In-situ construction of abundant active centers on hierarchically porous carbon electrode toward high-performance phosphate electrosorption: Synergistic effect of electric field and capture sites

Phosphate removal is crucial for eutrophication control and water quality improvement.Electro-assisted adsorption,an eco-friendly elec-trosorption process,exhibited a promising potential for wastewater treatment.However,there are few works focused on phosphate electro-sorption,and reported electrodes cannot attach satisfactory removal capacities and rates.Herein,electro-assisted adsorption of phosphate via in-situ construction of La active centers on hierarchically porous carbon(LaPC)has been originally demonstrated.The resulted LaPC composite not only possessed a hierarchically porous structure with uniformly dispersed La active sites,but also provided good conductivity for interfacial electron transfer.The LaPC electrode achieved an ultrahigh phosphate electrosorption capability of 462.01 mg g^(-1) at 1 V,outperforming most existing electrodes.The superior phosphate removal performance originates from abundant active centers formed by the coupling of electricfield and capture sites.Besides,the stability and selectivity toward phosphate capture were maintained well even under comprehensive conditions.Moreover,a series of kinetics and isotherms models were employed to validate the electrosorption process.This work demonstrates a deep understanding and promotes a new level of phosphate electrosorption.

An Adaptive Congestion Control Optimization Strategy in SDN-Based Data Centers

The traffic within data centers exhibits bursts and unpredictable patterns.This rapid growth in network traffic has two consequences:it surpasses the inherent capacity of the network’s link bandwidth and creates an imbalanced network load.Consequently,persistent overload situations eventually result in network congestion.The Software Defined Network(SDN)technology is employed in data centers as a network architecture to enhance performance.This paper introduces an adaptive congestion control strategy,named DA-DCTCP,for SDN-based Data Centers.It incorporates Explicit Congestion Notification(ECN)and Round-Trip Time(RTT)to establish congestion awareness and an ECN marking model.To mitigate incorrect congestion caused by abrupt flows,an appropriate ECN marking is selected based on the queue length and its growth slope,and the congestion window(CWND)is adjusted by calculating RTT.Simultaneously,the marking threshold for queue length is continuously adapted using the current queue length of the switch as a parameter to accommodate changes in data centers.The evaluation conducted through Mininet simulations demonstrates that DA-DCTCP yields advantages in terms of throughput,flow completion time(FCT),latency,and resistance against packet loss.These benefits contribute to reducing data center congestion,enhancing the stability of data transmission,and improving throughput.

Generation of macroscopic entanglement in ensemble systems based on silicon vacancy centers

Entanglement in macroscopic systems,as a fundamental quantum resource,has been utilized to propel the advancement of quantum technology and probe the boundary between the quantum and classical realms.This study focuses on a unique hybrid quantum system comprising of an ensemble of silicon vacancy(SiV)centers coupled to phononic waveguides in diamond via strain interactions.By employing two sets of time-dependent,non-overlapping driving fields,we investigate the generation process and dynamic properties of macroscopic quantum entanglement,providing fresh insights into the behavior of such hybrid quantum systems.Furthermore,it paves the way for new possibilities in utilizing quantum entanglement as an information carrier in quantum information processing and quantum communication.

Molecular dynamics simulation study of nitrogen vacancy color centers prepared by carbon ion implantation into diamond

Nitrogen vacancy(NV)color centers in diamond have useful applications in quantum sensing andfluorescent marking.They can be gen-erated experimentally by ion implantation,femtosecond lasers,and chemical vapor deposition.However,there is a lack of studies of the yield of NV color centers at the atomic scale.In the molecular dynamics simulations described in this paper,NV color centers are pre-pared by ion implantation in diamond with pre-doped nitrogen and subsequent annealing.The differences between the yields of NV color centers produced by implantation of carbon(C)and nitrogen(N)ions,respectively,are investigated.It is found that C-ion implantation gives a greater yield of NV color centers and superior location accuracy.The effects of different pre-doping concentrations(400–1500 ppm)and implantation energies(1.0–3.0 keV)on the NV color center yield are analyzed,and it is shown that a pre-doping concentra-tion of 1000 ppm with 2 keV C-ion implantation can produce a 13%yield of NV color centers after 1600 K annealing for 7.4 ns.Finally,a brief comparison of the NV color center identification methods is presented,and it is found that the error rate of an analysis utiliz-ing the identify diamond structure coordination analysis method is reduced by about 7%compared with conventional identification+methods.

Review of Load Balancing Mechanisms in SDN-Based Data Centers

With the continuous expansion of the data center network scale, changing network requirements, and increasing pressure on network bandwidth, the traditional network architecture can no longer meet people’s needs. The development of software defined networks has brought new opportunities and challenges to future networks. The data and control separation characteristics of SDN improve the performance of the entire network. Researchers have integrated SDN architecture into data centers to improve network resource utilization and performance. This paper first introduces the basic concepts of SDN and data center networks. Then it discusses SDN-based load balancing mechanisms for data centers from different perspectives. Finally, it summarizes and looks forward to the study on SDN-based load balancing mechanisms and its development trend.

Research on Adaptability Analysis of Environmental Space Demand and Design Optimization of Daycare Centers: Taking Chongqing’s Community F as an Example

Currently,there is a lack of research on the detailed environmental spatial design of community daycare centers at the micro level.This study focuses on Community F in Chongqing,using the elderly’s“willingness to demand”as a central aspect.It examines indoor and outdoor environmental space needs at a micro level,considering both functional requirements and spiritual needs based on existing research.The analysis incorporates three adaptive elements:current construction,surrounding environment,and operational management.It explores the feasibility of restructuring spatial layouts,utilizing local resources,and integrating Bayu cultural characteristics.Finally,through design optimization practices,the study proposes three strategies for aging optimization:functional integration and interaction,user-friendly facilities,and emotional connections to place.

Research on the Comprehensive Development Trend of National Fitness Activity Centers

With the further advancement of the“National Fitness”strategy and the continuous development of the information age,the National Fitness Activity Centers have become more comprehensive.The comprehensiveness is reflected in the design of diversified sports functions and spaces.The article serves to explore the comprehensive development trend of National Fitness Activity Centers.Through summarizing and sorting out domestic and foreign cases,the trend of the comprehensive development of National Fitness Activity Centers is predicted at three levels:industry,city,and individual functions.

Energy Cost Minimization Using String Matching Algorithm in Geo-Distributed Data Centers

Data centers are being distributed worldwide by cloud service providers(CSPs)to save energy costs through efficient workload alloca-tion strategies.Many CSPs are challenged by the significant rise in user demands due to their extensive energy consumption during workload pro-cessing.Numerous research studies have examined distinct operating cost mitigation techniques for geo-distributed data centers(DCs).However,oper-ating cost savings during workload processing,which also considers string-matching techniques in geo-distributed DCs,remains unexplored.In this research,we propose a novel string matching-based geographical load balanc-ing(SMGLB)technique to mitigate the operating cost of the geo-distributed DC.The primary goal of this study is to use a string-matching algorithm(i.e.,Boyer Moore)to compare the contents of incoming workloads to those of documents that have already been processed in a data center.A successful match prevents the global load balancer from sending the user’s request to a data center for processing and displaying the results of the previously processed workload to the user to save energy.On the contrary,if no match can be discovered,the global load balancer will allocate the incoming workload to a specific DC for processing considering variable energy prices,the number of active servers,on-site green energy,and traces of incoming workload.The results of numerical evaluations show that the SMGLB can minimize the operating expenses of the geo-distributed data centers more than the existing workload distribution techniques.

Ultralow-Energy-Barrier H_(2)O_(2)Dissociation on Coordinatively Unsaturated Metal Centers in Binary Ce-Fe Prussian Blue Analogue for Efficient and Stable Photo-Fenton Catalysis

The low intrinsic activity of Fenton catalytic site and high demand for light-energy input inhibit the organic-pollution control efficiency of photo-Fenton process.Here,through structural design with density functional theory(DFT)calculations,Ce is predicted to enable the construction of coordinatively unsaturated metal centers(CUCs)in Prussian blue analogue(PBA),which can strongly adsorb H_(2)O_(2)and donate sufficient electrons for directly splitting the O-O bond to produceOH.Using a substitution-co-assembly strategy,binary Ce-Fe PBA is then prepared,which rapidly degrades sulfamethoxazole with the pseudo-first-order kinetic rate constant exceeding reported values by 1-2 orders of magnitude.Meanwhile,the photogenerated electrons reduce Fe(Ⅲ)and Ce(Ⅳ)to promote the metal valence cycle in CUCs and make sulfamethoxazole degradation efficiency only lose 6.04%in 5 runs.Overall,by introducing rare earth metals into transition metal-organic frameworks,this work guides the whole process for highly active CUCs from design and construction to mechanism exploration with DFT calculations,enabling ultrafast and stable photo-Fenton catalysis.

Contraceptive Experiences of Women of Procreation Age Who Attended Two HealthCenters in the City of Abidjan (Cote d’Ivoire)

Introduction: Maternal mortality, which is estimated at 614 deaths per 100,000 births in Côte d’Ivoire, is associated with a low national contraceptive prevalence rate of 13.9%. In this study, we are interested in the contraceptive experiences of women who attend health centers to estimate their rate of contraceptive use and to assess the factors involved in the use of modern contraceptive methods among women of childbearing age who are exposed to the risk of pregnancy. Method: A descriptive cross-sectional study was conducted from December 2018 to September 2019 among 423 women, who attended two health centers in Abidjan. A bivariate analysis identified factors associated with contraceptive use by these women. A descriptive analysis determined the means for the quantitative variables and the frequencies and percentages of qualitative variables. Interpretation of results was based on significance (α = 5%, 95% CI). Results: Contraceptive prevalence was 37%. There was a significant relationship between contraceptive use and the socio-demographic and reproductive characteristics of women (p Conclusion: Women who were over 35 years age, uneducated, primary school graduates, housewives, unemployed, in the informal sector, Muslims, nulliparous, and lacking information and decision-making power were less likely to use modern contraceptive methods. They are the target population for strategic interventions to improve contraceptive prevalence.

Crossing Limit Cycles of Planar Piecewise Hamiltonian Systems with Linear Centers Separated by Two Parallel Straight Lines

In this paper, we have studied several classes of planar piecewise Hamiltonian systems with three zones separated by two parallel straight lines. Firstly, we give the maximal number of limit cycles in these classes of systems with a center in two zones and without equilibrium points in the other zone (or with a center in one zone and without equilibrium points in the other zones). In addition, we also give examples to illustrate that it can reach the maximal number.

On the Feasibility of the Chinese County-Level Convergence Media Centers in Participating in International Communication:Evidence from CDHT’s First-Hand Communication Practice

With the advent of new technologies,China is faced with the practical need to enhance its international communication capacity and address reforms in the modes,content,and channels of international communication.Therefore,more efforts should be made to further enrich the participants in international communication by optimizing China’s four-level journalism communication system and crafting a“great external publicity pattern.”Guiding and promoting county-level convergence media centers to participate in international communication is conducive to promoting the building of a vertical international communication system and a multi-level integrated communication matrix and facilitating the resource alignment and information sharing between domestic and international communication.In practice,some county-level convergence media centers in China have achieved certain results in international communication.A good example is the Chengdu Hi-tech Industrial Development Zone(CDHT),a pioneer in the reform of Chinese county-level convergence media.Therefore,this paper has used CDHT as an example to discuss the reality and basic conditions for Chinese county-level convergence media centers to participate in international communication and put forward general paths for county-level convergence media centers to engage in international communication.

An Overview of NV Centers

This paper is a literature review on the operating theory of NV centers and its applications. Extensive material online had been reviewed to provide a comprehensive explanation of NV centers in this literature review.

A Brief Introduction to Infrastructure Planning for Next-Generation Smart Computing Data Centers

Globally,digital technology and the digital economy have propelled technological revolution and industrial change,and it has become one of the main grounds of international industrial competition.It was estimated that the scale of China’s digital economy would reach 50 trillion yuan in 2022,accounting for more than 40%of GDP,presenting great market potential and room for the growth of the digital economy.With the rapid development of the digital economy,the state attaches great importance to the construction of digital infrastructure and has introduced a series of policies to promote the systematic development and large-scale deployment of digital infrastructure.In 2022 the Chinese government planned to build 8 arithmetic hubs and 10 national data center clusters nationwide.To proactively address the future demand for AI across various scenarios,there is a need for a well-structured computing power infrastructure.The data center,serving as the pivotal hub for computing power,has evolved from the conventional cloud center to a more intelligent computing center,allowing for a diversified convergence of computing power supply.Besides,the data center accommodates a diverse array of arithmetic business forms from customers,reflecting the multi-industry developmental trend.The arithmetic service platform is consistently broadening its scope,with ongoing optimization and innovation in the design scheme of machine room processes.The widespread application of submerged phase-change liquid cooling technology and cold plate cooling technology introduces a series of new challenges to the construction of digital infrastructure.This paper delves into the design objectives,industry considerations,layout,and other dimensions of a smart computing center and proposes a new-generation data center solution that is“flexible,resilient,green,and low-carbon.”

Congestion Control Using In-Network Telemetry for Lossless Datacenters

In the Ethernet lossless Data Center Networks (DCNs) deployedwith Priority-based Flow Control (PFC), the head-of-line blocking problemis still difficult to prevent due to PFC triggering under burst trafficscenarios even with the existing congestion control solutions. To addressthe head-of-line blocking problem of PFC, we propose a new congestioncontrol mechanism. The key point of Congestion Control Using In-NetworkTelemetry for Lossless Datacenters (ICC) is to use In-Network Telemetry(INT) technology to obtain comprehensive congestion information, which isthen fed back to the sender to adjust the sending rate timely and accurately.It is possible to control congestion in time, converge to the target rate quickly,and maintain a near-zero queue length at the switch when using ICC. Weconducted Network Simulator-3 (NS-3) simulation experiments to test theICC’s performance. When compared to Congestion Control for Large-ScaleRDMA Deployments (DCQCN), TIMELY: RTT-based Congestion Controlfor the Datacenter (TIMELY), and Re-architecting Congestion Managementin Lossless Ethernet (PCN), ICC effectively reduces PFC pause messages andFlow Completion Time (FCT) by 47%, 56%, 34%, and 15.3×, 14.8×, and11.2×, respectively.

NEWTON'S THEOREM WITH RESPECT TO A LOT OFCENTERS AND THEIR APPLICATIONS

In this paper we shall extend the paper [1] to a separate Taylor's Theorem with respect to a lot of centers, namely Newton's Theorem Of a lot of centers. From it we obtain the analogous results in the paper [2]. namely an interpolation formula of the difference of higher order. Finally we give their applications.

Language Training Centers: Factors Related to Their Success

A survey of language training centers(LTCs)in Dalian,China was conducted,to ascertain the strengths and weaknesses,or the differentiating factors,of such centers.The survey was undertaken to understand the current landscape of after-school institutes in the region,particularly those that offer training in English as a second/foreign language.The information uncovered by the research is considered beneficial not only to entrepreneurs who may wish to be involved in this industry,but also to college English majors who may wish to teach at an LTC.

How Chinese Financial Centers Integrate into Global Financial Center Networks:An Empirical Study Based on Overseas Expansion of Chinese Financial Service Firms

The increasing globalization of the Chinese economy has been enabled by both Chinese financial institutions operating globally as well as international firms operating within China. In geographical terms, this has been organized through a number of strategic cities serving as gateways for the exchange of financial functions, products and practices between China and the global economy. Drawing on location data of financial service firms in China listed on stock exchanges in Shenzhen, Shanghai and Hong Kong, this paper shows that Chinese financial firms are expanding globally and how Chinese financial centers are positioned and connected in the urban networks shaped by these financial service firms. It is found that Hong Kong, China, holds strategic positions in the integration of Chinese cities into global financial center networks, and that establishing a foothold in global financial centers such as New York and London has been a priority for Chinese financial institutions. The increasing capital flows directed by Chinese financial institutionssuggests a shifting global financial geography, with numerous Chinese cities playing increasingly important roles within global financial center networks.

Identifying Global Monsoon Troughs and Global Atmospheric Centers of Action on a Pentad Scale

Using two datasets of global pentad grid precipitation and global 850 hPa geopotential height during 1979-2007,this study identified global monsoon troughs and global atmospheric centers of action (ACAs) on a pentad scale.The global monsoon troughs consist of planetary-scale monsoon troughs and peninsula-scale monsoon troughs.Forced by seasonal variations in solar radiation,the inter-tropical convergence zones (ITCZs) represent the planetary-scale monsoon troughs,which are active and shift over the tropical North Pacific,the tropical North Atlantic,and the tropical South Indian oceans.The peninsula-scale monsoon troughs are originated from regional land-sea topography and varied with contrasts in seasonal land-sea surface temperatures and precipitation.During the boreal summer,five peninsula-scale troughs and one planetary-scale trough are distributed in the Asia-Northwest Pacific (NWP) region.In total,22 troughs,nine monsoon troughs,and 19 ACAs in the lower troposphere were identified.Relevant ACAs may be useful in constructing regional monsoon and circulation indices.

Paired-Pd(Ⅱ) centers embedded in HKUST-1 framework: Tuning the selectivity from dimethyl carbonate to dimethyl oxalate

CO oxidative coupling to dimethyl oxalate(DMO) is the most crucial step in coal to ethylene glycol. Pdbased supported catalysts have been verified effective for generating DMO, but concomitant generation of dimethyl carbonate(DMC) is always unavoidable. It is generally accepted that Pd(0) is the active species for producing DMO, while Pd(II) for DMC. However, density functional theory calculations have proposed that the selectivity to DMO or DMC highly depends on the space state of Pd species rather than its oxidative state. It is thus urgently desired to develop high-efficient catalysts with well-defined structure,and further to elucidate the structure-performance relationship. In this work, HKUST-1 with unique structure of paired-Cu(Ⅱ) centers was chosen as ideal support to construct the catalysts with respective paired-Pd(Ⅱ) centers and isolated-Pd(Ⅱ) centers via in situ Pd species doping. In despite of featuring Pdδ+(δ≈2) oxidation state, the synthesized paired-Pd(Ⅱ)/HKUST-1 catalyst still exhibited DMO as dominant product(90.8% of DMO selectivity). For isolated-Pd(Ⅱ)/HKUST-1 catalyst, however, the main product was DMC(84.8% of DMC selectivity). Based on catalyst characterizations, the structures of paired-Pd(Ⅱ) centers and isolated-Pd(Ⅱ) centers were determined. DMO was generated from the coupling of adjacent *COOCH;intermediates adsorbed on paired-Pd(Ⅱ) centers, while DMC was produced from the reaction between methyl nitrite and the *COOCH;intermediates formed on isolated-Pd(Ⅱ) centers. Current work is the first MOFs-based catalyst with well-defined structure being applied in CO oxidative coupling reaction, which not only sheds light on the structure-performance relationship, but also inspires the potential of using MOFs as tunable platform to design high-efficient catalysts in heterogeneous catalysis.