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Magnetic Proximity Effect in an Antiferromagnetic Insulator/Topological Insulator Heterostructure with Sharp Interface
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作者 Yuxin Liu Xuefan Niu +3 位作者 Rencong Zhang Qinghua Zhang Jing Teng Yongqing Li 《Chinese Physics Letters》 SCIE CAS CSCD 2021年第5期84-88,共5页
We report an experimental study of electron transport properties of MnSe/(Bi,Sb)_2Te_3 heterostructures,in which MnSe is an antiferromagnetic insulator,and(Bi,Sb)_2Te_3 is a three-dimensional topological insulator(TI)... We report an experimental study of electron transport properties of MnSe/(Bi,Sb)_2Te_3 heterostructures,in which MnSe is an antiferromagnetic insulator,and(Bi,Sb)_2Te_3 is a three-dimensional topological insulator(TI).Strong magnetic proximity effect is manifested in the measurements of the Hall effect and longitudinal resistances.Our analysis shows that the gate voltage can substantially modify the anomalous Hall conductance,which exceeds 0.1 e^(2)/h at temperature T=1.6 K and magnetic field μ_0H=5 T,even though only the top TI surface is in proximity to MnSe.This work suggests that heterostructures based on antiferromagnetic insulators provide a promising platform for investigating a wide range of topological spintronic phenomena. 展开更多
关键词 DIRAC Magnetic Proximity Effect in an Antiferromagnetic insulator/topological insulator Heterostructure with Sharp Interface SHARP
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Erratum:Magnetic Proximity Effect in an Antiferromagnetic Insulator/Topological Insulator Heterostructure with Sharp Interface[Chin.Phys.Lett.38(2021)057303]
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作者 Yuxin Liu Xuefan Niu +3 位作者 Rencong Zhang Qinghua Zhangg Jing Teng Yongqing Li 《Chinese Physics Letters》 SCIE CAS CSCD 2021年第10期70-70,共1页
We should add the following acknowledge:Jing Teng thanks the support from the Youth Innovation Promotion Association Project,Chinese Academy of Sciences.
关键词 insulator THANKS FERROMAGNETIC
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Optical study of magnetic topological insulator MnBi_(4)Te_7
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作者 廖知裕 沈冰 +1 位作者 邱祥冈 许兵 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期231-235,共5页
We present an infrared spectroscopy study of the magnetic topological insulator MnBi_(4)Te_7 with antiferromagnetic(AFM) order below the Neel temperature TN= 13 K. Our investigation reveals that the low-frequency opti... We present an infrared spectroscopy study of the magnetic topological insulator MnBi_(4)Te_7 with antiferromagnetic(AFM) order below the Neel temperature TN= 13 K. Our investigation reveals that the low-frequency optical conductivity consists of two Drude peaks, indicating a response of free carriers involving multiple bands. Interestingly, the narrow Drude peak grows strongly as the temperature decreases, while the broad Drude peak remains relatively unchanged. The onset of interband transitions starts around 2000 cm^(-1), followed by two prominent absorption peaks around 10000 cm^(-1) and 20000 cm^(-1). Upon cooling, there is a notable transfer of spectral weight from the interband transitions to the Drude response. Below TN, the AFM transition gives rise to small anomalies of the charge response due to a band reconstruction.These findings provide valuable insights into the interplay between magnetism and the electronic properties in MnBi_(4)Te_7. 展开更多
关键词 infrared spectroscopy magnetic topological insulator Drude model band reconstruction
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Higher-order topological Anderson insulator on the Sierpiński lattice
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作者 陈焕 刘峥嵘 +1 位作者 陈锐 周斌 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期218-222,共5页
Disorder effects on topological materials in integer dimensions have been extensively explored in recent years. However, its influence on topological systems in fractional dimensions remains unclear. Here, we investig... Disorder effects on topological materials in integer dimensions have been extensively explored in recent years. However, its influence on topological systems in fractional dimensions remains unclear. Here, we investigate the disorder effects on a fractal system constructed on the Sierpiński lattice in fractional dimensions. The system supports the second-order topological insulator phase characterized by a quantized quadrupole moment and the normal insulator phase. We find that the second-order topological insulator phase on the Sierpiński lattice is robust against weak disorder but suppressed by strong disorder. Most interestingly, we find that disorder can transform the normal insulator phase to the second-order topological insulator phase with an emergent quantized quadrupole moment. Finally, the disorder-induced phase is further confirmed by calculating the energy spectrum and the corresponding probability distributions. 展开更多
关键词 fractal system topological insulator
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Three-dimensional topological crystalline insulator without spin-orbit coupling in nonsymmorphic photonic metacrystal
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作者 Zhide Yu Lingbo Xia 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期282-286,共5页
By including certain point group symmetry in the classification of band topology,Fu proposed a class of threedimensionaltopological crystalline insulators(TCIs)without spin-orbit coupling in 2011.In Fu’s model,surfac... By including certain point group symmetry in the classification of band topology,Fu proposed a class of threedimensionaltopological crystalline insulators(TCIs)without spin-orbit coupling in 2011.In Fu’s model,surface states(ifpresent)doubly degenerate atГandM when time-reversal and C_(4) symmetries are preserved.The analogs of Fu’s modelwith surface states quadratically degenerate atM are widely studied,while surface states with quadratic degeneracy atГare rarely reported.In this study,we propose a three-dimensional TCI without spin-orbit coupling in a judiciously designednonsymmorphic photonic metacrystal.The surface states of photonic TCIs exhibit quadratic band degeneracy in the(001)surface Brillouin zone(BZ)center(Гpoint).The gapless surface states and their quadratic dispersion are protected by C4and time-reversal symmetries,which correspond to the nontrivial band topology characterized by Z_(2)topological invariant.Moreover,the surface states along lines fromГto the(001)surface BZ boundary exhibit zigzag feature,which is interpretedfrom symmetry perspective by building composite operators constructed by the product of glide symmetries with timereversalsymmetry.The metacrystal array surrounded with air possesses high order hinge states with electric fields highlylocalized at the hinge that may apply to optical sensors.The gapless surface states and hinge states reside in a cleanfrequency bandgap.The topological surface states emerge at the boundary of the metacrystal and perfect electric conductor(PEC),which provide a pathway for topologically manipulating light propagation in photonic devices. 展开更多
关键词 topological crystalline insulator nonsymmorphic photonic metacrystal
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From Topological Nodal-Line Semimetals to Quantum Spin Hall Insulators in Tetragonal SnX Monolayers(X=F,Cl,Br,I)
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作者 朱晔 赵宝 +3 位作者 薛阳 徐玮 徐文婷 杨中芹 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第6期98-111,共14页
Two-dimensional(2D)topological materials have recently garnered significant interest due to their profound physical properties and promising applications for future quantum nanoelectronics.Achieving various topologica... Two-dimensional(2D)topological materials have recently garnered significant interest due to their profound physical properties and promising applications for future quantum nanoelectronics.Achieving various topological states within one type of materials is,however,seldom reported.Based on first-principles calculations and tightbinding models,we investigate topological electronic states in a novel family of 2D halogenated tetragonal stanene(T-SnX,X=F,Cl,Br,I).All the four monolayers are found to be unusual topological nodal-line semimetals(NLSs),protected by a glide mirror symmetry.When spin-orbit coupling(SOC)is turned on,T-SnF and TSnCl are still ascertained as topological NLSs due to the remaining band inversion,primarily composed of Sn pxy orbitals,while T-Sn Br and T-SnI become quantum spin Hall insulators.The phase transition is ascribed to moving up in energy of Sn s orbitals and increasing of SOC strengths.The topology origin in the materials is uniformly rationalized through elementary band representations.The robust and diverse topological states found in the 2D T-SnX monolayers position them as an excellent material platform for development of innovative topological electronics. 展开更多
关键词 topological metals quantum
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Tuning Second Chern Number in a Four-Dimensional Topological Insulator by High-Frequency Time-Periodic Driving
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作者 刘峥嵘 陈锐 周斌 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第4期77-89,共13页
Floquet engineering has attracted considerable attention as a promising approach for tuning topological phase transitions.We investigate the effects of high-frequency time-periodic driving in a four-dimensional(4D)top... Floquet engineering has attracted considerable attention as a promising approach for tuning topological phase transitions.We investigate the effects of high-frequency time-periodic driving in a four-dimensional(4D)topological insulator,focusing on topological phase transitions at the off-resonant quasienergy gap.The 4D topological insulator hosts gapless three-dimensional boundary states,characterized by the second Chern number C_(2).We demonstrate that the second Chern number of 4D topological insulators can be modulated by tuning the amplitude of time-periodic driving.This includes transitions from a topological phase with C_(2)=±3 to another topological phase with C_(2)=±1,or to a topological phase with an even second Chern number C_(2)=±2,which is absent in the 4D static system.Finally,the approximation theory in the high-frequency limit further confirms the numerical conclusions. 展开更多
关键词 topological TRANSITIONS PERIODIC
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RKKY interaction in helical higher-order topological insulators
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作者 金莎 李健 +1 位作者 李清旭 朱家骥 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第7期587-593,共7页
We theoretically investigate the Ruderman–Kittel–Kasuya–Yosida(RKKY) interaction in helical higher-order topological insulators(HOTIs), revealing distinct behaviors mediated by hinge and Dirac-type bulk carriers. O... We theoretically investigate the Ruderman–Kittel–Kasuya–Yosida(RKKY) interaction in helical higher-order topological insulators(HOTIs), revealing distinct behaviors mediated by hinge and Dirac-type bulk carriers. Our findings show that hinge-mediated interactions consist of Heisenberg, Ising, and Dzyaloshinskii–Moriya(DM) terms, exhibiting a decay with impurity spacing z and oscillations with Fermi energy εF. These interactions demonstrate ferromagnetic behaviors for the Heisenberg and Ising terms and alternating behavior for the DM term. In contrast, bulk-mediated interactions include Heisenberg, twisted Ising, and DM terms, with a conventional cubic oscillating decay. This study highlights the nuanced interplay between hinge and bulk RKKY interactions in HOTIs, offering insights into designs of next-generation quantum devices based on HOTIs. 展开更多
关键词 magnetic impurity interactions magnetic ordering SPINTRONICS topological phases
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Topological states constructed by two different trivial quantum wires
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作者 Jing-Run Lin Linxi Lv Zheng-Wei Zuo 《Chinese Physics B》 2025年第1期246-255,共10页
The topological states of the two-leg and three-leg ladders formed by two trivial quantum wires with different lattice constants are theoretically investigated. Firstly, we take two trivial quantum wires with a lattic... The topological states of the two-leg and three-leg ladders formed by two trivial quantum wires with different lattice constants are theoretically investigated. Firstly, we take two trivial quantum wires with a lattice constant ratio of 1:2 as an example. For the symmetric nearest-neighbor intra-chain hopping two-leg ladder, the inversion symmetry protected topological insulator phase with two degenerate topological edge states appears. When the inversion symmetry is broken, the topological insulators with one or two topological edge states of different energies and topological metals with edge states embedded in the bulk states could emerge depending on the filling factor. The topological origin of these topological states in the two-leg ladders is the topological properties of the Chern insulators and Chern metals. According to the arrangement of two trivial quantum wires, we construct two types of three-leg ladders. Each type of the three-leg ladder could be divided into one trivial subspace and one topological nontrivial subspace by unitary transformation. The topological nontrivial subspace corresponds to the effective two-leg ladder model. As the filling factor changes, the system could be in topological insulators or topological metals phases. When the two-leg ladder is constructed by two trivial quantum wires with a lattice constant ratio of 1:3 and 2:3, the system could also realize rich topological states such as the topological insulators and topological metals with the topological edge states. These rich topological states in the two-leg and three-leg ladders could be confirmed by current experimental techniques. 展开更多
关键词 trivial quantum wire topological invariant inversion symmetric topological insulator Chern metal
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The Impairment Attention Capture by Topological Change in Children With Autism Spectrum Disorder
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作者 XU Hui-Lin XI Huan-Jun +4 位作者 DUAN Tao LI Jing LI Dan-Dan WANG Kai ZHU Chun-Yan 《生物化学与生物物理进展》 北大核心 2025年第1期223-232,共10页
Objective Autism spectrum disorder(ASD)is a neurodevelopmental condition characterized by difficulties with communication and social interaction,restricted and repetitive behaviors.Previous studies have indicated that... Objective Autism spectrum disorder(ASD)is a neurodevelopmental condition characterized by difficulties with communication and social interaction,restricted and repetitive behaviors.Previous studies have indicated that individuals with ASD exhibit early and lifelong attention deficits,which are closely related to the core symptoms of ASD.Basic visual attention processes may provide a critical foundation for their social communication and interaction abilities.Therefore,this study explores the behavior of children with ASD in capturing attention to changes in topological properties.Methods Our study recruited twenty-seven ASD children diagnosed by professional clinicians according to DSM-5 and twenty-eight typically developing(TD)age-matched controls.In an attention capture task,we recorded the saccadic behaviors of children with ASD and TD in response to topological change(TC)and non-topological change(nTC)stimuli.Saccadic reaction time(SRT),visual search time(VS),and first fixation dwell time(FFDT)were used as indicators of attentional bias.Pearson correlation tests between the clinical assessment scales and attentional bias were conducted.Results This study found that TD children had significantly faster SRT(P<0.05)and VS(P<0.05)for the TC stimuli compared to the nTC stimuli,while the children with ASD did not exhibit significant differences in either measure(P>0.05).Additionally,ASD children demonstrated significantly less attention towards the TC targets(measured by FFDT),in comparison to TD children(P<0.05).Furthermore,ASD children exhibited a significant negative linear correlation between their attentional bias(measured by VS)and their scores on the compulsive subscale(P<0.05).Conclusion The results suggest that children with ASD have difficulty shifting their attention to objects with topological changes during change detection.This atypical attention may affect the child’s cognitive and behavioral development,thereby impacting their social communication and interaction.In sum,our findings indicate that difficulties in attentional capture by TC may be a key feature of ASD. 展开更多
关键词 ATTENTION autism spectrum disorder perceptual object topological perception
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Mn-doped topological insulators: a review 被引量:1
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作者 Jing Teng Nan Liu Yongqing Li 《Journal of Semiconductors》 EI CAS CSCD 2019年第8期64-80,共17页
Topological insulators (TIs) host robust edge or surface states protected by time-reversal symmetry (TRS), which makes them prime candidates for applications in spintronic devices. A promising avenue of research for t... Topological insulators (TIs) host robust edge or surface states protected by time-reversal symmetry (TRS), which makes them prime candidates for applications in spintronic devices. A promising avenue of research for the development of functional TI devices has involved doping of three-dimensional (3D) TI thin film and bulk materials with magnetic elements. This approach aims to break the TRS and open a surface band gap near the Dirac point. Utilizing this gapped surface state allows for a wide range of novel physical effects to be observed, paving a way for applications in spintronics and quantum computation. This review focuses on the research of 3D TIs doped with manganese (Mn). We summarize major progress in the study of Mn doped chalcogenide TIs, including Bi2Se3, Bi2Te3, and Bi2(Te,Se)3. The transport properties, in particular the anomalous Hall effect, of the Mn-doped Bi2Se3 are discussed in detail. Finally, we conclude with future prospects and challenges in further studies of Mn doped TIs. 展开更多
关键词 topological insulators THIN films electron transport ANOMALOUS HALL effect magnetic DOPING
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Transport properties of topological insulators films and nanowires 被引量:1
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作者 刘易 马铮 +2 位作者 赵弇斐 Meenakshi Singh 王健 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第6期58-71,共14页
The last several years have witnessed the rapid developments in the study and understanding of topological insulators. In this review, after a brief summary of the history of topological insulators, we focus on the re... The last several years have witnessed the rapid developments in the study and understanding of topological insulators. In this review, after a brief summary of the history of topological insulators, we focus on the recent progress made in transport experiments on topological insulator films and nanowires. Some quantum phenomena, including the weak antilocalization, the Aharonov-Bobm effect, and the Shubnikov-de Haas oscillations, observed in these nanostructures are described. In addition, the electronic transport evidence of the superconducting proximity effect as well as an anomalous resistance enhancement in topological insulator/superconductor hybrid structures is included. 展开更多
关键词 topological insulator surface state transport property MAGNETORESISTANCE superconducting proximity effect
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Molecular-beam epitaxy of topological insulator Bi_2Se_3(111) and (221) thin films 被引量:1
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作者 谢茂海 郭欣 +1 位作者 徐忠杰 何永健 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第6期91-98,共8页
This paper presents an overview of the growth of Bi2Se3, a prototypical three-dimensional topological insulator, by molecular-beam epitaxy on various substrates. Comparison is made between the growth of Bi2 Se3 (111... This paper presents an overview of the growth of Bi2Se3, a prototypical three-dimensional topological insulator, by molecular-beam epitaxy on various substrates. Comparison is made between the growth of Bi2 Se3 (111) on van der Waals (vdW) and non-vdW substrates, with attention paid to twin suppression and strain. Growth along the [221] direction of Bi2Se3 on InP (001) and GaAs (001) substrates is also discussed. 展开更多
关键词 topological insulator molecular-beam epitaxy Bi2Se3 twin domain STRAIN
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Topological edge states and electronic structures of a 2D topological insulator: Single-bilayer Bi (111) 被引量:1
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作者 高春雷 钱冬 +2 位作者 刘灿华 贾金锋 刘锋 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第6期72-80,共9页
Providing the strong spin-orbital interaction, Bismuth is the key element in the family of three-dimensional topological insulators. At the same time, Bismuth itself also has very unusual behavior, existing from the t... Providing the strong spin-orbital interaction, Bismuth is the key element in the family of three-dimensional topological insulators. At the same time, Bismuth itself also has very unusual behavior, existing from the thinnest unit to bulk crystals. Ultrathin Bi (111) bilayers have been theoretically proposed as a two-dimensional topological insulator. The related experimental realization achieved only recently, by growing Bi (111) ultrathin bilayers on topological insulator Bi2Te3 or Bi2Se3 substrates. In this review, we started from the growth mode of Bi (111) bilayers and reviewed our recent progress in the studies of the electronic structures and the one-dimensional topological edge states using scanning tunneling microscopy/spectroscopy (STM/STS), angle-resolved photoemission spectroscopy (ARPES), and first principles calculations. 展开更多
关键词 topological insulators edge states electronic structures Bi bilayer
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Tunable Weyl fermions and Fermi arcs in magnetized topological crystalline insulators 被引量:1
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作者 Junwei Liu Chen Fang Liang Fu 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第4期41-46,共6页
Based on k · p analysis and realistic tight-binding calculations, we find that time-reversal-breaking Weyl semimetals can be realized in magnetically-doped(Mn, Eu, Cr, etc.) Sn_(1-x)Pb_x(Te, Se) class of topologi... Based on k · p analysis and realistic tight-binding calculations, we find that time-reversal-breaking Weyl semimetals can be realized in magnetically-doped(Mn, Eu, Cr, etc.) Sn_(1-x)Pb_x(Te, Se) class of topological crystalline insulators. All the Weyl points are well separated in momentum space and possess nearly the same energy due to high crystalline symmetry.Moreover, both the Weyl points and Fermi arcs are highly tunable by varying Pb/Sn composition, pressure, magnetization,temperature, surface potential, etc., opening up the possibility of manipulating Weyl points and rewiring the Fermi arcs. 展开更多
关键词 topological crystalline insulator magnetic WEYL SEMIMETAL magnetically-doped Sn1-x Pbx(Te Se) FERMI arc
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Topological insulator nanostructures and devices 被引量:1
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作者 修发贤 赵彤彤 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第9期40-53,共14页
Topological insulators' properties and their potential device applications are reviewed. We also explain why topologi- cal insulator (TI) nanostructnres are an important avenue for research and discuss some methods... Topological insulators' properties and their potential device applications are reviewed. We also explain why topologi- cal insulator (TI) nanostructnres are an important avenue for research and discuss some methods by which TI nanostructures are produced and characterized. The rapid development of high-quality TI nanostructures provides an ideal platform to ex- ploit salient physical phenomena that have been theoretically predicted but not yet experimentally realized. 展开更多
关键词 topological insulators NANOSTRUCTURES quantum spin Hall effect Aharonov-Bohm effect
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Probing the minigap in topological insulator-based Josephson junctions under radio frequency irradiation 被引量:1
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作者 Guang Yang Zhaozheng Lyu +2 位作者 Xiang Zhang Fanming Qu Li Lu 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第12期52-55,共4页
Recently,a contact-resistance-measurement method was developed to detect the minigap,hence the Andreev bound states(ABSs),in Josephson junctions constructed on the surface of three-dimensional topological insulators(3... Recently,a contact-resistance-measurement method was developed to detect the minigap,hence the Andreev bound states(ABSs),in Josephson junctions constructed on the surface of three-dimensional topological insulators(3D TIs).In this work,we further generalize that method to the circumstance with radio frequency(rf)irradiation.We find that with the increase of the rf power,the measured minigap becomes broadened and extends to higher energies in a way similar to the rf power dependence of the outer border of the Shapiro step region.We show that the corresponding data of contact resistance under rf irradiation can be well interpreted by using the resistively shunted Josephson junction(RSJ)model and the Blonder–Tinkham–Klapwijk(BTK)theory.Our findings could be useful when using the contact-resistancemeasurement method to study the Majorana-related physics in topological insulator-based Josephson junctions under rf irradiation. 展开更多
关键词 topological insulator Josephson junction contact-resistance-measurement method radio frequency irradiation
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Topological Anderson insulator in two-dimensional non-Hermitian systems 被引量:2
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作者 Hongfang Liu Zixian Su +1 位作者 Zhi-Qiang Zhang Hua Jiang 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第5期13-21,共9页
We study the disorder-induced phase transition in two-dimensional non-Hermitian systems.First,the applicability of the noncommutative geometric method(NGM)in non-Hermitian systems is examined.By calculating the Chern ... We study the disorder-induced phase transition in two-dimensional non-Hermitian systems.First,the applicability of the noncommutative geometric method(NGM)in non-Hermitian systems is examined.By calculating the Chern number of two different systems(a square sample and a cylindrical one),the numerical results calculated by NGM are compared with the analytical one,and the phase boundary obtained by NGM is found to be in good agreement with the theoretical prediction.Then,we use NGM to investigate the evolution of the Chern number in non-Hermitian samples with the disorder effect.For the square sample,the stability of the non-Hermitian Chern insulator under disorder is confirmed.Significantly,we obtain a nontrivial topological phase induced by disorder.This phase is understood as the topological Anderson insulator in non-Hermitian systems.Finally,the disordered phase transition in the cylindrical sample is also investigated.The clean non-Hermitian cylindrical sample has three phases,and such samples show more phase transitions by varying the disorder strength:(1)the normal insulator phase to the gapless phase,(2)the normal insulator phase to the topological Anderson insulator phase,and(3)the gapless phase to the topological Anderson insulator phase. 展开更多
关键词 disorder effect topological Anderson insulator non-Hermitian systems
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The preparation process and feature of the topological insulator Bi_2Te_3 被引量:1
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作者 Peng Chen Dajin Zhou +2 位作者 Pingyuan Li Yajing Cui Yongliang Chen 《Journal of Modern Transportation》 2014年第1期59-63,共5页
Topological insulators are insulating in the bulkbut have metallic surface states. Its unique physicochemicalproperties can find numerous applications in electronics,spintronics, photonics, the energy sciences, and th... Topological insulators are insulating in the bulkbut have metallic surface states. Its unique physicochemicalproperties can find numerous applications in electronics,spintronics, photonics, the energy sciences, and thesignal control of transportation. We report an experimentalapproach to synthesize the high-quality single crystal oftopological insulator Bi2Te3 by using self-flux method. Weobtained the optimal preparation conditions by adjustingthe parameters of heat treatment, and successfully preparedthe single-crystal Bi2Te3 sample. The as-grown sampleshave a surface with bright metallic luster and are soft andfragile. Furthermore, Bi2Te3 has the obvious layer structurefrom SEM results. The data of X-ray diffraction andscanning electron microscope show that Bi2Te3 singlecrystal grows along the c-axis with the order of Te(1)–Bi–Te(2)–Bi–Te(1) and crystallizes in the hexagonal systemwith space group of R/3 m. The q–T curve shows that qdecreases with temperature, showing metallic behaviorover the whole temperature range. 展开更多
关键词 BI2TE3 Single crystal topological insulator
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MoS_(2) on topological insulator Bi_(2)Te_(3) thin films:Activation of the basal plane for hydrogen reduction 被引量:1
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作者 Guowei Lia Jue Huang +6 位作者 Qun Yang Liguo Zhang Qingge Mu Yan Sun Stuart Parkin Kai Chang Claudia Felser 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第11期516-522,I0012,共8页
2H-MoS_(2) is a well-studied and promising non-noble metal electrocatalyst for heterogeneous reactions,such as the hydrogen evolution reaction(HER).The performance is largely limited by the chemically inert basal plan... 2H-MoS_(2) is a well-studied and promising non-noble metal electrocatalyst for heterogeneous reactions,such as the hydrogen evolution reaction(HER).The performance is largely limited by the chemically inert basal plane,which is unfavorable for surface adsorption and reactions.Herein,we report a facile method to boost the HER activities of 2H-MoS_(2) by coupling with epitaxial Bi2Te3 topological insulator films.The as-obtained MoS_(2)/Bi2Te3/SrTiO3 catalyst exhibits prominent HER catalytic activities compared to that of pure MoS_(2) structures,with a 189 mV decrease in the overpotential required to reach a current density of 10 mA cm^(−2) and a low Tafel slope of 58 mV dec−1.Theoretical investigations suggest that the enhanced catalytic activity originates from the charge redistribution at the interface between the Bi2Te3topological insulator films and the MoS_(2) layer.The delocalized sp-derived topological surface states could denote electrons to the MoS_(2) layer and activate the basal plane for hydrogen adsorption.This study demonstrates the potential of manipulating topological surface states to design high-performance electrocatalysts. 展开更多
关键词 MoS_(2) topological insulator Hydrogen evolution Surface states Electron transfer
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