Field lysimeter method was employed to investigate the downward movement and leaching of N applied to summer corn (Zea may L.) on dryland soil in Beiling. A N-fertilizer (120 kg N hm-2) and a control treatment were ar...Field lysimeter method was employed to investigate the downward movement and leaching of N applied to summer corn (Zea may L.) on dryland soil in Beiling. A N-fertilizer (120 kg N hm-2) and a control treatment were arranged for the study. Soil solution was collected at depths of 20, 40, 60, 120 and 170 cm,while leachate was collected at the bottom (200 cm) of the lysimeter. The results showed that the downward movement of NO3-N in soil profile was greatly affected by rainfall pattern. The peak of leached NO3-N from both treatments coincided with the peak of the rainfall. In addition, leached NO3-N from both treatments and rainfall were significantly correlated (P<0.05). The amount of leached NO3-N was not great in the N-fertilizer treatment. The results also suggested that N fertilization could cause NO3-N contamination of groundwater during the rainy season.展开更多
H3PO4 oxidation roasting followed by HCl acid leaching was proposed to remove magnesium and calcium from electric furnace titanium slag containing 3.12% MgO and 0.86% CaO. XRF, XRD and SEM techniques were used to char...H3PO4 oxidation roasting followed by HCl acid leaching was proposed to remove magnesium and calcium from electric furnace titanium slag containing 3.12% MgO and 0.86% CaO. XRF, XRD and SEM techniques were used to characterize the composition, mineral phase component and microstructure of the titanium slag. The H3PO4 oxidation thermodynamic, mineral phase transformation, microstructure, element distribution in titanium slag during H3PO4 oxidation process and leaching process were investigated. The thermodynamic analysis indicated that H3PO4 could promote the decomposition of MgTi2O5 and CaSiO3. The results indicated that H3PO4 could effectively promote the transformation of titanium-bearing mineral to rutile and enrich the impurities in MxTi（3-x）O5 into phosphate which could be removed by acid leaching process. Under the studied conditions, the leaching rates of magnesium and calcium reached 94.68% and 87.19%, respectively. The acid leached slag containing 0.19% MgO and 0.13% CaO（mass fraction） was obtained.展开更多
Gold bearing pyrite leaching was conducted in H2SO4-Fe2（SO4）3 system at different reaction temperatures,with different ferric ion concentrations,sulfuric acid concentrations and stirring speeds.The leaching kinetics...Gold bearing pyrite leaching was conducted in H2SO4-Fe2（SO4）3 system at different reaction temperatures,with different ferric ion concentrations,sulfuric acid concentrations and stirring speeds.The leaching kinetics and mechanism were studied.When the temperature ranged between 30-75 °C,the pyrite leaching was mainly controlled by chemical reaction with positive correlation to the ferric ion concentration.The activation energy obtained from Arrhenius empirical formula is 51.39 k J/mol.The EDS and XPS analyses suggest that the oxidation of sulfur within pyrite is through a series of intermediate stages,and eventually is oxidized to sulphate accompanied with the formation of element sulfur.This indicates a thiosulfate oxidation pathway of the gold bearing pyrite oxidation in H2SO4-Fe2（SO4）3 system.展开更多
文摘Field lysimeter method was employed to investigate the downward movement and leaching of N applied to summer corn (Zea may L.) on dryland soil in Beiling. A N-fertilizer (120 kg N hm-2) and a control treatment were arranged for the study. Soil solution was collected at depths of 20, 40, 60, 120 and 170 cm,while leachate was collected at the bottom (200 cm) of the lysimeter. The results showed that the downward movement of NO3-N in soil profile was greatly affected by rainfall pattern. The peak of leached NO3-N from both treatments coincided with the peak of the rainfall. In addition, leached NO3-N from both treatments and rainfall were significantly correlated (P<0.05). The amount of leached NO3-N was not great in the N-fertilizer treatment. The results also suggested that N fertilization could cause NO3-N contamination of groundwater during the rainy season.
文摘H3PO4 oxidation roasting followed by HCl acid leaching was proposed to remove magnesium and calcium from electric furnace titanium slag containing 3.12% MgO and 0.86% CaO. XRF, XRD and SEM techniques were used to characterize the composition, mineral phase component and microstructure of the titanium slag. The H3PO4 oxidation thermodynamic, mineral phase transformation, microstructure, element distribution in titanium slag during H3PO4 oxidation process and leaching process were investigated. The thermodynamic analysis indicated that H3PO4 could promote the decomposition of MgTi2O5 and CaSiO3. The results indicated that H3PO4 could effectively promote the transformation of titanium-bearing mineral to rutile and enrich the impurities in MxTi（3-x）O5 into phosphate which could be removed by acid leaching process. Under the studied conditions, the leaching rates of magnesium and calcium reached 94.68% and 87.19%, respectively. The acid leached slag containing 0.19% MgO and 0.13% CaO（mass fraction） was obtained.
基金Project(51474075)supported by the National Natural Science Foundation of China
文摘Gold bearing pyrite leaching was conducted in H2SO4-Fe2（SO4）3 system at different reaction temperatures,with different ferric ion concentrations,sulfuric acid concentrations and stirring speeds.The leaching kinetics and mechanism were studied.When the temperature ranged between 30-75 °C,the pyrite leaching was mainly controlled by chemical reaction with positive correlation to the ferric ion concentration.The activation energy obtained from Arrhenius empirical formula is 51.39 k J/mol.The EDS and XPS analyses suggest that the oxidation of sulfur within pyrite is through a series of intermediate stages,and eventually is oxidized to sulphate accompanied with the formation of element sulfur.This indicates a thiosulfate oxidation pathway of the gold bearing pyrite oxidation in H2SO4-Fe2（SO4）3 system.
