Transition-metal oxyhydroxides are attractive catalysts for oxygen evolution reactions(OERs).Further studies for developing transition-metal oxyhydroxide catalysts and understanding their catalytic mechanisms will ben...Transition-metal oxyhydroxides are attractive catalysts for oxygen evolution reactions(OERs).Further studies for developing transition-metal oxyhydroxide catalysts and understanding their catalytic mechanisms will benefit their quick transition to the next catalysts.Herein,Mo-doped CoOOH was designed as a high-performance model electrocatalyst with durability for 20 h at 10 mAcm−2.Additionally,it had an overpotential of 260 mV(glassy carbon)or 215 mV(nickel foam),which was 78 mV lower than that of IrO_(2)(338 mV).In situ,Raman spectroscopy revealed the transformation process of CoOOH.Calculations using the density functional theory showed that during OER,doped Mo increased the spin-up density of states and shrank the spin-down bandgap of the 3d orbits in the reconstructed CoOOH under the electrochemical activation process,which simultaneously optimized the adsorption and electron conduction of oxygen-related intermediates on Co sites and lowered the OER overpotentials.Our research provides new insights into the methodical planning of the creation of transition-metal oxyhydroxide OER catalysts.展开更多
Different sizes of layered CoOOH were synthesized by the molten-salt-assisted method at different temperatures.X-ray diffraction and scanning electron microscope studies reveal that CoOOH grew at(003)with increasing t...Different sizes of layered CoOOH were synthesized by the molten-salt-assisted method at different temperatures.X-ray diffraction and scanning electron microscope studies reveal that CoOOH grew at(003)with increasing temperature,and its size can reach dozens of microns.X-ray absorption near edge structure and XPS studies demonstrate that the Co valence state of CoOOH-750 is trivalent,and X-ray Absorption Fine Structure shows that it had a higher symmetry and lower disorder degree,indicating that CoOOH-750 has higher crystallinity and Co3+.The results of electrochemical tests show that CoOOH-750 exhibited the best oxygen-evolution-reaction(OER)catalytic activity.展开更多
Developing non‐noble‐metal electrocatalyst with efficient and durable activity is a urgent task for addressing the sluggish reaction kinetics of electrochemical water oxidation.Structural evolution of the electrocat...Developing non‐noble‐metal electrocatalyst with efficient and durable activity is a urgent task for addressing the sluggish reaction kinetics of electrochemical water oxidation.Structural evolution of the electrocatalyst is an important strategy for achieving enhanced performance.Herein,in situ evolution of surface Co_(2)CrO_(4) to CoOOH/CrOOH(CoOOH/CrOOH‐Co_(2)CrO_(4))by an electrochemical method under alkaline conditions was designed for enhancing the electrocatalytic performance of water oxidation.The experiments demonstrated that the synergy between CoOOH/CrOOH and Co_(2)CrO_(4) resulted in a marked increase in the number of active sites and improved the rate of charge transfer,which enhanced the activity for water oxidation.At a geometrical current density of 20 mA cm^(−2),the overpotential of the oxygen evolution reaction was 244 mV and the turnover frequency was 0.536 s^(−1) in 1.0 M NaOH.展开更多
基金The National Natural Science Foundation of China(Grant Nos.52072114 and 51922008)the 111 Project(Grant No.D17007),the Henan Center for Outstanding Overseas Scientists(Grant No.GZS2018003)+2 种基金Xinxiang Major Science and Technology Projects(Grant No.21ZD001)Guangdong Innovative and Entrepreneurial Research Team Program(2016ZT06N500)Guangdong Provincial Key Laboratory of Energy Materials for Electric Power(2018B030322001)all provided financial support for this work.
文摘Transition-metal oxyhydroxides are attractive catalysts for oxygen evolution reactions(OERs).Further studies for developing transition-metal oxyhydroxide catalysts and understanding their catalytic mechanisms will benefit their quick transition to the next catalysts.Herein,Mo-doped CoOOH was designed as a high-performance model electrocatalyst with durability for 20 h at 10 mAcm−2.Additionally,it had an overpotential of 260 mV(glassy carbon)or 215 mV(nickel foam),which was 78 mV lower than that of IrO_(2)(338 mV).In situ,Raman spectroscopy revealed the transformation process of CoOOH.Calculations using the density functional theory showed that during OER,doped Mo increased the spin-up density of states and shrank the spin-down bandgap of the 3d orbits in the reconstructed CoOOH under the electrochemical activation process,which simultaneously optimized the adsorption and electron conduction of oxygen-related intermediates on Co sites and lowered the OER overpotentials.Our research provides new insights into the methodical planning of the creation of transition-metal oxyhydroxide OER catalysts.
文摘利用工艺简单,成本低廉的共沉淀法制得Co OOH,并用作非水性锂-氧气电池阴极催化剂。通过恒流充放电、线性伏安扫描(LSV)和电化学阻抗(EIS)测试研究了电极的电化学性能。结果表明:由于Co OOH能够明显提高氧气还原反应(ORR)的催化活性,与未使用Co OOH的电极相比较,使用Co OOH为催化剂的电极首次放电容量高达5 093 m Ah·g^(-1),提高了1.7倍。电池的充电过电压降低了约460 m V,充电可逆性得到增强,充放电可逆性提高,使得循环性能得到显著改善。
基金This work was supported by“Transformational Technologies for Clean Energy and Demonstration”,Strategic Priority Research Program of the Chinese Academy of Sciences(Grant no.XDA21080200).
文摘Different sizes of layered CoOOH were synthesized by the molten-salt-assisted method at different temperatures.X-ray diffraction and scanning electron microscope studies reveal that CoOOH grew at(003)with increasing temperature,and its size can reach dozens of microns.X-ray absorption near edge structure and XPS studies demonstrate that the Co valence state of CoOOH-750 is trivalent,and X-ray Absorption Fine Structure shows that it had a higher symmetry and lower disorder degree,indicating that CoOOH-750 has higher crystallinity and Co3+.The results of electrochemical tests show that CoOOH-750 exhibited the best oxygen-evolution-reaction(OER)catalytic activity.
文摘Developing non‐noble‐metal electrocatalyst with efficient and durable activity is a urgent task for addressing the sluggish reaction kinetics of electrochemical water oxidation.Structural evolution of the electrocatalyst is an important strategy for achieving enhanced performance.Herein,in situ evolution of surface Co_(2)CrO_(4) to CoOOH/CrOOH(CoOOH/CrOOH‐Co_(2)CrO_(4))by an electrochemical method under alkaline conditions was designed for enhancing the electrocatalytic performance of water oxidation.The experiments demonstrated that the synergy between CoOOH/CrOOH and Co_(2)CrO_(4) resulted in a marked increase in the number of active sites and improved the rate of charge transfer,which enhanced the activity for water oxidation.At a geometrical current density of 20 mA cm^(−2),the overpotential of the oxygen evolution reaction was 244 mV and the turnover frequency was 0.536 s^(−1) in 1.0 M NaOH.
