This work adopts a multi⁃step etching⁃heat treatment strategy to prepare porous silicon microsphere com⁃posite with Sb⁃Sn surface modification and carbon coating(pSi/Sb⁃Sn@C),using industrial grade SiAl alloy micro⁃sp...This work adopts a multi⁃step etching⁃heat treatment strategy to prepare porous silicon microsphere com⁃posite with Sb⁃Sn surface modification and carbon coating(pSi/Sb⁃Sn@C),using industrial grade SiAl alloy micro⁃spheres as a precursor.pSi/Sb⁃Sn@C had a 3D structure with bimetallic(Sb⁃Sn)modified porous silicon micro⁃spheres(pSi/Sb⁃Sn)as the core and carbon coating as the shell.Carbon shells can improve the electronic conductivi⁃ty and mechanical stability of porous silicon microspheres,which is beneficial for obtaining a stable solid electrolyte interface(SEI)film.The 3D porous core promotes the diffusion of lithium ions,increases the intercalation/delithia⁃tion active sites,and buffers the volume expansion during the intercalation process.The introduction of active met⁃als(Sb⁃Sn)can improve the conductivity of the composite and contribute to a certain amount of lithium storage ca⁃pacity.Due to its unique composition and microstructure,pSi/Sb⁃Sn@C showed a reversible capacity of 1247.4 mAh·g^(-1) after 300 charge/discharge cycles at a current density of 1.0 A·g^(-1),demonstrating excellent rate lithium storage performance and enhanced electrochemical cycling stability.展开更多
The solar temperature field of a large three-span continuous bridge with steel-concrete composite box girder and variable cross-section is measured to verify a calculation method for the temperature field of steel-con...The solar temperature field of a large three-span continuous bridge with steel-concrete composite box girder and variable cross-section is measured to verify a calculation method for the temperature field of steel-concrete composite beams. The test results show that the temperature of an external steel web- plate is higher than that of an internal web-plate due to the difference in solar radiation. Air temperature inside the box matches the average temperature of the whole steel box. Based on actual measurements, a transient thermal analysis with multiple boundary conditions is also carried out by a software program ANSYS. Convective boundary situation and states of solar radiation on steel web plates in different situations are determined in the analysis. The feature of the temperature field is preliminarily achieved through a comparative study between the actual measurement and the finite element analysis. The computed results are in good consistence with the actual measurement results, with the maximum difference within 2 ℃. This indicates that the theoretical calculation method is reliable and it provides a foundation for further research on temperature field distribution in the steel-concrete composite box girder.展开更多
文摘This work adopts a multi⁃step etching⁃heat treatment strategy to prepare porous silicon microsphere com⁃posite with Sb⁃Sn surface modification and carbon coating(pSi/Sb⁃Sn@C),using industrial grade SiAl alloy micro⁃spheres as a precursor.pSi/Sb⁃Sn@C had a 3D structure with bimetallic(Sb⁃Sn)modified porous silicon micro⁃spheres(pSi/Sb⁃Sn)as the core and carbon coating as the shell.Carbon shells can improve the electronic conductivi⁃ty and mechanical stability of porous silicon microspheres,which is beneficial for obtaining a stable solid electrolyte interface(SEI)film.The 3D porous core promotes the diffusion of lithium ions,increases the intercalation/delithia⁃tion active sites,and buffers the volume expansion during the intercalation process.The introduction of active met⁃als(Sb⁃Sn)can improve the conductivity of the composite and contribute to a certain amount of lithium storage ca⁃pacity.Due to its unique composition and microstructure,pSi/Sb⁃Sn@C showed a reversible capacity of 1247.4 mAh·g^(-1) after 300 charge/discharge cycles at a current density of 1.0 A·g^(-1),demonstrating excellent rate lithium storage performance and enhanced electrochemical cycling stability.
文摘The solar temperature field of a large three-span continuous bridge with steel-concrete composite box girder and variable cross-section is measured to verify a calculation method for the temperature field of steel-concrete composite beams. The test results show that the temperature of an external steel web- plate is higher than that of an internal web-plate due to the difference in solar radiation. Air temperature inside the box matches the average temperature of the whole steel box. Based on actual measurements, a transient thermal analysis with multiple boundary conditions is also carried out by a software program ANSYS. Convective boundary situation and states of solar radiation on steel web plates in different situations are determined in the analysis. The feature of the temperature field is preliminarily achieved through a comparative study between the actual measurement and the finite element analysis. The computed results are in good consistence with the actual measurement results, with the maximum difference within 2 ℃. This indicates that the theoretical calculation method is reliable and it provides a foundation for further research on temperature field distribution in the steel-concrete composite box girder.
