Quantitative effect of kerogen type on the hydrocarbon generation potential of Paleogene lacustrine source rocks,Liaohe Western Depression,China

Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.

Logging curves characteristics and response mechanisms of basaltic facies and sub-facies: A case study from eastern sag of Liaohe depression, Northeast China

Based on five types of conventional logging curves including GR,RLLD,CNL,DEN and AC,and 39 core samples from 30 representative boreholes,the logging characteristics and lithofacies and sub-facies of the basaltic rocks were studied.Three basaltic facies and four sub-facies are recognized from the well logs,includ-ing volcanic conduit facies(post intrusive sub-facies),explosive facies,and effusive lava flow facies(tabular flow,compound flow and hyaloclastite sub-facies).The post intrusive,tabular flow and compound flow sub-facies logging curves are mainly controlled by the distribution of vesiculate zones and vesiculate content,which are characterized by four curves with good correlation.Post intrusive sub-facies are characterized by high RLLD,high DEN,with a micro-dentate logging curve pattern,abrupt contact relationships at the top and base.Tabular flow sub-facies are characterized by high RLLD,high DEN,with a bell-shaped log curve pattern,abrupt contact at the base and gradational contact at the top.Compound flow sub-facies are characterized by medium-low RLLD,with a micro-dentate or finger-like logging curve pattern,abrupt contact at the base and gradational contact at the top.Explosive facies and hyaloclastite sub-facies logging curves are mainly controlled by the distribution of the size and sorting of rock particles,which can be recognized by four kinds of logging curves with poor cor-relation.Explosive facies are characterized by low RLLD,medium-low CNL and low DEN,with a micro-dentate logging curve pattern.Hyaloclastite sub-facies are characterized by low RLLD,high CNL,low DEN and high AC,with a micro-dentate logging curve pattern.The present research is beneficial for the prediction of basaltic reser-voirs not only in the Liaohe depression but also in the other volcanic-sedimentary basins.

Research on Drainage Network Extraction in Liaohe Basin Based on SRTM DEM and ASTER GDEM

In this study,SRTM DEM data and ASTER GDEM data were used as the basic topographic data,and Arc Hydro Tools was utilized for extension module so as to study on extracting digital drainage network of watershed based on surface runoff model,as well as to compare the two extracted results.The result showed that through the introduction of drainage density parameter to determine the river drainage area threshold,the both extracted drainages showed the goodness-of-fit with the factual drainage network on 1∶250 000 scale topographic map,and the extracted digital river could be used in practical operation of the risk assessment model of mountain torrents disaster in Liaohe basin.

Study of the water quality in Liaohe Park based on the model of GAM

This paper assesses the quality of Daliao river through Liaohe Park based on the model of GAM for water quality analysis and the monitoring data from 2006 to 2011.The results showed that the value of pH per year tended to the average; the DO in 2011 was much higher than that in other years, and the DO in 2006 .was lower than the standard value; the quality risk in six sections was still higher than the standard value in 2007, which was caused by the high concentrations of COD. However, the value of ammonia nitrogen changes was only 40% related to DO and COD.

High Yield Cultivation Techniques of Two Fine Walnut Varieties, Qingxiang and Liaohe 1

Since the introduction of Qingxiang and Liaohe 1 in 2012, both varieties have shown characteristics of beautiful nuts appearance, high quality and high yield of nuts, strong disease resistance after six years regional varieties. Comparison shows that Qingxiang has strong tree vigor, making it suitable for loose planting, needs pollination tree, bears food late and shows very stable yield performance, while Liaohe 1 has medium tree vigor, bears food early and shows stable yield performance. Based on years of regional planting tests, suggestions were proposed to the high yield cultivation techniques of walnut.

Development of Overpressure in the Tertiary Damintun Depression, Liaohe Basin, Northern China

The Damintun depression is one of the four depressions in the Liaohe basin in northern China, and is a rift basin developed in the Paleogene. This paper discusses in detail the characteristics of pressure and fluid potential of the Damintun depression based on a synthesis of the data from boreholes, well tests and seismic surveys. Data from sonic logs, well tests and seismic velocity measurements are used to study the pressure characteristics of the areas. From the sonic log data, shales can be characterized as normally pressured, slightly overpressured or highly overpressured; from the well test data, the pressure-depth gradient in oil-producing intervals implies hydrostatic pressure in general. Most seismic profiles in the Damintun depression are of sufficiently high quality for seismic velocities to be measured. The fluid pressures, excess pressures and pressure coefficients in 47 representative seismic profiles are predicted using formula calculation methods, and further transformed to fluid potenti

Research on Methods of Ecological Security Assessment of the Middle and Lower Reaches of Liaohe River Based on GIS

Ecological security assessment and early warning research possess the attributes of spatiality, non-linearity and randomicity, so we must process much spatial information. Spatial analysis and data management are the advantages of GIS, which can define distribution trend and spatial relations of environmental factors, and show ecological security pattern graphically. Spatial differences of ecological security assessment based on GIS are discussed in this paper, of which the middle and lower reaches of the Liaohe River is taken as a study case. First, to work out pressure-state-response (P-S-R) assessment indicators system, and investigate in person and gather information; second, to digitize the watershed; third, to quantize and calculate by the fuzzy method; last, to construct GIS grid database, and expound spatial differences of ecological security by GIS interpolation and assembly analysis.

Water Quality Evaluation in Tidal River Reaches of Liaohe River Estuary, China Using a Revised QUAL2K Model

Rivers in the Liaohe River Estuary area have been seriously polluted by discharges of wastewater containing petroleum pol- lutants and nutrients. In this paper, The Enhanced Stream Water Quality Model （QUAL2K） and its revised model as well as One-dimensional Tide Mean Model （1D model） were applied to predict and assess the water quality of the tidal fiver reach of the Liaohe River Estuary. Dissolved oxygen （DO）, biochemical oxygen demand （BODs）, ammonia nitrogen （NH3-N） and total phosphorus （TP） were chosen as water quality indices in the two model simulations. The modelled results show that the major reasons for degraded rivers remain petroleum and non-point source pollution. Tidal water also has a critical effect on the variation of water quality. The sensitivity analysis identifies that flow rate, point load and diffuse load are the most sensitive parameters for the four water quality indices in the revised QUAL2K simulation. Uncertainty analysis based on a Monte Carlo simulation gives the probability distribution of the four wa- ter quality indices at two locations （6.50 km and 44.84 km from the river mouth）. The statistical outcomes indicate that the observed data fall within the 90% confidence intervals at all sites measured, and show that the revised QUAL2K gives better results in simulating the water quality of a tidal fiver.

Distribution and treatment of harmful gas from heavy oil production in the Liaohe Oilfield, Northeast China

The distribution and treatment of harmful gas （H2S） in the Liaohe Oilfield, Northeast China, were investigated in this study. It was found that abundant toxic gas （H2S） is generated in thermal recovery of heavy oil. The H2S gas is mainly formed during thermochemical sulfate reduction （TSR） occurring in oil reservoirs or the thermal decomposition of sulfocompounds （TDS） in crude oil. H2S generation is controlled by thermal recovery time, temperature and the injected chemical compounds. The quantity of SO4^2- in the injected compounds is the most influencing factor for the rate of TSR reaction. Therefore, for prevention of H2S formation, periodic and effective monitoring should be undertaken and adequate H2S absorbent should also be provided during thermal recovery of heavy oil. The result suggests that great efforts should be made to reduce the SO4^2- source in heavy oil recovery, so as to restrain H2S generation in reservoirs. In situ burning or desulfurizer adsorption are suggested to reduce H2S levels. Prediction and prevention of H2S are important in heavy oil production. This will minimize environmental and human health risks, as well as equipment corrosion.

Effects of Vegetation Type on Surface Elevation Change in Liaohe River Delta Wetlands Facing Accelerated Sea Level Rise

Rising sea levels threaten the sustainability of coastal wetlands around the globe. The ability of coastal marshes to maintain their position in the intertidal zone depends on the accumulation of both organic and inorganic materials, and vegetation is important in these processes. To study the effects of vegetation type on surface elevation change, we measured surface accretion and elevation change from 2011 to 2016 using rod surface elevation table and feldspar marker horizon method （RSET-MH） in two Phragmites and two Suaeda marshes in the Liaohe River Delta. The Phragmites marshes exhibited higher rates of surface accretion and elevation change than the Suaeda marshes. The two Phragmites marsh sites had average surface elevation change rates at 8.78 mm/yr and 9.26 mm/yr and surface accretion rates at 17.56 mm/yr and 17.88 mm/yr, respectively. At the same time, the two Suaeda marsh sites had average surface elevation change rates at 5.77 mmJyr and 5.91 mm/yr and surface accretion rates at 13.42 mm/yr and 14.38 mm/yr, respectively. The elevation change rates in both the Phragmites marshes and the Suaeda marshes in the Liaohe River Delta could keep pace and even continue to gain elevation relative to averaged sea level rise in the Bohai Sea reported by the 2016 State Oceanic Administration, Peo- ple＇s Republic of China projection （2.4-5.5 mm/yr） in current situations. Our data suggest that vegetation is important in the accretionary processes and vegetation type could regulate the wetland surface elevation. However, the vulnerability of coastal wetlands in the Liaohe River Delta need further assessment considering the accelerated sea level rise, the high rate of subsidence, and the declining sediment delivery, especially for the Suaeda marshes.

Ecological water demand:the case of the slope systems in the East Liaohe River Basin

The ecological water demand (EWD) is the least water amount required to maintain the structure and the function of the special eco-system and the temporal scale of a study on the EWD must be a season's time. Based on GIS and RS with the source information of hydrological data of 46 hydrological gauges covering 52 years and the digital images of Landsat TM in 1986, 1996 and 2000, the landscape patterns, precipitation and runoff in the East Liaohe River Basin were analyzed. With the result of the above analysis, the spatial and temporal changes of the ecological water demand in the slope systems (EWDSS) of the East Liaohe River Basin (ELRB) were derived. Landscapes in the ELRB are dispersed and strongly disturbed by human actions. The hydrological regime in ELRB has distinct spatial variations. The average annual EWDSS in the ELRB is 504.72 mm (324.08-618.89 mm), and the average EWDSS in the growth season (from May to September) is 88.29% of the year's total EWDSS .The ultimate guaranteeing ratio of the EWDSS in ELRB is 90%. The scarce EWDSS area in the whole year and in the growth season are 60.47% and 74.01% of the entire basin respectively. The trend of scarce EWDSS area is most serious according to the quantity and area of scarce EWDSS regions.

Water quantity-quality combined evaluation method for rivers＇ water requirements of the instream environment in dualistic water cycle： A case study of Liaohe River Basin

In this article the meaning of the quantity and quality of environmental flows of river in dualistic water cycle is discussed, and compared with the meaning of unitary water cycle. Based on the analysis of the relationship between environmental flows of river requirements, the efficiency of water resource usage, the consumption coefficient, and the concentration of waste water elimination, the water quantity and water quality calculation method of the environmental flows of river requirements in dualistic water cycle is developed, and the criteria for environmental flows of river requirements are established, and therefore the water quantity-quality combined evaluation of natural river flows requirements are realized Taking the Liaohe River as a model, the environmental flows of river requirements for Xiliao River, Dongliao River, mainstream Liaohe River, Huntai River and northeast rivers along the coasts of the Yellow and Bohai seas in unitary water cycle are calculated, each taking up 39.3%, 63.0%, 43.9%, 43.3% and 43.5% of runoff respectively. Evaluated according to Tennant recommended flow, the results show that： except Xiliao River is ＂median＂, the rest are all upon ＂good＂, the Dongliao River is even ＂very good＂. The corresponding results in dualistic water cycle are that, the proportion of natural flows for each river is 57.5%, 74.1%, 60.8%, 60.3% and 60.4%; while the combined evaluation results show that： considering ＂quantity＂, except Xiliao River, the rest rivers can all achieve the ＂quantity＂ criteria of the en- vironmental flows of river requirements, but if considering the aspect of ＂quality＂, only Dongliao River can reach the ＂quality＂ standard. By water quantity-quality combined evaluation method, only Dongliao River can achieve the criteria. So the water quality is the main factor that determines whether the environmental flows can meet the river ecosystem demands.

An rescaled range analysis on the characteristics of coal seam development in the Eastern depression of the Liaohe Basin

The characteristics of coal seam development,and the prospects of a favorable coal-forming area,were evaluated for the Liaohe Basin located in China.The Number 3 and Number 9 coal seam thickness series from 60 nearly equally spaced bores in the Eastern depression of the Liaohe Basin were examined by a rescaled range analysis.The results indicate that the Hurst exponents of the Number 3 and Number 9 coal seam thickness series are 0.69 and 0.68,respectively.This suggests the presence of persistence.As the bore spacing increases the Hurst exponent of the Number 3 series gradually decreases（H changes from 0.69 to 0.52） and shifts from persistence to randomness.The Hurst exponent of the Number 9 thickness data gradually increases（H changes from 0.68 to 0.91） and always shows the characteristic of persistence.A combination of geological characteristics and the series data allow the conclusion that it is more suitable for the Number 9 coal seam to form in the Northeastern part of the Eastern depression than the Number 3 coal seam.

Spatial Distribution and Seasonal Variations of Heavy Metal Contamination in Surface Waters of Liaohe River, Northeast China

Heavy metal pollutants are a worldwide concern due to slow decomposition, biocondensation, and negative effects on human health. We investigated seasonal and spatial variations of the five heavy metals and evaluated their health risk in the Liaohe River, Northeast China. A total of 324 surface water samples collected from 2009 to 2010 were analyzed. Levels(high to low) of heavy metals in the Liaohe River were: zinc(Zn) > chromium(Cr) > copper(Cu) > cadmium(Cd) > mercury(Hg). Spatial and seasonal changes impacting concentrations of Cu and Zn were significant, but not significant for Cr, Cd and Hg. The highest concentrations of heavy metals were: Hg at Liuheqiao, Cu at Fudedian, Zn at Tongjiangkou, Cr at Mahushan, and Cd at Shenglitang. The highest concentrations of Hg and Cr were found in the wet period, Cu and Cd in the level period, and Zn in the dry period. The surface water of a tributary was an important accumulation site for heavy metals. Health risks from carcinogens and non-carcinogens increased from upstream to downstream in the mainstream of the Liaohe River. The total health risk for one person in the Liaohe River exceeded acceptable levels. The total health risk was the greatest during the wet period and least in the dry period. Among the five heavy metals in the Liaohe River, Cr posed the greatest single health risk.

The Impact of Irrigation on Bacterial Community Composition and Diversity in Liaohe Estuary Wetland

In this study, the sequencing of 16S ribosomal DNA was used to characterize the soil bacterial community composition and diversity in Liaohe estuarine wetland. Soil samples were taken from different locations in the wetland dominated by reed. Moreover, the soil quality parameters were evaluated(p H, moisture, organic matter, total nitrogen, available nitrogen, total phosphorus, available phosphorus). The results showed that the organic matter and nutrient contents were significantly higher in irrigated wetland than those in natural wetland. Major phylogenic groups of bacteria in soil samples including Proteobacteria, Acidobacteria, Gemmatimonadetes, Actinobacteria and Cyanobacteria were analyzed and we found that Proteobacteria was the most abundant in the community, and the phylum Acidobacteria was more abundant in irrigated wetland. Beta diversity analyses indicated that the soil bacterial community was mainly affected by sampling sites rather than seasons. In general, the bacterial community in natural wetland was not significantly different with that in artificial irrigated wetland. Artificial hydraulic engineering irrigated according to the water requirement rule of reed, increased the production of reeds, changed the way of wetland soil material input, but the diversity of bacterial community kept stable relatively.

SPATIAL PATTERN AND FUNCTION OF CORRIDORS IN WETLANDS OF LIAOHE DELTA

Corridors are special patches with narrow and long shape, and often have the functions as transportation,protection, resources and aesthetics. Corridors in the study area can be classilied into 8 types, with a total length of 5167. 2 km, and conidor density of 1. 25 km/km2. The conidore are mainly composed of irrigation and drainag canals,the total length of which is 2794 km,about 54. 1% of all the corridors. The conidors have segmented the landscape, and changed the original situation of the natural landscapes. The types of conidors are clooely related to the landscape types they are distributed in. Canals are maily distributed in the wetland landscapes, while roads are mainly in the built-up area. Dikes are always along rivers or coastlines. The conidors are most densely distributed wherever human activity occurs most bouendy, such as in the artifical wedlands of paddy fields.

Effects of Reclamation on Soil Carbon and Nitrogen in Coastal Wetlands of Liaohe River Delta,China

To evaluate the influence of wetland reclamation on vertical distribution of carbon and nitrogen in coastal wetland soils, we measured the soil organic carbon(SOC), soil total nitrogen(STN) and selected soil properties at five sampling plots(reed marsh, paddy field, corn field, forest land and oil-polluted wetland) in the Liaohe River estuary in September 2013. The results showed that reclamation significantly changed the contents of SOC and STN in the Liaohe River estuary(P < 0.001). The SOC concentrations were in the order: oil-polluted wetland > corn field > paddy field > forest land > reed marsh, with mean values of 52.17, 13.14, 11.46, 6.44 and 6.16 g/kg, respectively. STN followed a similar order as SOC, with mean values of 1351.14, 741.04, 632.32, 496.17 and 390.90 mg/kg, respectively. Interaction of reclamation types and soil depth had significant effects on SOC and STN, while soil depth had significant effects on SOC, but not on STN. The contents of SOC and STN were negatively correlated with pH and redox potential(Eh) in reed marsh and corn field, while the SOC and STN in paddy field had positive correlations with electrical conductivity(EC). Dissolved organic carbon(DOC), ammonium nitrogen(NH_4^+-N) and nitrate nitrogen(NO_3~–-N) were also significantly changed by human activities. NH_4^+-N and NO_3~–-N increased to different degrees, and forest land had the highest NO_3~–-N concentration and lowest DOC concentration, which could have been caused by differences in soil aeration and fertilization. Overall, the results indicate that reed harvest increased soil carbon and nitrogen release in the Liaohe River Estuary, while oil pollution significantly increased the SOC and STN; however, these cannot be used as indicators of soil fertility and quality because of the serious oil pollution.

Effect of maize sowing area changes on agricultural water consumption from 2000 to 2010 in the West Liaohe Plain, China

The West Liaohe Plain is located in the eastern Inner Mongolia, known as the golden maize belt in China, where maize acreage has continued to rise in recent years. Water is the main limiting factor for maize production in the region, therefore, this study calculated the effect of maize sowing area changes on agricultural water consumption in the West Liaohe Plain in 2000, 2005 and 2010, based on remote sensing and meteorological data. Maize remote sensing classification was con- structed based on moderate-resolution imaging spectroradiometer, normalized difference vegatation index （MODIS NDVI） data. Then the maize sown area and water requirement and irrigation water resources were investigated. Finally, the effect of the maize sowing area changes on agricultural water consumption in the West Liaohe Plain was systematically analyzed in 2000, 2005, and 2010. The results showed that maize sown areas rose from 2000 to 2010 and were concentrated in the center of the West Liaohe Plain. Average per unit maize water deficit amount also increased in an uneven distribution, increasing from the south, east and north to the center and west of the West Liaohe Plain. The per unit area maize water deficit increased from 2000 to 2010, and reached 266 mm in 2000, 272 mm in 2005 and 273 mm in 2010, respectively. and the study concluded that water deficit during the whole growth period of maize in the West Liaohe Plain was defined by a single peak curve. The maize water requirements increased with maize sowing area changes from 2000 to 2010, and the maize water requirements increased from 0.89 billion m3 in 2000 to 1.19 billion m3 in 2005, and 1.21 billion m3 in 2010.

First Discovery of Gold Ore Bodies in the Lieryu Formation of the Liaohe Group in the Liaodong Area, China

Objective Numerous large deposits magnesite, and talc are Liaodong area, within of lead-zinc, gold, boron, distributed throughout the different layers of the Paleoproterozoic Liaohe Group. The Liaohe Group comprises five formations as follows （from bottom to top）. The Langzishan Formation consists of volcaniclastic rocks containing copper, cobalt, and iron deposits. The Lieryu Formation is a set of volcanic sedimentary facies accompanied by small amounts of continental-margin mixed volcanic sedimentary rocks containing boron and magnetite deposits. The Gaojiayu Formation consists of carbonaceous clay-bearing carbonate rocks and contains the most important graphite deposit. The Dashiqao Formation consists of carbonate rocks containing lead-zinc and magnesite deposits. The Gaixian Formation comprises clastic and volcaniclastic rocks, and contains the most important gold deposit. Historically, gold prospecting has focused on the Gaixian Formation; however, gold ore bodies have been discovered during iron ore mining in the Lieryu Formation （Dayinggou area）, indicating possible existence of larger gold deposits in the area.

Evaluation on Current Situation of the Water Ecology of the Main Rivers and Lakes in the Liaohe River Basin

In this paper,15 rivers and 10 lake reservoirs in the Liaohe River basin were taken as research objects. Based on six indexes: satisfaction situation of ecological water demand,standard-reaching rate of water quality in water function area,eutrophication index of lakes and reservoirs,longitudinal connectivity of rivers,reserve rate of important wetlands and status of important aquatic habitat,water ecological conditions of main rivers and lakes in the basin were evaluated. The results showed that the rivers with better ecology were mainly distributed in east mountainous area of Liaoning,such as the upper reaches of the Hunhe River and the Taizi River;the problems of water pollution,ecological water shortage and habitat shrinkage were widespread in the Liaohe River basin,and the situation of water ecological security in the Liaohe River basin still faced great pressure.