The Bikaner-Nagaur and Barmer Basins(Rajasthan)are the most important petroliferous sedimentary basins in India.For over a decade,the exploration and extraction of hydrocarbons in these basins.Paleocene-Eocene age roc...The Bikaner-Nagaur and Barmer Basins(Rajasthan)are the most important petroliferous sedimentary basins in India.For over a decade,the exploration and extraction of hydrocarbons in these basins.Paleocene-Eocene age rocks bear organic-rich sediments in these basins,including lignite and carbonaceous shale deposits.The present research investigates the source rock properties,petroleum potential and thermal maturity of the carbonaceous shale partings from the lignite mines of Gurha(Bikaner-Nagaur Basin)and Kapurdi(Barmer Basin)using petrographical and geochemical tools.The carbonaceous shales have high organic matter(OM),with considerable total organic carbon(TOC)contents ranging from 13%to 39%.Furthermore,they contain hydrogen-rich kerogen,including types II and II/III,as evidenced by the Rock-Eval and elemental analysis results.The existence of these kerogen types indicates the abundance of reactive(vitrinite and liptinite)macerals.However,the carbonaceous shales from the Bikaner–Nagaur Basin have oil generation potentials,with a high hydrogen index(up to 516 mg HC/g TOC)and a H/C ratio(up to 1.5)along with a significant presence of oil-prone liptinitic macerals.Apart from the geochemical and petrological results,the studied shales have low huminite reflectance(0.31%–0.48%),maximum temperature(S_(2) peak;Tmax)between 419℃ and 429℃,and low production index values(PI:0.01–0.03).These results indicate that these carbonaceous shales contain immature OM,and thereby,they cannot yet release commercial amount of oil.This immaturity level in the studied outcrop section is due to the shallow burial depth.Geochemical proxies further indicate the presence of both oil and gas-prone source rocks.展开更多
The Ordos Basin(OB)in the western part of the North China Craton(NCC),was located at the jointed area of multi-plates and has recorded the Mesozoic tectonic characteristics.Its tectonic evolution in the Mesozoic is si...The Ordos Basin(OB)in the western part of the North China Craton(NCC),was located at the jointed area of multi-plates and has recorded the Mesozoic tectonic characteristics.Its tectonic evolution in the Mesozoic is significant to understand the tectonic transformation of the northern margin of the NCC.In this work,the detrital zircon and apatite(U-Th)/He chronological system were analyzed in the northern part of the OB,and have provided new evidence for the regional tectonic evolution.The(U-Th)/He chronological data states the weighted ages of 240‒235 Ma,141 Ma with the peak distribution of 244 Ma,219 Ma,173 Ma,147‒132 Ma.The thermal evolution,geochronological data,and regional unconformities have proved four stages of regional tectonic evolution for the OB and its surroundings in the Mesozoic:(1)The Late Permian-Early Triassic;(2)the Late Triassic-Early Jurassic;(3)the Late Jurassic-Early Cretaceous;(4)the Late Cretaceous-Early Paleogene.It is indicated that the multi-directional convergence from the surrounding tectonic units has controlled the Mesozoic tectonic evolution of the OB.Four-stage tectonic evolution reflected the activation or end of different plate movements and provided new time constraints for the regional tectonic evolution of the NCC in the Mesozoic.展开更多
Carbonic acid produced by the dissolution of atmospheric and soil CO_(2)in water is usually the most dominant catalyst for chemical weathering,but a sulfuric aciddriven phenomenon,different from usual,was found in the...Carbonic acid produced by the dissolution of atmospheric and soil CO_(2)in water is usually the most dominant catalyst for chemical weathering,but a sulfuric aciddriven phenomenon,different from usual,was found in the orogenic belt watersheds dominated by silicate bedrock.This study,rooted in comprehensive field investigations in the Manas River Basin(MRB)north of the Tianshan Mountains,delves into the mechanisms and impacts of sulfuric and carbonic acid as catalysts driving diff erent types of chemical weathering in the Central Asian Orogenic Belt.Quantitative analyses elucidate that carbonate weathering constitutes 52.4%of the total chemical weathering,while silicate and evaporite account for 18.6%and 25.3%,respectively,with anthropogenic activities and atmospheric precipitation having little eff ect.The estimated total chemical weathering rate in MRB is approximately 0.075×10^(6)mol/km^(2)/year.Quantitative findings further suggest that,preceding carbonate precipitation(<10^(4)year),chemical weathering can absorb CO_(2).Subsequently,and following carbonate precipitation(10^(4)-10^(7)year),it will release CO_(2).The release significantly surpasses the global average CO_(2)consumption,contributing to a noteworthy climate impact.This study underscores the distinctive weathering mechanisms,wherein sulfuric acid emerges as the predominant catalyst.The quantity of sulfuric acid as a catalyst is approximately three times that of carbonic acid.Sulfuric acid-driven carbonate rock weathering(SCW)is identified as the sole chemical weathering type with a net CO_(2)release eff ect.SCW CO_(2)release flux(5176 mol/km^(2)/year)is roughly 2.5 times the CO_(2)absorption by Ca-Mg silicate weathering,highlighting the pivotal role of chemical weathering in sourcing atmospheric CO_(2)over the timescales of carbonate precipitation and sulfate reduction.Lastly,this study posits that catalyst and transport limitations are the most plausible critical factors in MRB.The interplay between sulfuric acid and dissolved CO_(2)competitively shapes the types and rates of chemical weathering reactions.展开更多
The productivity of vegetation is influenced by both climate change and human activities.Understanding the specific contributions of these influencing factors is crucial for ecological conservation and regional sustai...The productivity of vegetation is influenced by both climate change and human activities.Understanding the specific contributions of these influencing factors is crucial for ecological conservation and regional sustainability.This study utilized a combination of multi-source data to examine the spatiotemporal patterns of Net Primary Productivity(NPP)in the Yellow River Basin(YRB),China from 1982 to 2020.Additionally,a scenario-based approach was employed to compare Potential NPP(PNPP)with Actual NPP(ANPP)to determine the relative roles of climatic and human factors in NPP changes.The PNPP was estimated using the Lund-Potsdam-Jena General Ecosystem Simulator(LPJ-GUESS)model,while ANPP was evaluated by the Carnegie-Ames-Stanford Approach(CASA)model using different NDVI data sources.Both model simulations revealed that significant greening occurring in the YRB,with a gradual decrease observed from southeast to northwest.According to the LPJ_GUESS model simulations,areas experiencing an increasing trend in NPP accounted for 86.82% of the YRB.When using GIMMS and MODIS NDVI data with CASA model simulations,areas showing an increasing trend in NPP accounted for 71.42% and 97.02%,respectively.Furthermore,both climatic conditions and human factors had positive effects on vegetation restoration;approximated 41.15% of restored vegetation areas were influenced by both climate variation and human activities,while around 31.93% were solely affected by climate variation.However,it was found that human activities served as the principal driving force of vegetation degradation within the YRB,impacting 26.35% of degraded areas solely due to human activities.Therefore,effective management strategies encompassing both human activities and climate change adaptation are imperative for facilitating vegetation restoration within this region.These findings will valuable for enhancing our understanding in NPP changes and its underlying factors,thereby contributing to improved ecological management and the pursuit of regional carbon neutrality in China.展开更多
Mesozoic-Palaeozoic marine carbonate rocks are crucial hydrocarbon reservoirs in the Central Uplift area of the South Yellow Sea Basin(SYSB).Due to the scarcity of boreholes and the significant heterogeneity of carbon...Mesozoic-Palaeozoic marine carbonate rocks are crucial hydrocarbon reservoirs in the Central Uplift area of the South Yellow Sea Basin(SYSB).Due to the scarcity of boreholes and the significant heterogeneity of carbonate reservoirs,the distribution of porous carbonate reservoirs and their related key controlling factors remain unclear.In this study,factors affecting the distribution of porous Carboniferous-Early Permian carbonate reservoirs in the SYSB were investigated through seismic inversion and isotope analysis.The log-seismic characteristics of porous carbonate reservoirs,sensitive lithology parameters,and physical property parameters were extracted and analyzed.The pre-stack simultaneous inversion technique was applied to predict the lithology and physical properties of porous carbonate reservoirs.Moreover,the sedimentary of carbonate was analyzed using isotopes of carbon,oxygen,and strontium.The results show that porous carbonate reservoirs are mainly developed in the open platform sediments with porosities of 3%-5%and are mainly distributed in the paleo-highland(Huanglong Formation and Chuanshan Formation)and the slope of paleo-highland(Hezhou Formation).The porous carbonate reservoirs of the Qixia Formation are only locally developed.In addition,the negativeδ13C excursions indicate a warm and humid tropical climate with three sea-level fluctuations in the study area from the Carboniferous to Early Permian.The favorable conditions for developing porous carbonate rocks include the sedimentary environment and diagenetic process.The primary pore tends to form in high-energy environments of the paleo-highland,and the secondary pore is increased by dissolution during the syngenetic or quasi-syngenetic period.According to the hydrocarbon potential analysis,the Late Ordovician Wufeng Formation and Lower Silurian Gaojiabian Formation are the source rocks in the high-maturity-over-maturity stage,the Carboniferous-Lower Permian carbonate is the good reservoirs,and the Late Permian Longtan-Dalong Formation is the stable seal,ensuring a huge hydrocarbon accumulation potential in SYSB.The methods proposed in this study can be applied to other carbonate-dominated strata worldwide.展开更多
The Tianshan Mountains of Central Asia,highly sensitive to climate change,has been comprehensively assessed for its ecosystem vulnerability across multiple aspects.However,studies on the region's main river system...The Tianshan Mountains of Central Asia,highly sensitive to climate change,has been comprehensively assessed for its ecosystem vulnerability across multiple aspects.However,studies on the region's main river systems and hydropower resources remain limited.Thus,examining the impact of climate change on the runoff and gross hydropower potential(GHP)of this region is essential for promoting sustainable development and effective management of water and hydropower resources.This study focused on the Kaidu River Basin that is situated above the Dashankou Hydropower Station on the southern slope of the Tianshan Mountains,China.By utilizing an ensemble of bias-corrected global climate models(GCMs)from Coupled Model Intercomparison Project Phase 6(CMIP6)and the Variable Infiltration Capacity(VIC)model coupled with a glacier module(VIC-Glacier),we examined the variations in future runoff and GHP during 2017-2070 under four shared socio-economic pathway(SSP)scenarios(SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5)compared to the baseline period(1985-2016).The findings indicated that precipitation and temperature in the Kaidu River Basin exhibit a general upward trend under the four SSP scenarios,with the fastest rate of increase in precipitation under the SSP2-4.5 scenario and the most significant changes in mean,maximum,and minimum temperatures under the SSP5-8.5 scenario,compared to the baseline period(1980-2016).Future runoff in the basin is projected to decrease,with rates of decline under the SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5 scenarios being 3.09,3.42,7.04,and 7.20 m^(3)/s per decade,respectively.The trends in GHP are consistent with runoff,with rates of decline in GHP under the SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5 scenarios at 507.74,563.33,1158.44,and 1184.52 MW/10a,respectively.Compared to the baseline period(1985-2016),the rates of change in GHP under the SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5 scenarios are-20.66%,-20.93%,-18.91%,and-17.49%,respectively.The Kaidu River Basin will face significant challenges in water and hydropower resources in the future,underscoring the need to adjust water resource management and hydropower planning within the basin.展开更多
The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantl...The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.展开更多
Huaihe River Basin(HRB) is located in China’s north-south climatic transition zone,which is very sensitive to global climate change.Based on the daily maximum temperature,minimum temperature,and precipitation data of...Huaihe River Basin(HRB) is located in China’s north-south climatic transition zone,which is very sensitive to global climate change.Based on the daily maximum temperature,minimum temperature,and precipitation data of 40 meteorological stations and nine monthly large-scale ocean-atmospheric circulation indices data during 1959–2019,we present an assessment of the spatial and temporal variations of extreme temperature and precipitation events in the HRB using nine extreme climate indices,and analyze the teleconnection relationship between extreme climate indices and large-scale ocean-atmospheric circulation indices.The results show that warm extreme indices show a significant(P < 0.05) increasing trend,while cold extreme indices(except for cold spell duration) and diurnal temperature range(DTR) show a significant decreasing trend.Furthermore,all extreme temperature indices show significant mutations during 1959-2019.Spatially,a stronger warming trend occurs in eastern HRB than western HRB,while maximum 5-d precipitation(Rx5day) and rainstorm days(R25) show an increasing trend in the southern,central,and northwestern regions of HRB.Arctic oscillation(AO),Atlantic multidecadal oscillation(AMO),and East Atlantic/Western Russia(EA/WR) have a stronger correlation with extreme climate indices compared to other circulation indices.AO and AMO(EA/WR) exhibit a significant(P < 0.05) negative(positive)correlation with frost days and diurnal temperature range.Extreme warm events are strongly correlated with the variability of AMO and EA/WR in most parts of HRB,while extreme cold events are closely related to the variability of AO and AMO in eastern HRB.In contrast,AMO,AO,and EA/WR show limited impacts on extreme precipitation events in most parts of HRB.展开更多
The Linxia Basin is characterized by an abundance of Cenozoic sediments,that contain exceptionally rich fossil resources.Equids are abundant in the Linxia Basin,the fossil record of equids in this region including 16 ...The Linxia Basin is characterized by an abundance of Cenozoic sediments,that contain exceptionally rich fossil resources.Equids are abundant in the Linxia Basin,the fossil record of equids in this region including 16 species that represent 10 genera.In comparison to other classic late Cenozoic areas in China,the Linxia Basin stands out,because the fauna and chronological data accompanying Linxia equids render them remarkably useful for biostratigraphy.The anchitheriines in the region,such as Anchitherium and Sinohippus,represent early equids that appeared in the late stages of the middle and late Miocene,respectively.Among the equines,most species of Chinese hipparions have been identified in the Linxia Basin and some species of the genera Hipparion and Hippotherium have FAD records for China.Furthermore,Equus eisenmannae is one of the earliest known species of Equus in the Old World and is well-represented at the Longdan locality.Some species with precise geohistorical distributions can serve as standards for high-resolution chronological units within this framework.Located at the eastern margin of the Tibetan Plateau and subject to considerable uplift,the Linxia Basin has served as a biogeographic transition area for equids throughout the late Cenozoic.展开更多
The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth ...The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth of 8780e8840 m,also the deepest in Asia in terms of oil discovery.In this paper,the geochemical characteristics of Sinian oil and gas from the well were investigated and compared with those of Cambrian oil and gas discovered in the same basin.The oil samples,with Pr/Ph ratio of 0.78 and a whole oil carbon isotopic value of31.6‰,have geochemical characteristics similar to those of Ordovician oils from the No.1 fault in the North Shuntuoguole area(also named Shunbei area)and the Middle Cambrian oil from wells Zhongshen 1(ZS1)and Zhongshen 5(ZS5)of Tazhong Uplift.The maturity of light hydrocarbons,diamondoids and aromatic fractions all suggest an approximate maturity of 1.5%e1.7%Ro for the samples.The(4-+3-)methyldiamantane concentration of the samples is 113.5 mg/g,indicating intense cracking with a cracking degree of about 80%,which is consistent with the high bottom hole temperature(179℃).The Sinian gas samples are dry with a dryness coefficient of 0.97.The gas is a mixture of kerogen-cracking gas and oil-cracking gas and has Ro values ranging between 1.5%and 1.7%,and methane carbon isotopic values of41.6‰.Based on the equivalent vitrinite reflectance(R_(eqv)=1.51%e1.61%)and the thermal evolution of source rocks from the Cambrian Yu'ertusi Formation of the same well,it is proposed that the Sinian oil and gas be mainly sourced from the Cambrian Yu'ertusi Formation during the Himalayan period but probably also be joined by hydrocarbon of higher maturity that migrated from other source rocks in deeper formations.The discovery of Sinian oil and gas from Well TS5 suggests that the ancient ultra-deep strata in the northern Tarim Basin have the potential for finding volatile oil or condensate reservoirs.展开更多
To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin,this paper presents a systematic research on the coal rock distribution,coal ro...To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin,this paper presents a systematic research on the coal rock distribution,coal rock reservoirs,coal rock quality,and coal rock gas features,resources and enrichment.Coal rock gas is a high-quality resource distinct from coalbed methane,and it has unique features in terms of burial depth,gas source,reservoir,gas content,and carbon isotopic composition.The Benxi Formation coal rocks cover an area of 16×104km^(2),with thicknesses ranging from 2 m to 25 m,primarily consisting of bright and semi-bright coals with primitive structures and low volatile and ash contents,indicating a good coal quality.The medium-to-high rank coal rocks have the total organic carbon(TOC)content ranging from 33.49%to 86.11%,averaging75.16%.They have a high degree of thermal evolution(Roof 1.2%-2.8%),and a high gas-generating capacity.They also have high stable carbon isotopic values(δ13C1of-37.6‰to-16‰;δ13C2of-21.7‰to-14.3‰).Deep coal rocks develop matrix pores such as gas bubble pores,organic pores,and inorganic mineral pores,which,together with cleats and fractures,form good reservoir spaces.The coal rock reservoirs exhibit the porosity of 0.54%-10.67%(averaging 5.42%)and the permeability of(0.001-14.600)×10^(-3)μm^(2)(averaging 2.32×10^(-3)μm^(2)).Vertically,there are five types of coal rock gas accumulation and dissipation combinations,among which the coal rock-mudstone gas accumulation combination and the coal rock-limestone gas accumulation combination are the most important,with good sealing conditions and high peak values of total hydrocarbon in gas logging.A model of coal rock gas accumulation has been constructed,which includes widespread distribution of medium-to-high rank coal rocks continually generating gas,matrix pores and cleats/fractures in coal rocks acting as large-scale reservoir spaces,tight cap rocks providing sealing,source-reservoir integration,and five types of efficient enrichment patterns(lateral pinchout complex,lenses,low-amplitude structures,nose-like structures,and lithologically self-sealing).According to the geological characteristics of coal rock gas,the Benxi Formation is divided into 8 plays,and the estimated coal rock gas resources with a buried depth of more than 2000 m are more than 12.33×10^(12)m^(3).The above understandings guide the deployment of risk exploration.Two wells drilled accordingly obtained an industrial gas flow,driving the further deployment of exploratory and appraisal wells.Substantial breakthroughs have been achieved,with the possible reserves over a trillion cubic meters and the proved reserves over a hundred billion cubic meters,which is of great significance for the reserves increase and efficient development of natural gas in China.展开更多
文摘The Bikaner-Nagaur and Barmer Basins(Rajasthan)are the most important petroliferous sedimentary basins in India.For over a decade,the exploration and extraction of hydrocarbons in these basins.Paleocene-Eocene age rocks bear organic-rich sediments in these basins,including lignite and carbonaceous shale deposits.The present research investigates the source rock properties,petroleum potential and thermal maturity of the carbonaceous shale partings from the lignite mines of Gurha(Bikaner-Nagaur Basin)and Kapurdi(Barmer Basin)using petrographical and geochemical tools.The carbonaceous shales have high organic matter(OM),with considerable total organic carbon(TOC)contents ranging from 13%to 39%.Furthermore,they contain hydrogen-rich kerogen,including types II and II/III,as evidenced by the Rock-Eval and elemental analysis results.The existence of these kerogen types indicates the abundance of reactive(vitrinite and liptinite)macerals.However,the carbonaceous shales from the Bikaner–Nagaur Basin have oil generation potentials,with a high hydrogen index(up to 516 mg HC/g TOC)and a H/C ratio(up to 1.5)along with a significant presence of oil-prone liptinitic macerals.Apart from the geochemical and petrological results,the studied shales have low huminite reflectance(0.31%–0.48%),maximum temperature(S_(2) peak;Tmax)between 419℃ and 429℃,and low production index values(PI:0.01–0.03).These results indicate that these carbonaceous shales contain immature OM,and thereby,they cannot yet release commercial amount of oil.This immaturity level in the studied outcrop section is due to the shallow burial depth.Geochemical proxies further indicate the presence of both oil and gas-prone source rocks.
基金This study was jointly supported by the Science&Technology Fundamental Resources Investigation Program(2022FY101800)National Science Foundation(92162212)+1 种基金the project from the Key Laboratory of Tectonics and Petroleum Resources(China University of Geosciences,Wuhan)(TPR-2022-22)the International Geoscience Programme(IGCP-675)。
文摘The Ordos Basin(OB)in the western part of the North China Craton(NCC),was located at the jointed area of multi-plates and has recorded the Mesozoic tectonic characteristics.Its tectonic evolution in the Mesozoic is significant to understand the tectonic transformation of the northern margin of the NCC.In this work,the detrital zircon and apatite(U-Th)/He chronological system were analyzed in the northern part of the OB,and have provided new evidence for the regional tectonic evolution.The(U-Th)/He chronological data states the weighted ages of 240‒235 Ma,141 Ma with the peak distribution of 244 Ma,219 Ma,173 Ma,147‒132 Ma.The thermal evolution,geochronological data,and regional unconformities have proved four stages of regional tectonic evolution for the OB and its surroundings in the Mesozoic:(1)The Late Permian-Early Triassic;(2)the Late Triassic-Early Jurassic;(3)the Late Jurassic-Early Cretaceous;(4)the Late Cretaceous-Early Paleogene.It is indicated that the multi-directional convergence from the surrounding tectonic units has controlled the Mesozoic tectonic evolution of the OB.Four-stage tectonic evolution reflected the activation or end of different plate movements and provided new time constraints for the regional tectonic evolution of the NCC in the Mesozoic.
基金support from the Third Xinjiang Scientific Expedition Program(2021XJKK0803)the National Natural Science Foundation of China(No.41930640)the Project of the Second Comprehensive Scientific Investigation on the Qinghai-Tibetan Plateau(2019QZKK1003)。
文摘Carbonic acid produced by the dissolution of atmospheric and soil CO_(2)in water is usually the most dominant catalyst for chemical weathering,but a sulfuric aciddriven phenomenon,different from usual,was found in the orogenic belt watersheds dominated by silicate bedrock.This study,rooted in comprehensive field investigations in the Manas River Basin(MRB)north of the Tianshan Mountains,delves into the mechanisms and impacts of sulfuric and carbonic acid as catalysts driving diff erent types of chemical weathering in the Central Asian Orogenic Belt.Quantitative analyses elucidate that carbonate weathering constitutes 52.4%of the total chemical weathering,while silicate and evaporite account for 18.6%and 25.3%,respectively,with anthropogenic activities and atmospheric precipitation having little eff ect.The estimated total chemical weathering rate in MRB is approximately 0.075×10^(6)mol/km^(2)/year.Quantitative findings further suggest that,preceding carbonate precipitation(<10^(4)year),chemical weathering can absorb CO_(2).Subsequently,and following carbonate precipitation(10^(4)-10^(7)year),it will release CO_(2).The release significantly surpasses the global average CO_(2)consumption,contributing to a noteworthy climate impact.This study underscores the distinctive weathering mechanisms,wherein sulfuric acid emerges as the predominant catalyst.The quantity of sulfuric acid as a catalyst is approximately three times that of carbonic acid.Sulfuric acid-driven carbonate rock weathering(SCW)is identified as the sole chemical weathering type with a net CO_(2)release eff ect.SCW CO_(2)release flux(5176 mol/km^(2)/year)is roughly 2.5 times the CO_(2)absorption by Ca-Mg silicate weathering,highlighting the pivotal role of chemical weathering in sourcing atmospheric CO_(2)over the timescales of carbonate precipitation and sulfate reduction.Lastly,this study posits that catalyst and transport limitations are the most plausible critical factors in MRB.The interplay between sulfuric acid and dissolved CO_(2)competitively shapes the types and rates of chemical weathering reactions.
基金Under the auspices of National Natural Science Foundation of China(No.41991231,U21A2011)。
文摘The productivity of vegetation is influenced by both climate change and human activities.Understanding the specific contributions of these influencing factors is crucial for ecological conservation and regional sustainability.This study utilized a combination of multi-source data to examine the spatiotemporal patterns of Net Primary Productivity(NPP)in the Yellow River Basin(YRB),China from 1982 to 2020.Additionally,a scenario-based approach was employed to compare Potential NPP(PNPP)with Actual NPP(ANPP)to determine the relative roles of climatic and human factors in NPP changes.The PNPP was estimated using the Lund-Potsdam-Jena General Ecosystem Simulator(LPJ-GUESS)model,while ANPP was evaluated by the Carnegie-Ames-Stanford Approach(CASA)model using different NDVI data sources.Both model simulations revealed that significant greening occurring in the YRB,with a gradual decrease observed from southeast to northwest.According to the LPJ_GUESS model simulations,areas experiencing an increasing trend in NPP accounted for 86.82% of the YRB.When using GIMMS and MODIS NDVI data with CASA model simulations,areas showing an increasing trend in NPP accounted for 71.42% and 97.02%,respectively.Furthermore,both climatic conditions and human factors had positive effects on vegetation restoration;approximated 41.15% of restored vegetation areas were influenced by both climate variation and human activities,while around 31.93% were solely affected by climate variation.However,it was found that human activities served as the principal driving force of vegetation degradation within the YRB,impacting 26.35% of degraded areas solely due to human activities.Therefore,effective management strategies encompassing both human activities and climate change adaptation are imperative for facilitating vegetation restoration within this region.These findings will valuable for enhancing our understanding in NPP changes and its underlying factors,thereby contributing to improved ecological management and the pursuit of regional carbon neutrality in China.
基金This study was supported by the project ofthe Science and Technology Innovation Fund of Command Center of Natural Resources Intergrated Survey entitled“Temporal and spatial distribution of paleochannel and origin of organic carbon burial in the Western Bohai Sea since 2.28Ma”(KC20220011)the project entitled“Characterization of Carboniferous-Early Permian heterogeneous porous carbonate reservoirs and hydrocarbon potential analysis in the central uplift of the South Yellow Sea Basin”(KLSG2304)+3 种基金by the Key laboratory of Submarine Science,Ministry of Natural Resources,the project entitled“1∶50000 Marine regional Geological survey in Caofeidian Sea Area,Bohai Sea”(ZD20220602)“1∶250000 Marine regional Geological survey in Weihai Sea Area,North Yellow Sea”(DD20230412)“Geological survey on tectonic and sedimentary conditions of Laoshan uplift”(DD2016015)by the China Geological Survey,and the project entitled“Study on Hydrocarbon Accumulation Failure and Fluid Evolution Reduction of the Permian Reservoir in the Laoshan Uplift,South Yellow Sea”(42076220)organized by the National Natural Science Foundation of China.
文摘Mesozoic-Palaeozoic marine carbonate rocks are crucial hydrocarbon reservoirs in the Central Uplift area of the South Yellow Sea Basin(SYSB).Due to the scarcity of boreholes and the significant heterogeneity of carbonate reservoirs,the distribution of porous carbonate reservoirs and their related key controlling factors remain unclear.In this study,factors affecting the distribution of porous Carboniferous-Early Permian carbonate reservoirs in the SYSB were investigated through seismic inversion and isotope analysis.The log-seismic characteristics of porous carbonate reservoirs,sensitive lithology parameters,and physical property parameters were extracted and analyzed.The pre-stack simultaneous inversion technique was applied to predict the lithology and physical properties of porous carbonate reservoirs.Moreover,the sedimentary of carbonate was analyzed using isotopes of carbon,oxygen,and strontium.The results show that porous carbonate reservoirs are mainly developed in the open platform sediments with porosities of 3%-5%and are mainly distributed in the paleo-highland(Huanglong Formation and Chuanshan Formation)and the slope of paleo-highland(Hezhou Formation).The porous carbonate reservoirs of the Qixia Formation are only locally developed.In addition,the negativeδ13C excursions indicate a warm and humid tropical climate with three sea-level fluctuations in the study area from the Carboniferous to Early Permian.The favorable conditions for developing porous carbonate rocks include the sedimentary environment and diagenetic process.The primary pore tends to form in high-energy environments of the paleo-highland,and the secondary pore is increased by dissolution during the syngenetic or quasi-syngenetic period.According to the hydrocarbon potential analysis,the Late Ordovician Wufeng Formation and Lower Silurian Gaojiabian Formation are the source rocks in the high-maturity-over-maturity stage,the Carboniferous-Lower Permian carbonate is the good reservoirs,and the Late Permian Longtan-Dalong Formation is the stable seal,ensuring a huge hydrocarbon accumulation potential in SYSB.The methods proposed in this study can be applied to other carbonate-dominated strata worldwide.
基金funded by the National Natural Science Foundation of China(42067062).
文摘The Tianshan Mountains of Central Asia,highly sensitive to climate change,has been comprehensively assessed for its ecosystem vulnerability across multiple aspects.However,studies on the region's main river systems and hydropower resources remain limited.Thus,examining the impact of climate change on the runoff and gross hydropower potential(GHP)of this region is essential for promoting sustainable development and effective management of water and hydropower resources.This study focused on the Kaidu River Basin that is situated above the Dashankou Hydropower Station on the southern slope of the Tianshan Mountains,China.By utilizing an ensemble of bias-corrected global climate models(GCMs)from Coupled Model Intercomparison Project Phase 6(CMIP6)and the Variable Infiltration Capacity(VIC)model coupled with a glacier module(VIC-Glacier),we examined the variations in future runoff and GHP during 2017-2070 under four shared socio-economic pathway(SSP)scenarios(SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5)compared to the baseline period(1985-2016).The findings indicated that precipitation and temperature in the Kaidu River Basin exhibit a general upward trend under the four SSP scenarios,with the fastest rate of increase in precipitation under the SSP2-4.5 scenario and the most significant changes in mean,maximum,and minimum temperatures under the SSP5-8.5 scenario,compared to the baseline period(1980-2016).Future runoff in the basin is projected to decrease,with rates of decline under the SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5 scenarios being 3.09,3.42,7.04,and 7.20 m^(3)/s per decade,respectively.The trends in GHP are consistent with runoff,with rates of decline in GHP under the SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5 scenarios at 507.74,563.33,1158.44,and 1184.52 MW/10a,respectively.Compared to the baseline period(1985-2016),the rates of change in GHP under the SSP1-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5 scenarios are-20.66%,-20.93%,-18.91%,and-17.49%,respectively.The Kaidu River Basin will face significant challenges in water and hydropower resources in the future,underscoring the need to adjust water resource management and hydropower planning within the basin.
基金supported by the National Natural Science Foundation of China(Grant No.42072168)the National Key R&D Program of China(Grant No.2019YFC0605405)the Fundamental Research Funds for the Central Universities(Grant No.2023ZKPYDC07)。
文摘The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.
基金Under the auspices of National Natural Science Foundation of China(No.52279016,51909106,51879108,42002247,41471160)Natural Science Foundation of Guangdong Province,China(No.2020A1515011038,2020A1515111054)+1 种基金Special Fund for Science and Technology Development in 2016 of Department of Science and Technology of Guangdong Province,China(No.2016A020223007)the Project of Jinan Science and Technology Bureau(No.2021GXRC070)。
文摘Huaihe River Basin(HRB) is located in China’s north-south climatic transition zone,which is very sensitive to global climate change.Based on the daily maximum temperature,minimum temperature,and precipitation data of 40 meteorological stations and nine monthly large-scale ocean-atmospheric circulation indices data during 1959–2019,we present an assessment of the spatial and temporal variations of extreme temperature and precipitation events in the HRB using nine extreme climate indices,and analyze the teleconnection relationship between extreme climate indices and large-scale ocean-atmospheric circulation indices.The results show that warm extreme indices show a significant(P < 0.05) increasing trend,while cold extreme indices(except for cold spell duration) and diurnal temperature range(DTR) show a significant decreasing trend.Furthermore,all extreme temperature indices show significant mutations during 1959-2019.Spatially,a stronger warming trend occurs in eastern HRB than western HRB,while maximum 5-d precipitation(Rx5day) and rainstorm days(R25) show an increasing trend in the southern,central,and northwestern regions of HRB.Arctic oscillation(AO),Atlantic multidecadal oscillation(AMO),and East Atlantic/Western Russia(EA/WR) have a stronger correlation with extreme climate indices compared to other circulation indices.AO and AMO(EA/WR) exhibit a significant(P < 0.05) negative(positive)correlation with frost days and diurnal temperature range.Extreme warm events are strongly correlated with the variability of AMO and EA/WR in most parts of HRB,while extreme cold events are closely related to the variability of AO and AMO in eastern HRB.In contrast,AMO,AO,and EA/WR show limited impacts on extreme precipitation events in most parts of HRB.
基金supported by National Key Research and Development Program of China(Grant No.2023YFF0804501)the Youth Innovation Promotion Association,Chinese Academy of Sciences(Grant No.2021069)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB31000000)the Second Comprehensive Scientific Expedition on the Tibetan Plateau(Grant No.2019QZKK0705)the All China Commission of Stratigraphy(Grant No.DD20221829).
文摘The Linxia Basin is characterized by an abundance of Cenozoic sediments,that contain exceptionally rich fossil resources.Equids are abundant in the Linxia Basin,the fossil record of equids in this region including 16 species that represent 10 genera.In comparison to other classic late Cenozoic areas in China,the Linxia Basin stands out,because the fauna and chronological data accompanying Linxia equids render them remarkably useful for biostratigraphy.The anchitheriines in the region,such as Anchitherium and Sinohippus,represent early equids that appeared in the late stages of the middle and late Miocene,respectively.Among the equines,most species of Chinese hipparions have been identified in the Linxia Basin and some species of the genera Hipparion and Hippotherium have FAD records for China.Furthermore,Equus eisenmannae is one of the earliest known species of Equus in the Old World and is well-represented at the Longdan locality.Some species with precise geohistorical distributions can serve as standards for high-resolution chronological units within this framework.Located at the eastern margin of the Tibetan Plateau and subject to considerable uplift,the Linxia Basin has served as a biogeographic transition area for equids throughout the late Cenozoic.
基金funded by projects of the National Natural Science Foundation of China(Nos.:42272167,U19B6003 and 41772153)projects of the Science&Technology Department of Sinopec(Nos.:P22121,P21058-8 and P23167).
文摘The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth of 8780e8840 m,also the deepest in Asia in terms of oil discovery.In this paper,the geochemical characteristics of Sinian oil and gas from the well were investigated and compared with those of Cambrian oil and gas discovered in the same basin.The oil samples,with Pr/Ph ratio of 0.78 and a whole oil carbon isotopic value of31.6‰,have geochemical characteristics similar to those of Ordovician oils from the No.1 fault in the North Shuntuoguole area(also named Shunbei area)and the Middle Cambrian oil from wells Zhongshen 1(ZS1)and Zhongshen 5(ZS5)of Tazhong Uplift.The maturity of light hydrocarbons,diamondoids and aromatic fractions all suggest an approximate maturity of 1.5%e1.7%Ro for the samples.The(4-+3-)methyldiamantane concentration of the samples is 113.5 mg/g,indicating intense cracking with a cracking degree of about 80%,which is consistent with the high bottom hole temperature(179℃).The Sinian gas samples are dry with a dryness coefficient of 0.97.The gas is a mixture of kerogen-cracking gas and oil-cracking gas and has Ro values ranging between 1.5%and 1.7%,and methane carbon isotopic values of41.6‰.Based on the equivalent vitrinite reflectance(R_(eqv)=1.51%e1.61%)and the thermal evolution of source rocks from the Cambrian Yu'ertusi Formation of the same well,it is proposed that the Sinian oil and gas be mainly sourced from the Cambrian Yu'ertusi Formation during the Himalayan period but probably also be joined by hydrocarbon of higher maturity that migrated from other source rocks in deeper formations.The discovery of Sinian oil and gas from Well TS5 suggests that the ancient ultra-deep strata in the northern Tarim Basin have the potential for finding volatile oil or condensate reservoirs.
基金Supported by the PetroChina Science and Technology Major Project(2023ZZ18-03)Changqing Oilfield Major Science and Technology Project(2023DZZ01)。
文摘To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin,this paper presents a systematic research on the coal rock distribution,coal rock reservoirs,coal rock quality,and coal rock gas features,resources and enrichment.Coal rock gas is a high-quality resource distinct from coalbed methane,and it has unique features in terms of burial depth,gas source,reservoir,gas content,and carbon isotopic composition.The Benxi Formation coal rocks cover an area of 16×104km^(2),with thicknesses ranging from 2 m to 25 m,primarily consisting of bright and semi-bright coals with primitive structures and low volatile and ash contents,indicating a good coal quality.The medium-to-high rank coal rocks have the total organic carbon(TOC)content ranging from 33.49%to 86.11%,averaging75.16%.They have a high degree of thermal evolution(Roof 1.2%-2.8%),and a high gas-generating capacity.They also have high stable carbon isotopic values(δ13C1of-37.6‰to-16‰;δ13C2of-21.7‰to-14.3‰).Deep coal rocks develop matrix pores such as gas bubble pores,organic pores,and inorganic mineral pores,which,together with cleats and fractures,form good reservoir spaces.The coal rock reservoirs exhibit the porosity of 0.54%-10.67%(averaging 5.42%)and the permeability of(0.001-14.600)×10^(-3)μm^(2)(averaging 2.32×10^(-3)μm^(2)).Vertically,there are five types of coal rock gas accumulation and dissipation combinations,among which the coal rock-mudstone gas accumulation combination and the coal rock-limestone gas accumulation combination are the most important,with good sealing conditions and high peak values of total hydrocarbon in gas logging.A model of coal rock gas accumulation has been constructed,which includes widespread distribution of medium-to-high rank coal rocks continually generating gas,matrix pores and cleats/fractures in coal rocks acting as large-scale reservoir spaces,tight cap rocks providing sealing,source-reservoir integration,and five types of efficient enrichment patterns(lateral pinchout complex,lenses,low-amplitude structures,nose-like structures,and lithologically self-sealing).According to the geological characteristics of coal rock gas,the Benxi Formation is divided into 8 plays,and the estimated coal rock gas resources with a buried depth of more than 2000 m are more than 12.33×10^(12)m^(3).The above understandings guide the deployment of risk exploration.Two wells drilled accordingly obtained an industrial gas flow,driving the further deployment of exploratory and appraisal wells.Substantial breakthroughs have been achieved,with the possible reserves over a trillion cubic meters and the proved reserves over a hundred billion cubic meters,which is of great significance for the reserves increase and efficient development of natural gas in China.