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3D scattering of obliquely incident plane SV waves by an alluvial valley embedded in a fluid-saturated, poroelastic layered half-space 被引量:3
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作者 Zhenning Ba Jianwen Liang Xiongyi Mei 《Earthquake Science》 2013年第2期107-116,共10页
The indirect boundary element method is used to study the 3D dynamic response of an infinitely long alluvial valley embedded in a saturated layered half-space for obli- quely incident SV waves. A wave-number transform... The indirect boundary element method is used to study the 3D dynamic response of an infinitely long alluvial valley embedded in a saturated layered half-space for obli- quely incident SV waves. A wave-number transform is first applied along the valley's axis to reduce a 3D problem to a 2D plane strain problem. The problem is then solved in the section perpendicular to the axis of the valley. Finally, the 3D dynamic responses of the valley are obtained by an inverse wave-number transform. The validity of the method is con- firmed by comparison with relevant results. The differences between the responses around the valley embedded in dry and in saturated poroelastic medium are studied, and the effects of drainage conditions, porosity, soil layer stiffness, and soil layer thickness on the dynamic response are dis- cussed in detail resulting in some conclusions. 展开更多
关键词 Saturated layered half-space 3D scattering Alluvial valley Plane SV wavesMoving Green's functions
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B3Y-FETAL effective interaction in the folding analysis of elastic scattering of ^(16)O+^(16)O 被引量:1
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作者 I.Ochala J.O.Fiase 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2021年第8期34-47,共14页
In this paper,a new M3Y-type effective nucleon–nucleon interaction,derived based on the lowest order constrained variational approach(LOCV)and termed B3Y-Fetal,has been used in DDM3Y1,BDM3Y1,BDM3Y2,and BDM3Y3 density... In this paper,a new M3Y-type effective nucleon–nucleon interaction,derived based on the lowest order constrained variational approach(LOCV)and termed B3Y-Fetal,has been used in DDM3Y1,BDM3Y1,BDM3Y2,and BDM3Y3 density-dependent versions in a heavy ion(HI)optical potential based on four types of a real folded potential and a phenomenological Woods–Saxon imaginary potential to study the elastic scattering of the^(16)O+^(16)O nuclear system within the framework of the optical model(OM)by computing the associated differential cross sections at various incident energies.The results of the folding analyses have shown the DDB3Y1-Fetal and BDB3Y1-Fetal,out of the four folded potentials,give a reasonably better description of the elastic data of the nuclear system.These best-fit folded potentials are followed,in performance,by the BDB3Y2-Fetal,with the BDB3Y3-Fetal potential coming last.This performance trend was also demonstrated by the optical potentials based on the M3Y-Reid interaction.Furthermore,the best-fit folded potentials,renormalized by a factor NRof approximately 0.9,have been shown to reproduce the energy dependence of the real optical potential for^(16)O scattering found in previous optical model analyses creditably well.In excellent agreement with previous works,they have also been identified in this work to belong to the family of deep refractive potentials because they have been able to reproduce and consistently describe the evolution of Airylike structures,at large scattering angles,observed in the^(16)O scattering data at different energies.Finally,a comparison of the performances of B3Y-Fetal and M3Y-Reid effective interactions undertaken in this work has shown impressive agreement between them. 展开更多
关键词 B3Y-Fetal Folding analysis Elastic scattering Optical model Incident energies
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Generalized 3D Scattering Channel Model with MIMO Antenna Systems 被引量:5
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作者 Jie Zhou Hao Jiang Hisakazu Kikuchi 《China Communications》 SCIE CSCD 2016年第5期66-81,共16页
In this paper, a generalized three-dimensional(3D) scattering channel model for macrocellular land mobile environments is considered. This model simultaneously describes angular arrival of multi-path signals in the az... In this paper, a generalized three-dimensional(3D) scattering channel model for macrocellular land mobile environments is considered. This model simultaneously describes angular arrival of multi-path signals in the azimuth and elevation planes in an environment where uniformly distributed scatterers are assumed to be present in hemispheroids around the base station(BS) and mobile station(MS). Using this channel model, we first derive the closed-form expression for the joint and marginal probability density functions of the angle-of-arrival and time-of-arrival measured at the BS and the MS corresponding to the azimuth and elevation angles. Next, we derive an expression for the Doppler spectral distribution caused by motion of the MSs. Furthermore, we analyze the performance of multiple-input multiple-output antenna systems numerically. The results show that the proposed 3D scattering channel model performs better than previously proposed two-dimensional(2D) models for indoor and outdoor environments. We compare the results with previous scattering channel models and measurement results to validate the generalizability of our model. 展开更多
关键词 3D scattering channel model angle of arrival Doppler spectra multiple-input multiple-output
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Structural properties of Bi_(1-x)La_xFeO_3 studied by micro-Raman scattering
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作者 杨洋 刘玉龙 +4 位作者 朱恪 张丽艳 马树元 刘洁 将毅坚 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第3期551-556,共6页
This paper reports that La-doped BiFeO3 (Bil-xLaxFeO3, x = 0, 0.1, 0.2, 0.3, 0.6, 0.8 and 1.0) were studied by using micro-Raman spectroscopy and x-ray diffraction (XRD). The XRD patterns indicate that the structu... This paper reports that La-doped BiFeO3 (Bil-xLaxFeO3, x = 0, 0.1, 0.2, 0.3, 0.6, 0.8 and 1.0) were studied by using micro-Raman spectroscopy and x-ray diffraction (XRD). The XRD patterns indicate that the structure of Bi1-xLaxFeO3 changes from rhombohedral BiFeO3 to orthorhombic LaFeO3. The results of Raman spectroscopy show good agreement with the XRD results. Strikingly, the phonon peak at around 610 cm^-1 and the two-phonon peaks in the high frequency range exist in all compounds and enhance with increasing La substitution. The increasing intensity of the 610 cm-1 peak is attributed to the changes in the FeO6 octahedron during the rhombohedral-orthorhombic phase transition. The enhancements of the two-phonon peaks are associated with the breakdown of the cycloid spin configuration with the appearance of the orthorhombic structure. These results indicate the existence of strong spin phonon coupling in Bi1-xLaxFeO3, which may provide useful information for understanding the effects of La content on the structural and magnetic properties of Bi1 -xLaxFeO3. 展开更多
关键词 Bi1-xLaxFeO3 Raman scattering phase transition spin phonon coupling
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3-D Scattering of Obliquely Incident Plane P Waves by Alluvial Valley Embedded in Layered Half-Space
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作者 巴振宁 梁建文 任强强 《Transactions of Tianjin University》 EI CAS 2012年第5期357-365,共9页
The indirect boundary element method(IBEM) was established to solve the problem of 3-D seismic responses of 2-D topographies,by calculating the free-field responses with the direct-stiffness method and simulating the ... The indirect boundary element method(IBEM) was established to solve the problem of 3-D seismic responses of 2-D topographies,by calculating the free-field responses with the direct-stiffness method and simulating the scattering wave fields with the dynamic Green's functions of moving distributed loads.The proposed method yields accurate results,because the 3-D dynamic stiffness matrixes used are exact and the fictitious moving distributed loads can be acted directly on the interface between the alluvial valley and the layered half-space without singularity.The comparison with the published methods verifies the validity of the proposed method.And the numerical analyses are performed to give some beneficial conclusions.The study shows that 3-D scattering by an alluvial valley is essentially different from the 2-D case,and that the presence of soil layer affects not only the amplitude value of surface displacements but also the distribution of surface displacements. 展开更多
关键词 3-D scattering layered half-space alluvial valley plane P waves
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Determination of elastic,piezoelectric,and dielectric constants of an R:BaTiO_3 single crystal by Brillouin scattering
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作者 何小亢 曾立波 +3 位作者 吴琼水 张丽艳 朱恪 刘玉龙 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第6期510-514,共5页
From the sound velocity measured using the Brillouin scattering technique, the elastic, piezoelectric, and dielectric constants of a high-quality monodomain tetragonal Rh:BaTiO3 single crystal are determined at room ... From the sound velocity measured using the Brillouin scattering technique, the elastic, piezoelectric, and dielectric constants of a high-quality monodomain tetragonal Rh:BaTiO3 single crystal are determined at room temperature. The elastic constants are in fairly good agreement with those of the BaTiO3 single crystal, measured previously by Brillouin scattering and the low-frequency equivalent circuit methods. However, their electromeehanical properties are significantly different. Based on the sound propagation equations and these results, the directional dependence of the compressional modulus and the shear modulus of Rh:BaTiO3 in the (010) plane is investigated. Some properties of sound propagation and electromechanical coupling in the crystal are discussed. 展开更多
关键词 Brillouin scattering elastic and piezoelectric constants Rh:BaTiO3 single crystal
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External-Strain-Induced Raman Scattering Modification in g-C3N4 Structures
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作者 李廷会 李海涛 +2 位作者 潘江洪 郭俊宏 胡芳仁 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第10期84-88,共5页
Regulation of optical properties and electronic structure of graphitic carbon nitride (g-C3N4 ) via external strain has attracted much attention due to its potential in photocatalyst and electronic devices. However,... Regulation of optical properties and electronic structure of graphitic carbon nitride (g-C3N4 ) via external strain has attracted much attention due to its potential in photocatalyst and electronic devices. However, the identifi- cation of g-C3N4 structure transformation induced by strain is greatly lacking. In this work, the Raman spectra of g-C3N4 with external strain are determined theoretically based on the density function theory. Deformation induced by external strain not only regulates the Raman mode positions but also leads to a I^aman mode split- ting, which can be ascribed to crystal symmetry destruction by strain engineering. Our results suggest the use of Raman scattering in structural identification in deformed 9-C3N4 structure. 展开更多
关键词 External-Strain-Induced Raman scattering Modification in g-C3N4 Structures
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Reconstruction of Temperature Field in 3-D, Absorbing, Emitting, and Anisotropically Scattering Medium
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作者 赵敬德 刘妮 钟珂 《Journal of Donghua University(English Edition)》 EI CAS 2006年第2期17-21,共5页
The soft measurement technology of flame temperature field is an efficient method to learn the combustion status in furnace. Generally, it reconstructs the temperature field in furnace through the image of flame, whic... The soft measurement technology of flame temperature field is an efficient method to learn the combustion status in furnace. Generally, it reconstructs the temperature field in furnace through the image of flame, which is a process to solve radiative inverse problem. In this paper, the flame of pulverized coal is considered as 3-D, absorbing, emitting, and anisotropically scattering non-gray medium. Through the study on inverse problem of radiative heat transfer, the temperature field in this kind of medium has been reconstructed. The mechanism of 3-D radiative heat transfer in a rectangular media, which is 2 m×3 m× 5 m and full of CO2, N2 and carbon particles, is studied with Monte Carlo method. The 3-D temperature field in this rectangular space is reconstructed and the influence of particles density profile is discussed. 展开更多
关键词 reconstruction of 3-D temperature field anisotropically scattering non-gray medium Monte Carlo method density profile inverse problem of radiative heat transfer.
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High-Frequency Guided Wave Scattering by a Partly Through-Thickness Hole Based on 3D Theory
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作者 张海燕 徐建 马世伟 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第8期94-97,共4页
We present a theoretical investigation of the scattering of high frequency S0 Lamb mode from a circular blind hole defect in a plate based on the 3D theory. The SO wave is incident at the frequency above the A1 mode c... We present a theoretical investigation of the scattering of high frequency S0 Lamb mode from a circular blind hole defect in a plate based on the 3D theory. The SO wave is incident at the frequency above the A1 mode cut-off frequency, in which the popular approximate plate theories are inapplicable. Due to the non-symmetric blind hole defect, the scattered fields will contain higher order converted modes in addition to the fundamental SO and AO modes. The far-field scattering amplitudes of various propagating Lamb modes for different hole sizes are inspected. The results are compared with those of lower frequencies and some different phenomena are found. Two-dimensional Fourier transform (2DFT) results of transient scattered Lamb and SH wave signals agree well with the analytical dispersion curves, which check the validity of the solutions from another point of view. 展开更多
关键词 High-Frequency Guided Wave scattering by a Partly Through-Thickness Hole Based on 3D Theory
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CsPbBr_(3)晶体生长及变温霍尔效应研究
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作者 王杰 金致远 +3 位作者 彭静 张绍卿 黄巍 何知宇 《功能材料》 CAS CSCD 北大核心 2024年第5期5101-5105,5113,共6页
以定向凝固法提纯的CsPbBr_(3)多晶为原料,采用垂直布里奇曼法生长出尺寸为∅30 mm×70 mm的CsPbBr_(3)单晶。采用ICP-OES对提纯后的多晶测试表明,提纯后的CsPbBr_(3)多晶中杂质含量减少了28.7%。经XRD和EDS对切割得到的晶片分析发现... 以定向凝固法提纯的CsPbBr_(3)多晶为原料,采用垂直布里奇曼法生长出尺寸为∅30 mm×70 mm的CsPbBr_(3)单晶。采用ICP-OES对提纯后的多晶测试表明,提纯后的CsPbBr_(3)多晶中杂质含量减少了28.7%。经XRD和EDS对切割得到的晶片分析发现,晶片的晶面方向属{210}晶面族,晶体中Cs、Pb、Br_(3)种元素分布均匀,原子百分含量符合化学计量比。采用傅里叶红外光谱仪和紫外-可见分光光度计对晶体的透过率测试显示,生长晶体在500~4000 cm^(-1)波数范围内的红外透过率超过75%,紫外短波截止边为552 nm,拟合计算出对应的禁带宽度为2.246 eV。选取7个不同温度点对CsPbBr_(3)单晶进行变温霍尔效应测试发现,生长晶体为P型导电,在250~300 K和300~350 K之间晶体中主要的载流子散射机制分别为声学波散射和电离杂质散射,在150~250 K温度范围内,更符合多种散射机构共同作用的散射机制。进一步拟合载流子浓度p与1/T的关系,计算获得晶体中杂质电离能ΔE_(A)=0.3042 eV。 展开更多
关键词 晶体生长 CsPbBr_(3)单晶 垂直布里奇曼法 变温霍尔 散射机制
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Scattering of seismic waves by three-dimensional large-scale hill topography simulated by a fast parallel IBEM 被引量:2
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作者 Liu Zhongxian Shang Ce +2 位作者 Huang Lei Liang Jianwen Li Jie 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2020年第4期855-873,共19页
To solve seismic wave scattering by a large-scale three-dimensional(3-D) hill topography, a fast parallel indirect boundary element method(IBEM) is developed by proposing a new construction method for the wave field, ... To solve seismic wave scattering by a large-scale three-dimensional(3-D) hill topography, a fast parallel indirect boundary element method(IBEM) is developed by proposing a new construction method for the wave field, modifying the generalized minimum residual(GMRES) algorithm and constructing an Open MP plus MPI parallel model. The validations of accuracy and efficiency show that this method can solve 3-D seismic response of a large-scale hill topography for broadband waves, and overcome the weakness of large storage and low efficiency of the traditional IBEM. Based on this new algorithm architecture, taking the broadband scattering of plane SV waves by a large-scale Gaussian-shaped hill of thousands-meters height as an example, the influence of several important parameters is investigated, including the incident frequency, the incident angle and the height-width and length-width ratio of the hill. The numerical results illustrate that the amplification effect on the ground motion by a near-hemispherical hill is more significant than the narrow hill. For low-frequency waves, the scattering effect of the higher hill is more pronounced, and there is only a single peak near the top of the hill. However, for high-frequency waves, rapid spatial variation of displacement amplitude appears on the hill surface. 展开更多
关键词 scattering of seismic waves 3-D hill topography indirect boundary element method(IBEM) parallel calculation
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Long-Range Correlation in Positron-Hydrogen Scattering System near the Threshold of <i>Ps</i>(<i>n</i>= 2) Formation
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作者 Chi Yu Hu David Caballero 《Journal of Modern Physics》 2013年第5期622-627,共6页
This is a short report of a recently uncovered resonant phenomenon. The modified Faddeev equation that correctly includes all six open channels is used. The calculation is carried out in s-partial wave. We report a nu... This is a short report of a recently uncovered resonant phenomenon. The modified Faddeev equation that correctly includes all six open channels is used. The calculation is carried out in s-partial wave. We report a number of resonant peaks in the elastic cross sections as well as the wave amplitudes involved. This is the energy region where the Stark-effect induced electric dipole energy split in the target dominates the physics and the Long-Range behavior of the 3-body scattering system. It is found that when the center of mass collision energy in the new channels is in integer proportion to the corresponding electric dipole energy split, Bremsstrahlung photon mediated resonant scattering occurs. The corresponding wave amplitudes deform into wave-packets hundreds to thousands of Bohr radii in width. The physical implication of this phenomenon will be discussed. 展开更多
关键词 Faddeev RESONANCE Cross Section 3-body scattering
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正负磁阻共存的Fe/Bi_(0.5)Sb_(1.5)Te_(3)热电磁薄膜
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作者 柯少秋 叶先峰 +6 位作者 张昊俊 聂晓蕾 陈天天 刘承姗 朱婉婷 魏平 赵文俞 《物理学报》 SCIE EI CAS CSCD 北大核心 2024年第22期257-267,共11页
具有优异电输运性能的热电薄膜是发展高效面内散热技术的关键材料,但是过低的电输运性能是制约其应用的重要难题.热电磁耦合新效应是近年来发展的一种优化综合热电性能的新方法.为了探索热电磁耦合新效应对热电薄膜电输运性能的影响机制... 具有优异电输运性能的热电薄膜是发展高效面内散热技术的关键材料,但是过低的电输运性能是制约其应用的重要难题.热电磁耦合新效应是近年来发展的一种优化综合热电性能的新方法.为了探索热电磁耦合新效应对热电薄膜电输运性能的影响机制,本研究发展了一种球磨分散-丝网印刷-热压固化一体化成型的方法,成功制备了一系列Fe纳米粒子作为第二相的xFe/BST/环氧树脂热电磁薄膜,并重点研究了其热电磁耦合作用及其对电热输运性能的影响规律.研究发现,xFe/Bi_(0.5)Sb_(1.5)Te_(3)(BST)/环氧树脂热电磁薄膜中存在正、负磁阻共存的现象;BST(000l)择优取向因子与正磁阻(MR+)之间呈正比例关系并增加热电磁薄膜的电导率;源于强铁磁性Fe纳米粒子局部磁矩的自旋相关散射的负磁阻(MR-)会增加Seebeck系数.因此,室温附近Fe/BST/环氧树脂热电磁薄膜的功率因子高达2.87 mW/(K^(2)·m),与BST/环氧树脂热电薄膜相比,提高了78%.这些结果表明,热电磁薄膜中正、负磁阻的共存不仅可解耦热电材料中电导率与Seebeck系数之间的耦合关系,还可以为磁纳米粒子诱导优异热电转换性能提供新的物理机制. 展开更多
关键词 p型Bi_(2)Te_(3) 基热电磁薄膜 磁各向异性 磁阻 自旋相关散射
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氧化钪(Sc_(2)O_(3))的热漫散射强度解析
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作者 王瑞刚 刘泽朋 +1 位作者 香莲 孙勇 《物理学报》 SCIE EI CAS CSCD 北大核心 2024年第6期193-200,共8页
热漫散射分析在凝聚态物理和材料科学研究中具有巨大潜力与实用性.氧化钪(Sc_(2)O_(3))独特的物理化学性质,使其具有较高的研究和应用价值.在室温26℃下对Sc_(2)O_(3)进行了X射线衍射实验.其热漫散射强度呈明显的振动形状,将Sc_(2)O_(3... 热漫散射分析在凝聚态物理和材料科学研究中具有巨大潜力与实用性.氧化钪(Sc_(2)O_(3))独特的物理化学性质,使其具有较高的研究和应用价值.在室温26℃下对Sc_(2)O_(3)进行了X射线衍射实验.其热漫散射强度呈明显的振动形状,将Sc_(2)O_(3)的全衍射背底强度方程展开,并计算热漫散射强度的理论值,直至计算到第14近邻原子(r为0.3816 nm)全衍射背底强度图谱.将理论值与实验值拟合,得到了最近邻原子至第7近邻原子所对应的原子间热振动相关效应值μ,最近邻原子到第7近邻原子距离r的值分别为0.2067,0.2148,0.2161,0.2671,0.2945,0.3229和0.3265 nm,所对应的原子间热振动相关效应值μ分别为0.64,0.63,0.62,0.61,0.60,0.58和0.57.研究发现Sc_(2)O_(3)热漫散射强度大小与原子的热振动密切相关,对热漫散射强度振动形状影响最大的是第7近邻原子Sc_(1)-Sc_(2)间的热振动相关效应μ,原子间热振动相关效应值μ对研究材料的力热性质提供很重要的参数,为下一步计算比热和原子间力常数打下基础,其对于材料的力热方面的用途与发展有着至关重要的作用. 展开更多
关键词 Sc_(2)O_(3) 热漫散射 原子间热振动相关效应值
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Analysis of the joint detection capability of the SMILE satellite and EISCAT-3D radar 被引量:2
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作者 JiaoJiao Zhang TianRan Sun +7 位作者 XiZheng Yu DaLin Li Hang Li JiaQi Guo ZongHua Ding Tao Chen Jian Wu Chi Wang 《Earth and Planetary Physics》 EI CSCD 2024年第1期299-306,共8页
The Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)satellite is a small magnetosphere–ionosphere link explorer developed cooperatively between China and Europe.It pioneers the use of X-ray imaging technology... The Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)satellite is a small magnetosphere–ionosphere link explorer developed cooperatively between China and Europe.It pioneers the use of X-ray imaging technology to perform large-scale imaging of the Earth’s magnetosheath and polar cusp regions.It uses a high-precision ultraviolet imager to image the overall configuration of the aurora and monitor changes in the source of solar wind in real time,using in situ detection instruments to improve human understanding of the relationship between solar activity and changes in the Earth’s magnetic field.The SMILE satellite is scheduled to launch in 2025.The European Incoherent Scatter Sciences Association(EISCAT)-3D radar is a new generation of European incoherent scatter radar constructed by EISCAT and is the most advanced ground-based ionospheric experimental device in the high-latitude polar region.It has multibeam and multidirectional quasi-real-time three-dimensional(3D)imaging capabilities,continuous monitoring and operation capabilities,and multiple-baseline interferometry capabilities.Joint detection by the SMILE satellite and the EISCAT-3D radar is of great significance for revealing the coupling process of the solar wind–magnetosphere–ionosphere.Therefore,we performed an analysis of the joint detection capability of the SMILE satellite and EISCAT-3D,analyzed the period during which the two can perform joint detection,and defined the key scientific problems that can be solved by joint detection.In addition,we developed Web-based software to search for and visualize the joint detection period of the SMILE satellite and EISCAT-3D radar,which lays the foundation for subsequent joint detection experiments and scientific research. 展开更多
关键词 Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)satellite European Incoherent scatter Sciences Association(EISCAT)-3D radar joint detection
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基于水热合成法制备的MoO_(3-x)纳米槽SERS基底的特性研究
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作者 舒敏 梁俊辉 +2 位作者 陈达 陈招 秦来顺 《人工晶体学报》 CAS 北大核心 2024年第6期1061-1068,共8页
表面增强拉曼散射(SERS)技术可以快速检测微量分子,在医药材料分析、有害物残留、食品安全等领域受到广泛关注。而SERS对被检测物质的响应极限则取决于基底性能,并直接影响最终检测效果。本文着眼于增加基底的比表面积及其与被检测物之... 表面增强拉曼散射(SERS)技术可以快速检测微量分子,在医药材料分析、有害物残留、食品安全等领域受到广泛关注。而SERS对被检测物质的响应极限则取决于基底性能,并直接影响最终检测效果。本文着眼于增加基底的比表面积及其与被检测物之间的光诱导电荷转移能力,通过简单的水热合成法成功制备出具有氧空位缺陷的MoO_(3-x)纳米槽。结合X射线光电子能谱(XPS)、紫外-可见光谱(UV-Vis)、傅里叶变换红外光谱(FT-IR)等手段,对MoO_(3-x)纳米槽的电子结构、光学性质和表面化学环境进行了分析。使用MoO_(3-x)纳米槽作为SERS基底,对罗丹明6G(R6G)、结晶紫(CV)和玫瑰红B(RhB)三种有机染料分子进行了检测,实验结果显示,其对R6G的检测极限可以达到10^(-10)mol/L,与同类型的半导体基底相比,它具有更好的拉曼增强活性。 展开更多
关键词 MoO_(3-x)纳米槽 表面增强拉曼散射 微量分子检测 氧空位缺陷 光诱导电荷转移 R6G
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Enhancing Lab Source Anomalous Scattering Using Cr Kα Radiation for Its Potential Application in Determining Macromolecular Structures
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作者 Sibi Narayanan Devadasan Velmurugan 《Crystal Structure Theory and Applications》 2012年第3期84-91,共8页
Obtaining phase information for the solution of macromolecular structures is a bottleneck in X-ray crystallography. Anomalous dispersion was recognized as a powerful tool for phasing macromolecular structures. It was ... Obtaining phase information for the solution of macromolecular structures is a bottleneck in X-ray crystallography. Anomalous dispersion was recognized as a powerful tool for phasing macromolecular structures. It was used mainly to supplement the isomorphous replacement or to locate the anomalous scatterer itself. The first step in solving macromolecular structures by SAD (single-wavelength anomalous diffraction) is the location of the anomalous scatterers. The SAD method for experimental phasing has evolved substantially in the recent years. A phasing tool, 5-amino-2,4,6- triiodoisophthalic acid (I3C—magic triangle), was incorporated into three proteins, lysozyme, glucose isomerase and thermolysin using quick-soaking and co-crystallization method in order to understand the binding of metal ion with proteins. The high quality of the diffraction data, the use of chromium anode X-ray radiation and the required amount of anomalous signal enabled way for successful structure determination and automated model building. An analysis and/or comparison of the sulfur and iodine anomalous signals at the Cr Kα wavelength are discussed. 展开更多
关键词 ANOMALOUS scattering SAD PHASING I3C LYSOZYME Glucose ISOMERASE THERMOLYSIN
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Raman spectroscopy and ionic structure of Na_3AlF_(6-)Al_2O_3 melts 被引量:6
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作者 胡宪伟 曲俊月 +3 位作者 高炳亮 石忠宁 刘风国 王兆文 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第2期402-406,共5页
Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were... Raman spectrum of molten cryolite was recorded. Based on the new understanding of the scattering coefficients, contents of various structural entities in acidic NaF-AlF3 melts at 942-1 024 ℃ in previous research were reanalyzed. The new quantitative analysis results show that when cryolite ratio(CR) is less than 2, AlF4- is the dominant anion in the melts, and its mole fraction is about 0.70 for melts with CR=1.5 and 0.50 for melts with CR=2. When CR is more than 2.5, the mole fraction of AlF6^3- is relatively large, which is around 0.45 for melts with CR=2.5. Ionic structure of Na3AlF6-Al2O3 melts was investigated by UV-Raman spectroscopy. Octahedral AlF6^3- and tetrahedral AlF4- are proved to exist with possible partial replacement of F- by O^2-. Al2O2F4^2- with a large scattering coefficient also exists in the melts in which alumina concentration is more than 4% (mass fraction). The increase of temperature causes blue-shift of the bands in the Raman spectra. 展开更多
关键词 Raman spectroscopy Na3AlF6-Al2O3 melts scattering coefficient complex ion aluminum electrolysis sealed cell
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Fe^(3+)-十二烷基苯磺酸钠作探针的共振瑞利散射法测定血清蛋白 被引量:4
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作者 胡庆红 杨阳 +1 位作者 江波 袁泽利 《光谱实验室》 CAS CSCD 2008年第4期722-726,共5页
在酸性条件下,十二烷基苯磺酸钠-Fe3+与蛋白质形成离子缔合物,使共振瑞利散射(RRS)急剧增强。研究了相应的光谱特征,适宜的反应条件和影响因素。在最佳条件下,不同蛋白质在一定浓度范围内与散射强度呈良好的线性关系,可用于多种蛋白质... 在酸性条件下,十二烷基苯磺酸钠-Fe3+与蛋白质形成离子缔合物,使共振瑞利散射(RRS)急剧增强。研究了相应的光谱特征,适宜的反应条件和影响因素。在最佳条件下,不同蛋白质在一定浓度范围内与散射强度呈良好的线性关系,可用于多种蛋白质的测定,方法的检出限在14.5—53.0ng/mL之间。本法灵敏、简便和重现性好,已用于人血清样品中总蛋白含量的测定,获得满意结果。 展开更多
关键词 共振瑞利散射 FE^3+ 十二烷基苯磺酸钠 蛋白质
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La_(0.67)Sr_xMnO_(3-δ)的制备及表征 被引量:3
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作者 周圣明 李爱侠 +3 位作者 刘艳美 汪洪 吴桂芳 赵宗彦 《安徽大学学报(自然科学版)》 CAS 2000年第2期61-64,共4页
利用固态反应法制得名义组份为La0 .67SrxMnO3-δ(x=0 .33,0 .2 8,0 .2 3,0 .1 8和 0 .1 3)的多晶样品。X射线衍射表明当 0 .1 8≤x≤ 0 .33时样品是单相的钙钛矿型结构 ,这表明A位可以存在较多的空位。红外吸收光谱显示 ,随着A位空位增... 利用固态反应法制得名义组份为La0 .67SrxMnO3-δ(x=0 .33,0 .2 8,0 .2 3,0 .1 8和 0 .1 3)的多晶样品。X射线衍射表明当 0 .1 8≤x≤ 0 .33时样品是单相的钙钛矿型结构 ,这表明A位可以存在较多的空位。红外吸收光谱显示 ,随着A位空位增多 ,MnO6 八面体基团的伸缩振动模 (波数约为 60 0cm- 1 )的红外活性增强 ,同时电声子散射也随之增强。 展开更多
关键词 电声子散射 钙钛矿型结构 LAMNO3 巨磁电阻材料
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