粉末粒度对于高温钨渗铜材料骨架性能的影响

高温钨渗铜材料是由高温烧结钨骨架经熔渗金属铜而制成的互不固溶型复合材料 ,钨骨架的连续程度、钨颗粒的连接状态以及孔隙形态和大小等因素将直接影响材料的使用性能。本文从钨粉粒度的角度出发 ,研究其对于钨渗铜材料骨架性能的影响 ,实验表明 ,在相同的烧结制度 (2 2 30℃× 5h)下 ,细颗粒钨粉所得到的骨架密度比中颗粒钨粉所得到的要高 ,但其内部形成大量封闭孔隙 ,使得其连通性能不及中颗粒钨粉所得骨架 ,不利于金属铜的熔渗 ;对于相近骨架密度 (86± 0 5 % )的两种试样 ,从渗铜结果来看 ,二者的骨架连通性能相当。从SEM照片来看 ,细颗粒钨骨架的晶粒尺寸明显比同骨架密度中颗粒钨骨架的晶粒尺寸小 ,高温拉伸结果显示细颗粒钨渗铜材料比相应中颗粒钨渗铜材料的强度要高的多 ,这一点说明了钨骨架的晶粒细化对钨渗铜材料有明显的强化作用。

一种面向构件化并行应用程序的性能骨架分析方法

性能骨架分析技术通过刻画并行应用程序的程序结构,为并行应用程序性能建模提供输入,是大规模并行应用程序性能分析、性能优化的基础。文中针对数值模拟领域中的一类构件化并行应用程序,在面向通用程序二进制文件的动静态结构分析技术的基础上,提出并实现了一种基于"构件-循环-调用"关系树(Component-Loop-Call-Tree, CLCT)的程序结构自动化生成方法,在此基础上,研制了一种面向构件化并行应用程序的性能骨架分析工具(CLCT SkeleTon Analysis Toolkit, CLCT-STAT)。该方法可以自动识别构件化应用程序中构件类成员函数符号,生成以构件为最小单位的并行应用程序性能骨架。在多个构件化并行应用程序上的测试表明,相比分析建模手动生成性能骨架的方法,所提方法不仅能提供更丰富的程序结构信息,还可以节约人工分析的时间成本。

骨架密实型水泥稳定碎石性能影响因素研究

研究了含水量、水泥剂量、集料类型等因素对骨架密实型水泥稳定碎石性能的影响。结果显示对于同样的级配,水泥剂量越大,最大干密度、无侧限抗压强度、劈裂强度和干缩变形越大。压实含水量和水泥剂量会影响水泥稳定碎石基层中的结合水的含量,进而对混合料的干缩特性造成影响。最佳含水量下随着水泥含量的增加,干缩系数变大。

Seismic performance of double- skin steel- concrete composite box piers: Part Ⅰ——Bidirectional quasi-static testing

To study the seismic performance of double-skin steelconcrete composite box（ DSCB） piers, a total of 11 DSCB pier specimens were tested under bidirectional cyclic loading. The effects of the loading pattern, the steel plate thickness, the axial load ratio, the slenderness ratio and the aspect ratio were taken into consideration. The damage evolution process and failure modes of the tested specimens are presented in detail. Test results are also discussed in terms of the hysteretic curve, skeleton curve, ductility and energy dissipation capacity of DSCB pier specimens. It can be concluded that the hysteretic performance of DSCB piers in one direction is affected and weakened by the cyclic loading in the other direction. DSCB piers under bidirectional cyclic loading exhibit good performance in terms of load carrying capacity, ductility, and energy dissipation capacity. Overall, DSCB piers can meet the basic aseismic requirements. The research results can be taken as a reference for using DSCB piers as high piers in bridges in strong earthquakeprone areas.

Design of dense gap-graded friction course mixture

The design procedure of a dense gap-graded friction course（DGGFC） with coarse aggregate void filling method is presented. Testing results show that a DGGFC mixture possesses a dense stone-matrix structure, good stability and almost the same texture depth as stone matrix asphalt （SMA）. It also has a coarse and even surface after paving and has no separation during construction. It is durable and impermeable. It balances and improves the inherent inconsistency of asphalt mixture between the large texture depth for skid resistance and the impermeability for durability. The actual application in the Nanning-Liuzhou Expressway also shows that the performance of the DGGFC is as excellent as that of SMA, while the DGGFC mixture is cheaper than SMA. The DGGFC mixture is good for wearing course of pavement. Further research on DGGFC can be helpful for improving the surface skid resistance, prolonging the life-span period and reducing the construction costs of asphalt pavement.

Seismic performance of double-skin steel-concrete composite box piers: Part Ⅱ—Nonlinear finite element analysis

An accurate finite element （ FE） model was constructed to examine the hysteretic behavior of double-skin steel-concrete composite box （ DSCB） piers for further understanding the seismic performance of DSCB piers; where the local buckling behavior of steel tubes, the confinement of the in-filled concrete and the interface action between steel tube and in-filled concrete were considered. The accuracy of the proposed FE model was verified by the bidirectional cyclic loading test results. Based on the validated FE model, the effects of some key parameters, such as section width to steel thickness ratio, slenderness ratio, aspect ratio and axial load ratio on the hysteretic behavior of DSCB piers were investigated. Finally, the skeleton curve model of DSCB piers was proposed. The numerical simulation results reveal that the peak strength and elastic stiffness decrease with the increase of the section width to steel thickness ratio. Moreover, the increase of the slenderness ratio may result in a significant reduction in the peak strength and elastic stiffness while the ultimate displacement increases. The proposed skeleton curve model can be taken as a reference for seismic performance analyses of the DSCB piers.

Design of metal-organic frameworks(MOFs)-based photocatalyst for solar fuel production and photo-degradation of pollutants

Metal organic frameworks(MOFs)is a research hotspot in the solar fuel production and photo-degradation of pollutants field due to high surface area,rich metal/organic species,large pore volume,and adjustability of structures and compositions.Therefore,in this review,we first summarized the design factors of photocatalytic materials based on MOF from the perspective of"star"MOF.The modification strategies of MOFs-based photocatalysts were discussed to improve its photocatalytic activity and specific applications were summarized as well,including photocatalytic CO_(2)reduction,photocatalytic water splitting and photo-degradation of pollutants.Finally,the advantages and disadvantages of MOFs-based photocatalysts were discussed,the current challenges were highlighted,and suggestions for future research directions were proposed.

Fine decoration of carbon nanotubes with metal organic frameworks for enhanced performance in supercapacitance and oxygen reduction reaction

Efficient electrode material is crucial for energy conversion from renewable sources such as solar electricity. We present a method for preparation of carbon nanotubes （CNTs） with zeolitic imidazolate frameworks （ZIFs, e.g., ZIF-8） via an in situ pyrolysis process. The resultant materials are completely new carbon composites with desirable hierarchical porosity and nitrogen-doped features. Electron microscopy images show that CNTs with small external diameters enable more uniform dispersion of ZlF-8-derived carbons, subsequently yielding a unique hierarchically porous structure. Such carbon shows superior activity in oxygen reduction reaction （ORR） and high performance of supercapacitance, making it a valu- able metal-flee electrode material and a competent alternative to the state-of-the-art Pt/C catalyst. The electrocatalytic performance of CNTs can be dramatically improved by the incorporation of ZIF-8-derived carbons, which is attributed to the combination of good conductivity, abundant accessible dopant species, as well as proper porosity. Our method offers a new avenue for constructing electrocatalysts by effective integration of ZlF-8-derived carbon and the CNTs skeleton.

Structure evolution of thiophene-containing conjugated polymer photocatalysts for high-efficiency photocatalytic hydrogen production

Conjugated polymer photocatalysts have received extensive attention in the field of photocatalytic hydrogen evolution owing to their tunable molecular structures and electronic properties.Herein,we developed three donoracceptor(D-A)type thiophene-containing narrow-band-gap conjugated polymers with pyrene as a donor and different fused-thiophene derivatives as acceptors via direct C-H arylation coupling polymerization.It was found that the band gap of the polymers can be tuned by adjusting the number of the fused-thiophene rings.The visible light absorption range can be extended by increasing the number of the thiophene rings,the planar molecular structure for both donor and acceptor units facilitates the charge transmission along the polymer skeleton,and the D-A type polymer structure promotes the dissociation of photo-induced electrons and holes.As a result,a high photocatalytic hydrogen evolution rate of 33.07 mmol h^(−1)g^(−1) was obtained by PyTP-2 with an optimized molecular structure under visible light irradiation(λ>420 nm)without the aid of Pt co-catalyst.In addition,PyTP-2 also shows a photocatalytic activity for oxygen evolution with an average oxygen evolution rate of 58.37µmol h^(−1)g^(−1).