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Intramolecular Hydrogen Bond Improved Durability and Kinetics for Zinc‑Organic Batteries
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作者 Tianjiang Sun Jun Pan +5 位作者 Weijia Zhang Xiaodi Jiang Min Cheng Zhengtai Zha Hong Jin Fan Zhanliang Tao 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期138-148,共11页
Organic compounds have the advantages of green sustainability and high designability,but their high solubility leads to poor durability of zinc-organic batteries.Herein,a high-performance quinone-based polymer(H-PNADB... Organic compounds have the advantages of green sustainability and high designability,but their high solubility leads to poor durability of zinc-organic batteries.Herein,a high-performance quinone-based polymer(H-PNADBQ)material is designed by introducing an intramolecular hydrogen bonding(HB)strategy.The intramolecular HB(C=O⋯N-H)is formed in the reaction of 1,4-benzoquinone and 1,5-naphthalene diamine,which efficiently reduces the H-PNADBQ solubility and enhances its charge transfer in theory.In situ ultraviolet-visible analysis further reveals the insolubility of H-PNADBQ during the electrochemical cycles,enabling high durability at different current densities.Specifically,the H-PNADBQ electrode with high loading(10 mg cm^(-2))performs a long cycling life at 125 mA g^(-1)(>290 cycles).The H-PNADBQ also shows high rate capability(137.1 mAh g^(−1)at 25 A g^(−1))due to significantly improved kinetics inducted by intramolecular HB.This work provides an efficient approach toward insoluble organic electrode materials. 展开更多
关键词 Zn-organic batteries H-PNADBQ polymer intramolecular hydrogen bond Reduced solubility Improvedπ-conjugated level
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Regulating intramolecular hydrogen bonds of p-phenylenediimidazole-based small-molecule compounds towards the enhanced lithium storage capacity
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作者 Liping Zheng Bei Wang +7 位作者 Jianze Zhang Wenjie Zhou Jiayi Ren Huige Ma Rui Li Chengming Li Mingjun Hu Jun Yang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期406-413,共8页
The use of redox-active organic electrode materials in energy storage is restricted due to their inferior solvent resistance,abysmal conductivity,and the resultant low practical capacity.To address these issues,a clas... The use of redox-active organic electrode materials in energy storage is restricted due to their inferior solvent resistance,abysmal conductivity,and the resultant low practical capacity.To address these issues,a class of bipolar p-phenylenediimidazole-based small-molecule compounds are designed and fabricated.Theπ-conjugated backbone of these small molecules allows for electron delocalization on a big conjugation plane,endowing them with good conductivity and reaction reversibility.Furthermore,when the para-positions of phenylene are occupied by hydroxyl groups,as-formed intramolecular hydrogen bonds(N-H...O)between phenolic hydroxyl groups and the–NH groups of imidazole rings further enhance the structural planarity,resulting in higherπ-conjugation degree and better conductivity,and thus higher utilization of active sites and electrode capacity,proved by both experimental results and theoretical calculations.The optimized composite electrode DBNQ@rGO-45 shows a high specific capacity(∼308 mA h g^(−1)at 100 mA g^(−1))and a long cycling stability(112.9 mA h g^(−1)after 6000 cycles at 2000 mA g^(−1)).The significantly better electrochemical properties for hydroxyl group-containing compounds than those without hydroxyl groups attributed to intramolecular hydrogen bond-induced conjugation enhancement will inspire the structure design of organic electrodes for better energy storage. 展开更多
关键词 Bipolar P-phenylenedimidazole intramolecular hydrogenbonds Planarity and conjugationd egree High capacity
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Synthesis of Fluorene Derivatives Via TfOH-catalyzed Intramolecular Friedel-Crafts Alkylation Reactions
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作者 ZHOU Ziyang YI Ying +3 位作者 ZHANG Fanglin XU Wengang LU Zhi LUO Tian 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第5期1184-1189,共6页
We devoloped an efficient and simple method to synthesize fluorene derivatives via intramolecular Friedel-Crafts alkylation of chalcones.The transform is catalyzed by TfOH in CH_(3)NO_(2)at 80℃and the yield is up to ... We devoloped an efficient and simple method to synthesize fluorene derivatives via intramolecular Friedel-Crafts alkylation of chalcones.The transform is catalyzed by TfOH in CH_(3)NO_(2)at 80℃and the yield is up to 99%. 展开更多
关键词 FLUORENE intramolecular alkylation TfOH
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Design Strategy of Infrared 4-Hydroxybenzylidene-imidazolinone-Type Chromophores based on Intramolecular Charge Transfer:a Theoretical Perspective
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作者 Jian Song WenLong Liang +1 位作者 Shouning Yang Huayan Yang 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2023年第5期582-592,I0002,共12页
Partial genetically encoded 4-hy-droxybenzylidene-imidazolinone(HBI)-type chromophores are new promising fluorescent probes,which are suitable for imaging and detection of living cells.How-ever,the lack of infrared ch... Partial genetically encoded 4-hy-droxybenzylidene-imidazolinone(HBI)-type chromophores are new promising fluorescent probes,which are suitable for imaging and detection of living cells.How-ever,the lack of infrared chro-mophores hinders the develop-ment seriously.Here more than 30 HBI-type chromophores with reg-ular structure modifications were employed and typical spectral redshift change laws and mechanisms were investigated by quantum methods.Results show that both one-photon spectrum(OPS,absorption/emission)and two-photon absorption(TPA)can achieve large redshift via either extending conjugated lengths of frag-3 or enlarging conjugated areas of frag-1 of HBI skeleton.Spectral redshifts of all chromophores are highly related to intramolecular charge transfer(ICT),but neutral ones are closely related to the total ICT or electron-accept-ing-numbers of frag-3,and the high correlative factor of anions is the aromaticity of frag-2 bridge.The frag-2 bridge with high aromaticity can open a reverse charge transfer channel in anion relative to neutral,obtaining significant redshift.Based on analysis,a new 6-hydroxyl-naphthalene-imidazolinone(HNI)series,which have larger conjugated area in frag-1,are pre-dicted.The OPS and TPA of anionic HNI ones acquire about 76−96 nm and 119−146 nm red-shift relative to traditional HBI series respectively as a whole.The longest emission of anionic HNI-4 realizes more 244 nm redshift relative to HBI-1.Our work clarifies worthy spectral reg-ularities and redshift mechanisms of HBI-type chromophores and provides valuable design strategy for infrared chromophores synthesis in experiment. 展开更多
关键词 intramolecular charge transfer Near-infrared fluorescent chromophore 4-Hy-droxybenzylidene-imidazolinone One-photon spectrum Two-photon absorption
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Deep-red and near-infrared organic lasers based on centrosymmetric molecules with excited-state intramolecular double proton transfer activity
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作者 Chang-Cun Yan Zong-Lu Che +2 位作者 Wan-Ying Yang Xue-Dong Wang Liang-Sheng Liao 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2023年第7期19-28,共10页
Organic lasers that emit light in the deep-red and near-infrared(NIR)region are of essential importance in laser communication,night vision,bioimaging,and information-secured displays but are still challenging because... Organic lasers that emit light in the deep-red and near-infrared(NIR)region are of essential importance in laser communication,night vision,bioimaging,and information-secured displays but are still challenging because of the lack of proper gain materials.Herein,a new molecular design strategy that operates by merging two excited-state intramolecular proton transfer-active molecules into one excited-state double proton transfer(ESDPT)-active molecule was demonstrated.Based on this new strategy,three new materials were designed and synthesized with two groups of intramolecular resonance-assisted hydrogen bonds,in which the ESDPT process was proven to proceed smoothly based on theoretical calculations and experimental results of steady-state and transient spectra.Benefiting from the effective six-level system constructed by the ESDPT process,all newly designed materials showed low threshold laser emissions at approximately 720 nm when doped in PS microspheres,which in turn proved the existence of the second proton transfer process.More importantly,our well-developed NIR organic lasers showed high laser stability,which can maintain high laser intensity after 12000 pulse lasing,which is essential in practical applications.This work provides a simple and effective method for the development of NIR organic gain materials and demonstrates the ESDPT mechanism for NIR lasing. 展开更多
关键词 excited-state intramolecular proton transfer organic laser near-infrared emission molecular design
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Experimental and Theoretical Investigation on Excited State Intramolecular Proton Transfer Coupled Charge Transfer Reaction of Baicalein
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作者 胡闪闪 刘琨 +2 位作者 丁倩倩 彭伟 陈茂笃 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第1期51-56,I0003,共7页
The excited state intramolecular proton transfer (ESIPT) coupled charge transfer of baicalein has been investigated using steady-state spectroscopic experiment and quantum chemistry calculations. The absence of the ... The excited state intramolecular proton transfer (ESIPT) coupled charge transfer of baicalein has been investigated using steady-state spectroscopic experiment and quantum chemistry calculations. The absence of the absorption peak from S1 excited state both in the experi-mental and calculated absorption spectra indicates that S1 is a dark state. The dark excited state S1 results in the very weak fluorescence of solid baicalein in the experiment. The fron- tier molecular orbital and the charge difference densities of baicalein show clearly that the S1 state is a charge-transfer state whereas the S2 state is a locally excited state. The only one stationary point on the potential energy profile of excited state suggests that the ESIPT reaction of baicalein is a barrierless process. 展开更多
关键词 Excited state intramolecular proton transfer intramolecular charge transfer Time-dependent density functional theory Dark state BAICALEIN
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Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy 被引量:1
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作者 蒋礼林 刘伟龙 +1 位作者 宋云飞 孙山林 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第10期533-537,共5页
Photo-induced intramolecular electron transfer (PIET) and intramolecular vibrational relaxation (IVR) dynamics of the excited state of rhodamine 6G (Rh6G+) in DMSO are investigated by multiplex transient gratin... Photo-induced intramolecular electron transfer (PIET) and intramolecular vibrational relaxation (IVR) dynamics of the excited state of rhodamine 6G (Rh6G+) in DMSO are investigated by multiplex transient grating. Two major compo- nents are resolved in the dynamics of Rh6G+. The first component, with a lifetime τTPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range ZIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G+ are quantitatively determined, and a better understanding of the relationship between these processes is obtained. 展开更多
关键词 photo-induced intramolecular electron transfer intramolecular vibrational relaxation excitedstate multiplex transient grating
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Theoretical investigation on the excited state intramolecular proton transfer in Me_(2)N substituted flavonoid by the time-dependent density functional theory method
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作者 Hang Yin Ying Shi 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第5期534-538,共5页
Time-dependent density functional theory(TDDFT)method is used to investigate the details of the excited state intramolecular proton transfer(ESIPT)process and the mechanism for temperature effect on the Enol^(*)/Keto^... Time-dependent density functional theory(TDDFT)method is used to investigate the details of the excited state intramolecular proton transfer(ESIPT)process and the mechanism for temperature effect on the Enol^(*)/Keto^(*)emission ratio for the Me_(2)N-substited flavonoid(MNF)compound.The geometric structures of the S_(0) and S_(1) states are denoted as the Enol,Enol^(*),and Keto*.In addition,the absorption and fluorescence peaks are also calculated.It is noted that the calculated large Stokes shift is in good agreement with the experimental result.Furthermore,our results confirm that the ESIPT process happens upon photoexcitation,which is distinctly monitored by the formation and disappearance of the characteristic peaks of infrared(IR)spectra involved in the proton transfer and in the potential energy curves.Besides,the calculations of highest occupied molecular orbital(HOMO)and lowest unoccupied molecular orbital(LUMO)reveal that the electronegativity change of proton acceptor due to the intramolecular charge redistribution in the S_(1) state induces the ESIPT.Moreover,the thermodynamic calculation for the MNF shows that the Enol^(*)/Keto^(*)emission ratio decreasing with temperature increasing arises from the barrier lowering of ESIPT. 展开更多
关键词 time-dependent density functional theory excited state intramolecular proton transfer intramolecular charge transfer transition state
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Electron Momentum Spectroscopy of Valence Orbitals of n-Propyl Iodide: Spin-Orbit Coupling Effect and Intramolecular Orbital Interaction
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作者 王恩亮 史钰峰 +3 位作者 单旭 阳弘江 张卫 陈向军 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第5期503-511,I0003,共10页
The binding energy spectrum and electron momentum distributions for the outer valence orbitals of n-propyl iodide molecule have been measured using the electron momentum spectrometer employing non-coplanar asymmetric ... The binding energy spectrum and electron momentum distributions for the outer valence orbitals of n-propyl iodide molecule have been measured using the electron momentum spectrometer employing non-coplanar asymmetric geometry at impact energy of 2.5 keV plus binding energy. The ionization bands have been assigned in detail via the high accuracy SACCI general-R method calculation and the experimental momentum profiles are compared with the theoretical ones calculated by Hartree-Fock and B3LYP/aug-cc-pVTZ(C,H)6-311G??(I). The spin-orbit coupling effect and intramolecular orbital interaction have been analyzed for the outermost two bands, which are assigned to the iodine 5p lone pairs, using NBO method and non-relativistic as well as relativistic calculations. It is found that both of the interactions will lead to the observed differences in electron momentum distributions. The experimental results agree with the relativistic theoretical momentum profiles, indicating that the spin-orbit coupling effect dominates in n-propyl iodide molecule. 展开更多
关键词 n-Propyl iodide Electron momentum spectroscopy Spin-orbit coupling effect intramolecular orbital interaction
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An altemative synthetic approach towards erythrinan and homoerythrinan alkaloids by tandem semipinacol/intramolecular Schmidt reaction 被引量:1
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作者 Pei Ming Gu Yu Ming Zhao Yong QiangTu Min Wang Shu Yu Zhang 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第8期917-919,共3页
An alternative construction of A-B-D ring-system of erythrinan and homoerythrinan alkaloids by TiCl4-mediated tandem semipinacol/intramolecular Schmidt reaction of α-siloxyepoxyazide was addressed and the unusual epo... An alternative construction of A-B-D ring-system of erythrinan and homoerythrinan alkaloids by TiCl4-mediated tandem semipinacol/intramolecular Schmidt reaction of α-siloxyepoxyazide was addressed and the unusual epoxidation stereoselectivity was observed in preparation of the substrate once again. 展开更多
关键词 TANDEM intramolecular Schmidt reaction Semipinacol ALKALOID
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Asymmetric Intramolecular Cyclopropanation Induced by (β-Diketone)-copper Complex 被引量:1
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作者 QingFangCHENG XingYouXU +1 位作者 WeiXingMA TianPaYOU 《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第3期331-334,共4页
Asymmetric intramolecular cyclopropanation of allylic diazoacetate was investigated using a chiral (β-diketone)-copper complex as catalyst, excellent yield and enantioselectivity were achieved. Some factors influenci... Asymmetric intramolecular cyclopropanation of allylic diazoacetate was investigated using a chiral (β-diketone)-copper complex as catalyst, excellent yield and enantioselectivity were achieved. Some factors influencing enantioselectivity were discussed. 展开更多
关键词 intramolecular CYCLOPROPANATION ASYMMETRICCATALYSIS (β-diketone)-copper.
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The Luminescence Properties and Intramolecular Energy Transfer of Rare Earth Complexes with Aromatic Carboxylic Acids 被引量:1
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作者 YAN Bing ZHANG Hong-jie NI Jia-zuan 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1998年第3期23-27,共5页
The triplet state energies of para aminobenzoic acid and nicotinic acid were determined by means of low temperature phosphorescence spectrometry. The energy matches between them and the resonant emitting energy l... The triplet state energies of para aminobenzoic acid and nicotinic acid were determined by means of low temperature phosphorescence spectrometry. The energy matches between them and the resonant emitting energy levels of Eu 3+ , Tb 3+ , Sm 3+ , Dy 3+ were studied. The intramolecular energy transfer processes from the two aromatic carboxylic acid ligands to rare earth ions were also discussed on the basis of the measurement results of luminescence intensities, lifetimes and quantum efficiencies. 展开更多
关键词 Luminescence properties intramolecular energy transfer Rare earth complexes
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RATE OF INTRAMOLECULAR CONTACT FORMATION IN PROTEINS 被引量:1
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作者 Lin-xi Zhang Ting-ting Sun Xiang-hong Wang 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2007年第2期197-201,共5页
In this paper, we estimate the rate of contact formation between two residues in the interior of the proteins using the Szabo, Schulten, and Schulten formula with the probability distribution P(r) based on 375 prote... In this paper, we estimate the rate of contact formation between two residues in the interior of the proteins using the Szabo, Schulten, and Schulten formula with the probability distribution P(r) based on 375 proteins from PDB (Protein Data Bank). The probability distribution for residue pair in proteins is different from the Gaussian distribution, especially for short distance between two residues in proteins. The rate of contact formation in the interior of protein is discussed as a function of distance n (=|j -i|) between two residues, and it decreases monotonically with n and follows the scaling relationship of k ∝ n^-γ with γ= 1.43 for the contact radius a = 0.40 nm and γ=1.05 for a = 0.50 nm. The diffusion coefficient for the relative diffusion of two residues in the interior of proteins is estimated as D = 6.4 × 10^-6 cm^2/s, which is close to the result that is found for monomer diffusion. 展开更多
关键词 Rate of intramolecular contact formation Probability distribution P(r).
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Phase-Transfer-Catalyzed Intramolecular Hydroaryloxylation and Hydroamination of C≡C Triple Bonds: An Efficient Synthesis of Benzo[<i>b</i>]furan and 3-Methyleneisoindoline-1-one Derivatives 被引量:1
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作者 Jie Hu Lei Liu +3 位作者 Xiangchuan Wang Yuanyuan Hu Shangdong Yang Yongmin Liang 《Green and Sustainable Chemistry》 2011年第4期165-169,共5页
Phase-transfer-catalyzed intramolecular cyclization reaction of forming benzo[b]furan and 3-methyleneisoin- doline-1-one derivatives has been developed. The cyclization reaction of propargylic carbonates was also de- ... Phase-transfer-catalyzed intramolecular cyclization reaction of forming benzo[b]furan and 3-methyleneisoin- doline-1-one derivatives has been developed. The cyclization reaction of propargylic carbonates was also de- scribed under metal-free condition and the reaction was reported by Pd and Ni before. The reaction condi- tions and the scope of the process are examined. The catalysts are cheap and environmentally friendly and the substrates are readily available and the procedure is simple, rapid, and general. The development of C-O and C-N bond formation processes via an overall structural isomerization represents the most atom-eco- nomical approach. 展开更多
关键词 PTC intramolecular Cyclization Metal-Free
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The substituent effect on the excited state intramolecular proton transfer of 3-hydroxychromone
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作者 Yuzhi Song Songsong Liu +3 位作者 Jiajun Lu Hui Zhang Changzhe Zhang Jun Du 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第9期150-156,共7页
The excited state intramolecular proton transfer of four derivatives(FM, BFM, BFBC, CCM) of 3-hydroxychromone is investigated.The geometries of different substituents are optimized to study the substituent effects on ... The excited state intramolecular proton transfer of four derivatives(FM, BFM, BFBC, CCM) of 3-hydroxychromone is investigated.The geometries of different substituents are optimized to study the substituent effects on proton transfer.The mechanism of hydrogen bond enhancement is qualitatively elucidated by comparing the infrared spectra, the reduced density gradient, and the frontier molecular orbitals.The calculated electronic spectra are consistent with the experimental results.To quantify the proton transfer, the potential energy curves(PECs) of the four derivatives in S0 and S1 states are scanned.It is concluded that the ability of proton transfer follows the order: FM > BFM > BFBC > CCM. 展开更多
关键词 EXCITED state intramolecular PROTON transfer(ESIPT) hydrogen BOND reduced density gradient(RDG) SUBSTITUENTS
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Dynamical correlation between quantum entanglement and intramolecular energy in molecular vibrations:An algebraic approach
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作者 冯海冉 孟祥佳 +1 位作者 李鹏 郑雨军 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第7期387-393,共7页
The dynamical correlation between quantum entanglement and intramolecular energy in realistic molecular vibrations is explored using the Lie algebraic approach. The explicit expression of entanglement measurement can ... The dynamical correlation between quantum entanglement and intramolecular energy in realistic molecular vibrations is explored using the Lie algebraic approach. The explicit expression of entanglement measurement can be achieved using algebraic operations. The common and different characteristics of dynamical entanglement in different molecular vibrations are also provided. The dynamical study of quantum entanglement and intramolecular energy in small molecular vibrations can be helpful for controlling the entanglement and further understanding the intramolecular dynamics. 展开更多
关键词 quantum entanglement molecular vibration intramolecular energy Lie algebra
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A Simple Approach to the Synthesis of 2H-1-Benzopyrans and 3H-Naphtho[2,1-b] pyran Via Intramolecular Wittig Reactiont
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作者 曹卫国 张平生 +2 位作者 陈米 沈嵘 丁维钰 《Advances in Manufacturing》 SCIE CAS 1997年第1期83-86,共4页
In the presence of K2CO3, 2-hydroxyethyltripheny phosphonium bromide (1) reacts with substituted salicylaldehyde (2) and 2-hydroxy-1 naphthaldehyde (4) at 110 ℃ in a sealed tube. The title compounds were prepared in ... In the presence of K2CO3, 2-hydroxyethyltripheny phosphonium bromide (1) reacts with substituted salicylaldehyde (2) and 2-hydroxy-1 naphthaldehyde (4) at 110 ℃ in a sealed tube. The title compounds were prepared in medium yield. The ratio of bromide (1) to aldehyde derivatives was also discussed in this paper. 展开更多
关键词 PHOSPHORANE aldehyde bezopyran NAPHTHOPYRAN intramolecular Wittig reaction
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A DFT Study on Intramolecular Hydrogen Bond in Substituted Catechols and Their Radicals
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作者 Hong Yu +4 位作者 ZHANG You Min SUN 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第2期209-212,共4页
Density functional theory (DFT) at B3LYP/6-31G(d,p) level was employed to calculate intramolecular hydrogen bond enthalpies (HIHB), O-H charge differences, O-H bond lengths and bond orders for various substituted cate... Density functional theory (DFT) at B3LYP/6-31G(d,p) level was employed to calculate intramolecular hydrogen bond enthalpies (HIHB), O-H charge differences, O-H bond lengths and bond orders for various substituted catechols and their radicals generated after H-abstraction. It was found that although the charge difference between hydrogen-bonded H and O played a role in determining HIHB, HIHB was mainly governed by the hydrogen bond length. As the oxygen-centered radical has great tendency to form a chemical bond with the H atom, hydrogen bond lengths in catecholic radicals are systematically shorter than those in catechols. Hence, the HIHB for the former are higher than those for the latter. 展开更多
关键词 CATECHOL catecholic radical density functional theory intramolecular hydrogen bond.
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Intramolecular Charge Transfer Dual Fluorescence pH Sensing using p-Dibutylaminobenzoic Acid-β-cyclodextrin Inclusion Complex
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作者 Li Rong LIN Zhao LI +2 位作者 Wen Liang YANG Hong CHEN Yun Bao JIANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第5期495-498,共4页
The intramolecular charge transfer dual fluorescence of p-dibutylaminobenzoic acid-b-cyclodextrin inclusion complex showed a substantially higher sensitivity toward aqueous solution pH variation when compared with tha... The intramolecular charge transfer dual fluorescence of p-dibutylaminobenzoic acid-b-cyclodextrin inclusion complex showed a substantially higher sensitivity toward aqueous solution pH variation when compared with that of p-dibutylaminobenzoic acid alone, which established a new principle for direct CT fluorescence sensing in aqueous solution by using the CT fluorophore-cyclodextrin inclusion complex. 展开更多
关键词 pH sensing dual fluorescence intramolecular charge transfer cyclodextrin inclusion complex p-dibutylaminobenzoic acid.
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Direct Fluorescence Sensing of Metal Ions in Aqueous Solution Using Intramolecular Charge Transfer Emission from Aggregates of Pentaerythrityl Tetra(p-dimethylaminobenzoate)
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作者 ZhenChangWEN YunBaoJIANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第5期551-554,共4页
Pentaerythrityl tetra(p-dimethylaminobenzoate) (PTDMAB) was synthesized and shown to emit in water-rich aqueous dioxane solutions the intramolecular charge transfer fluorescence that was sensitive to the presence of m... Pentaerythrityl tetra(p-dimethylaminobenzoate) (PTDMAB) was synthesized and shown to emit in water-rich aqueous dioxane solutions the intramolecular charge transfer fluorescence that was sensitive to the presence of metal ions. 展开更多
关键词 intramolecular charge transfer aggregation fluorescence sensing pentaerythrityl tetra- (p-dimethylaminobenzoate) alkaline metal ions.
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