A novel size-dependent model is developed herein to study the bending behavior of beam-type micro/nano-structures considering combined effects of nonlocality and micro-rotational degrees of freedom. To accomplish this...A novel size-dependent model is developed herein to study the bending behavior of beam-type micro/nano-structures considering combined effects of nonlocality and micro-rotational degrees of freedom. To accomplish this aim, the micropolar theory is combined with the nonlocal elasticity. To consider the nonlocality, both integral (original) and differential formulations of Eringen’s nonlocal theory are considered. The beams are considered to be Timoshenko-type, and the governing equations are derived in the variational form through Hamilton’s principle. The relations are written in an appropriate matrix-vector representation that can be readily utilized in numerical approaches. A finite element (FE) approach is also proposed for the solution procedure. Parametric studies are conducted to show the simultaneous nonlocal and micropolar effects on the bending response of small-scale beams under different boundary conditions.展开更多
Interaction rule between representative RE and Sn, Sb, Pb, Cu, S, P low melting point elements respectively in Fe , Cu , Al , Ni base liquid solutions including totally 34 ternary and quarternary systems was inve...Interaction rule between representative RE and Sn, Sb, Pb, Cu, S, P low melting point elements respectively in Fe , Cu , Al , Ni base liquid solutions including totally 34 ternary and quarternary systems was investigated. For each system some thermodynamic properties were obtained, such as the standard free energies of equilibrium reactions, activity interaction coefficients etc ..展开更多
Laser ablation–inductively coupled plasma–mass spectrometry（LA–ICP–MS） was used to determine the trace element concentrations of magnetite from the Heifengshan, Shuangfengshan, and Shaquanzi Fe（–Cu） deposits ...Laser ablation–inductively coupled plasma–mass spectrometry（LA–ICP–MS） was used to determine the trace element concentrations of magnetite from the Heifengshan, Shuangfengshan, and Shaquanzi Fe（–Cu） deposits in the Eastern Tianshan Orogenic Belt. The magnetite from these deposits typically contains detectable Mg, Al, Ti, V, Cr, Mn, Co, Ni, Zn and Ga. The trace element contents in magnetite generally vary less than one order of magnitude. The subtle variations of trace element concentrations within a magnetite grain and between the magnetite grains in the same sample probably indicate local inhomogeneity of ore–forming fluids. The variations of Co in magnetite between samples are probably due to the mineral proportion of magnetite and pyrite. Factor analysis has discriminated three types of magnetite： Ni–Mn–V–Ti（Factor 1）, Mg–Al–Zn（Factor 2）, and Ga– Co（Factor 3） magnetite. Magnetite from the Heifengshan and Shuangfengshan Fe deposits has similar normalized trace element spider patterns and cannot be discriminated according to these factors. However, magnetite from the Shaquanzi Fe–Cu deposit has affinity to Factor 2 with lower Mg and Al but higher Zn concentrations, indicating that the ore–forming fluids responsible for the Fe–Cu deposit are different from those for Fe deposits. Chemical composition of magnetite indicates that magnetite from these Fe（–Cu） deposits was formed by hydrothermal processes rather than magmatic differentiation. The formation of these Fe（–Cu） deposits may be related to felsic magmatism.展开更多
By use of self-consistent field Xα scattered-wave (SCF-Xα-SW) method, the electronic structure was calculated for four models of Ti4Al14X (X=Al, Fe, Ni and Cu) clusters. The Ti4Al14X cluster was developed based on L...By use of self-consistent field Xα scattered-wave (SCF-Xα-SW) method, the electronic structure was calculated for four models of Ti4Al14X (X=Al, Fe, Ni and Cu) clusters. The Ti4Al14X cluster was developed based on L12 Al3Ti-base intermetallic compound. The results are presented using the density of states (DOS) and one-electron properties, such as relative binding tendency between the atom and the model cluster, and hybrid bonding tendency between the alloying element and the host atoms. By comparing the four models of Ti4Al14X cluster, the effect of the Fe, Ni or Cu atom on the physical properties of Al3Ti-based L12 intermetallic compounds is analyzed. The results indicate that the addition of the Fe, Ni or Cu atom intensifies the relative binding tendency between Ti atom and Ti4Al14X cluster. It was found that the Fermi level (EF) lies in a maximum in the DOS for Ti4Al14Al cluster; on the contrary, the EF comes near a minimum tn the DOS for Ti4Al14X (X=Fe, Ni and Cu) cluster. Thus the L12 crystal structure for binary Al3Ti alloy is unstable, and the addition of the Fe, Ni or Cu atom to Al3Ti is benefical to stabilize L12 crystal structure. The calculation also shows that the Fe, Ni or Cu atom strengthens the hybrid bonding tendency between the central atom and the host atoms for Ti4Al14X cluster and thereby may lead to the constriction of the lattice of Al3Ti-base intermetallic compounds.展开更多
The effect of the addition of rare earths in Fe-based high chromium alloy powders on elements distribution in matrix materials and mechanical properties were studied. The results show that the addition of cerium can i...The effect of the addition of rare earths in Fe-based high chromium alloy powders on elements distribution in matrix materials and mechanical properties were studied. The results show that the addition of cerium can increase the chromium amount in carbonides and increase the micro-hardness after carbonization and the wear-resistant property of materials.展开更多
The storage of hydrogen gas in lined rock caverns(LRCs)may enable the implementation of the firstlarge-scale fossil-free steelmaking process in Sweden,but filling such storage causes joints in the rockmass to open,con...The storage of hydrogen gas in lined rock caverns(LRCs)may enable the implementation of the firstlarge-scale fossil-free steelmaking process in Sweden,but filling such storage causes joints in the rockmass to open,concentrating strains in the lining.The structural interaction between the LRC componentsmust be able to reduce the strain concentration in the sealing steel lining;however,this interaction iscomplex and difficult to predict with analytical methods.In this paper,the strain concentration in LRCsfrom the opening of rock joints is studied using finite element(FE)analyses,where the large-and small-scale deformation behaviors of the LRC are coupled.The model also includes concrete crack initiation anddevelopment with increasing gas pressure and rock joint width.The interaction between the jointed rockmass and the reinforced concrete,the sliding layer,and the steel lining is demonstrated.The results showthat the rock mass quality and the spacing of the rock joints have the greatest influence on the straindistributions in the steel lining.The largest effect of rock joints on the maximum strains in the steellining was observed for geological conditions of“good”quality rock masses.展开更多
REE and other trace elements in ores, wall rocks, alkaline volcanic rocks and diabase dikes have been determined in the Yinachang Fe-Cu-REE deposit. Comparative studies of REE and trace element geochemical characteris...REE and other trace elements in ores, wall rocks, alkaline volcanic rocks and diabase dikes have been determined in the Yinachang Fe-Cu-REE deposit. Comparative studies of REE and trace element geochemical characteristics of these geological bodies indicate that the ores and alkaline volcanic rocks contain abundant REE and Y ({65.9}-{4633})×10+{-6}, with higher abundances of As, Mo, Nb, Co and U than those of the crust. Their chondrite-normalized patterns show a strong enrichment of LREE and a positive Eu anomaly, in contrast to those of the dolomites which are characterized by slight LREE enrichment and moderate negative Eu anomaly. The REE patterns of ores are similar to those of hydrothermal sediment cores in the East Pacific Rise, whereas the REE patterns of dolomites are similar to those of PAAS (Post-Archean Average Shale). In combination with the geological setting of the deposit, the primary ore-forming fluids might have higher REE and volatile elements, and might have been derived from mantle degassing, or the alkaline volcanic magmas. The Yinachang Fe-Cu-REE ore deposit is considered to be of volcanic exhalation-hydrothermal sedimentary origin.展开更多
文摘A novel size-dependent model is developed herein to study the bending behavior of beam-type micro/nano-structures considering combined effects of nonlocality and micro-rotational degrees of freedom. To accomplish this aim, the micropolar theory is combined with the nonlocal elasticity. To consider the nonlocality, both integral (original) and differential formulations of Eringen’s nonlocal theory are considered. The beams are considered to be Timoshenko-type, and the governing equations are derived in the variational form through Hamilton’s principle. The relations are written in an appropriate matrix-vector representation that can be readily utilized in numerical approaches. A finite element (FE) approach is also proposed for the solution procedure. Parametric studies are conducted to show the simultaneous nonlocal and micropolar effects on the bending response of small-scale beams under different boundary conditions.
基金Project Sponsored by the National Natural Science Foundation
文摘Interaction rule between representative RE and Sn, Sb, Pb, Cu, S, P low melting point elements respectively in Fe , Cu , Al , Ni base liquid solutions including totally 34 ternary and quarternary systems was investigated. For each system some thermodynamic properties were obtained, such as the standard free energies of equilibrium reactions, activity interaction coefficients etc ..
基金financially supported by the Chinese 973 project(2012CB416804)the ‘‘CAS Hundred Talents’’ Project from the Chinese Academy of Sciences(KZCX2-YW-BR-09)to Qi Liang
文摘Laser ablation–inductively coupled plasma–mass spectrometry（LA–ICP–MS） was used to determine the trace element concentrations of magnetite from the Heifengshan, Shuangfengshan, and Shaquanzi Fe（–Cu） deposits in the Eastern Tianshan Orogenic Belt. The magnetite from these deposits typically contains detectable Mg, Al, Ti, V, Cr, Mn, Co, Ni, Zn and Ga. The trace element contents in magnetite generally vary less than one order of magnitude. The subtle variations of trace element concentrations within a magnetite grain and between the magnetite grains in the same sample probably indicate local inhomogeneity of ore–forming fluids. The variations of Co in magnetite between samples are probably due to the mineral proportion of magnetite and pyrite. Factor analysis has discriminated three types of magnetite： Ni–Mn–V–Ti（Factor 1）, Mg–Al–Zn（Factor 2）, and Ga– Co（Factor 3） magnetite. Magnetite from the Heifengshan and Shuangfengshan Fe deposits has similar normalized trace element spider patterns and cannot be discriminated according to these factors. However, magnetite from the Shaquanzi Fe–Cu deposit has affinity to Factor 2 with lower Mg and Al but higher Zn concentrations, indicating that the ore–forming fluids responsible for the Fe–Cu deposit are different from those for Fe deposits. Chemical composition of magnetite indicates that magnetite from these Fe（–Cu） deposits was formed by hydrothermal processes rather than magmatic differentiation. The formation of these Fe（–Cu） deposits may be related to felsic magmatism.
文摘By use of self-consistent field Xα scattered-wave (SCF-Xα-SW) method, the electronic structure was calculated for four models of Ti4Al14X (X=Al, Fe, Ni and Cu) clusters. The Ti4Al14X cluster was developed based on L12 Al3Ti-base intermetallic compound. The results are presented using the density of states (DOS) and one-electron properties, such as relative binding tendency between the atom and the model cluster, and hybrid bonding tendency between the alloying element and the host atoms. By comparing the four models of Ti4Al14X cluster, the effect of the Fe, Ni or Cu atom on the physical properties of Al3Ti-based L12 intermetallic compounds is analyzed. The results indicate that the addition of the Fe, Ni or Cu atom intensifies the relative binding tendency between Ti atom and Ti4Al14X cluster. It was found that the Fermi level (EF) lies in a maximum in the DOS for Ti4Al14Al cluster; on the contrary, the EF comes near a minimum tn the DOS for Ti4Al14X (X=Fe, Ni and Cu) cluster. Thus the L12 crystal structure for binary Al3Ti alloy is unstable, and the addition of the Fe, Ni or Cu atom to Al3Ti is benefical to stabilize L12 crystal structure. The calculation also shows that the Fe, Ni or Cu atom strengthens the hybrid bonding tendency between the central atom and the host atoms for Ti4Al14X cluster and thereby may lead to the constriction of the lattice of Al3Ti-base intermetallic compounds.
文摘The effect of the addition of rare earths in Fe-based high chromium alloy powders on elements distribution in matrix materials and mechanical properties were studied. The results show that the addition of cerium can increase the chromium amount in carbonides and increase the micro-hardness after carbonization and the wear-resistant property of materials.
基金supported by the Swedish Energy Agency(Grant Nos.42684-2,P2022-00209).
文摘The storage of hydrogen gas in lined rock caverns(LRCs)may enable the implementation of the firstlarge-scale fossil-free steelmaking process in Sweden,but filling such storage causes joints in the rockmass to open,concentrating strains in the lining.The structural interaction between the LRC componentsmust be able to reduce the strain concentration in the sealing steel lining;however,this interaction iscomplex and difficult to predict with analytical methods.In this paper,the strain concentration in LRCsfrom the opening of rock joints is studied using finite element(FE)analyses,where the large-and small-scale deformation behaviors of the LRC are coupled.The model also includes concrete crack initiation anddevelopment with increasing gas pressure and rock joint width.The interaction between the jointed rockmass and the reinforced concrete,the sliding layer,and the steel lining is demonstrated.The results showthat the rock mass quality and the spacing of the rock joints have the greatest influence on the straindistributions in the steel lining.The largest effect of rock joints on the maximum strains in the steellining was observed for geological conditions of“good”quality rock masses.
文摘REE and other trace elements in ores, wall rocks, alkaline volcanic rocks and diabase dikes have been determined in the Yinachang Fe-Cu-REE deposit. Comparative studies of REE and trace element geochemical characteristics of these geological bodies indicate that the ores and alkaline volcanic rocks contain abundant REE and Y ({65.9}-{4633})×10+{-6}, with higher abundances of As, Mo, Nb, Co and U than those of the crust. Their chondrite-normalized patterns show a strong enrichment of LREE and a positive Eu anomaly, in contrast to those of the dolomites which are characterized by slight LREE enrichment and moderate negative Eu anomaly. The REE patterns of ores are similar to those of hydrothermal sediment cores in the East Pacific Rise, whereas the REE patterns of dolomites are similar to those of PAAS (Post-Archean Average Shale). In combination with the geological setting of the deposit, the primary ore-forming fluids might have higher REE and volatile elements, and might have been derived from mantle degassing, or the alkaline volcanic magmas. The Yinachang Fe-Cu-REE ore deposit is considered to be of volcanic exhalation-hydrothermal sedimentary origin.
