To solve the problem of the severe mismatch between the product and roll materials in the preliminary rolling line,a new graphitic steel material was designed,its microstructure and high-temperature friction and wear ...To solve the problem of the severe mismatch between the product and roll materials in the preliminary rolling line,a new graphitic steel material was designed,its microstructure and high-temperature friction and wear properties were investigated.Moreover,the feasibility of replacing semi-steel with this new material in the V1 stand roll was studied herein.The results show that the graphitic steel matrix is strengthened by silicon and nickel elements.The presence of spherical graphite also provides self-lubrication and heat conduction and prevents the propagation of cracks.Carbides in the appropriate amount and size strengthen the matrix,reduce the cracking effect of the matrix,and are not easily broken,thereby reducing high-temperature abrasive wear.Under the same hightemperature friction and wear conditions,compared with semi-steel,the wear-scar surface of graphitic steel exhibits less wear-scar depth and wear volume,a smaller friction coefficient,reduced oxide layer thickness,and fewer instances of peeling and microcracks.Therefore,the newly designed graphitic steel has higher wear resistance and hot-crack resistance than semi-steel,which makes it feasible for use in replacing semi-steel as a new V1 frame roll material in the blooming mill.展开更多
Fasteners of 718 alloys are used to set up connection between each support and other components for ITER system, metal-based Ag solid lubricant coating is widely used as an anti-seizure lubricant coating due to its st...Fasteners of 718 alloys are used to set up connection between each support and other components for ITER system, metal-based Ag solid lubricant coating is widely used as an anti-seizure lubricant coating due to its strong low-temperature shear resistance. But the poor adhesion to the steel surfaces has been a critical restriction for applying the silver coatings to the practical machine elements. In this work, an 8-μm silver self-lubricating coating was deposited on the surface of 718 alloy by the method of magnetron sputtering. The coating was uniform, dense and consistent. The wear mechanism was investigated by analyzing the friction and wear properties of the coating. Stress is one of the important impacts on the friction coefficient, the results showed that it first increased and then decreased with the increase of pressure at room temperature and under vacuum. Temperature exerted an effect on the silver self-lubricating coating. A study was conducted under vacuum on the friction and wear performance of the coating at 300 K, 225 K, 155 K, and 77 K, respectively. The results showed that the wear mechanism and wear state varied under various low-temperature conditions, with the severity of wear reaching the maximum only at 225 K. Through the same silver coating process, the washer of superbolt was improved by silver coating treatment.展开更多
Graphene/Inconel 718 composites were innovatively synthesized through selective laser melting,and the mechanical and tribological performances of the grapheme-reinforced Inconel 718 matrix composites were evaluated.Th...Graphene/Inconel 718 composites were innovatively synthesized through selective laser melting,and the mechanical and tribological performances of the grapheme-reinforced Inconel 718 matrix composites were evaluated.The composite microstructures were characterized by XRD,SEM and Raman spectroscopy.The results show that selective laser melting is a viable method to fabricate Inconel 718 matrix composite and the addition of graphene nanoplatelets leads to a significant strengthening of Inconel 718 alloy,as well as the improvement of tribological performance.The yield strength and ultimate tensile strength of 1.0%graphene/Inconel 718 composites(mass fraction)are 42%and 53%higher than those of pure material,and the friction coefficient and wear rate are 22.4%and 66.8%lower than those of pure material.The decrease of fraction coefficient and wear rate is attributed to the improved hardness of composites and the formation of graphene nanoplatelet protective layer on the worn surfaces.展开更多
Copper-graphite composites were prepared by spark plasma sintering(SPS)using coppercoated graphite powder.Hydrophobic surfaces were successfully constructed by chemical etching and surface treatment.The density,metall...Copper-graphite composites were prepared by spark plasma sintering(SPS)using coppercoated graphite powder.Hydrophobic surfaces were successfully constructed by chemical etching and surface treatment.The density,metallographic structure,microstructure,Shore hardness,resistivity,water contact angle,and friction/wear properties of the composites were investigated using the Archimedes drainage method,a metallographic microscope,a scanning electron microscope,a hardness tester,a resistometer,a surface science tester,and a friction tester.The results showed that the relative density and Shore hardness of the copper-graphite composites increased slightly from 90.04%and 56 HSD to 92.66%and 59 HSD,respectively,when the sintering temperature increased from 700 to 900℃.The copper and graphite phases in the copper-graphite composites were uniformly distributed with a continuous and network-like structure at various sintering temperatures.The interface between the copper and graphite was in good condition,without any obvious cracks or voids.The optimum process for hydrophobic surface construction included etching with a 1 mol/L K_(2)Cr_(2)O_(7)-H_(2)SO_(4)solution for 1 min,and soaking in a 0.09 mol/L cetylbenzene sulfonic acid alcohol solution for 1 h.The contact angle of the copper-graphite composite reached 130°.Hydrophobic treatment was beneficial for reducing the friction coefficient(from 0.18-0.19 to 0.13-0.15)and the wear rate(from 4.1-6.2×10^(-3)to 1.1-2.1×10^(-3)mm^(3)/(N·m)),demonstrating obvious antifriction and wear-resisting properties.The resistivities of the hydrophobic-treated samples increased slightly,from(4-8)×10^(-7)Ω·m to(5-15)×10^(-7)Ω·m,meeting the resistivity requirements of copper-graphite composite pantograph sliders and current receiver sliders in actual working conditions.展开更多
In this study,effects of B addition on the sintering densification,microstructure,hardness,friction and wear properties of sintered Fe-2.4C-4Cr-1Mo-0.5P-0.7Si-2.5Cu(in wt%)were investigated.In spite of the decreased s...In this study,effects of B addition on the sintering densification,microstructure,hardness,friction and wear properties of sintered Fe-2.4C-4Cr-1Mo-0.5P-0.7Si-2.5Cu(in wt%)were investigated.In spite of the decreased sintered density,the addition of B changes the phase composition of the materials and their ratio.Moreover,hardness of either the matrix or the liquid solidification structure dramatically increases.These changes in micro structure result in higher friction coefficient and lower wear loss.It is observed that the addition of0.1 wt%B offers the optimum friction and wear properties with a running-in period of only 30 s and wear volume loss of 0.006 mm^(3) under the testing conditions.Such friction and wear properties are superior to those of the other two widely used cam materials,cast iron and 45 steel.展开更多
The friction and wear behavior and mechanism as well as the mechanical properties of polytetrafluoroethylene (PTFE) composites filled with potassium titanate whiskers (PTW) and short carbon fibers (CF) under dry...The friction and wear behavior and mechanism as well as the mechanical properties of polytetrafluoroethylene (PTFE) composites filled with potassium titanate whiskers (PTW) and short carbon fibers (CF) under dry, wet and alkaline conditions were investigated. Experiments indicated that owing to appropriate cooling and boundary lubricating effects, the filled PTFE composites showed much lower frictional coefficient and better wear resistance under alkaline than dry and wet sliding conditions. The wear resistance of carbon-fiber-filled PTFE was much better than that of potassium titanate-whisker-filled PTFE composites in water. Results also showed that the transfer film on counterpart rings was significantly hindered by water and alkali. Hydrophilic-filler-reinforced PTFE composites yield higher wear rate when sliding under water.展开更多
A Nomex fabric/phenolic composite was prepared,and its tribological properties were evaluated under dry and water‐bathed sliding conditions by a pin‐on‐disk tribometer.The resulting size of the friction coefficient...A Nomex fabric/phenolic composite was prepared,and its tribological properties were evaluated under dry and water‐bathed sliding conditions by a pin‐on‐disk tribometer.The resulting size of the friction coefficient for the Nomex fabric/phenolic composite in the study occurred in the following order:dry sliding condition>distilled water‐bathed sliding condition>sea water‐bathed sliding condition.The fabric composite’s wear rate from high to low was as follows:distilled water‐bathed sliding condition>sea water‐bathed sliding condition>dry sliding condition.Under water‐bathed sliding conditions,penetration of water into the cracks accelerated the composite’s invalidation process,resulting in a higher wear rate.We also found that the extent of corrosion and transfer film formed on the counterpart pin significantly influenced the wear rate of the Nomex fabric composite.Discussion of the Nomex fabric composite’s wear mechanisms under the sliding conditions investigated is provided on the basis of the characterization results.展开更多
文摘To solve the problem of the severe mismatch between the product and roll materials in the preliminary rolling line,a new graphitic steel material was designed,its microstructure and high-temperature friction and wear properties were investigated.Moreover,the feasibility of replacing semi-steel with this new material in the V1 stand roll was studied herein.The results show that the graphitic steel matrix is strengthened by silicon and nickel elements.The presence of spherical graphite also provides self-lubrication and heat conduction and prevents the propagation of cracks.Carbides in the appropriate amount and size strengthen the matrix,reduce the cracking effect of the matrix,and are not easily broken,thereby reducing high-temperature abrasive wear.Under the same hightemperature friction and wear conditions,compared with semi-steel,the wear-scar surface of graphitic steel exhibits less wear-scar depth and wear volume,a smaller friction coefficient,reduced oxide layer thickness,and fewer instances of peeling and microcracks.Therefore,the newly designed graphitic steel has higher wear resistance and hot-crack resistance than semi-steel,which makes it feasible for use in replacing semi-steel as a new V1 frame roll material in the blooming mill.
文摘Fasteners of 718 alloys are used to set up connection between each support and other components for ITER system, metal-based Ag solid lubricant coating is widely used as an anti-seizure lubricant coating due to its strong low-temperature shear resistance. But the poor adhesion to the steel surfaces has been a critical restriction for applying the silver coatings to the practical machine elements. In this work, an 8-μm silver self-lubricating coating was deposited on the surface of 718 alloy by the method of magnetron sputtering. The coating was uniform, dense and consistent. The wear mechanism was investigated by analyzing the friction and wear properties of the coating. Stress is one of the important impacts on the friction coefficient, the results showed that it first increased and then decreased with the increase of pressure at room temperature and under vacuum. Temperature exerted an effect on the silver self-lubricating coating. A study was conducted under vacuum on the friction and wear performance of the coating at 300 K, 225 K, 155 K, and 77 K, respectively. The results showed that the wear mechanism and wear state varied under various low-temperature conditions, with the severity of wear reaching the maximum only at 225 K. Through the same silver coating process, the washer of superbolt was improved by silver coating treatment.
基金Project supported by the Ganpo 555 Program for Leading Talents of Jiangxi Province,China
文摘Graphene/Inconel 718 composites were innovatively synthesized through selective laser melting,and the mechanical and tribological performances of the grapheme-reinforced Inconel 718 matrix composites were evaluated.The composite microstructures were characterized by XRD,SEM and Raman spectroscopy.The results show that selective laser melting is a viable method to fabricate Inconel 718 matrix composite and the addition of graphene nanoplatelets leads to a significant strengthening of Inconel 718 alloy,as well as the improvement of tribological performance.The yield strength and ultimate tensile strength of 1.0%graphene/Inconel 718 composites(mass fraction)are 42%and 53%higher than those of pure material,and the friction coefficient and wear rate are 22.4%and 66.8%lower than those of pure material.The decrease of fraction coefficient and wear rate is attributed to the improved hardness of composites and the formation of graphene nanoplatelet protective layer on the worn surfaces.
基金the Open Subject of The State Key Laboratory of Heavy Duty AC Drive Electric Locomotive Systems Integration(No.172195100710)。
文摘Copper-graphite composites were prepared by spark plasma sintering(SPS)using coppercoated graphite powder.Hydrophobic surfaces were successfully constructed by chemical etching and surface treatment.The density,metallographic structure,microstructure,Shore hardness,resistivity,water contact angle,and friction/wear properties of the composites were investigated using the Archimedes drainage method,a metallographic microscope,a scanning electron microscope,a hardness tester,a resistometer,a surface science tester,and a friction tester.The results showed that the relative density and Shore hardness of the copper-graphite composites increased slightly from 90.04%and 56 HSD to 92.66%and 59 HSD,respectively,when the sintering temperature increased from 700 to 900℃.The copper and graphite phases in the copper-graphite composites were uniformly distributed with a continuous and network-like structure at various sintering temperatures.The interface between the copper and graphite was in good condition,without any obvious cracks or voids.The optimum process for hydrophobic surface construction included etching with a 1 mol/L K_(2)Cr_(2)O_(7)-H_(2)SO_(4)solution for 1 min,and soaking in a 0.09 mol/L cetylbenzene sulfonic acid alcohol solution for 1 h.The contact angle of the copper-graphite composite reached 130°.Hydrophobic treatment was beneficial for reducing the friction coefficient(from 0.18-0.19 to 0.13-0.15)and the wear rate(from 4.1-6.2×10^(-3)to 1.1-2.1×10^(-3)mm^(3)/(N·m)),demonstrating obvious antifriction and wear-resisting properties.The resistivities of the hydrophobic-treated samples increased slightly,from(4-8)×10^(-7)Ω·m to(5-15)×10^(-7)Ω·m,meeting the resistivity requirements of copper-graphite composite pantograph sliders and current receiver sliders in actual working conditions.
基金financially supported by the National High-tech R&D Program (No.2013AA031101)the Major Science and Technology Projects (No.2012ZX04009011)the Technology Project of Huairou District in Beijing (No.2017-8)。
文摘In this study,effects of B addition on the sintering densification,microstructure,hardness,friction and wear properties of sintered Fe-2.4C-4Cr-1Mo-0.5P-0.7Si-2.5Cu(in wt%)were investigated.In spite of the decreased sintered density,the addition of B changes the phase composition of the materials and their ratio.Moreover,hardness of either the matrix or the liquid solidification structure dramatically increases.These changes in micro structure result in higher friction coefficient and lower wear loss.It is observed that the addition of0.1 wt%B offers the optimum friction and wear properties with a running-in period of only 30 s and wear volume loss of 0.006 mm^(3) under the testing conditions.Such friction and wear properties are superior to those of the other two widely used cam materials,cast iron and 45 steel.
基金National Natural Science Foundation of China (Nos. 20676062, 20376032) National High-Tech Research Development Program (863 Program: 2003AA333010, 2006AA03Z455) Chinese National Fundamental Research Development Program (973 Program: 2003CB615700).
文摘The friction and wear behavior and mechanism as well as the mechanical properties of polytetrafluoroethylene (PTFE) composites filled with potassium titanate whiskers (PTW) and short carbon fibers (CF) under dry, wet and alkaline conditions were investigated. Experiments indicated that owing to appropriate cooling and boundary lubricating effects, the filled PTFE composites showed much lower frictional coefficient and better wear resistance under alkaline than dry and wet sliding conditions. The wear resistance of carbon-fiber-filled PTFE was much better than that of potassium titanate-whisker-filled PTFE composites in water. Results also showed that the transfer film on counterpart rings was significantly hindered by water and alkali. Hydrophilic-filler-reinforced PTFE composites yield higher wear rate when sliding under water.
基金The authors acknowledge the financial support of the National Science Foundation of China grant Nos.51375472 and 51305429.
文摘A Nomex fabric/phenolic composite was prepared,and its tribological properties were evaluated under dry and water‐bathed sliding conditions by a pin‐on‐disk tribometer.The resulting size of the friction coefficient for the Nomex fabric/phenolic composite in the study occurred in the following order:dry sliding condition>distilled water‐bathed sliding condition>sea water‐bathed sliding condition.The fabric composite’s wear rate from high to low was as follows:distilled water‐bathed sliding condition>sea water‐bathed sliding condition>dry sliding condition.Under water‐bathed sliding conditions,penetration of water into the cracks accelerated the composite’s invalidation process,resulting in a higher wear rate.We also found that the extent of corrosion and transfer film formed on the counterpart pin significantly influenced the wear rate of the Nomex fabric composite.Discussion of the Nomex fabric composite’s wear mechanisms under the sliding conditions investigated is provided on the basis of the characterization results.