Companion cropping can influence cucumber productivity by altering soil chemical characteristics and microbial communities. However, how these alterations affect the growth of cucumber is still unknown. In this study,...Companion cropping can influence cucumber productivity by altering soil chemical characteristics and microbial communities. However, how these alterations affect the growth of cucumber is still unknown. In this study, seven different plant species were selected as companion plants for testing their effects on cucumber productivity. The effects of different companion plants on changes in soil chemical properties such as electrical conductivity (EC) and contents of essential nutrients as well as the structure and abundance of the soil Pseudomonas community were evaluated. The results showed a higher cucumber yield in the wheat/cucumber companion system than that in the cucumber monocultured and other companion cropping systems. The lowest phosphorus (P) and potassium (K) contents in the soil were found in the cucumber monocultured system, and the highest NO3+-N and NH4*-N contents were observed in the rye/cucumber companion system. PCR-denaturing gradient gel electrophoresis (DGGE) and real-time PCR analysis showed that the trifolium/cucumber companion system increased the diversity of the soil Pseudomonas community, while the chrysanthemum/cucumber companion system increased its abundance. Interestingly, plant-soil feedback trials revealed that inoculating the soil of the wheat/cucumber companion system increased the growth of cucumber seedlings. In conclusion, the effects of different companion plants on cucumber productivity, soil chemical characteristics and the soil Pseudomonas community were different, and wheat was a more suitable companion plant for increasing cucumber productivity. In addition, the altered microbial community caused by companion cropping with wheat contributed to increased cucumber productivity.展开更多
[Objective] The study aimed at analysing the chemical characteristics of shallow groundwater and causes of formation around Poyang Lake area. [Method] The quality of shallow groundwater under seven counties or cities ...[Objective] The study aimed at analysing the chemical characteristics of shallow groundwater and causes of formation around Poyang Lake area. [Method] The quality of shallow groundwater under seven counties or cities around Poyang Lake was investigated in 2010, and compared different regions from salinity, hardness, conductivity, hydrochemistry types and so forth, so as to reveal the status quo, change characteristics and reasons of shallow groundwater. [Result] Except for pH, other water quality indicators of shallow groundwater around Poyang Lake were better, attaining Class I water quality standards. Among these regions, the salinity, hardness, conductivity, Na+, K+, Ca2+, Mg2+, Cl- and HCO-3 concentration of shallow groundwater in Nanchang city were up to the maximum values, while pH and SO2-4 concentration were the highest in Duchang County; Mg2+ concentration and pH were the lowest in Poyang County, and hardness, K+, Ca2+, SO2-4 and Cl- concentration in Yongxiu County reached the minimum values, while Na+ concentration, salinity and conductivity were the lowest in Jinxian County. In addition, the better quality of groundwater around Poyang Lake was closely related to the low level of economic development in Jiangxi Province. Meanwhile, many water quality indices in Nanchang City reached the maximum values, and even tended to Class Ⅱ water quality standards, which resulted from the high level of economic development and decisive role of human activities. [Conclusion] The research could provide references for the establishment of management strategies for regional shallow groundwater.展开更多
Taking streaming current(SC)as the electrokinetic parameter,this paper demon- strated the electrokinetic chemical characteristics of humic and dannic acids(HA and DA)in sus- pensions including turbid water,coagulated ...Taking streaming current(SC)as the electrokinetic parameter,this paper demon- strated the electrokinetic chemical characteristics of humic and dannic acids(HA and DA)in sus- pensions including turbid water,coagulated water and HA or DA contained water.Accordingly, the studies were carried out for determining the relationship between streaming current and zeta po- tential ζ(expressed by eleetrophoretie mobility EM)in above water conditions.In addition,the mechanisms of HA effecting on streaming current within or after coagulant addition and the elec- trokinetic detection principles for HA or DA were also investigated on experiments and theoretical analysis.The results indicated that the change of SC like ζ presented meaningful information con- cerning the degree for destabilization of a particulate suspension,and HA or DA in water could re- markably decrease the effect of inorganic coagulant upon streaming current,which is in accordance with their influence on coagulation.展开更多
The anatomical and chemical characteristics of a rolling leaf mutant (rlm) of rice (Oryza sativa L.) and its ecophysiological properties in photosynthesis and apoplastic transport were investigated. Compared with ...The anatomical and chemical characteristics of a rolling leaf mutant (rlm) of rice (Oryza sativa L.) and its ecophysiological properties in photosynthesis and apoplastic transport were investigated. Compared with the wild type (WT), the areas of whole vascular bundles and xylem as well as the ratios of xylem area/whole vascular bundles area and xylem area/phloem area were higher in rim, whereas the area and the width of foliar bulliform cell were lower. The Fourier transform infrared (FTIR) microspectroscopy spectra of foliar cell walls differed greatly between rim and WT. The rim exhibited lower protein and polysaccharide contents of foliar cell walls. An obvious reduction of pectin content was also found in rim by biochemical measurements. Moreover, the rate of photosynthesis was depressed while the conductance of stoma and the intercellular CO2 concentration were enhanced in rim. The PTS fluorescence, which represents the ability of apoplastic transport, was 11% higher in rim than in WT. These results suggest that the changes in anatomical and chemical characteristics of foliar vascular bundles, such as the reduction of proteins, pectins, and other polysaccharides of foliar cell walls, participate in the leaf rolling mutation, and consequently lead to the reduced photosynthetic dynamics and apoplastic transport ability in the mutant.展开更多
Taking tomato "Kate two" as the experimental material, the effects of different dosage of garlic straw on physical and chemical characteristics of continuous cropping soil and root activity of tomato in solar greenh...Taking tomato "Kate two" as the experimental material, the effects of different dosage of garlic straw on physical and chemical characteristics of continuous cropping soil and root activity of tomato in solar greenhouse were studied. The results showed that after applying with garlic straw, maximal and minimal temperatures in 0-15 cm soil layers were directly proportional to the amount of returned garlic straw, which were 2.39 ℃ and 1℃ higher than that of the control respectively. The unit weight was decreasing upon the amount of applied garlic straws of soils in different depths, but the porosity of soil was increasing. For example, unit weight and porosity changed the most significantly in soils in the depths of 0-10 cm, which went down by 6.71% and 6.18%, respectively. Besides, garlic straw returning to field improved soil pH, reduced soil conductivity and soil acidification and relieved soil secondary salinization, especially in 0-20 cm soil layers. In addition to that, the application of garlic straw increased the root activity of tomato (max 31.45%), and delayed root system senescence in late stage. Therefore, garlic straw returning could improve the physical and chemical characteristics of soil by succession planting and root activity of tomato in solar greenhouse.展开更多
1 Introduction The uranium deposits related with Indosinian and Yanshanian granite have provided the abundant resource of uranium during the past several decades in China.The deposits are mainly distributing in the Gu...1 Introduction The uranium deposits related with Indosinian and Yanshanian granite have provided the abundant resource of uranium during the past several decades in China.The deposits are mainly distributing in the Guidong granite展开更多
[ Objective] The aim was to provide scientific basis for purifying water quality, ecological restoration and fishery breeding of GaoBaZhou reservoir multiplication and stocking. [ Method] Monitoring of normal water ph...[ Objective] The aim was to provide scientific basis for purifying water quality, ecological restoration and fishery breeding of GaoBaZhou reservoir multiplication and stocking. [ Method] Monitoring of normal water physical, chemical characteristics and different number of data of GaoBaZhou reservoir was conducted in 2010 and 2011 after different amount of filter-feeding fishes stocking in this reservoir. [ Result] The water physical and chemical factors TN, NO2, NO3-N-N, TP and COD, Chl. a in 2011 were significantly less than 2010, 2011 month average 1.389 mg/L, 0.039 6 rng/L, 1.211 7 mg/L, 0.137 3 mg/L, 16.191 mg/L, 10.226 8 mg/m3, 2010 month average 1.659 mg/L, 0.066 2 mg/L, 1.472 9 mg/L, 0.099 9 rag/L, 18.314 8 mg/L, 14.917 8 mg/L. The calculation results of TSIM showed that 2011 reservoir eutrophication TSIM were less than 2010, up to 53.78 and 57.36. E Coaclusion: The whole reservoir area revealed mild eutrophication (the TSIM 〉 53), and it suggested that the filterfeeding fishes amount could be increased in the reservoir.展开更多
The Kuda ophiolite belongs to the early Paleozoic ophiolite belt in Western Kunlun Mountains and is composed of metamorphic peridotites,cumulate peridotites,mafic volcanic rocks and quartzites(Li et al.,
In order to clarify the chemical properties of rainfall in typical tobacco areas in Chenzhou City, Hunan Province, and analyze its potential for soil and flue-cured tobacco planting, rainfall samples in 2020 were coll...In order to clarify the chemical properties of rainfall in typical tobacco areas in Chenzhou City, Hunan Province, and analyze its potential for soil and flue-cured tobacco planting, rainfall samples in 2020 were collected by rainfall instruments in Fangyuan Town and Aoquan Town of Guiyang County, and the chemical properties that are closely related to the quality of flue-cured tobacco were determined, such as pH, EC, total nitrogen (TN), nitrate nitrogen (), ammonium nitrogen () and ion concentrations (K<sup>+</sup>, Na<sup>+</sup>, Ca<sup>2+</sup>, Mg<sup>2+</sup>, , Al<sup>3+</sup>, , Cl<sup>−</sup>,). The results show that the pH values of rainfall samples at Fangyuan and Aoquan monitoring sites are in the range of 4.92 - 6.17 and 4.93 - 5.69 respectively, with an average of 5.27 and 5.27 respectively. The acid rain characteristic is very obvious, which is mainly dominated by . The variation of rainfall EC has seasonal characteristics. EC is low from January to September, in the range of 6.09 - 56.72 and 11.83 - 30.93 μS/cm respectively, besides, it is high from October to December, in the range of 102.63 - 174.60 and 25.05 - 86.37 μS/cm respectively. The annual deposition of TN was 22.19 and 20.76 kg/hm<sup>2</sup>/yr respectively, which were higher than that in the western regions with less human disturbance, but lower than or equal to that in the developed agricultural regions in eastern China. The proportion of in the annual deposition of TN was higher than that of at two monitoring sites, with an average of 56.51% and 38.86% respectively. Ammonia volatilization from agricultural activities contributed more to rainfall nitrogen content. The ratios of ammonium nitrogen to nitrate nitrogen deposition at two monitoring points were 1.84, 1.81, 1.86 and 1.34, 1.46, and 1.29 during the whole year, summer and autumn, winter and spring respectively. The ratio is higher in summer and autumn than in winter and spring. The weighted average equivalent concentrations of the main ions at two monitoring sites were 238.88 μeq/L and 211.21 μeq/L respectively, and the orders of the ion concentrations were slightly different. Both the concentrations of and are higher, while Mg<sup>2+</sup>, and Al<sup>3+</sup> are lower. , and are mainly from human activities with a contribution rate between 91.90% and 99.35%. Ca<sup>2+</sup> mainly comes from soil and ground dust, besides, Cl<sup>−</sup> and Mg<sup>2+</sup> mainly come from marine sources and K<sup>+</sup> mainly comes from terrestrial sources. In general, the acidic rainfall and higher concentration are beneficial to reducing the high pH value of soil in Aoquan tobacco area and improving the quality of flue-cured tobacco. Higher concentrations of and in rainfall are not conducive to the improvement of flue-cured tobacco quality, because of the high content of soil available sulfur in Chenzhou tobacco area and the characteristics of flue-cured tobacco’s preference for ammonium.展开更多
Some physicochemical characteristics of calamondin(Citrus microcarpa)from Hainan were determined in this study.The mean length,width,and thickness of calamondin were(2.763±0.262),(2.721±0.189),and(2.684±...Some physicochemical characteristics of calamondin(Citrus microcarpa)from Hainan were determined in this study.The mean length,width,and thickness of calamondin were(2.763±0.262),(2.721±0.189),and(2.684±0.201)cm,respectively.The average values for geometric mean diameter,sphericity,fruit shape index,mass,surface area,volume,true density,bulk density and porosity were(2.721±0.196)cm,(98.79±5.149)%,(101.64±7.609)%,(11.18±2.149)g,(23.36±3.362)cm2,(11.16±2.115)cm3,(1.00±0.060)g/cm3,0.44 g/cm3,and(56.40±0.027)%,respectively.The mean edible part,juice rate,and soluble solids were(85.77±3.53),(48.36±4.20),and(7.86±0.09)%,respectively.The total flavonoids,pectin,limonin,reducing sugar and volatile oil contents of the peel were 1.00,7.14,0.51,5.98,and 4.25%,respectively.The total flavonoids,pectin,limonin and reducing sugar contents of the pulp were 0.02,5.04,0.03 and 4.56%,respectively.The total flavonoids,total acid,reducing sugar and vitamin E contents of the juice were 0.11,6.74,0.37%,and 1.68 mg/kg,respectively,while the content of vitamins A,B1,B2,B3,B6,and D in the juice was very low.The seeds had limonin,reducing sugar and oil contents of 0.46,1.39,and 30.46%,respectively.The vitamin B2,B3,B6 and E contents of the fruit residue were 44.83,19.31,17.55,and 15.72 mg/kg,respectively.The amino acid profile of the residue included aspartic acid,glutamate,cystine,serine,glycine,histidine,arginine,threonine,alanine,proline,tyrosine,valine,methionine,isoleucine,leucine,phenylalanine and lysine,with respective contents of 4.42,1.81,2.10,0.78,0.59,0.20,0.72,0.160.67,3.650.50,0.67,0.59,1.00,0.76,0.57 and 0.91 g/kg.展开更多
To analyze the effect of different lowland rice varieties and different cooking methods on physical and chemical characteristics of cooked rice. A factorial randomized block design with two factors was used and each c...To analyze the effect of different lowland rice varieties and different cooking methods on physical and chemical characteristics of cooked rice. A factorial randomized block design with two factors was used and each combination of the factors was repeated three times. The first factor was rice variety(Ciherang and Ciliwung) and the second factor was the cooking method(stovetop, boiling and steaming, and rice cooker). Results showed that Ciherang and Ciliwung varieties were classified into slender grain rice type with yellowred color. The amylose content of Ciherang was classified as moderate, while the amylose content of Ciliwung classified as low. The most abundant amino acid contained in Ciherang and Ciliwung varieties was glutamic acid. Statistical analysis showed that cooking method had significant effects on texture, lightness, chroma, hue and moisture content of cooked rice. Rice cooked with liwet method had the lowest texture value, lowest lightness value, highest chroma value, and highest moisture content.展开更多
Two sulfated polysaccharides, designated MP and SP, were extracted from the marine green alga Enteromorpha linza using hot water and then purified using ion-exchange and size-exclusion chromatography. The anticoagulan...Two sulfated polysaccharides, designated MP and SP, were extracted from the marine green alga Enteromorpha linza using hot water and then purified using ion-exchange and size-exclusion chromatography. The anticoagulant activities of MP and SP were examined by determination of their activated partial thromboplastin time (APTT), thrombin time (TT) and prothrombin time (PT) using human plasma. Results showed that MP and SP were composed of abundant rhamnose with small amounts of xylose and glucuronic acid, whereas SP also contained a small amount of galactose. Approximate molecular weights of MP and SP were 535 and 502 kDa, respectively. As compared with SP, MP had higher contents of sulfate ester (19.0%) and uronic acid (14.9%). The MP mainly consisted of (1→4)-linked rhamnose residues with partially sulfated groups at the C-3 position, and small amounts of (1→3, 4)-linked rhamnose, (1→2,4)-linked rhamnose, (1→4)-linked glucuronic acid and (1→4)-linked xylose residues. The SP contained abundant (1→4)-linked rhamnose with minor amounts of (1→3)-linked rhanmose, (1→3, 4)-linked rhamnose, (1→2, 4)-linked rhanmose, (1→4)4inked glucuronic acid, (1→4)-linked xylose, and (1→3)-linked galactose residues. The sulfate groups were mainly located at C-3 of (1→4)-linked rhamnose residues. Both MP and SP, in particular the former, effectively prolonged APTT and TT. This work demonstrates that MP and SP have unique structural characteristics distinct from those of other sulfated polysaccharides from Enteromorpha. The MP is a potential source of anticoagulant, and the difference in anticoagulant activities of the two sulfated polysaccharides is directly linked to the discrepancy of their chemical features.展开更多
Over-exploitation and sand-gravel mining affect groundwater resources in terms of both quantity and quality. Groundwater level and well yields in and around the sand-gravel pits significantly decrease. Sand-gravel min...Over-exploitation and sand-gravel mining affect groundwater resources in terms of both quantity and quality. Groundwater level and well yields in and around the sand-gravel pits significantly decrease. Sand-gravel mining also changes the turbidity levels and temperature of groundwater. Reduction and destruction of valuable aquifers are significant issues. In this case, the natural state of the aquifer disappears. The Kazan Plain in central Turkey is a dramatic example of these kinds of results. The productive sand-gravel aquifer in the Kazan plain has been substantially damaged due to intensive sand-gravel mining since the 1980s. Additionally, over-exploitation has caused notable declines in groundwater levels, particularly in the 2000s. This study focuses on the hydrogeochemical situation of the Kazan Plain alluvium aquifer after intensive sand-gravel mining and over-exploitation. Groundwater samples were collected seasonally in 2015, five years after the over-exploitation and heavy sand-gravel mining. The decline reached 20 m (about half of the saturated thickness of the sand-gravel aquifer) in the region where the intensive groundwater abstraction lasted until 2010. Some quarries continued to operate until 2010, but after that mining activity continued only at a minimum level. Today, groundwater quality has been significantly degraded due to the over-exploitation of sand-gravel mining and also the cessation of recharge from fresh river water.展开更多
Some of the chemical and physical water qualities of the Graff River in the city of Kut were studied, and for two sites of the river, One was at the Crimea site, the other in the Jihad district, and for the period fro...Some of the chemical and physical water qualities of the Graff River in the city of Kut were studied, and for two sites of the river, One was at the Crimea site, the other in the Jihad district, and for the period from October/2018 to March/2019, Seven variables of river water have been analyzed: temperature PH, electrical conductivity, TDS, turbidity, alkaline, and chloride. The results showed that most of the chemical and physical water properties of the river were in normal proportions and did not rise, except for the turbidity, which was at a very high level, and that the pH values were close to the basal side. The results of the statistical analysis revealed positive significant relationships between the pH and (chloride and TDS). On the other hand, between electrical conductivity and both previous variables as well. And a negative significant connection between temperature and alkaline.展开更多
Soil physicochemical parameters are the physical and chemical characteristics of soil such as pH, bulk density, organic carbon, nitrogen content, and nutrient levels at different soil depths. These parameters vary fro...Soil physicochemical parameters are the physical and chemical characteristics of soil such as pH, bulk density, organic carbon, nitrogen content, and nutrient levels at different soil depths. These parameters vary from one vegetation to the other and from one soil to the other. The study assessed the variations in soil physicochemical parameters of the natural forest and plantations in Agu Eke (Eke bush) in Etti village, Nanka and Umunnebo village, Ufuma both located in Orumba North Local Government Area, Anambra State. The experimental research design and stratified random sampling methods were used for the study and a total of 12 soil samples were collected at 30 cm depth from the selected locations of natural forest, cashew and palm plantations. The samples were analyzed using laboratory Varian AA240 Atomic Absorption Spectrophotometer, after which the result was subjected to statistical analysis—Analysis of Variance (ANOVA). The study found that there was no significant difference (variation) between the moisture contents of natural forests and the plantations;that is, the moisture contents were the same. It was also found that there was no significant variation between the bulk densities of the natural forest, oil plantation, and cashew plantation, meaning that the bulk densities were significantly the same. However, there were significant variations in nitrogen, potassium and phosphates, with p-values: sig = .000 < .05, sig = .010 < .05 and sig = .000 < .05, respectively. That is, the nitrogen and phosphate contents of the natural forest significantly vary more than those of the oil palm and cashew plantations, which probably means that by reducing natural forest to plantation, the nitrogen and phosphate contents of the natural forest reduced from what it used to be when the lands were mere forests. This shows that plantations do not have the same function of maintaining or improving soil quality as natural forests. The study recommended adopting a sustainable plantation agricultural system, such as using diverse nutrient sources (manure and compost), in order to maintain the desired soil quality.展开更多
Size-resolved aerosols were continuously collected by a Nano Sampler for 13 days at an urban site in Beijing during winter 2012 to measure the chemical composition of ambient aerosol particles. Data collected by the N...Size-resolved aerosols were continuously collected by a Nano Sampler for 13 days at an urban site in Beijing during winter 2012 to measure the chemical composition of ambient aerosol particles. Data collected by the Nano Sampler and an ACSM(Aerodyne Aerosol Chemical Speciation Monitor) were compared. Between the data sets,similar trends and strong correlations were observed,demonstrating the validity of the Nano Sampler. PM10 and PM2.5concentrations during the measurement were 150.5 ± 96.0 μg/m3(mean ± standard variation)and 106.9 ± 71.6 μg/m3,respectively. The PM2.5/PM10 ratio was 0.70 ± 0.10,indicating that PM2.5dominated PM10. The aerosol size distributions showed that three size bins of 0.5–1,1–2.5 and 2.5–10 μm contributed 21.8%,23.3% and 26.0% to the total mass concentration(TMC),respectively. OM(organic matter) and SIA(secondary ionic aerosol,mainly SO42-,NO3-and NH4+) were major components of PM2.5. Secondary compounds(SIA and secondary organic carbon) accounted for half of TMC(about 49.8%) in PM2.5,and suggested that secondary aerosols significantly contributed to the serious particulate matter pollution observed in winter. Coal burning,biomass combustion,vehicle emissions and SIA were found to be the main sources of PM2.5. Mass concentrations of water-soluble ions and undetected materials,as well as their fractions in TMC,strikingly increased with deteriorating particle pollution conditions,while OM and EC(elemental carbon) exhibited different variations,with mass concentrations slightly increasing but fractions in TMC decreasing.展开更多
To study the characteristics of precipitation in eastern China, an automatic sampler was used to collect rainwater samples from 19 precipitation events at Mangdang Mountain, Nanping City, Fujiang Province, in the spri...To study the characteristics of precipitation in eastern China, an automatic sampler was used to collect rainwater samples from 19 precipitation events at Mangdang Mountain, Nanping City, Fujiang Province, in the spring of 2009. We used ion chromatography to analyze the ionic components and concentrations, and inductively coupled plasma mass spectrometry (ICP-MS) to analyze dement compositions and contents. The results demonstrated remarkable acidic characteristics: in more than 80% of precipitation events the pH was less than 5.6, with an average of 4.81. Mass concentration results showed SO42- was the main anionic component (36.2% of the total anion mass), while N/-/4+ was the main cationic component (47.7% of the total cation mass) and main ion for acidity neutralization in the rainwater. Organic acid content accounted for 30.9% of total anion mass. The main trace metals were Ca, K, and Na. The S042-/N03- ratio was 1.4, indicating that precipitation in this region was influenced by complex air pollution - the product of individual coal-burning combined with vehicle exhaust pollution. Correlation analysis of the chemical composition of the precipitation indicated that acidity in this region was determined by a combination of all acidic and neutralization ions rather than any single ion component. The results also showed that Na+ and C1- contributions were mainly by seawater; Mg2+ by seawater and crustal materials; the NH4+, K~, Ca2+, NO3- and SO42- by anthropogenic sources; the trace metals were from the Earth's crust; and organic acids were potentially from combustion of biomass.展开更多
Atmospheric particles(total suspended particles(TSPs); particulate matter(PM) with particle size below 10 μm, PM10; particulate matter with particle size below 2.5 μm, PM2.5)were collected and analyzed during ...Atmospheric particles(total suspended particles(TSPs); particulate matter(PM) with particle size below 10 μm, PM10; particulate matter with particle size below 2.5 μm, PM2.5)were collected and analyzed during heating and non-heating periods in Harbin. The sources of PM10 and PM2.5were identified by the chemical mass balance(CMB) receptor model.Results indicated that PM2.5/TSP was the most prevalent and PM2.5was the main component of PM210, while the presence of PM10–100was relatively weak. SO-4and NO-3concentrations were more significant than other ions during the heating period. As compared with the non-heating period, Mn, Ni, Pb, S, Si, Ti, Zn, As, Ba, Cd, Cr, Fe and K were relatively higher during the heating period. In particular, Mn, Ni, S, Si, Ti, Zn and As in PM2.5were obviously higher during the heating period. Organic carbon(OC) in the heating period was 2–5 times higher than in the non-heating period. Elemental carbon(EC) did not change much. OC/EC ratios were 8–11 during the heating period, which was much higher than in other Chinese cities(OC/EC: 4–6). Results from the CMB indicated that 11 pollution sources were identified, of which traffic, coal combustion, secondary sulfate, secondary nitrate, and secondary organic carbon made the greatest contribution. Before the heating period, dust and petrochemical industry made a larger contribution. In the heating period, coal combustion and secondary sulfate were higher. After the heating period, dust and petrochemical industry were higher. Some hazardous components in PM2.5were higher than in PM10, because PM2.5has a higher ability to absorb toxic substances. Thus PM2.5pollution is more significant regarding human health effects in the heating period.展开更多
With the increasing occurrence of haze during the summer, the physicochemical characteristics and toxicity differences in PM2.5 in different seasons are of great concern. Hangzhou is located in an area that has a subt...With the increasing occurrence of haze during the summer, the physicochemical characteristics and toxicity differences in PM2.5 in different seasons are of great concern. Hangzhou is located in an area that has a subtropical monsoon climate where the humidity is very high during both the summer and winter. However, there are limited studies on the seasonal differences in PM2.5 in these weather conditions. In this test, PM2.5 samples were collected in the winter and summer, the morphology and chemical composition of PM2.5 were analyzed, the toxicity of PM2.5 to human bronchial cells BEAS-2B was compared, and the correlation between PM2.5 toxicity and the chemical compo- sition was discussed. The results showed that during both the winter and summer, the main compounds in the PM2.5 samples were water-soluble ions, particularly SO4^2-, NO3^-, and NH4^+, followed by organic components, while heavy metals were present at lower levels. The higher the mass concentration of PM2.5, the greater its impact on cell viability and ROS levels. However, when the mass concentration of PM2.5 was similar, the water extraction from the summer samples showed a greater impact on BEAS-2B than that from the winter samples. The cytotoxicity of PM2.5 was closely associated with heavy metals and organic pollutants but less related to water-soluble ions.展开更多
This paper seeks to identify macroscopic metallogenic mechanisms of various mineral deposits by studying microscopic typomorphic characteristics of typical minerals associated with the deposits and to reveal the mecha...This paper seeks to identify macroscopic metallogenic mechanisms of various mineral deposits by studying microscopic typomorphic characteristics of typical minerals associated with the deposits and to reveal the mechanism of lattice gold in detail by studying both physical and chemical characteristics of quartz from representative gold deposits in the North China Platform.As part of their extensive research,the authors examine the relationship between trace elements with wall rock,the ore-forming media,and gold immigration of various types of gold deposits,including their salinity,type,temperature.These are key factors to revealing the mineralization mechanism,and indicators for mineral prospecting,exploration,mining,and metallurgical technology.In order to address the questions posed,the following methods were used:field investigations of geology and sampling of the representative gold deposits,physical study and chemical analysis of quartz including,but not limited to,fluid inclusions as well as their compositions and trace elements in quartz,the unit cell parameters,electron paramagnetic resonance spectrum(EPR),and infrared spectroscopic analysis(ISA).As a result of this study,the authors observe the following key findings:unit cell parameters of quartz vary with their contents of foreign elements including gold,paragenetic stage,wall rock type,and other factors;the higher the forming temperature and the lower the gold content in quartz,the smaller the unit cell parameters,and vice versa.Additionally,the EPR absorption lines resulted from the O–Al defect center.The density of these types of hole centers increases and the EPR signal strengthens when the temperature decreases.Based on the findings,the authors conclude that lattice gold exists in quartz.Gold,in the form of Au^(+)and/or Au^(3+),entering quartz and producing an electron–hole center,namely,the O-Au hole center,makes the center produce spin resonance absorption and results in the EPR absorption peak#I.Both unit cell parameters and EPR of quartz can potentially be used in mineral prospecting,relative ore-forming temperature determination,and grade control during mining.展开更多
基金supported by the earmarked fund for the China Agriculture Research System (CARS-25)the National Natural Science Foundation of China (31471917)
文摘Companion cropping can influence cucumber productivity by altering soil chemical characteristics and microbial communities. However, how these alterations affect the growth of cucumber is still unknown. In this study, seven different plant species were selected as companion plants for testing their effects on cucumber productivity. The effects of different companion plants on changes in soil chemical properties such as electrical conductivity (EC) and contents of essential nutrients as well as the structure and abundance of the soil Pseudomonas community were evaluated. The results showed a higher cucumber yield in the wheat/cucumber companion system than that in the cucumber monocultured and other companion cropping systems. The lowest phosphorus (P) and potassium (K) contents in the soil were found in the cucumber monocultured system, and the highest NO3+-N and NH4*-N contents were observed in the rye/cucumber companion system. PCR-denaturing gradient gel electrophoresis (DGGE) and real-time PCR analysis showed that the trifolium/cucumber companion system increased the diversity of the soil Pseudomonas community, while the chrysanthemum/cucumber companion system increased its abundance. Interestingly, plant-soil feedback trials revealed that inoculating the soil of the wheat/cucumber companion system increased the growth of cucumber seedlings. In conclusion, the effects of different companion plants on cucumber productivity, soil chemical characteristics and the soil Pseudomonas community were different, and wheat was a more suitable companion plant for increasing cucumber productivity. In addition, the altered microbial community caused by companion cropping with wheat contributed to increased cucumber productivity.
基金Supported by Major Direction Project for Knowledge Innovation Project of Chinese Academy of Sciences (KZCX2-YW-306)Major State Basic Research Development Program (2006CB403200)+1 种基金International Science and Technology Cooperation Project (2006DFB91920)National Key Technology R & D Program in the 11th Five year Plan of China (2007BAB23CO2)
文摘[Objective] The study aimed at analysing the chemical characteristics of shallow groundwater and causes of formation around Poyang Lake area. [Method] The quality of shallow groundwater under seven counties or cities around Poyang Lake was investigated in 2010, and compared different regions from salinity, hardness, conductivity, hydrochemistry types and so forth, so as to reveal the status quo, change characteristics and reasons of shallow groundwater. [Result] Except for pH, other water quality indicators of shallow groundwater around Poyang Lake were better, attaining Class I water quality standards. Among these regions, the salinity, hardness, conductivity, Na+, K+, Ca2+, Mg2+, Cl- and HCO-3 concentration of shallow groundwater in Nanchang city were up to the maximum values, while pH and SO2-4 concentration were the highest in Duchang County; Mg2+ concentration and pH were the lowest in Poyang County, and hardness, K+, Ca2+, SO2-4 and Cl- concentration in Yongxiu County reached the minimum values, while Na+ concentration, salinity and conductivity were the lowest in Jinxian County. In addition, the better quality of groundwater around Poyang Lake was closely related to the low level of economic development in Jiangxi Province. Meanwhile, many water quality indices in Nanchang City reached the maximum values, and even tended to Class Ⅱ water quality standards, which resulted from the high level of economic development and decisive role of human activities. [Conclusion] The research could provide references for the establishment of management strategies for regional shallow groundwater.
文摘Taking streaming current(SC)as the electrokinetic parameter,this paper demon- strated the electrokinetic chemical characteristics of humic and dannic acids(HA and DA)in sus- pensions including turbid water,coagulated water and HA or DA contained water.Accordingly, the studies were carried out for determining the relationship between streaming current and zeta po- tential ζ(expressed by eleetrophoretie mobility EM)in above water conditions.In addition,the mechanisms of HA effecting on streaming current within or after coagulant addition and the elec- trokinetic detection principles for HA or DA were also investigated on experiments and theoretical analysis.The results indicated that the change of SC like ζ presented meaningful information con- cerning the degree for destabilization of a particulate suspension,and HA or DA in water could re- markably decrease the effect of inorganic coagulant upon streaming current,which is in accordance with their influence on coagulation.
基金supported by the National Natural Science Foundation of China (Grant No. 30470274)the Zhejiang Natural Science Foundation of China (Grant No. Y306087)the Zijin Program of Zhejiang University for Young Teachers, China.
文摘The anatomical and chemical characteristics of a rolling leaf mutant (rlm) of rice (Oryza sativa L.) and its ecophysiological properties in photosynthesis and apoplastic transport were investigated. Compared with the wild type (WT), the areas of whole vascular bundles and xylem as well as the ratios of xylem area/whole vascular bundles area and xylem area/phloem area were higher in rim, whereas the area and the width of foliar bulliform cell were lower. The Fourier transform infrared (FTIR) microspectroscopy spectra of foliar cell walls differed greatly between rim and WT. The rim exhibited lower protein and polysaccharide contents of foliar cell walls. An obvious reduction of pectin content was also found in rim by biochemical measurements. Moreover, the rate of photosynthesis was depressed while the conductance of stoma and the intercellular CO2 concentration were enhanced in rim. The PTS fluorescence, which represents the ability of apoplastic transport, was 11% higher in rim than in WT. These results suggest that the changes in anatomical and chemical characteristics of foliar vascular bundles, such as the reduction of proteins, pectins, and other polysaccharides of foliar cell walls, participate in the leaf rolling mutation, and consequently lead to the reduced photosynthetic dynamics and apoplastic transport ability in the mutant.
文摘Taking tomato "Kate two" as the experimental material, the effects of different dosage of garlic straw on physical and chemical characteristics of continuous cropping soil and root activity of tomato in solar greenhouse were studied. The results showed that after applying with garlic straw, maximal and minimal temperatures in 0-15 cm soil layers were directly proportional to the amount of returned garlic straw, which were 2.39 ℃ and 1℃ higher than that of the control respectively. The unit weight was decreasing upon the amount of applied garlic straws of soils in different depths, but the porosity of soil was increasing. For example, unit weight and porosity changed the most significantly in soils in the depths of 0-10 cm, which went down by 6.71% and 6.18%, respectively. Besides, garlic straw returning to field improved soil pH, reduced soil conductivity and soil acidification and relieved soil secondary salinization, especially in 0-20 cm soil layers. In addition to that, the application of garlic straw increased the root activity of tomato (max 31.45%), and delayed root system senescence in late stage. Therefore, garlic straw returning could improve the physical and chemical characteristics of soil by succession planting and root activity of tomato in solar greenhouse.
基金supported by projects from Chinese Geological Survery Programme (12120115035601)
文摘1 Introduction The uranium deposits related with Indosinian and Yanshanian granite have provided the abundant resource of uranium during the past several decades in China.The deposits are mainly distributing in the Guidong granite
基金funded by the National Public Welfare(Agriculture)Special Research(200903048-09)
文摘[ Objective] The aim was to provide scientific basis for purifying water quality, ecological restoration and fishery breeding of GaoBaZhou reservoir multiplication and stocking. [ Method] Monitoring of normal water physical, chemical characteristics and different number of data of GaoBaZhou reservoir was conducted in 2010 and 2011 after different amount of filter-feeding fishes stocking in this reservoir. [ Result] The water physical and chemical factors TN, NO2, NO3-N-N, TP and COD, Chl. a in 2011 were significantly less than 2010, 2011 month average 1.389 mg/L, 0.039 6 rng/L, 1.211 7 mg/L, 0.137 3 mg/L, 16.191 mg/L, 10.226 8 mg/m3, 2010 month average 1.659 mg/L, 0.066 2 mg/L, 1.472 9 mg/L, 0.099 9 rag/L, 18.314 8 mg/L, 14.917 8 mg/L. The calculation results of TSIM showed that 2011 reservoir eutrophication TSIM were less than 2010, up to 53.78 and 57.36. E Coaclusion: The whole reservoir area revealed mild eutrophication (the TSIM 〉 53), and it suggested that the filterfeeding fishes amount could be increased in the reservoir.
基金supported by National Natural Science Foundation Project(grant number 41302051)Shaanxi Province Science Technology Research Development Plan Project(grant number 2014JM2-4037)National Sci-Tech Support Plan Project(grant number 2011BAB06B05-02)
文摘The Kuda ophiolite belongs to the early Paleozoic ophiolite belt in Western Kunlun Mountains and is composed of metamorphic peridotites,cumulate peridotites,mafic volcanic rocks and quartzites(Li et al.,
文摘In order to clarify the chemical properties of rainfall in typical tobacco areas in Chenzhou City, Hunan Province, and analyze its potential for soil and flue-cured tobacco planting, rainfall samples in 2020 were collected by rainfall instruments in Fangyuan Town and Aoquan Town of Guiyang County, and the chemical properties that are closely related to the quality of flue-cured tobacco were determined, such as pH, EC, total nitrogen (TN), nitrate nitrogen (), ammonium nitrogen () and ion concentrations (K<sup>+</sup>, Na<sup>+</sup>, Ca<sup>2+</sup>, Mg<sup>2+</sup>, , Al<sup>3+</sup>, , Cl<sup>−</sup>,). The results show that the pH values of rainfall samples at Fangyuan and Aoquan monitoring sites are in the range of 4.92 - 6.17 and 4.93 - 5.69 respectively, with an average of 5.27 and 5.27 respectively. The acid rain characteristic is very obvious, which is mainly dominated by . The variation of rainfall EC has seasonal characteristics. EC is low from January to September, in the range of 6.09 - 56.72 and 11.83 - 30.93 μS/cm respectively, besides, it is high from October to December, in the range of 102.63 - 174.60 and 25.05 - 86.37 μS/cm respectively. The annual deposition of TN was 22.19 and 20.76 kg/hm<sup>2</sup>/yr respectively, which were higher than that in the western regions with less human disturbance, but lower than or equal to that in the developed agricultural regions in eastern China. The proportion of in the annual deposition of TN was higher than that of at two monitoring sites, with an average of 56.51% and 38.86% respectively. Ammonia volatilization from agricultural activities contributed more to rainfall nitrogen content. The ratios of ammonium nitrogen to nitrate nitrogen deposition at two monitoring points were 1.84, 1.81, 1.86 and 1.34, 1.46, and 1.29 during the whole year, summer and autumn, winter and spring respectively. The ratio is higher in summer and autumn than in winter and spring. The weighted average equivalent concentrations of the main ions at two monitoring sites were 238.88 μeq/L and 211.21 μeq/L respectively, and the orders of the ion concentrations were slightly different. Both the concentrations of and are higher, while Mg<sup>2+</sup>, and Al<sup>3+</sup> are lower. , and are mainly from human activities with a contribution rate between 91.90% and 99.35%. Ca<sup>2+</sup> mainly comes from soil and ground dust, besides, Cl<sup>−</sup> and Mg<sup>2+</sup> mainly come from marine sources and K<sup>+</sup> mainly comes from terrestrial sources. In general, the acidic rainfall and higher concentration are beneficial to reducing the high pH value of soil in Aoquan tobacco area and improving the quality of flue-cured tobacco. Higher concentrations of and in rainfall are not conducive to the improvement of flue-cured tobacco quality, because of the high content of soil available sulfur in Chenzhou tobacco area and the characteristics of flue-cured tobacco’s preference for ammonium.
基金Technical Development Project of Provincial Scientific Research Institutes in Hainan(KYYS-2019-30)Technical Innovation Project of Provincial Scientific Research Institutes in Hainan(jscx202034).
文摘Some physicochemical characteristics of calamondin(Citrus microcarpa)from Hainan were determined in this study.The mean length,width,and thickness of calamondin were(2.763±0.262),(2.721±0.189),and(2.684±0.201)cm,respectively.The average values for geometric mean diameter,sphericity,fruit shape index,mass,surface area,volume,true density,bulk density and porosity were(2.721±0.196)cm,(98.79±5.149)%,(101.64±7.609)%,(11.18±2.149)g,(23.36±3.362)cm2,(11.16±2.115)cm3,(1.00±0.060)g/cm3,0.44 g/cm3,and(56.40±0.027)%,respectively.The mean edible part,juice rate,and soluble solids were(85.77±3.53),(48.36±4.20),and(7.86±0.09)%,respectively.The total flavonoids,pectin,limonin,reducing sugar and volatile oil contents of the peel were 1.00,7.14,0.51,5.98,and 4.25%,respectively.The total flavonoids,pectin,limonin and reducing sugar contents of the pulp were 0.02,5.04,0.03 and 4.56%,respectively.The total flavonoids,total acid,reducing sugar and vitamin E contents of the juice were 0.11,6.74,0.37%,and 1.68 mg/kg,respectively,while the content of vitamins A,B1,B2,B3,B6,and D in the juice was very low.The seeds had limonin,reducing sugar and oil contents of 0.46,1.39,and 30.46%,respectively.The vitamin B2,B3,B6 and E contents of the fruit residue were 44.83,19.31,17.55,and 15.72 mg/kg,respectively.The amino acid profile of the residue included aspartic acid,glutamate,cystine,serine,glycine,histidine,arginine,threonine,alanine,proline,tyrosine,valine,methionine,isoleucine,leucine,phenylalanine and lysine,with respective contents of 4.42,1.81,2.10,0.78,0.59,0.20,0.72,0.160.67,3.650.50,0.67,0.59,1.00,0.76,0.57 and 0.91 g/kg.
基金supported by International Rice Research Institute (IRRI)Research Center of Sub-Optimal Land (PUR-PLSO) Universitas Sriwijaya
文摘To analyze the effect of different lowland rice varieties and different cooking methods on physical and chemical characteristics of cooked rice. A factorial randomized block design with two factors was used and each combination of the factors was repeated three times. The first factor was rice variety(Ciherang and Ciliwung) and the second factor was the cooking method(stovetop, boiling and steaming, and rice cooker). Results showed that Ciherang and Ciliwung varieties were classified into slender grain rice type with yellowred color. The amylose content of Ciherang was classified as moderate, while the amylose content of Ciliwung classified as low. The most abundant amino acid contained in Ciherang and Ciliwung varieties was glutamic acid. Statistical analysis showed that cooking method had significant effects on texture, lightness, chroma, hue and moisture content of cooked rice. Rice cooked with liwet method had the lowest texture value, lowest lightness value, highest chroma value, and highest moisture content.
基金supported by the National Natural Science Foundation of China (No.41076086)the National Oceanographic Center of Qingdao, China and the Science and Technology Development Program of Shandong Province, China (No.2010GHY10509)
文摘Two sulfated polysaccharides, designated MP and SP, were extracted from the marine green alga Enteromorpha linza using hot water and then purified using ion-exchange and size-exclusion chromatography. The anticoagulant activities of MP and SP were examined by determination of their activated partial thromboplastin time (APTT), thrombin time (TT) and prothrombin time (PT) using human plasma. Results showed that MP and SP were composed of abundant rhamnose with small amounts of xylose and glucuronic acid, whereas SP also contained a small amount of galactose. Approximate molecular weights of MP and SP were 535 and 502 kDa, respectively. As compared with SP, MP had higher contents of sulfate ester (19.0%) and uronic acid (14.9%). The MP mainly consisted of (1→4)-linked rhamnose residues with partially sulfated groups at the C-3 position, and small amounts of (1→3, 4)-linked rhamnose, (1→2,4)-linked rhamnose, (1→4)-linked glucuronic acid and (1→4)-linked xylose residues. The SP contained abundant (1→4)-linked rhamnose with minor amounts of (1→3)-linked rhanmose, (1→3, 4)-linked rhamnose, (1→2, 4)-linked rhanmose, (1→4)4inked glucuronic acid, (1→4)-linked xylose, and (1→3)-linked galactose residues. The sulfate groups were mainly located at C-3 of (1→4)-linked rhamnose residues. Both MP and SP, in particular the former, effectively prolonged APTT and TT. This work demonstrates that MP and SP have unique structural characteristics distinct from those of other sulfated polysaccharides from Enteromorpha. The MP is a potential source of anticoagulant, and the difference in anticoagulant activities of the two sulfated polysaccharides is directly linked to the discrepancy of their chemical features.
文摘Over-exploitation and sand-gravel mining affect groundwater resources in terms of both quantity and quality. Groundwater level and well yields in and around the sand-gravel pits significantly decrease. Sand-gravel mining also changes the turbidity levels and temperature of groundwater. Reduction and destruction of valuable aquifers are significant issues. In this case, the natural state of the aquifer disappears. The Kazan Plain in central Turkey is a dramatic example of these kinds of results. The productive sand-gravel aquifer in the Kazan plain has been substantially damaged due to intensive sand-gravel mining since the 1980s. Additionally, over-exploitation has caused notable declines in groundwater levels, particularly in the 2000s. This study focuses on the hydrogeochemical situation of the Kazan Plain alluvium aquifer after intensive sand-gravel mining and over-exploitation. Groundwater samples were collected seasonally in 2015, five years after the over-exploitation and heavy sand-gravel mining. The decline reached 20 m (about half of the saturated thickness of the sand-gravel aquifer) in the region where the intensive groundwater abstraction lasted until 2010. Some quarries continued to operate until 2010, but after that mining activity continued only at a minimum level. Today, groundwater quality has been significantly degraded due to the over-exploitation of sand-gravel mining and also the cessation of recharge from fresh river water.
文摘Some of the chemical and physical water qualities of the Graff River in the city of Kut were studied, and for two sites of the river, One was at the Crimea site, the other in the Jihad district, and for the period from October/2018 to March/2019, Seven variables of river water have been analyzed: temperature PH, electrical conductivity, TDS, turbidity, alkaline, and chloride. The results showed that most of the chemical and physical water properties of the river were in normal proportions and did not rise, except for the turbidity, which was at a very high level, and that the pH values were close to the basal side. The results of the statistical analysis revealed positive significant relationships between the pH and (chloride and TDS). On the other hand, between electrical conductivity and both previous variables as well. And a negative significant connection between temperature and alkaline.
文摘Soil physicochemical parameters are the physical and chemical characteristics of soil such as pH, bulk density, organic carbon, nitrogen content, and nutrient levels at different soil depths. These parameters vary from one vegetation to the other and from one soil to the other. The study assessed the variations in soil physicochemical parameters of the natural forest and plantations in Agu Eke (Eke bush) in Etti village, Nanka and Umunnebo village, Ufuma both located in Orumba North Local Government Area, Anambra State. The experimental research design and stratified random sampling methods were used for the study and a total of 12 soil samples were collected at 30 cm depth from the selected locations of natural forest, cashew and palm plantations. The samples were analyzed using laboratory Varian AA240 Atomic Absorption Spectrophotometer, after which the result was subjected to statistical analysis—Analysis of Variance (ANOVA). The study found that there was no significant difference (variation) between the moisture contents of natural forests and the plantations;that is, the moisture contents were the same. It was also found that there was no significant variation between the bulk densities of the natural forest, oil plantation, and cashew plantation, meaning that the bulk densities were significantly the same. However, there were significant variations in nitrogen, potassium and phosphates, with p-values: sig = .000 < .05, sig = .010 < .05 and sig = .000 < .05, respectively. That is, the nitrogen and phosphate contents of the natural forest significantly vary more than those of the oil palm and cashew plantations, which probably means that by reducing natural forest to plantation, the nitrogen and phosphate contents of the natural forest reduced from what it used to be when the lands were mere forests. This shows that plantations do not have the same function of maintaining or improving soil quality as natural forests. The study recommended adopting a sustainable plantation agricultural system, such as using diverse nutrient sources (manure and compost), in order to maintain the desired soil quality.
基金supported by the National Natural Science Foundation of China (No.41175018)the Ministry of Science and Technology of China (No.2013CB955804)the special fund of State Key Joint Laboratory of Environment Simulation and Pollution Control (Nos.13Z02ESPCP and 13K04ESPCP)
文摘Size-resolved aerosols were continuously collected by a Nano Sampler for 13 days at an urban site in Beijing during winter 2012 to measure the chemical composition of ambient aerosol particles. Data collected by the Nano Sampler and an ACSM(Aerodyne Aerosol Chemical Speciation Monitor) were compared. Between the data sets,similar trends and strong correlations were observed,demonstrating the validity of the Nano Sampler. PM10 and PM2.5concentrations during the measurement were 150.5 ± 96.0 μg/m3(mean ± standard variation)and 106.9 ± 71.6 μg/m3,respectively. The PM2.5/PM10 ratio was 0.70 ± 0.10,indicating that PM2.5dominated PM10. The aerosol size distributions showed that three size bins of 0.5–1,1–2.5 and 2.5–10 μm contributed 21.8%,23.3% and 26.0% to the total mass concentration(TMC),respectively. OM(organic matter) and SIA(secondary ionic aerosol,mainly SO42-,NO3-and NH4+) were major components of PM2.5. Secondary compounds(SIA and secondary organic carbon) accounted for half of TMC(about 49.8%) in PM2.5,and suggested that secondary aerosols significantly contributed to the serious particulate matter pollution observed in winter. Coal burning,biomass combustion,vehicle emissions and SIA were found to be the main sources of PM2.5. Mass concentrations of water-soluble ions and undetected materials,as well as their fractions in TMC,strikingly increased with deteriorating particle pollution conditions,while OM and EC(elemental carbon) exhibited different variations,with mass concentrations slightly increasing but fractions in TMC decreasing.
基金supported by the National Basic Research Program (973) of China (No. 2005CB422204)
文摘To study the characteristics of precipitation in eastern China, an automatic sampler was used to collect rainwater samples from 19 precipitation events at Mangdang Mountain, Nanping City, Fujiang Province, in the spring of 2009. We used ion chromatography to analyze the ionic components and concentrations, and inductively coupled plasma mass spectrometry (ICP-MS) to analyze dement compositions and contents. The results demonstrated remarkable acidic characteristics: in more than 80% of precipitation events the pH was less than 5.6, with an average of 4.81. Mass concentration results showed SO42- was the main anionic component (36.2% of the total anion mass), while N/-/4+ was the main cationic component (47.7% of the total cation mass) and main ion for acidity neutralization in the rainwater. Organic acid content accounted for 30.9% of total anion mass. The main trace metals were Ca, K, and Na. The S042-/N03- ratio was 1.4, indicating that precipitation in this region was influenced by complex air pollution - the product of individual coal-burning combined with vehicle exhaust pollution. Correlation analysis of the chemical composition of the precipitation indicated that acidity in this region was determined by a combination of all acidic and neutralization ions rather than any single ion component. The results also showed that Na+ and C1- contributions were mainly by seawater; Mg2+ by seawater and crustal materials; the NH4+, K~, Ca2+, NO3- and SO42- by anthropogenic sources; the trace metals were from the Earth's crust; and organic acids were potentially from combustion of biomass.
基金supported by the National Natural Science Foundation of China(No.51408168)the Open Project of the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.ES201417)
文摘Atmospheric particles(total suspended particles(TSPs); particulate matter(PM) with particle size below 10 μm, PM10; particulate matter with particle size below 2.5 μm, PM2.5)were collected and analyzed during heating and non-heating periods in Harbin. The sources of PM10 and PM2.5were identified by the chemical mass balance(CMB) receptor model.Results indicated that PM2.5/TSP was the most prevalent and PM2.5was the main component of PM210, while the presence of PM10–100was relatively weak. SO-4and NO-3concentrations were more significant than other ions during the heating period. As compared with the non-heating period, Mn, Ni, Pb, S, Si, Ti, Zn, As, Ba, Cd, Cr, Fe and K were relatively higher during the heating period. In particular, Mn, Ni, S, Si, Ti, Zn and As in PM2.5were obviously higher during the heating period. Organic carbon(OC) in the heating period was 2–5 times higher than in the non-heating period. Elemental carbon(EC) did not change much. OC/EC ratios were 8–11 during the heating period, which was much higher than in other Chinese cities(OC/EC: 4–6). Results from the CMB indicated that 11 pollution sources were identified, of which traffic, coal combustion, secondary sulfate, secondary nitrate, and secondary organic carbon made the greatest contribution. Before the heating period, dust and petrochemical industry made a larger contribution. In the heating period, coal combustion and secondary sulfate were higher. After the heating period, dust and petrochemical industry were higher. Some hazardous components in PM2.5were higher than in PM10, because PM2.5has a higher ability to absorb toxic substances. Thus PM2.5pollution is more significant regarding human health effects in the heating period.
基金Project supported by the National Natural Science Foundation of China(No.41371447)the National Key Technologies R&D Program of China(No.2013BAC16B04)
文摘With the increasing occurrence of haze during the summer, the physicochemical characteristics and toxicity differences in PM2.5 in different seasons are of great concern. Hangzhou is located in an area that has a subtropical monsoon climate where the humidity is very high during both the summer and winter. However, there are limited studies on the seasonal differences in PM2.5 in these weather conditions. In this test, PM2.5 samples were collected in the winter and summer, the morphology and chemical composition of PM2.5 were analyzed, the toxicity of PM2.5 to human bronchial cells BEAS-2B was compared, and the correlation between PM2.5 toxicity and the chemical compo- sition was discussed. The results showed that during both the winter and summer, the main compounds in the PM2.5 samples were water-soluble ions, particularly SO4^2-, NO3^-, and NH4^+, followed by organic components, while heavy metals were present at lower levels. The higher the mass concentration of PM2.5, the greater its impact on cell viability and ROS levels. However, when the mass concentration of PM2.5 was similar, the water extraction from the summer samples showed a greater impact on BEAS-2B than that from the winter samples. The cytotoxicity of PM2.5 was closely associated with heavy metals and organic pollutants but less related to water-soluble ions.
文摘This paper seeks to identify macroscopic metallogenic mechanisms of various mineral deposits by studying microscopic typomorphic characteristics of typical minerals associated with the deposits and to reveal the mechanism of lattice gold in detail by studying both physical and chemical characteristics of quartz from representative gold deposits in the North China Platform.As part of their extensive research,the authors examine the relationship between trace elements with wall rock,the ore-forming media,and gold immigration of various types of gold deposits,including their salinity,type,temperature.These are key factors to revealing the mineralization mechanism,and indicators for mineral prospecting,exploration,mining,and metallurgical technology.In order to address the questions posed,the following methods were used:field investigations of geology and sampling of the representative gold deposits,physical study and chemical analysis of quartz including,but not limited to,fluid inclusions as well as their compositions and trace elements in quartz,the unit cell parameters,electron paramagnetic resonance spectrum(EPR),and infrared spectroscopic analysis(ISA).As a result of this study,the authors observe the following key findings:unit cell parameters of quartz vary with their contents of foreign elements including gold,paragenetic stage,wall rock type,and other factors;the higher the forming temperature and the lower the gold content in quartz,the smaller the unit cell parameters,and vice versa.Additionally,the EPR absorption lines resulted from the O–Al defect center.The density of these types of hole centers increases and the EPR signal strengthens when the temperature decreases.Based on the findings,the authors conclude that lattice gold exists in quartz.Gold,in the form of Au^(+)and/or Au^(3+),entering quartz and producing an electron–hole center,namely,the O-Au hole center,makes the center produce spin resonance absorption and results in the EPR absorption peak#I.Both unit cell parameters and EPR of quartz can potentially be used in mineral prospecting,relative ore-forming temperature determination,and grade control during mining.