鲁西地区太古宙表壳岩包括新太古代早期和晚期两期表壳岩,早期表壳岩主要由变质玄武岩-科马提岩组成,晚期表壳岩主要由变质火山岩-碎屑沉积岩和BIF(Banded Iron Formations)组成。韩旺铁矿位于鲁西的西北部,铁矿区内存在大量变质玄武岩...鲁西地区太古宙表壳岩包括新太古代早期和晚期两期表壳岩,早期表壳岩主要由变质玄武岩-科马提岩组成,晚期表壳岩主要由变质火山岩-碎屑沉积岩和BIF(Banded Iron Formations)组成。韩旺铁矿位于鲁西的西北部,铁矿区内存在大量变质玄武岩-科马提岩,早期认为该BIF形成于新太古代早期,而新的研究认为鲁西地区BIF都形成于新太古代晚期。本文对韩旺铁矿区内与BIF互层的黑云变粒岩和侵入其中的片麻状花岗闪长岩开展锆石SHRIMP U-Pb定年,获得年龄分别为(2529±7)Ma和(2534±11)Ma。黑云变粒岩和片麻状花岗闪长岩的TREE、(La/Yb)N、Eu/Eu*分别为76×10^(–6)、19.8、0.84和82.7×10^(–6)、17.3、1.14,它们的岩浆锆石的εHf值、单阶段Hf同位素模式年龄分别为5.5~9.46、2.5~2.6 Ga和6.3~9.4、2.48~2.60 Ga。研究支持了鲁西地区BIF形成于新太古代晚期的认识。表壳岩形成、变质变形和花岗闪长岩侵入发生在一个很短的时间范围内。研究还表明,黑云变粒岩的原岩为英安质火山岩,很可能形成于新生玄武质岩浆的强烈结晶分异作用,花岗闪长岩形成于新生玄武质岩石部分熔融,形成过程中有陆壳物质的加入。展开更多
Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area...Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area is identified by the high elevated zone which is remained the witness of stable zone, not affected by the ancienst erosion process. Zatua Hills are in the superior Kibalian formation dated to Neoarchaen, hosted in Upper Congo Granites Massifs of DRC covering a large central zone of NE of DRC, and consisting to dolerite, phyllade, clay rich sediment, poor Banded Iron Formations (BIFs), enriched BIFs, friable hematite, hard hematite, mineralized and unmineralized brechias. Magnetite, martite and hematite are associated to some secondary minerals such as goethite, gibbsite, kaolinite, strengite, variscite and others clay minerals present in BIFs. Petrographic analysis made from the samples collected in situ showed, as well as BIFs and iron ore associated, that magnetite was much abundant oxide mineral which is oxided to martite before to stabilize to hematite during the deposition time. Having about hundred meters of thickness, the rich iron ore of this area content, in the majority less deleterious elements which, are harmful in metallurgic process of iron. These secondary minerals were precipitated at various degrees in the leached cavities of rocks between martite and hematite aggregates to botryoidal texture and, are rich to Al, and are mainly consisting to gibbsite and solid solution series of variscite-strengite (AlPO<sub>4</sub>·2H<sub>2</sub>O and FePO<sub>4</sub>·2H<sub>2</sub>O). Low degree of metamorphism played when magnetite was converted to martite, with the presence of variscite and anatase like witnesses of this event in which, martite was crystalized to hematite.展开更多
Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has rem...Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has remained a witness to a stable zone not affected by the ancient erosion process. BIFs are most abundant and are dated to the Neoarchaean and Late Kibalian, hosted in the Upper Congo Granites Massifs of the DR. Congo. Zatua Hills consist of dolerite, phyllade, clay-rich sediment, poor itabirite, enriched BIFs, friable hematite, hard hematite, and mineralized and unmineralized breccias. Field study and geochemistry analysis by XRF, XRD, and ICP-MS are executed in order to know the geochemistry signature and paragenesis of Zatua Hills and the probably process could lead the BIFs to iron ore. The geochemistry analysis by XRF, XRD, and ICP-MS shows that Iron ore content has an iron rate between 57% and 69% with less deleterious elements such as Si, P, and Al. These deleterious elements are secondary and have silicium composition (probably quartz or chert, goethite, and Kaolinite), aluminum (probably gibbsite, variscite, cadwaladérite, goethite, and Kaolinite), phosphorous (probably variscite), and hydrated minerals, which are grown LOI in the samples. Hypogen and supergen processes are played in BIFs for iron ore conversion and, respectively, silica dissolution and leaching. Metamorphism was also impacted and marked by the Ti element (anatase) in samples, contributing to the crystallization of martite to hematite after magnetite oxidation.展开更多
文摘Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area is identified by the high elevated zone which is remained the witness of stable zone, not affected by the ancienst erosion process. Zatua Hills are in the superior Kibalian formation dated to Neoarchaen, hosted in Upper Congo Granites Massifs of DRC covering a large central zone of NE of DRC, and consisting to dolerite, phyllade, clay rich sediment, poor Banded Iron Formations (BIFs), enriched BIFs, friable hematite, hard hematite, mineralized and unmineralized brechias. Magnetite, martite and hematite are associated to some secondary minerals such as goethite, gibbsite, kaolinite, strengite, variscite and others clay minerals present in BIFs. Petrographic analysis made from the samples collected in situ showed, as well as BIFs and iron ore associated, that magnetite was much abundant oxide mineral which is oxided to martite before to stabilize to hematite during the deposition time. Having about hundred meters of thickness, the rich iron ore of this area content, in the majority less deleterious elements which, are harmful in metallurgic process of iron. These secondary minerals were precipitated at various degrees in the leached cavities of rocks between martite and hematite aggregates to botryoidal texture and, are rich to Al, and are mainly consisting to gibbsite and solid solution series of variscite-strengite (AlPO<sub>4</sub>·2H<sub>2</sub>O and FePO<sub>4</sub>·2H<sub>2</sub>O). Low degree of metamorphism played when magnetite was converted to martite, with the presence of variscite and anatase like witnesses of this event in which, martite was crystalized to hematite.
文摘Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has remained a witness to a stable zone not affected by the ancient erosion process. BIFs are most abundant and are dated to the Neoarchaean and Late Kibalian, hosted in the Upper Congo Granites Massifs of the DR. Congo. Zatua Hills consist of dolerite, phyllade, clay-rich sediment, poor itabirite, enriched BIFs, friable hematite, hard hematite, and mineralized and unmineralized breccias. Field study and geochemistry analysis by XRF, XRD, and ICP-MS are executed in order to know the geochemistry signature and paragenesis of Zatua Hills and the probably process could lead the BIFs to iron ore. The geochemistry analysis by XRF, XRD, and ICP-MS shows that Iron ore content has an iron rate between 57% and 69% with less deleterious elements such as Si, P, and Al. These deleterious elements are secondary and have silicium composition (probably quartz or chert, goethite, and Kaolinite), aluminum (probably gibbsite, variscite, cadwaladérite, goethite, and Kaolinite), phosphorous (probably variscite), and hydrated minerals, which are grown LOI in the samples. Hypogen and supergen processes are played in BIFs for iron ore conversion and, respectively, silica dissolution and leaching. Metamorphism was also impacted and marked by the Ti element (anatase) in samples, contributing to the crystallization of martite to hematite after magnetite oxidation.
