High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,...High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking.展开更多
The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO<sub>2</sub>, 10% CeO<sub>2</sub>/HZSM-5 and 20% CeO<sub>2</sub>/HZSM-5, wh...The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO<sub>2</sub>, 10% CeO<sub>2</sub>/HZSM-5 and 20% CeO<sub>2</sub>/HZSM-5, which were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and nitrogen adsorption at 77K. The catalytic tests were performed via thermogravimetric analysis (TG) at heating rates of 5, 10 and 20˚C min<sup>−1</sup> in a temperature range from 30˚C to 900˚C. For the tests, a ratio of 30% by mass of each catalytic material mixed with PS was used and the activation energy of the degradation process was determined by the Vyazovkin method. The obtained results showed that the addition of the catalyst to the PS in general reduced its degradation temperature. The 10% CeO<sub>2</sub>/HZSM-5 catalyst showed greater efficiency, as it resulted in lower activation energy for PS degradation. Thus, the combination of CeO<sub>2</sub> with HZSM-5 resulted in materials with potential for application in the catalytic degradation of polystyrene and the results indicate that the production of a composite material can be a good strategy to generate an increase in catalytic activity and a decrease in energy process activation.展开更多
以水热处理的纳米HZSM-5为载体,通过螯合剂乙二胺四乙酸(EDTA)改性制备了一种具有较高脱硫活性和稳定性的EDTA-NiMo/HZSM-5催化剂,并用XRD,ICP,FTIR,27Al MAS NMR,TG-DTA,Py-IR及NH3-TPD等手段对催化剂进行了表征.结果表明,EDTA与载体...以水热处理的纳米HZSM-5为载体,通过螯合剂乙二胺四乙酸(EDTA)改性制备了一种具有较高脱硫活性和稳定性的EDTA-NiMo/HZSM-5催化剂,并用XRD,ICP,FTIR,27Al MAS NMR,TG-DTA,Py-IR及NH3-TPD等手段对催化剂进行了表征.结果表明,EDTA与载体之间具有较强的相互作用,这种强相互作用减弱了金属活性组分与载体之间的作用力,抑制了非活性NiAl2O4和Al2(MoO4)3的形成,有利于活性组分在载体表面的分散,并且添加的螯合剂与金属组分镍可以形成稳定的螯合物,在硫化过程中能改变催化剂的硫化顺序,促使有效脱硫活性中心的形成,提高了催化剂的脱硫活性和稳定性.展开更多
基金the financial support from the National Natural Science Foundation of China(21908010)Jilin Provincial Department of Science and Technology(20220101089JC)the Education Department of Jilin Province(JJKH20220694KJ)。
文摘High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking.
文摘The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO<sub>2</sub>, 10% CeO<sub>2</sub>/HZSM-5 and 20% CeO<sub>2</sub>/HZSM-5, which were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and nitrogen adsorption at 77K. The catalytic tests were performed via thermogravimetric analysis (TG) at heating rates of 5, 10 and 20˚C min<sup>−1</sup> in a temperature range from 30˚C to 900˚C. For the tests, a ratio of 30% by mass of each catalytic material mixed with PS was used and the activation energy of the degradation process was determined by the Vyazovkin method. The obtained results showed that the addition of the catalyst to the PS in general reduced its degradation temperature. The 10% CeO<sub>2</sub>/HZSM-5 catalyst showed greater efficiency, as it resulted in lower activation energy for PS degradation. Thus, the combination of CeO<sub>2</sub> with HZSM-5 resulted in materials with potential for application in the catalytic degradation of polystyrene and the results indicate that the production of a composite material can be a good strategy to generate an increase in catalytic activity and a decrease in energy process activation.
文摘以水热处理的纳米HZSM-5为载体,通过螯合剂乙二胺四乙酸(EDTA)改性制备了一种具有较高脱硫活性和稳定性的EDTA-NiMo/HZSM-5催化剂,并用XRD,ICP,FTIR,27Al MAS NMR,TG-DTA,Py-IR及NH3-TPD等手段对催化剂进行了表征.结果表明,EDTA与载体之间具有较强的相互作用,这种强相互作用减弱了金属活性组分与载体之间的作用力,抑制了非活性NiAl2O4和Al2(MoO4)3的形成,有利于活性组分在载体表面的分散,并且添加的螯合剂与金属组分镍可以形成稳定的螯合物,在硫化过程中能改变催化剂的硫化顺序,促使有效脱硫活性中心的形成,提高了催化剂的脱硫活性和稳定性.
