the nitrile hydration.In addition,the selectivity-control feature of manganese oxide catalysts is mainly related to their crystalline nature rather than oxide morphology,although the morphological issue is usually regarded as a crucial factor in many reactions. 展开更多
关键词 Manganese oxide AMMOXIDATION NITRILE AMIDE Crystal structure
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Transcript profiles of mitochondrial and cytoplasmic manganese superoxide dismutases in Exopalaemon carinicauda under ammonia stress 被引量:2
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作者 任海 李健 +3 位作者 李吉涛 刘萍 梁忠秀 吴建华 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2015年第3期714-724,共11页
Superoxide dismutase (SOD) is one of the most important antioxidant defense enzymes, and is considered as the first line against oxidative stress. In this study, we cloned a mitochondrial manganese (Mn) SOD (mMn... Superoxide dismutase (SOD) is one of the most important antioxidant defense enzymes, and is considered as the first line against oxidative stress. In this study, we cloned a mitochondrial manganese (Mn) SOD (mMnSOD) cDNA from the ridgetail white prawn Exopalaemon carinicauda by using rapid amplification of cDNA ends (RACE) methods. The fulMength cDNA for mMnSOD was 1 014-bp long, containing a 5'-untranslated region (UTR) of 37-bp, a 3'-UTR of 321-bp with a poly (A) tail, and included a 657-bp open reading frame encoding a protein of 218 amino acids with a 16-amino-acid signal peptide. The protein had a calculated molecular weight of 23.87 kDa and a theoretical isoelectric point of 6.75. The mMnSOD sequence included two putative N-glycosylation sites (NHT and NLS), the MnSOD signature sequence 18~DVWEHAYY^87, and four putative Mn binding sites (H48, H96, D180, and H184). Sequence comparison showed that the mMnSOD deduced amino acid sequence of E. carinicauda shared 97%, 95%, 89%, 84%, 82%, 72%, and 69% identity with that ofMacrobrachium rosenbergii, Macrobrachium nipponense, Fenneropeneaus chinensis, Callinectes sapidus, Perisesarma bidens, Danio rerio, and Homo sapiens, resectively. Quantitative real-time RT-PCR analysis showed that mMnSOD transcripts were present in all E. carinicauda tissues examined, with the highest levels in the hepatopancreas. During an ammonia stress treatment, the transcript levels of mMnSOD and cMnSOD were up-regulated at 12 h in hemocytes and at 24 h in the hepatopancreas. As the duration of the ammonia stress treatment extended to 72 h, the transcript levels of mMnSOD and cMnSOD significantly decreased both in hemocytes and hepatopancreas. These findings indicate that the SOD system is induced to respond to acute ammonia stress, and may be involved in environmental stress responses in E. carinicauda. 展开更多
关键词 Exopalaemon carinicauda mitochondrial manganese superoxide dismutase (mMnSOD) cytosolic manganese superoxide dismutase (cMnSOD) CLONING expression
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Synthesis, oxygenation and catalytic performance of manganese complex with p-aminomethyl benzoic acid Schiff base
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作者 刘丰良 李元建 +1 位作者 黄可龙 肖震 《Journal of Central South University of Technology》 EI 2007年第6期793-797,共5页
The amino acid Schiff base complex (Sal-AMBA-Mn) was prepared with p-amino-methylbenzoic acid, salicylaldehyde and Mn(OAc)2·4H2O. Its structures was characterized with IR and UV spectra. Oxygenation mechanism of ... The amino acid Schiff base complex (Sal-AMBA-Mn) was prepared with p-amino-methylbenzoic acid, salicylaldehyde and Mn(OAc)2·4H2O. Its structures was characterized with IR and UV spectra. Oxygenation mechanism of the complex in N, N-dimethylformamide solution was investigated. The results show that lower temperature is in favor of the oxygenation, and energy, enthalpy and entropy are -3.8 kJ/mol, -4.2 J/mol and -161.44 J/(mol·K), respectively. In the presence of the manganese complex, dehydroepiandrosterone acetate is effectively oxidized by molecular oxygen and the corresponding enone 7-ketodehydroepiandrosterone acetate is obtained. The yield is 62.1% when the oxidation is carried out under the reaction conditions of 60 ℃, 2 MPa of O2 pressure, C5H5N as a solvent and molar ratio of the substrate to the complex of 1:10. 展开更多
关键词 amino acid Schiff base manganese complex OXYGENATION catalysis dehydroepiandrosterone acetate aerobic oxidation
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