In this study for the first time, a novel copper Solid Phase Microextraction (SPME) fiber has been introduced for removal of naphthalene, phenanthrene and anthracene from aqueous solution. Copper was used as a solid s...In this study for the first time, a novel copper Solid Phase Microextraction (SPME) fiber has been introduced for removal of naphthalene, phenanthrene and anthracene from aqueous solution. Copper was used as a solid support, which was at first coated by 3-mercaptopropyltrimethoxysi- lane. A stationary phase of oxidized multi walled carbon nanotube (MWCNTs)) was bonded to the surface of the copper wire. The developed SPME was characterized by IR and Scanning Electron Microscopy (SEM) and coupled to gas chromatography for separation of the analytes. Stability of the fiber, the effect of coating thickness and recovery time were optimized. The MWCNTs film thickness was about 5 μm which was perfect for a rapid mass transfer. The detection limits were at the range of 0.005 to 0.1 μg·L<sup>-1</sup>. The calibration curves were linear R<sup>2</sup> > 0.9813 in the range of 0.01 to 5 μg·L<sup>-1</sup>. The method has been successfully applied for real samples with standard addition of 5 μL<sup>-1</sup> of each sample. Stability study of the fiber to acid and alkali shows that it can be used for more than 50 times.展开更多
文摘In this study for the first time, a novel copper Solid Phase Microextraction (SPME) fiber has been introduced for removal of naphthalene, phenanthrene and anthracene from aqueous solution. Copper was used as a solid support, which was at first coated by 3-mercaptopropyltrimethoxysi- lane. A stationary phase of oxidized multi walled carbon nanotube (MWCNTs)) was bonded to the surface of the copper wire. The developed SPME was characterized by IR and Scanning Electron Microscopy (SEM) and coupled to gas chromatography for separation of the analytes. Stability of the fiber, the effect of coating thickness and recovery time were optimized. The MWCNTs film thickness was about 5 μm which was perfect for a rapid mass transfer. The detection limits were at the range of 0.005 to 0.1 μg·L<sup>-1</sup>. The calibration curves were linear R<sup>2</sup> > 0.9813 in the range of 0.01 to 5 μg·L<sup>-1</sup>. The method has been successfully applied for real samples with standard addition of 5 μL<sup>-1</sup> of each sample. Stability study of the fiber to acid and alkali shows that it can be used for more than 50 times.
