Recent Developments of Transition Metal Compounds-Carbon Hybrid Electrodes for High Energy/Power Supercapacitors

Due to their rapid power delivery,fast charging,and long cycle life,supercapacitors have become an important energy storage technology recently.However,to meet the continuously increasing demands in the fields of portable electronics,transportation,and future robotic technologies,supercapacitors with higher energy densities without sacrificing high power densities and cycle stabilities are still challenged.Transition metal compounds(TMCs)possessing high theoretical capacitance are always used as electrode materials to improve the energy densities of supercapacitors.However,the power densities and cycle lives of such TMCs-based electrodes are still inferior due to their low intrinsic conductivity and large volume expansion during the charge/discharge process,which greatly impede their large-scale applications.Most recently,the ideal integrating of TMCs and conductive carbon skeletons is considered as an effective solution to solve the above challenges.Herein,we summarize the recent developments of TMCs/carbon hybrid electrodes which exhibit both high energy/power densities from the aspects of structural design strategies,including conductive carbon skeleton,interface engineering,and electronic structure.Furthermore,the remaining challenges and future perspectives are also highlighted so as to provide strategies for the high energy/power TMCs/carbon-based supercapacitors.

A new model of the L–H transition and H-mode power threshold

In order to understand the mechanism of the confinement bifurcation and H-mode power threshold in magnetically confined plasma,a new dynamical model of the L-H transition based on edge instability phase transition（EIPT） has been developed.With the typical plasma parameters of the EAST tokamak,the self-consistent turbulence growth rate is analyzed using the simplest case of pressure-driven ballooning-type instability,which indicates that the L-H transition can be caused by the stabilization of the edge instability through EIPT.The weak E？×？B flow shear in L-mode is able to increase the ion inertia of the electrostatic motion by increasing the radial wave number of the tilted turbulence structures,which play an important role for accelerating the trigger process of EIPT rather than directly to suppress the turbulent transport.With the acceleration mechanism of E？×？B flow shear,fast L-H and H-L transitions are demonstrated under the control of the input heating power.Due to the simplified scrape-offlayer boundary condition applied,the ratio between the heating powers at the H-L and L-H transition respectively differs from the ratio by Nusselt number.The results of the modeling reveal a scaling of the power threshold of the L-H transition,P_（L-H）？∝？n^（0.76） B^（0.8） for deuterium plasma.It is found finite Larmor radius induces an isotope effect of the H-mode power threshold.

Mass-Based Environmental Factor and Energy Assessment of Microwave-Assisted Synthesized Transition Metal Nanostructures

This paper describes mass-based energy phase-space projection of microwave-assisted synthesis of transition metals (zinc oxide, palladium, silver, platinum, and gold) nanostructures. The projection uses process energy budget (measured in kJ) on the horizontal axes and process density (measured in kJg−1) on the vertical axes. These two axes allow both mass usage efficiency (Environmental-Factor) and energy efficiency to be evaluated for a range of microwave applicator and metal synthesis. The metrics are allied to the: second, sixth and eleventh principle of the twelve principle of Green Chemistry. This analytical approach to microwave synthesis (widely considered as a useful Green Chemistry energy source) allows a quantified dynamic environmental quotient to be given to renewable plant-based biomass associated with the reduction of the metal precursors. Thus allowing a degree of quantification of claimed “eco-friendly” and “sustainable” synthesis with regard to waste production and energy usage.

The Major Power Diplomacy with Chinese Characteristics in the Transition of International Order

The early 21st century finds great change in international order. China＇s foreign relations have entered a new phase where its driving force is rapidly rising for the emerging countries and new global economic govemance mechanism is gradually established. To follow the trend of the times, China has actively participated in global economic govemance and supply of public goods. China＇ s foreign relations present a new vision, idea and strategy under the leadership of President Xi Jinping. It is a new starting point for China to further integrate itself into the world and open itself wider to the world. China takes an active part to participate in global governance and plays an important role in the issues of economic integration, environmental governance, climate change, nuclear nonproliferation, energy crisis, intemet security and anti-terrorism, especially anti-terrorism. This article explains the performance of international relations in current transition order and tries to tackle prior （and in some ways more intractable） issues and to analyze the internal logics and external environment of impact of multi-polarization on China＇s major power diplomacy with its characteristics in the transition of International order.

A New Zero-Voltage Transition Power Factor Corrected Single-Phase Single-Stage AC-to-DC Converter

This paper presents a new ZVT （zero-voltage transition） single-stage ac-to-dc converter using PWM （pulse width modulation） and HF （high frequency） transformer isolation with capacitive output filter. In this converter a front-end power factor corrected boost stage integrates with a cascaded dc-to-dc bridge HF converter. The front-end boost converter operates in discontinuous current mode and ensures natural power factor correction with very simple control. The auxiliary circuit of this topology deals with very small power and is placed out of the main power path. As a result, the auxiliary circuit components have smaller power rating as opposed to main converter components. Also, output rectifier voltage is clamped to output voltage due to capacitive output filter. Identification and analyses of different operating modes of this converter are presented. Based on these analyses design example of a 50 kHz, 48 V, 1 kW ac-to-dc converter is presented. PSPICE simulation results of the designed converter are presented and explained to verify the performance of this converter.

Global Power Structure Shifted and Transitional Multi-polarity Emerged

The world is facing the third important global power shift.The United States,EU, Japan,Russia,China,and the newly emerging power group are becoming the six big forces in the international center stage,while the former three forces and the latter three belong to two groups,waning and waxing respectively.The major shift in the global balance of power is bound to give rise to the transitional multi-polar configuration,which implies a shifting of leadership over the configuration,China and U.S.outweighing other forces,global issues looming large,homogeneity blending with heterogeneity,and a shifting center of world powers.The transitional multi-polar configuration is all about change,upon which China is one of the decisive forces.

Recent advances in pseudocapacitor electrode materials: Transition metal oxides and nitrides

Faraday pseudocapacitors take both advantages of secondary battery with high energy density and supercapacitors with high power density,and electrode material is the key to determine the performance of Faraday pseudocapacitors.Transition metal oxides and nitrides,as the two main kinds of pseudocapacitor electrode materials,can enhance energy density while maintaining high power capability.Recent advances in designing nanostructured architectures and preparing composites with high specific surface areas based on transition metal oxides and nitrides,including ruthenium oxides,nickel oxides,manganese oxides,vanadium oxides,cobalt oxides,iridium oxides,titanium nitrides,vanadium nitrides,molybdenum nitrides and niobium nitrides,are addressed,which would provide important significances for deep researches on pseudocapacitor electrode materials.

Influence of soil resistivity on stray current in power supply system of urban rail transit

In order to explore the influence of soil resistivity on stray current in power supply system of urban rail transit,we establish an equivalent circuit model of the rail-to-ground structure based on resistance network method first.After measuring the soil resistivity of a real subway system,a simulation model is established in Matlab to obtain the stray currents at different soil resistivities.Then the influence of soil resistivity on stray current is analyzed.Afterwards,to verify the rationality and reliability of the simulation model,we design a test circuit to measure the stray current and rail-to-ground voltage in a real subway system,and a comparison of the experimentally measured results and simulation results is presented.The results show that the stray current is the maximum when the soil resistivity is 211.57Ω·m;when the soil resistivity is 768.47Ω·m,the stray current is the minimum,that is,the smaller the soil resistivity,the greater the stray current.Therefore,the resistivity should be increased as much as possible when ramming the track foundation in urban rail transit system.

Industrial frequency single-phase AC traction power supply system for urban rail transit and its key technologies

To avoid stray current and maintain the benefit of no phase-split in the DC traction power supply system, an AC traction power supply system was proposed for the urban public transport such as metro and light rail transit. The proposed system consists of a main substation （MSS） and cable traction network （CTN）. The MSS includes a single-phase main traction transformer and a negative-se- quence compensation device, while the CTN includes double-core cables, traction transformers, overhead catenary system, rails, etc. Several key techniques for the proposed system were put forward and discussed, which can be summarized as （1） the power supply principle, equivalent circuit and transmission ability of the CTN, the cable-catenary matching technique, and the selection of catenary voltage level; （2） the segmentation technology and status identification method for traction power supply network, distributed and centralized protection schemes, etc.; （3） a power supply scheme for single-line MSS and a power supply scheme of MSS shared by two or more lines. The proposed industrial frequency single-phase AC traction power supply system shows an excellent technical performance, good economy, and high reliability, hence provides a new alternative for metro and urban rail transit power supply systems.

INVESTIGATION OF DOMINANT FREQUENCIES IN TRANSITION REYNOLDS NUMBER RANGE OF FLOW AROUND A CIRCULAR CYLINDER PARTⅡ: THEORETICAL DETERMINATION OF THE RELATIONSHIP BETWEEN VORTEX SHEDDING AND TRANSITION FREQUENCIES AT DIFFERENT REYNOLDS NUMBERS

An attempt has been made to explore whether the power relation can be obtained from theoretical considerations. The classical laminar and turbulent boundary layer concepts have been employed to determine appropriate values of the scaling lengths associated with vortex shedding and shear layer frequencies to predict the power law relationship with Reynolds number. The predicted results are in good agreement with experimental results. The findings will provide a greater insight into the overall phenomenon involved.

The effect of transition metal ions (M^(2+)=Mn^(2+),Ni^(2+),Co^(2+),Cu^(2+)) on the chemical synthesis polyaniline as counter electrodes in dye-sensitized solar cells

The effect of transition metal ions(M^(2+)=Mn^(2+),Ni^(2+),Co^(2+),Cu^(2+)) on the chemical synthesis of polyaniline(PANI) used as a platinum-free counter electrode(CE) in dye-sensitized solar cells(DSSCs) was investigated.PANI was synthesized by co-polymerization of aniline in the presence of different transition metal ions by using potassium dichromate in acidic medium. It was found that the ion doping of PANI showed a certain catalytic activity for the regeneration of traditional iodide/triiodide(I^-/I_3^-) redox couples. The power conversion efficiency(η) of PANI CEs doped with Mn^(2+),Ni^(2+),Co^(2+) (4.41%, 2.36% and 2.10%, respectively) were higher than 1.94%, the value measured for PANI CE without doping. Doping with Cu^(2+)decreased the power conversion efficiency of PANI CE(PANI-Cu^(2+) η = 1.41%). The electrical properties of the PANI, PANI-Ni^(2+), PANI-Co^(2+),PANI-Mn^(2+) and PANI-Cu^(2+) were studied by cyclic voltammetry(CV), impedance(EIS), and Tafel polarization curve. The experimental results confirmed that PANI was affected by the doping of different transition metal ions(M^(2+)=Mn^(2+),Ni^(2+),Co^(2+),Cu^(2+)). These results indicate a potential application of ion doped PANI as counter electrode in cost-effective DSSCs.

Advances in Inductively Coupled Power Transfer Technology for Rail Transit

Traditional power supply method for moving electric railway vehicles is based on contact type power collection technology.This sometimes cannot meet the requirements of modern rail transportation.A new wireless power transfer(WPT)technology can offer significant benefits in modern rail transportation particularly in some stringent environments.This paper reviews the status and the development of rail transit power supply technology,and introduces a new challenging technology--inductive power transfer(IPT)technology for rail transit.Tesla established the underpinning of IPT technology and creatively and significantly demonstrated power transfer by using highly resonant tuned coils long time ago.However,only in recent years the IPT technology has been significantly improved including the transfer air-gap length,transfer efficiency,coupling factor,power transfer capability and so on.This is mainly due to innovative semiconductor switches,higher control frequency,better coil designs and high performance material,new track and vehicle construction techniques.Recent advances in IPT for rail transit and major milestones of the developments are summarized in this paper.Some important technical issues such as coupling coil structures,power supply schemes,segmentation switching techniques for long-distance power supply,and bidirectional IPT systems for braking energy feedback are discussed.

Disclosure of Duke's Power in My Last Duchess Through Analysis of Transitivity

This thesis attempts to analyze the presentation of Duke's power in Robert Browning's My Last Duchess through theory of transitivity in functional stylistics. Through transitivity analysis, Duke's dominating position will be revealed, and the thematic significance and language features of this poem would be shed light upon as well.

INVESTIGATION OF DOMINANT FREQUENCIES IN TRANSITION REYNOLDS NUMBER RANGE OF FLOW AROUND A CIRCULAR CYLINDER PART I:EXPERIMENTAL STUDY OF THE RELATION BETWEEN VORTEX SHEDDING AND TRANSITION FREQUENCIES

A comprehensive hot wire investigation of the flow around a circular cylinder is carried out in an 18＂ × 18＂ wind tunnel to look into the dominant frequencies at the stagnation, separation and separated shear layers in the transition Reynolds number range. The majority of the experiments are carried out at Reynolds number of 4.5×104, with additional transition frequency tests at Reynolds numbers of 2.9×104, 3.3×104 and 9.7×104 respectively. The results are analysed in terms of power spectral density. While the frequency associated with stagnation is found to be essentially due to vortex shedding, frequency doubling of vortex shedding is also evident in the separated shear layers. Two peaks associated with transition frequencies are detected and their possible implications are presented.

Quantum phase transitions in CePdAl probed by ultrasonic and thermoelectric measurements

CePdAl has been recently recognized as a frustrated antiferromagnetic heavy-fermion compound with a pressureor field-tuned,extended quantum critical phase at zero temperature.Identifying characteristic signatures of the emerging quantum critical phase,which are expected to be distinct from those near a quantum critical point,remains challenging.In this work,by performing ultrasonic and thermoelectric measurements down to very low temperatures in a^(3)He–^(4)He dilution refrigerator in the presence of magnetic field,we are able to obtain some crucial thermodynamic and thermal transport features of the quantum critical phase,including a frustration-related elastic softening detected by ultrasound and a Fermi-surface change probed by thermoelectric effect.

Myanmar＇s Political Transition and the Adjustments of U Thein Sein Administra-tion＇s Policies towards China

During 2010-2011, Myanmar started its political transition. The U Thein SeinAdministration has made obvious policy adjustments towards China after it replaced the Mili-tary government. However, such adjustments were limited, as Myanmar hasn＇t totally lean tothe West, but keeping relatively closer political contact with China. Empirical analysis showsthat political institu6on and ideology are not the key reasons leading to such adjustments？China-Myanmar relations had undergone fluctuation, osdlla6on and stability during 2011-2016, the root causes of which are the legality of political power, national security based ongeopolitics and economic development demands of＂ Myanmar people. Moreover, those threefactors remain the primary considerations of the NLD Government when it handling relationswith China.

The Impacts of Global Energy Transition on Middle East Politics

Due to the symbiotic relations between oil and the contemporary Middle East, a global energy transition is bound to affect the Middle East's international status and the power structure among its countries. The power gap between rich and poor countries will widen, and the “big politics of small states” in countries such as the United Arab Emirates and Qatar may become more prominent. As economic development has become the top priority of national strategies, many hot spots in the Middle East have cooled down as relations between rival countries have eased and there are even signs of multilateral economic cooperation. Meanwhile, there are signs of vicious economic competition among related countries. With the decline of the Middle East's global importance, the United States and Europe are moving further away while the interdependence between Asia and the Middle East is increasing. Reforms to tackle the energy transition in the Middle East are a race against time, difficult, and uncertain, but the signs so far are positive.

Transitivity System and Power Relationship-Analysis of William Faulkner＇ s A Rose for Emily

This paper explores how transitivity system functions in the novel A Rose for Emily, especially how it builds up and reflects the suppression on Emily by Emily's father, who represents the patriarchal value system and by the citizens who represents the southern traditional value system. This paper also elaborates how Emily appeared to be powerless and was dominated by the two groups of power, and how her humanity and emotions were suppressed in the conflict of the two categories of power.

Green Chemistry Allometry Test of Microwave-Assisted Synthesis of Transition Metal Nanostructures

Microwave irradiation is considered an important approach to Green Chemistry, because of its ability to rapidly increase the internal temperature of polar-organic compounds that lead to synthesis times of minutes rather than hours when compared to conventional thermal heating. This works describes a dual allometry test for the discrimination between the solvents and reagents used in the microwave-assisted synthesis of transition metal (zinc oxide, palladium silver, platinum, and gold) nanostructures. The test is performed in log-log process energy phase-space projection, where the synthesis data (kJ against kJ·mol-1) has a power-law signature. The test is shown to discriminate between recommended Green Chemistry, problematic Green Chemistry, and Green Chemistry hazardous solvents. Typically, recommended Green chemistry exhibits a broad y-axes distribution within an upper exponent = 1 and lower exponent = 0.5. Problematic Green Chemistry exhibits a y-axes narrower distribution with an upper exponent = 0.94 and lower exponent = 0.64. Non-Green Chemistry hazardous data exhibits a further narrowing of the y-axes distribution within upper exponent = 0.87 and lower exponent = 0.66. In all three cases, the y-axes is aligned to original database power-law signature. It is also shown that in the x-axes direction (process energy budget) the grouped order of magnitude decreases from four orders for recommended Green Chemistry solvent and reagent data, through two orders for non-Green Chemistry hazardous material and down to one order for problematic Green Chemistry.

A mathematical Model to Predict Transition-to-Fatigue During Isometric Exercise on Muscles of the Lower Extremities

Surface Electromyography (sEMG) activities of the four muscles were studied from twelve healthy subjects to analyze muscle fatigue. Data were recorded while subjects performed isometric exercises for a period of time until fatigue. The signal was segmented with 5000 samples to enable the evolutionary process. Based on the mean power spectrum and Median Frequency (MDF) of each segment, we developed a methodology that is able to detect the signal into a meaningful sequence of Non-Fatigue to Transition-to-Fatigue. By identifying this transitional fatigue stage, it is possible to predict when fatigue will occur, which provides the foundation of the automated system that has the potential to aid in many applications of our lives, including sports, rehabilitation and ergonomics.