Phosphates are important candidates for ultraviolet/deep-ultraviolet(UV/DUV)nonlinear optical(NLO)materials by good transparency ability and variability of anion species as well as different coordinated cations.Phosph...Phosphates are important candidates for ultraviolet/deep-ultraviolet(UV/DUV)nonlinear optical(NLO)materials by good transparency ability and variability of anion species as well as different coordinated cations.Phosphates have been reported as minerals or NLO materials with abundant condensed anionic framework.For phosphate-based NLO materials,how to improve the second harmonic generation(SHG)response and birefringence re-mains a great challenge.Herein,this review analyzes the structure-property relationship of the representative UV/DUV phosphates,and the microscopic mechanism to achieve a balance between the short absorption edge and large SHG response is summarized.It provides a new idea to study the UV/DUV phosphate NLO materials.展开更多
Efficient and eco-friendly disinfection of air-borne human respiratory RNA viruses is pursued in both public environment and portable usage.The AlGaN-based deep ultraviolet(DUV)light-emission diode(LED)has high practi...Efficient and eco-friendly disinfection of air-borne human respiratory RNA viruses is pursued in both public environment and portable usage.The AlGaN-based deep ultraviolet(DUV)light-emission diode(LED)has high practical potentials because of its advantages of variable wavelength,rapid sterilization,environmental protection,and miniaturization.Therefore,whether the emission wavelength has effects on the disinfection as well as whether the device is feasible to sterilize various respiratory RNA viruses under portable conditions is crucial.Here,we fabricate AlGaN-based DUV LEDs with different wavelength on high-temperature-annealed(HTA)AlN/Sapphire templates and investigate the inactivation effects for several respiratory RNA viruses.The AlN/AlGaN superlattices are employed between the template and upper n-AlGaN to release the strong compressive stress(SCS),improving the crystal quality and interface roughness.DUV LEDs with the wavelength of 256,265,and 278 nm,corresponding to the light output power of 6.8,9.6,and 12.5 mW,are realized,among which the 256 nm-LED shows the most potent inactivation effect in human respiratory RNA viruses,including SARS-CoV-2,influenza A virus(IAV),and human parainfluenza virus(HPIV),at a similar light power density(LPD)of~0.8 mW/cm2 for 10 s.These results will contribute to the advanced DUV LED application of disinfecting viruses with high potency and broad spectrum in a portable and eco-friendly use.展开更多
Theε-Ga_(2)O_(3) thin film was grown on sapphire substrate by using metalorganic chemical vapor deposition(MOCVD)method,and then was used to fabricate a deep-ultraviolet(DUV)photodetector(PD).Theε-Ga_(2)O_(3) thin f...Theε-Ga_(2)O_(3) thin film was grown on sapphire substrate by using metalorganic chemical vapor deposition(MOCVD)method,and then was used to fabricate a deep-ultraviolet(DUV)photodetector(PD).Theε-Ga_(2)O_(3) thin film shown good crystal quality and decent surface morphology.Irradiated by a 254-nm DUV light,the photodetector displayed good optoelectronic performance and high wavelength selectivity,such as photoresponsivity(R)of 175.69 A/W,detectivity(D*)of 2.46×10^(15) Jones,external quantum efficiency(EQE)of 8.6×10^(4)%and good photocurrent-intensity linearity,suggesting decent DUV photosensing performance.At 5 V and under illumination with light intensity of 800μW/cm2,the photocurrent gain is as high as 859 owing to the recycling gain mechanism and delayed carrier recombination;and the photocurrent gain decreases as the incident light intensity increases because of the recombination of photogenerated carriers by the large photon flux.展开更多
Recently ozone is one of natural hazards which comes from cars, industry using ozone for sterilization of organic and inorganic materials and for water purification. So, ozone sensing becomes very important, and conve...Recently ozone is one of natural hazards which comes from cars, industry using ozone for sterilization of organic and inorganic materials and for water purification. So, ozone sensing becomes very important, and convenient and accurate ozone sensor is required. A new high sensitivity ozone sensing system using an deep ultra-violet light emitting diode (DUV-LED) operated at the wavelength of 280 nm has been successfully constructed. The fabrication of diode operated at 280 nm is much easier than that of DUV-LED operated at Hg lamp wavelength of 254 nm. The system is compact and possible to sense the ozone concentration less than 0.1 ppm with an accuracy of 0.5% easily with low power DUV-LED of around 200 micro Watts operated at 280 nm without any data processing circuit.展开更多
基金supprted by the National Natural Science Foundation of China(51962033)the Xinjiang Major Science and Technology Project(2021A01001-3).
文摘Phosphates are important candidates for ultraviolet/deep-ultraviolet(UV/DUV)nonlinear optical(NLO)materials by good transparency ability and variability of anion species as well as different coordinated cations.Phosphates have been reported as minerals or NLO materials with abundant condensed anionic framework.For phosphate-based NLO materials,how to improve the second harmonic generation(SHG)response and birefringence re-mains a great challenge.Herein,this review analyzes the structure-property relationship of the representative UV/DUV phosphates,and the microscopic mechanism to achieve a balance between the short absorption edge and large SHG response is summarized.It provides a new idea to study the UV/DUV phosphate NLO materials.
基金supports from the National Key R&D Program of China(2022YFB3605001)National Natural Science Foundation of China(62121005,62004196,61725403,31922004,and 61827813)+2 种基金Youth Innovation Promotion Association of Chinese Academy of Sciences(2023223)Young Elite Scientist Sponsorship Program by CAST(YESS20200182)Innovation Team Project from the Hubei Province(2020CFA015).
文摘Efficient and eco-friendly disinfection of air-borne human respiratory RNA viruses is pursued in both public environment and portable usage.The AlGaN-based deep ultraviolet(DUV)light-emission diode(LED)has high practical potentials because of its advantages of variable wavelength,rapid sterilization,environmental protection,and miniaturization.Therefore,whether the emission wavelength has effects on the disinfection as well as whether the device is feasible to sterilize various respiratory RNA viruses under portable conditions is crucial.Here,we fabricate AlGaN-based DUV LEDs with different wavelength on high-temperature-annealed(HTA)AlN/Sapphire templates and investigate the inactivation effects for several respiratory RNA viruses.The AlN/AlGaN superlattices are employed between the template and upper n-AlGaN to release the strong compressive stress(SCS),improving the crystal quality and interface roughness.DUV LEDs with the wavelength of 256,265,and 278 nm,corresponding to the light output power of 6.8,9.6,and 12.5 mW,are realized,among which the 256 nm-LED shows the most potent inactivation effect in human respiratory RNA viruses,including SARS-CoV-2,influenza A virus(IAV),and human parainfluenza virus(HPIV),at a similar light power density(LPD)of~0.8 mW/cm2 for 10 s.These results will contribute to the advanced DUV LED application of disinfecting viruses with high potency and broad spectrum in a portable and eco-friendly use.
基金the National Natural Science Foundation of China(Ganrt No.62004047)。
文摘Theε-Ga_(2)O_(3) thin film was grown on sapphire substrate by using metalorganic chemical vapor deposition(MOCVD)method,and then was used to fabricate a deep-ultraviolet(DUV)photodetector(PD).Theε-Ga_(2)O_(3) thin film shown good crystal quality and decent surface morphology.Irradiated by a 254-nm DUV light,the photodetector displayed good optoelectronic performance and high wavelength selectivity,such as photoresponsivity(R)of 175.69 A/W,detectivity(D*)of 2.46×10^(15) Jones,external quantum efficiency(EQE)of 8.6×10^(4)%and good photocurrent-intensity linearity,suggesting decent DUV photosensing performance.At 5 V and under illumination with light intensity of 800μW/cm2,the photocurrent gain is as high as 859 owing to the recycling gain mechanism and delayed carrier recombination;and the photocurrent gain decreases as the incident light intensity increases because of the recombination of photogenerated carriers by the large photon flux.
文摘Recently ozone is one of natural hazards which comes from cars, industry using ozone for sterilization of organic and inorganic materials and for water purification. So, ozone sensing becomes very important, and convenient and accurate ozone sensor is required. A new high sensitivity ozone sensing system using an deep ultra-violet light emitting diode (DUV-LED) operated at the wavelength of 280 nm has been successfully constructed. The fabrication of diode operated at 280 nm is much easier than that of DUV-LED operated at Hg lamp wavelength of 254 nm. The system is compact and possible to sense the ozone concentration less than 0.1 ppm with an accuracy of 0.5% easily with low power DUV-LED of around 200 micro Watts operated at 280 nm without any data processing circuit.
