The cooling gradient of Mg-3 Zn-1 Ca-0.5 Sr alloy in cast ingots under different cooling methods(air cooling,warm-water cooling and ice-water-mixture cooling) was examined and the effect of cooling rate on the structu...The cooling gradient of Mg-3 Zn-1 Ca-0.5 Sr alloy in cast ingots under different cooling methods(air cooling,warm-water cooling and ice-water-mixture cooling) was examined and the effect of cooling rate on the structure and corrosion properties was studied.The microstructure of the alloy was composed of α-Mg,Ca_(2) Mg_(6) Zn_(3) and Mg_(17)Sr_(2) phases.As the solidification cooling rate increased,the grain was refined,Zn and Sr were less segregated,the distributions of Zn and Sr were more uniform,and corrosion rate was found to first increase and then decrease;this contradicts the findings of recent research.With cooling rate increasing,the number of corroded microcouples comprising second phase and α-Mg increases.More α-Mg participates in corrosion,leading to a layered and deep corrosion pit and an increased corrosion rate.However,as the microstructure became sufficiently dense,the corroded structure protected the deep α-Mg from participating in corrosion,thus reducing the corrosion rate.展开更多
Degradable Mg-Zn-Ca alloys with Sr addition were prepared by vacuum melting and hot extrusion.Effect of Sr on microstructure,mechanical and corrosion properties of hot extruded Mg-2Zn-0.5Ca-xSr(x=0,0.5,1.0)alloys was ...Degradable Mg-Zn-Ca alloys with Sr addition were prepared by vacuum melting and hot extrusion.Effect of Sr on microstructure,mechanical and corrosion properties of hot extruded Mg-2Zn-0.5Ca-xSr(x=0,0.5,1.0)alloys was investigated.The results show that Sr addition into Mg-2Zn-0.5Ca alloys produced significant grain refinement in ingots and obvious texture weakening effects in extruded bars.The ultimate compressive strength increased as the Sr content increased,while the ultimate tensile strength increased firstly and then declined with the increasing of Sr content.Electrochemical tests indicated the corrosion current density of the surface parallel to extrusion direction(ED)was much lower than that of the surface perpendicular to ED.In-vitro immersion tests demonstrated the increase in the pH of solution and weight loss of Mg-2Zn-0.5Ca-0.5Sr alloy remain the lowest during immersion tests.The best comprehensive property was obtained in Mg-2Zn-0.5Ca-0.5Sr alloy,which has the largest strength and the best corrosion resistance.展开更多
目的通过电感耦合等离子体质谱(inductively coupled plasma mass spectrometry,ICP-MS)法建立加味左金丸中Cd、Pb、As、Hg、Co、V、Ni、Cu、Li、Sb、Ba、Mo、Sn、Cr、Na、Mg、Al、Ca、Ti、Mn、Fe、Zn、Ga、Se、Sr、Tl共计26种无机元素...目的通过电感耦合等离子体质谱(inductively coupled plasma mass spectrometry,ICP-MS)法建立加味左金丸中Cd、Pb、As、Hg、Co、V、Ni、Cu、Li、Sb、Ba、Mo、Sn、Cr、Na、Mg、Al、Ca、Ti、Mn、Fe、Zn、Ga、Se、Sr、Tl共计26种无机元素的测定方法。方法加味左金丸通过微波消解法处理后,根据相对分子质量的大小选择内标物,其中^(7)Li、^(23)Na、^(24)Mg、^(27)Al、^(40)Ca、^(48)Ti、^(51)V、^(52)Cr、^(55)Mn、^(56)Fe、^(58)Ni、^(59)Co、^(63)Cu、^(66)Zn、^(70)Ga、^(75)As、^(77)Se、^(86)Sr以^(72)Ge作为内标;^(95)Mo、^(114)Cd、^(118)Sn、^(121)Sb、^(137)Ba以^(115)In作为内标;^(202)Hg、^(205)Tl、^(208)Pb以^(209)Bi作为内标。对标准品溶液、空白溶液与供试品溶液进行分析,采用标准曲线法进行定量分析。通过ICP-MS法进行测定。结果26种无机元素线性的相关系数r≥0.9996,检出限为0.001~1.500μg/L,定量限为0.01~5.00μg/L,精密度与重复性试验的RSD均小于5%,平均回收率在82.64%~106.44%,RSD均小于5%。对3个厂家的12批样品进行了测定,26种元素的含量差异较大,其中Na、Mg、Ca、Fe 4种元素的含量比较高,均大于500μg/g,Cd、Pb、As、Hg、Co、Li、Sb、Mo、Sn、Cr、Se、Tl的含量比较低,均小于1μg/g。由结果可知,人体的常量元素,如Na、Mg、Ca的含量比较高,Cd、Pb、As、Hg等有害元素含量比较低。根据《中国药典》2020年版一部的要求,本品中Cd、Pb、As、Hg与Cu均符合规定。结论该方法快速、准确,可以用于加味左金丸中无机元素的测定。展开更多
基金Jiangsu Province Achievement Transformation Project(BA2017044)。
文摘The cooling gradient of Mg-3 Zn-1 Ca-0.5 Sr alloy in cast ingots under different cooling methods(air cooling,warm-water cooling and ice-water-mixture cooling) was examined and the effect of cooling rate on the structure and corrosion properties was studied.The microstructure of the alloy was composed of α-Mg,Ca_(2) Mg_(6) Zn_(3) and Mg_(17)Sr_(2) phases.As the solidification cooling rate increased,the grain was refined,Zn and Sr were less segregated,the distributions of Zn and Sr were more uniform,and corrosion rate was found to first increase and then decrease;this contradicts the findings of recent research.With cooling rate increasing,the number of corroded microcouples comprising second phase and α-Mg increases.More α-Mg participates in corrosion,leading to a layered and deep corrosion pit and an increased corrosion rate.However,as the microstructure became sufficiently dense,the corroded structure protected the deep α-Mg from participating in corrosion,thus reducing the corrosion rate.
基金supports from the key research and development program of Shandong Province(Grant No.2021ZLGX01).
文摘Degradable Mg-Zn-Ca alloys with Sr addition were prepared by vacuum melting and hot extrusion.Effect of Sr on microstructure,mechanical and corrosion properties of hot extruded Mg-2Zn-0.5Ca-xSr(x=0,0.5,1.0)alloys was investigated.The results show that Sr addition into Mg-2Zn-0.5Ca alloys produced significant grain refinement in ingots and obvious texture weakening effects in extruded bars.The ultimate compressive strength increased as the Sr content increased,while the ultimate tensile strength increased firstly and then declined with the increasing of Sr content.Electrochemical tests indicated the corrosion current density of the surface parallel to extrusion direction(ED)was much lower than that of the surface perpendicular to ED.In-vitro immersion tests demonstrated the increase in the pH of solution and weight loss of Mg-2Zn-0.5Ca-0.5Sr alloy remain the lowest during immersion tests.The best comprehensive property was obtained in Mg-2Zn-0.5Ca-0.5Sr alloy,which has the largest strength and the best corrosion resistance.
