Seismic Responses of Asymmetric Base-Isolated Structures under Near-Fault Ground Motion

An inter-story shear model of asymmetric base-isolated structures incorporating deformation of each isolation bearing was built, and a method to simultaneously simulate bi-directional near-fault and far-field ground motions was proposed. A comparative study on the dynamic responses of asymmetric base-isolated structures under near-fault and far-field ground motions were conducted to investigate the effects of eccentricity in the isolation system and in the superstructures, the ratio of the uncoupled torsional to lateral frequency of the superstructure and the pulse period of near-fault ground motions on the nonlinear seismic response of asymmetric base-isolated structures. Numerical results show that eccentricity in the isolation system makes asymmetric base-isolated structure more sensitive to near-fault ground motions, and the pulse period of near-fault ground motions plays an import role in governing the seismic responses of asymmetric base-isolated structures.

12.6μm-Thick Asymmetric Composite Electrolyte with Superior Interfacial Stability for Solid-State Lithium-Metal Batteries

Solid-state lithium metal batteries(SSLMBs)show great promise in terms of high-energy-density and high-safety performance.However,there is an urgent need to address the compatibility of electrolytes with high-voltage cathodes/Li anodes,and to minimize the electrolyte thickness to achieve highenergy-density of SSLMBs.Herein,we develop an ultrathin(12.6μm)asymmetric composite solid-state electrolyte with ultralight areal density(1.69 mg cm^(−2))for SSLMBs.The electrolyte combining a garnet(LLZO)layer and a metal organic framework(MOF)layer,which are fabricated on both sides of the polyethylene(PE)separator separately by tape casting.The PE separator endows the electrolyte with flexibility and excellent mechanical properties.The LLZO layer on the cathode side ensures high chemical stability at high voltage.The MOF layer on the anode side achieves a stable electric field and uniform Li flux,thus promoting uniform Li^(+)deposition.Thanks to the well-designed structure,the Li symmetric battery exhibits an ultralong cycle life(5000 h),and high-voltage SSLMBs achieve stable cycle performance.The assembled pouch cells provided a gravimetric/volume energy density of 344.0 Wh kg^(−1)/773.1 Wh L^(−1).This simple operation allows for large-scale preparation,and the design concept of ultrathin asymmetric structure also reveals the future development direction of SSLMBs.

A modified Kelvin impact model for pounding simulation of base-isolated building with adjacent structures

Base isolation can effectively reduce the seismic forces on a superstructure, particularly in lowto medium-rise buildings. However, under strong near-fault ground motions, pounding may occur at the isolation level between the baseisolated building （BIB） and its surrounding retaining walls. To effectively investigate the behavior of the BIB pounding with adjacent structures, after assessing some commonly used impact models, a modified Kelvin impact model is proposed in this paper. Relevant parameters in the modified Kelvin model are theoretically derived and numerically verified through a simple pounding case. At the same time, inelasticity of the isolated superstructure is introduced in order to accurately evaluate the potential damage to the superstructure caused by the pounding of the BIB with adjacent structures. The reliability of the modified Kelvin impact model is validated through numerical comparisons with other impact models. However, the difference between the numerical results from the various impact analytical models is not significant. Many numerical simulations of BIBs are conducted to investigate the influence of various design parameters and conditions on the peak inter-story drifts and floor accelerations during pounding. It is shown that pounding can substantially increase floor accelerations, especially at the ground floor where impacts occur. Higher modes of vibration are excited during poundings, increasing the inter-story drifts instead of keeping a nearly rigid-body motion of the superstructure. Furthermore, higher ductility demands can be imposed on lower floors of the superstructure. Moreover, impact stiffness seems to play a significant role in the acceleration response at the isolation level and the inter-story drifts of lower floors of the superstructure. Finally, the numerical results show that excessive flexibility of the isolation system used to minimize the floor accelerations may cause the BIB to be more susceptible to pounding under a limited seismic gap.

ASYMMETRICAL STRUCTURES OF THE TEMPERATURE AND HUMIDITY OF TROPICAL CYCLONES

Based on NCEP/CFSR 0.5° reanalysis data and the best track data from the Japan Tokyo Typhoon Center,composite and comparative analyses demonstrate the asymmetrical structures of the temperature and humidity in tropical cyclones over the Western North Pacific and the South China Sea from 1979 to 2010.The results are shown as follows.(1) With intensifying tropical cyclones,the flow field tends to become gradually more axisymmetric;however,the asymmetry of the specific humidity in the outer regions is more obvious.(2) In general,tropical cyclones have a non-uniform,vertical, "double warm-core" structure.The "warm-cores" in the lower level of weak tropical cyclones and in the higher level of strong tropical cyclones are the stronger of the two.(3) The distribution area of a "warm-core" is enhanced with cyclone intensification and tends to become more axisymmetric.At 200 hPa,the "warm-core" of a weak cyclone has a weak anticyclone in the center,whereas that of a strong cyclone has a weak cyclone in the center.(4)The "wet-core" of a tropical cyclone is primarily located in the lower level(700-850 hPa).With the cyclone's intensification,the intensity of the "wet-core" increases and the scope of the 0.8 g kg^(-1) specific humidity anomaly tends to expand to higher levels.(5) With the cyclone's deepening,the pseudo-equivalent potential temperature at different levels in different regions increases.In addition,the largest warming rates at each intensity level in the different regions occur in the core area,followed in turn by the envelope and outer areas.

Stable single longitudinal mode erbium-doped silica fiber laser based on an asymmetric linear three-cavity structure

We present a stable linear-cavity single longitudinal mode （SLM） erbium-doped silica fiber laser. It consists of four fiber Bragg gratings （FBGs） directly written in a section of photosensitive erbium-doped fiber （EDF） to form an asymmetric three-cavity structure. The stable SLM operation at a wavelength of 1545.112 nm with a 3-dB bandwidth of 0.012 nm and an optical signal-to-noise ratio （OSNR） of about 60 dB is verified experimentally. Under laboratory conditions, the performance of a power fluctuation of less than 0.05 dB observed from the power meter for 6 h and a wavelength variation of less than 0.01 nm obtained from the optical spectrum analyzer （OSA） for about 1.5 h are demonstrated. The gain fiber length is no longer limited to only several centimeters for SLM operation because of the excellent mode-selecting ability of the asymmetric three-cavity structure. The proposed scheme provides a simple and cost-effective approach to realizing a stable SLM fiber laser.

Structured illumination microscopy based on asymmetric three-beam interference

Structured illumination microscopy(SIM)is a rapidly developing super-resolution technology.It has been widely used in various application fields of biomedicine due to its excellent two-and three-dimensional imaging capabilities.Furthermore,faster three-dimensional imaging methods are required to help enable more research-oriented living cell imaging.In this paper,a fast and sensitive three-dimensional structured illumination microscopy based on asymmetric three-beam interference is proposed.An innovative time-series acquisition method is employed to halve the time required to obtain each raw image.A segmented half-wave plate as a substantial linear polarization modulation method is applied to the three-dimensional SIM system for the first time.Although it needs to acquire 21 raw images instead of 15 to reconstruct one super-resolution image,the SIM setup proposed in this paper is 30%faster than the traditional spatial light modulator-SIM(SLM-SIM)in imaging each super-resolution image.The related theoretical derivation,hardware system,and verification experiment are elaborated in this paper.The stable and fast 3D super-resolution imaging method proposed in this paper is of great significance to the research of organelle interaction,intercellular communication,and other biomedical fields.

AN ANALYSIS OF THE ASYMMETRICAL STRUCTURE OF TYPHOON AERE'S PRECIPITATION

The structural characteristics of 2004 typhoon Aere's precipitation are analyzed using the high-resolution data from the Tropical Rainfall Measuring Mission(TRMM) of the National Aeronautics Space Administration(NASA).It is found that the typhoon's characteristics vary at different stages of its development.To analyze the asymmetric causation of precipitation distribution,data from the National Center for Environmental Prediction(NCEP) reanalysis are used to calculate the vertical integral of the water vapor flux vector.The results show that because of this process,along with the unique phenomenon of twin-typhoon circulation,the easterly air current of the typhoon's northern side and the southwesterly air current of its southern side play a joint role in transporting water vapor.Furthermore,its transport effects vary greatly at the different stages of development,showing the peculiarity of the water source for this typhoon process.The distributions of the typhoon convection area—characterized by heavy precipitation and a maximum-value area of the water vapor flux,as well as a strong ascending-motion area—differ at different stages of the typhoon's development.The non-uniform distribution of water vapor flux and the vertical motion bring about asymmetrical distribution of the typhoon precipitation.

Bcklund Transformation and Localized Coherent Structure for the (2+1)-Dimensional Asymmetric Nizhnik-Novikov-Veselov Equation

This article is concerned with the extended homogeneous balance method for studying the abundant localized solution structure of the (2+1) dimensional asymmetric Nizhnik Novikov Veselov equation. A B a¨ cklund transformation was first obtained, and then the richness of the localized coherent structures was found, which was caused by the entrance of two variable separated arbitrary functions, in the model. For some special choices of the arbitrary functions, it is shown that the localized structures of the model may be dromions, lumps, and ring solitons.

Asymmetric structure of atomic above-threshold ionization spectrum in two-color elliptically polarized laser fields

According to the frequency-domain theory, we investigate the asymmetric structure of above-threshold ionization(ATI) spectrum of an atom in two-color elliptically polarized(EP) laser fields. When both laser fields are linearly polarized(LP), the spectrum shows that the multi-plateau structure is symmetric about the emitted angle of electron at π/2, while the spectrum becomes asymmetric and shifts rightwards with the increase of the EP degree of the IR laser field. Since the total ATI process is regarded as including direct ATI and the rescattering ATI, we analyze the spectrum structure of direct ATI and rescattering ATI separately. Using the saddle-point approximation, we find that for direct ATI, the fringes on the spectrum are mainly attributed to the fact that the ionization probability becomes very small when the direction of emitted electrons is perpendicular to the direction of the XUV laser polarization;while for the rescattering ATI, the interference fringes on the spectrum mainly come from the superposition of the waist structures on the spectra of all sub-channels.

NUMERICAL EXPERIMENTS OF THE INFLUENCE OF DIABATIC HEATING ON TROPICAL CYCLONE ASYMMETRIC STRUCTURE

Using the barotropic volticity equation that contains forcing from diabatic heating with appropriate parameterization. a number of numerical experiments are conducted for the tropical cyclone that is initially symmetric The result shows that the diabatic heating has important effects on the asymmetric structure in addition to the roll of the β term and nonlinear advection term in its formation. It again confirms the conclusion that the diabatic heating is a possible mechanism responsible for such structures in the tropical cyclone.

A NUMERICAL ANALYSIS ON TYPHOON ASYMMETRIC STRUCTUREAND MOTION

Five prediction experiments are carried out with two typhoons in 1992 using a limited -arca primitiveequations and two-way interactive model in a movable ,nested mesh. The result indicates good agreementin terms of motion between the prediction and observation. Studying the asymmetric structure in the cas-es selected, a close link is uncovered between the temporal evolutions of the structure and the track of motion in a tropical cyclone. Understanding of real asymmetric structure will help to improve the skill offorecasting tropical cyclones.

Effect of the asymmetric geometry on the wake structures of a pitching foil

The two-dimensional wake produced by a time-periodic pitching foil with the asymmetric geometry is investigated in the present work. Through numerically solving nonlinear Navier–Stokes equations, we discuss the relationship among the kinematics of the prescribed motion, the asymmetric parameter K ranged as-1 ≤ K ≤ 1, and the types of the wakes including the mP＋nS wake, the B′enard–von K′arm′an wake, the reverse B′enard–von K′arm′an wake, and the deviated wake.Compared with previous studies, we reveal that the asymmetric geometry of a pitching foil directly affects the foil＇s wake structures. The numerical results show that the reverse B′enard–von K′arm′an wake is easily deviated at K 〈 0, while the symmetry-breaking of the reverse B′enard–von K′arm′an wake is delayed at K 〉 0. Through the vortex dynamic method,we understand that the initial velocity of the vortex affected by the foil＇s asymmetry plays a key role in the deviation of the reverse B′enard–von K′arm′an wake. Moreover, we provide a theoretical model to predict the wake deviation of the asymmetric foil.

Synthesis and Crystal Structure of (R)-4-Hydroxymethyl-2-thioxo Thiazolidine and Its Asymmetric Catalysis

（R）-4-Hydroxymethyl-2-thioxo thiazolidine as a new chiral catalyst in the asymmetric addition of diethylzinc to benzaldehyde was synthesized from （R）-4-hydroxymethyl-2-thioxo thiazolidine carboxylic acid and its crystal structure was determined by X-ray diffraction method. The compound was crystallized in the orthorhombic system, space group P212121 with unit cell dimensions a=0.67253（12） nm; b=0.89164（17） nm; c=1.06146（19） nm, volume 0.6365（2） nm^3; Z=4, calculated denisity 1.557 Mg/m^3; absorption coefficient 0.733 mm^-1; F（000）=312. The X-ray crystal structure analysis reveals that the compound has a thione group.

The role of viscoelastic damping on retrofitting seismic performance of asymmetric reinforced concrete structures

The primary purpose of this research is to improve the seismic response of a complex asymmetric tall structure using viscoelastic(VE) dampers. Asymmetric structures have detrimental effects on the seismic performance because such structures create abrupt changes in the stiffness or strength that may lead to undesirable stress concentrations at weak locations. Structural control devices are one of the effective ways to reduce seismic impacts, particularly in asymmetric structures. For passive vibration control of structures, VE dampers are considered among the most preferred devices for energy dissipation. Therefore, in this research, VE dampers are implemented at strategic locations in a realistic case study structure to increase the level of distributed damping without occupying significant architectural space and reducing earthquake vibrations in terms of story displacements(drifts) and other design forces. It has been concluded that the seismic response of the considered structure retrofitted with supplemental VE dampers corresponded well in controlling the displacement demands. Moreover, it has been demonstrated that seismic response in terms of interstory drifts was effectively mitigated with supplemental damping when added up to a certain level. Exceeding the supplemental damping from this level did not contribute to additional mitigation of the seismic response of the considered structure. In addition, it was found that the supplemental damping increased the total acceleration of the considered structure at all floor levels, which indicates that for irregular tall structures of this type, VE dampers were only a good retrofitting measure for earthquake induced interstory deformations and their use may not be suitable for acceleration sensitive structures. Overall, the research findings demonstrate how seismic hazards to these types of structures can be reduced by introducing additional damping into the structure.

SYNTHESIS AND STRUCTURE OF AN ASYMMETRIC TRICOBALT COMPOUND Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3

Compound Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3 was obtained by reaction of CoCl_2, o-HOC_6H_4SH(H_2mD)and PEt_3 in ethanol in the presence of NaOCH_3.The three Co atoms are triangularly arranged and asymmetrically bridged by four S and one O atoms from the four H_2mp ligands and terminally ligated by one O and three P atoms.Two free hydroxyl groups form two internal hydrogen bonds with adjacent oxo donor atoms.

Adaptive base-isolation of civil structures using variable amplification

Semi-active dampers are used in base-isolation to reduce the seismic response of civil engineering structures. In the present study, a new semi-active damping system using variable amplification will be investigated for adaptive baseisolation. It uses a novel variable amplification device （VAD） connected in series with a passive damper. The VAD is capable of producing multiple amplification factors, each corresponding to a different amplification state. Forces from the damper are amplified to the structure according to the current amplification state, which is selected via a semi-active control algorithm specifically tailored to the system＇s tmique damping characteristics. To demonstrate the effectiveness of the VAD-damper system for adaptive base-isolation, numerical simulations are conducted for three and seven-story base-isolated buildings subject to both far and near-field ground motions. The results indicate that the system can achieve significant reductions in response compared to the base-isolated buildings with no damper. The proposed system is also found to perform well compared to a typical semi-active damper.

Asymmetric N,O-Coordinated Single Atomic Co Sites for Stable Lithium Metal Anodes

Lithium metal has been considered one of the most promising anodes for next-generation rechargeable batteries,but its practical application is largely hindered by the uncontrollable dendrite growth and infinite volume change.Here,inspired by superior catalytic effects of single-atom catalysts,carbon-supported single atomic Co with asymmetric N,O-coordination(Co-N/O)is developed for Li metal battery.Experimental results and theoretical calculations indicate that single atomic Co atoms with asymmetric N,O-coordination present enhanced binding ability toward Li in comparison with N-coordinated atomic Co site and isolated O site,enabling uniform Li plating/stripping.Moreover,the asymmetric N,O-coordination around Co atoms induces co-activation effects,lowering the energy barriers toward Li^(+)to Li^(0)conversion and largely promoting the deposition kinetics.When used as a Li deposition host,the Co-N/O achieves a high average coulombic efficiency of 98.6%at a current density of 1 mA cm^(-2)and a capacity of 2 mAh cm^(-2),long cycling life of 2000 h in symmetrical cells,and excellent rate performance(voltage hysteresis of 23 mV at 8 mA cm^(-2)).This work provides a comprehensive understanding of single atomic metals with asymmetric heteroatom coordination in the design of Li metal anode.

Unidirectional transport of both wettable and nonwettable liquids on an asymmetrically concave structured surface

Unidirectional liquid transport(UDLT)has been widely used in various fields as an important process for transferring both mass and energy.However,UDLT driven by a structural gradient has been witnessed for a long time only in wettable liquids.For nonwettable liquids,UDLT can hardly proceed merely by a structural gradient.Herein,we propose an asymmetrically concave structured surface(AMC-surface),featuring tip-to-base periodically arranged pyramid-shaped concave structures with a certain degree of overlap,which enables the UDLT of both wettable and nonwettable liquids.For wettable liquids,the capillary force along each corner leads to the UDLT pointing toward the base side of the concave pyramid,while for nonwettable liquids,the UDLT is attributable to the static liquid pressure overwhelming the repulsive Laplace pressure induced by the asymmetric grooves and overlapping part.As a result,both wettable and nonwettable liquids transport spontaneously and unidirectionally on the AMC-surface with no energy input.Moreover,the concave structure endows good mechanical stability and can be easily prepared using a facile nail-punching approach over a large area.We also demonstrated its application in a continuous chemical reaction in a confined area.We envision that the unique UDLT behavior on the as-developed AMC-surface will shed new light on the programmable manipulation of various liquids.

Asymmetric Price Transmission and Structural Breaks in the Relationship between Costa Rican Markets of Livestock Cattle, Beef and Milk

The vertical price transmission is generally considered as the relationship between two markets of the same production chain However, we can expand this concept to another relation which has not been deeply investigated： the joint products. They are the products which are produced in a single production process, but not correspond to the same chain. An especial case is the beef and milk markets in Costa Rica. Even if these products usually correspond to disconnect chains, in Costa Rica farms make use of cattle to produce both meat and milk. The cointegration framework is applied in order to indentify the price transmission among these markets. In addition, the asymmetric behavior and structural breaks are taken into account. Price transmission between each market pair was found. First, the cattle prices adjust in the milk-cattle relationship, second, beef meat prices adjust in the cattle-beef meat and in the milk - beef meat relationship. Finally, the equations allowing for structural breaks affect the estimates in the following three ways： after the break the elasticities became higher than 1, there is more evidence of cointegration, and the adjustment coefficients are significant only when a change in the long run is allowed.

Asymmetric reversible structural switching of a diene coordination polymer promoted by UV-visible light

In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switching behavior is required,it is desirable that the reversible reaction goes as close to symmetric as possible;however,such systems are uncommon.Herein,we report an example of ultraviolet(UV)-visible light-regulated asymmetric reversible structural switching involving a diene-based coordination polymer,CP1 and its monocyclobutane product,CP1a.It is possible to cycle at least ten times through a forward [2+2] photocycloaddition reaction and the reverse,photocleavage reaction.A single cycle can be completed within a few minutes.The transformation is accompanied by fast and distinct fluorescence changes,arising from optimisation of the reaction conditions.Density functional theory calculations allow rationalisation of the asymmetric reversible transformation between CP1 and CP1a rather than between CP1 and its dicyclobutane product CP1b.This work provides a clear illustration of reversible structural switching which approaches symmetric behaviour with respect to reaction rate and stimuli.The insights gained from this work also assist in the design of fast,reversible switching materials.