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Effect of Arbuscular Mycorrhiza on the Content of Nitrogen and Nitrogenous Matter in Amur Corktree Seedlings 被引量:2
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作者 范继红 高琼 邹原东 《Agricultural Science & Technology》 CAS 2012年第8期1695-1698,共4页
[Objective] This study aimed to explore the effect of arbuscular mycorrhiza on the content of nitrogen and nitrogenous matter in amur corktree(Phellodendron amurense Rupr.)seedlings. [Method] The annual seedlings of... [Objective] This study aimed to explore the effect of arbuscular mycorrhiza on the content of nitrogen and nitrogenous matter in amur corktree(Phellodendron amurense Rupr.)seedlings. [Method] The annual seedlings of Phellodendron amurense Rupr. were inoculated with four arbuscular mycorrhiza fungi in a pot experiment to study the influences of arbuscular mycorrhiza on the content of nitrogen and nitrogenous matter in Phellodendron amurense Rupr. [Result] After inoculation with arbuscular mycorrhiza fungi, the Phellodendron amurense Rupr. seedlings developed arbuscular mycorrhiza, leading to an enhancement of photosynthetic capacity. The leaf nitrogen content of those inoculated with Glomus mosseae increased to 1.28- 1.60 times as compared with the control. The chlorophyll content and chlorophyll a/b ratio were also raised, with an increase over 25% of chlorophyll a content. In addition, IAA content in plants increased to 1.65-2.41 times; and nitrate reductase activity was also enhanced, as well as soluble protein content, 1.67-2.49 times as high as the control, which improved the nitrogen metabolic ability, and promoted the plant growth, as well as the secondary metabolic ability. [Conclusion] This study provides a theoretical basis for the application of arbuscular mycorrhiza on Phellodendron amurense Rupr. 展开更多
关键词 Arbuscular mycorrhiza Phellodendron amurense Rupr. NITROGEN nitrogenous matter CONTENT
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Yield and Quality of Forage Oat (<i>Avena sativa</i>L.) Cultivars as Affected by Seed Inoculation with Nitrogenous Strains 被引量:3
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作者 Muhammad Saleem M. Shahid Ibni Zamir +7 位作者 Ihtishamul Haq M. Zahid Irshad M. Kamran Khan M. Asim Qamaruz Zaman Ihtisham Ali Aman Khan Saeedur Rehman 《American Journal of Plant Sciences》 2015年第19期3251-3259,共9页
Nitrogen availability can be enhanced with the application of nitrogen fixing bacteria and it may be helpful in increasing forage yield and improving quality of oat. Therefore, a field trial to evaluate the effect of ... Nitrogen availability can be enhanced with the application of nitrogen fixing bacteria and it may be helpful in increasing forage yield and improving quality of oat. Therefore, a field trial to evaluate the effect of seed inoculation with nitrogen fixing bacteria on forage yield and quality of oat was carried out at Agronomic Research Area, University of Agriculture, Faisalabad during Rabi season 2013-14. The experiment was laid out in Randomized Complete Block Design (RCBD) with factorial arrangements using three replications. The experiment was comprised of two integrated approaches. The first approach was oat cultivars consisting of four treatments, V1 (AVON), V2 (S-2000), V3 (S-2011) and V4 (PD2LV65) and the second approach was seed inoculation consisting of three treatments, S0 (control), S1 (Azotobacter spp.), S2 (Azospirillum spp.). Fisher’s analysis of variance technique was used for statistically interpretation of data by using least significant difference (LSD) test at 5% level of probability. Nitrogen fixing bacteria significantly affect the germination count (m2), plant height (cm), number of tillers (m2), number of leaves per tiller, leaf area per tiller (cm2), green forage yield (t·ha-1) and dry matter yield (t ha-1). The maximum green forage yield (85.2 t·ha-1), dry matter yield (14.1 t ·ha-1) and crude protein (11.5%) were recorded where Azotobacter inoculation was applied. The interaction between cultivars and nitrogenous strains was significant for green forage yield (t·ha-1), dry matter yield (t·ha-1) and crude protein (%). Conclusion showed that cultivar Sargodha-2011 which was inoculated with Azotobacter spp. gave higher forage yield of good quality. 展开更多
关键词 Oat CULTIVARS nitrogenous STRAINS Quality and FORAGE Yield
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Effects of a Combined Application of Nitrogenous and Phosphorus Fertilizers on the Growth of Pinus radiata
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作者 Jianshe HE Qimei KANG +6 位作者 Hua YANG Xinwei ZHU Xiaoqiang TANG Ying KANG Junfang REN Yonghong TANG Qianli LIU 《Agricultural Biotechnology》 CAS 2019年第4期126-128,共3页
In the arid valley of the upper reaches of the Minjiang river,combined application tests of nitrogenous and phosphorus fertilizers were conducted to the 1-year-old seedlings of Pinus radiate to investigate the appropr... In the arid valley of the upper reaches of the Minjiang river,combined application tests of nitrogenous and phosphorus fertilizers were conducted to the 1-year-old seedlings of Pinus radiate to investigate the appropriate amount of fertilization,so as to provide bases of fertilization management of young P.radiate in the arid val-ley.Different combined application amounts of nitrogenous and phosphorus were studied based on the randomized blocks design.The results showed that in comparing 3 treatment groups with the control,the first and second treatments significantly increased the ground diameter and height of P.radiate,while the third treatment merely significantly increased the ground diameter.Under the conditions of this study,the recommended fertilization amount was 30 g of urea and 150 g of calcium superphosphate per plant for the one-year-old P.radiate. 展开更多
关键词 nitrogenous and PHOSPHORUS fertilizers COMBINED FERTILIZATION PINUS RADIATA GROWTH Influence
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Effects of typical nitrogenous compounds on trihalomethanes formation and chlorine demand during drinking water chlorination
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作者 陶辉 赵志伟 +4 位作者 陈卫 刘成 李星 王花平 李圭白 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2010年第3期303-307,共5页
Glycine(Gly),cysteine(Cys),aspartic acid(Asp),leucine(Leu),lysine(Lys),and methyl amine(MA) were chosen as typical nitrogenous compounds,and the effects of them on trihalomethanes (THMs) formation and chlorine demand ... Glycine(Gly),cysteine(Cys),aspartic acid(Asp),leucine(Leu),lysine(Lys),and methyl amine(MA) were chosen as typical nitrogenous compounds,and the effects of them on trihalomethanes (THMs) formation and chlorine demand were performed on filtrated water. Results show that the nitrogenous compounds enhance THMs formation,and the increased levels are controlled by characteristics and the concentration of nitrogenous compounds. The increase in THMs formation follows the order of Asp(126 μg/L)>Cys(119 μg/L)>MA(106 μg/L)>Lys(97 μg/L)≈Gly(96 μg/L)>Leu(80 μg/L)(while nitrogenous compounds=1.0 mg/L,and background THMs=60 μg/L). The increase in chlorine demand is approximately proportionate to the content of nitrogenous compounds,which illustrates that the increase is mainly caused by the reaction of nitrogenous compounds with chlorine. And the increase in chlorine demand follows the order of Cys(27.8 mg/L)>Asp(22.6 mg/L)=Gly(22.6 mg/L)>Lys(21.6 mg/L)>MA(14.1 mg/L)>Leu(11.8 mg/L) (while nitrogenous compounds=1.0 mg/L,and background chorine demand=1.8 mg/L). The mechanisms of nitrogenous compounds enhancing THMs formation are summ the increase of chlorine demand raising THMs formation in reaction of NOM with chlorine,and the THMs formation in chlorination of nitrogenous compounds themselves. 展开更多
关键词 nitrogenous compounds TRIHALOMETHANE chlorine demand
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Effects of Nitrogenous Fertilizer on Pungency of Hot Pepper (Capsicum annuum L.) Fruits
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作者 WANG Jin-ling LV Chang-shan YU Guang-jian 《Journal of Northeast Agricultural University(English Edition)》 CAS 2005年第2期102-104,共3页
The response of pungency of hot pepper fruits nitrogenous fertilizer on was invesigated. The results indicated that nitrogenous fertilizer had a significant effect on the capsaicin content of hot pepper fruits at 35 a... The response of pungency of hot pepper fruits nitrogenous fertilizer on was invesigated. The results indicated that nitrogenous fertilizer had a significant effect on the capsaicin content of hot pepper fruits at 35 and 42 days after flowering;, capsaicin content gradually decreased, while peroxidase activity increased with nitrogenous fertilizer increasing. 展开更多
关键词 capsaicin hot pepper nitrogenous fertilizer peroxidase activity
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Effect of Nitrogenous Fertilizer Treatment on Mineral Metabolism in Grazing Yaks 被引量:3
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作者 SHEN Xiao-yun 《Agricultural Sciences in China》 CAS CSCD 2009年第3期361-368,共8页
To assess the impact of N fertilization on contents of mineral elements in herbage and the effect of increased forage S on the copper metabolism of grazing yaks, study was conducted during the summer grazing season (... To assess the impact of N fertilization on contents of mineral elements in herbage and the effect of increased forage S on the copper metabolism of grazing yaks, study was conducted during the summer grazing season (2005, 2006, and 2007). Pasture replicates (20 ha; n=3 per treatment) received the same fertilizer treatment in each growing season, consisting of i) 90 kg N ha^-1 from quickly available nitrogen, ii) 90 kg N ha^-1 from ammonium nitrate, iii) 90 kg N ha^-1 from ammonium sulfate, and iv) control (no fertilizer). Forage sampling was collected at 60 days intervals following fertilization (10 samples per pasture) for Cu, Mo, Mn, Se, Fe, Zn, Ca, and P. To determine the effect of fertilizer treatment on mineral metabolism in grazing yaks, liver and blood samples were collected at the start and end of the study period in 2005, 2006, and 2007. Ammonium sulfate fertilization increased (P 〈 0.01) forage S concentration. Plant tissue N concentrations were increased by N fertilization, regardless of source in 2005, 2006, and 2007. Yaks grazing S fertilization pastures had lower (P〈0.05) liver and blood Cu concentrations at the end of the study period in 2005, 2006, and 2007, compared with urea, ammonium nitrate, and control. Nominal increases in forage in vitro organic matter digestibility were realized by fertilization, regardless of N source in each year. 展开更多
关键词 yaks nitrogen fertilizer treatment alpine meadow FORAGE mineral element metabolism
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Electrocatalytic synthesis of C-N coupling compounds from CO_(2) and nitrogenous species 被引量:1
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作者 Zheng Zhang Danyang Li +12 位作者 Yunchuan Tu Jiao Deng Huiting Bi Yongchao Yao Yan Wang Tingshuai Li Yongsong Luo Shengjun Sun Dongdong Zheng Sónia A.C.Carabineiro Zhou Chen Junjiang Zhu Xuping Sun 《SusMat》 SCIE EI 2024年第2期51-74,共24页
The electrocatalytic synthesis of C-N coupling compounds from CO_(2) and nitrogenous species not only offers an effective avenue to achieve carbon neutral-ity and reduce environmental pollution,but also establishes a ... The electrocatalytic synthesis of C-N coupling compounds from CO_(2) and nitrogenous species not only offers an effective avenue to achieve carbon neutral-ity and reduce environmental pollution,but also establishes a route to synthesize valuable chemicals,such as urea,amide,and amine.This innovative approach expands the application range and product categories beyond simple carbona-ceous species in electrocatalytic CO_(2) reduction,which is becoming a rapidly advancing field.This review summarizes the research progress in electrocatalytic urea synthesis,using N_(2),NO_(2)^(-),and NO_(3)^(-)as nitrogenous species,and explores emerging trends in the electrosynthesis of amide and amine from CO_(2) and nitro-gen species.Additionally,the future opportunities in this field are highlighted,including electrosynthesis of amino acids and other compounds containing C-N bonds,anodic C-N coupling reactions beyond water oxidation,and the catalytic mechanism of corresponding reactions.This critical review also captures the insights aimed at accelerating the development of electrochemical C-N coupling reactions,confirming the superiority of this electrochemical method over the traditional techniques. 展开更多
关键词 C-N coupling CO_(2) reduction ELECTROCATALYSIS nitrogenous species reaction mechanism
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Preparation of a novel lactose-lignin hydrogel catalyst with self-reduction capacity for nitrogenous wastewater treatment
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作者 Fan Zhang Yanzhu Guo +4 位作者 Xianhong Wu Ce Gao Qingda An Zhongjian Tian Runcang Sun 《Frontiers of Chemical Science and Engineering》 SCIE EI CSCD 2024年第9期25-36,共12页
A novel carboxylated lactose/sodium lignosulfonate/polyacrylic acid hydrogel composites with self-reduction capacity was successfully synthesized by self-assembly method.The hydrogel with well-developed porous structu... A novel carboxylated lactose/sodium lignosulfonate/polyacrylic acid hydrogel composites with self-reduction capacity was successfully synthesized by self-assembly method.The hydrogel with well-developed porous structure provided abundant anchoring points and reduction capacity for transforming Ag^(+)into silver nanoparticles.Silver nanoparticles dispersed among the network of hydrogel and the composites exhibited catalytic capacity.The catalytic performance was evaluated via degradation of p-nitrophenol,rhodamine B,methyl orange and methylene blue,which were catalyzed with corresponding reaction rate constants of 0.04338,0.07499,0.04891,and 0.00628 s^(–1),respectively.In addition,the catalyst exhibited stable performance under fixed-bed condition and the corresponding conversion rate still maintained more than 80%after 540 min.Moreover,the catalytic performance still maintained effective in tap water and simulated seawater.The catalytic efficiency still remained 99.7%with no significant decrease after 8 cycles. 展开更多
关键词 carboxylated lactose Ag NPs self-reduction nitrogenous wastewater
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Increased dependence on nitrogen-fixation of a native legume in competition with an invasive plant 被引量:1
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作者 Meixu Han Haiyang Zhang +12 位作者 Mingchao Liu Jinqi Tang Xiaocheng Guo Weizheng Ren Yong Zhao Qingpei Yang Binglin Guo Qinwen Han Yulong Feng Zhipei Feng Honghui Wu Xitian Yang Deliang Kong 《Plant Diversity》 SCIE CAS CSCD 2024年第4期510-518,共9页
Suppression of roots and/or their symbiotic microorganisms,such as mycorrhizal fungi and rhizobia,is an effective way for alien plants to outcompete native plants.However,little is known about how invasive and native ... Suppression of roots and/or their symbiotic microorganisms,such as mycorrhizal fungi and rhizobia,is an effective way for alien plants to outcompete native plants.However,little is known about how invasive and native plants interact with the quantity and activity of nutrient-acquisition agents.Here a pot experiment was conducted with monoculture and mixed plantings of an invasive plant,Xanthium strumarium,and a common native legume,Glycine max.We measured traits related to root and nodule quantity and activity and mycorrhizal colonization.Compared to the monoculture,fine root quantity(biomass,surface area)and activity(root nitrogen(N)concentration,acid phosphatase activity)of G.max decreased in mixed plantings;nodule quantity(biomass)decreased by 45%,while nodule activity in Nfixing via rhizobium increased by 106%;mycorrhizal colonization was unaffected.Contribution of N fixation to leaf N content in G.max increased in the mixed plantings,and this increase was attributed to a decrease in the rhizosphere soil N of G.max in the mixed plantings.Increased root quantity and activity,along with a higher mycorrhizal association was observed in X.strumarium in the mixed compared to monoculture.Together,the invasive plant did not directly scavenge N from nodule-fixed N,but rather depleted the rhizosphere soil N of the legume,thereby stimulating the activity of N-fixation and increasing the dependence of the native legume on this N source.The quantity-activity framework holds promise for future studies on how native legumes respond to alien plant invasions. 展开更多
关键词 Mycorrhizal strategy Nitrogen depletion Plant invasion Root nutrient acquisition strategy Symbiotic nitrogen fixation
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Regulation of 2-acetyl-1-pyrroline and grain quality in early-season indica fragrant rice by nitrogen and silicon fertilization under different plantation methods 被引量:1
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作者 Yongjian Chen Lan Dai +7 位作者 Siren Cheng Yong Ren Huizi Deng Xinyi Wang Yuzhan Li Xiangru Tang Zaiman Wang Zhaowen Mo 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第2期511-535,共25页
Fragrant rice has a high market value,and it is a popular rice type among consumers owing to its pleasant flavor.Plantation methods,nitrogen(N)fertilizers,and silicon(Si)fertilizers can affect the grain yield and frag... Fragrant rice has a high market value,and it is a popular rice type among consumers owing to its pleasant flavor.Plantation methods,nitrogen(N)fertilizers,and silicon(Si)fertilizers can affect the grain yield and fragrance of fragrant rice.However,the core commercial rice production attributes,namely the head rice yield(HRY)and 2-acetyl-1-pyrroline(2-AP)content of fragrant rice,under various nitrogen and silicon(N-Si)fertilization levels and different plantation methods remain unknown.The field experiment in this study was performed in the early seasons of 2018 and 2019 with two popular indica fragrant rice cultivars(Yuxiangyouzhan and Xiangyaxiangzhan).They were grown under six N-Si fertilization treatments(combinations of two levels of Si fertilizer,0 kg Si ha^(−1)(Si0)and 150 kg Si ha^(−1)(Si1),and three levels of N fertilizer,0 kg N ha^(−1)(N0),150 kg N ha^(−1)(N1),and 220 kg N ha^(−1)(N2))and three plantation methods(artificial transplanting(AT),mechanical transplanting(MT),and mechanical direct-seeding(MD)).The results showed that the N-Si fertilization treatments and all the plantation methods significantly affected the HRY and 2-AP content and related parameters of the two different fragrant rice cultivars.Compared with the Si0N0 treatment,the N-Si fertilization treatments resulted in higher HRY and 2-AP contents.The rates of brown rice,milled rice,head rice,and chalky rice of the fragrant rice also improved with the N-Si fertilization treatments.The N-Si fertilization treatments increased the activities of N metabolism enzymes and the accumulation of N and Si in various parts of the fragrant rice,and affected their antioxidant response parameters.The key parameters for the HRY and 2-AP content were assessed by redundancy analysis.Furthermore,the structural equation model revealed that the Si and N accumulation levels indirectly affected the HRY by affecting the N metabolism enzyme activity,N use efficiency,and grain quality of fragrant rice.Moreover,high N and Si accumulation directly promoted the 2-AP content or affected the antioxidant response parameters and indirectly regulated 2-AP synthesis.The interactions of the MT method with the N-Si fertilization treatments varied in the fragrant rice cultivars in terms of the HRY and 2-AP content,whereas the MD method was beneficial to the 2-AP content in both fragrant rice cultivars under the N-Si fertilization treatments. 展开更多
关键词 fragrant rice 2-AP content head rice yield mechanical planting NITROGEN silicon
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Active MoS_(2)-based electrode for green ammonia synthesis 被引量:1
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作者 Xin Liu Lei Yang +2 位作者 Tao Wei Shanping Liu Beibei Xiao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期268-275,共8页
Nitrogen electro-reduction under mild conditions is one promising alternative approach of the energyconsuming Haber-Bosch process for the artificial ammonia synthesis.One critical aspect to unlocking this technology i... Nitrogen electro-reduction under mild conditions is one promising alternative approach of the energyconsuming Haber-Bosch process for the artificial ammonia synthesis.One critical aspect to unlocking this technology is to discover the catalysts with high selectivity and efficiency.In this work,the N_(2)-to-NH_(3)conversion on the functional MoS_(2)is fully investigated by density functional theory calculations since the layered MoS_(2)provides the ideal platform for the elaborating copies of the nitrogenase found in nature,wherein the functionalization is achieved via basal-adsorption,basal-substitution or edge-substitution of transition metal elements.Our results reveal that the edge-functionalization is a feasible strategy for the activity promotion;however,the basal-adsorption and basal-substitution separately suffer from the electrochemical instability and the NRR inefficiency.Specifically,MoS_(2)functionalized via edge W-substitution exhibits an exceptional activity.The energetically favored reaction pathway is through the distal pathway and a limiting potential is less than 0.20 V.Overall,this work escalates the rational design of the high-effective catalysts for nitrogen fixation and provides the explanation why the predicated catalyst have a good performance,paving the guidance for the experiments. 展开更多
关键词 Nitrogen reduction reaction Density functional theory calculations Molybdenum disulfide ELECTROCHEMISTRY CATALYST THERMODYNAMICS
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Microfluidic-oriented synthesis of enriched iridium nanodots/carbon architecture for robust electrocatalytic nitrogen fixation 被引量:1
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作者 Hengyuan Liu Xingjiang Wu +2 位作者 Yuhao Geng Xin Li Jianhong Xu 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第3期544-555,共12页
Electrocatalytic nitrogen reduction reaction(NRR)is considered as a promising candidate to achieve ammonia synthesis because of clean electric energy,moderate reaction condition,safe operating process and harmless by-... Electrocatalytic nitrogen reduction reaction(NRR)is considered as a promising candidate to achieve ammonia synthesis because of clean electric energy,moderate reaction condition,safe operating process and harmless by-products.However,the chemical inertness of nitrogen and poor activated capacity on catalyst surface usually produce low ammonia yield and faradic efficiency.Herein,the microfluidic technology is proposed to efficiently fabricate enriched iridium nanodots/carbon architecture.Owing to in-situ co-precipitation reaction and microfluidic manipulation,the iridium nanodots/carbon nanomaterials possess small average size,uniform dispersion,high conductivity and abundant active sites,producing good proton activation and rapid electrons transmission and moderate adsorption/desorption capacity.As a result,the as-prepared iridium nanodots/carbon nanomaterials realize large ammonia yield of 28.73 μg h^(-1) cm^(-2) and faradic efficiency of 9.14%in KOH solution.Moreover,the high ammonia yield of 11.21 μg h^(-1) cm^(-2) and faradic efficiency of 24.30%are also achieved in H_(2)SO_(4) solution.The microfluidic method provides a reference for large-scale fabrication of nano-sized catalyst materials,which may accelerate the progress of electrocatalytic NRR in industrialization field. 展开更多
关键词 Iridium nanodots CARBON Microfluidic technology Efficient synthesis Electrocatalytic nitrogen fixation
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Optimizing the Bacillus thuringiensis(Bt)protein concentration in cotton:Coordinated application of exogenous amino acids and EDTA to reduce spatiotemporal variability in boll and leaf toxins 被引量:1
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作者 Zhenyu Liu Shu Dong +8 位作者 Yuting Liu Hanjia Li Fuqin Zhou Junfeng Ding Zixu Zhao Yinglong Chen Xiang Zhang Yuan Chen Dehua Chen 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第10期3419-3436,共18页
During the boll formation stage,cotton bolls exhibit the lowest expression of Bacillus thuringiensis(Bt)insecticidal proteins.Resistance to insects varies notably among different organs,which poses challenges for cont... During the boll formation stage,cotton bolls exhibit the lowest expression of Bacillus thuringiensis(Bt)insecticidal proteins.Resistance to insects varies notably among different organs,which poses challenges for controlling cotton bollworms.Consequently,an experimental strategy was designed in the 2020-2021 cotton growing season to coordinate the enhancement of protein synthesis and the attenuation of degradation.Two Bt cultivars of Gossypium hirsutum,namely the hybrid Sikang 3 and the conventional Sikang 1,were used as test materials.Three treatments were applied at the peak flowering period:CK(the control),T1(amino acids),and T2(amino acids and EDTA).The results show that,in comparison to the CK group,the Bt protein contents were significantly increased in both cotton bolls and their subtending leaves under the T1 and T2 treatments.The maximum levels of increase observed were 67.5%in cotton bolls and 21.7%in leaves.Moreover,the disparity in Bt protein content between cotton bolls and their subtending leaves notably decreased by 31.2%.Correlation analysis suggested that the primary physiological mechanisms for augmenting Bt protein content involve increased protein synthesis and reduced protein catabolism,which are independent of Bt gene expression levels.Stepwise regression and path analysis revealed that elevating the soluble protein content and transaminase activity,while reducing the catabolic enzyme activities,are instrumental in enhancing the Bt protein content.Consequently,the coordinated application of amino acids and EDTA emerges as a strategy that can improve the overall resistance of Bt cotton and mitigate the spatiotemporal variations in Bt toxin concentrations in both cotton bolls and leaves. 展开更多
关键词 Gossypium hirsutum Bt cotton insecticidal protein bolls and their subtending leaves nitrogen metabolism
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p-d Orbital Hybridization Engineered Single-Atom Catalyst for Electrocatalytic Ammonia Synthesis 被引量:1
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作者 Jingkun Yu Xue Yong Siyu Lu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期119-125,共7页
The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is challenging.Two-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising SACs.Up to now,... The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is challenging.Two-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising SACs.Up to now,the roles of individual metals,coordination atoms,and their synergy effect on the electroanalytic performance remain unclear.Therefore,in this work,a series of 2DMOFs with different metals and coordinating atoms are systematically investigated as electrocatalysts for ammonia synthesis using density functional theory calculations.For a specific metal,a proper metal-intermediate atoms p-d orbital hybridization interaction strength is found to be a key indicator for their NRR catalytic activities.The hybridization interaction strength can be quantitatively described with the p-/d-band center energy difference(Δd-p),which is found to be a sufficient descriptor for both the p-d hybridization strength and the NRR performance.The maximum free energy change(ΔG_(max))andΔd-p have a volcanic relationship with OsC_(4)(Se)_(4)located at the apex of the volcanic curve,showing the best NRR performance.The asymmetrical coordination environment could regulate the band structure subtly in terms of band overlap and positions.This work may shed new light on the application of orbital engineering in electrocatalytic NRR activity and especially promotes the rational design for SACs. 展开更多
关键词 first-principle calculations Nitrogen reduction p-d orbital hybridization single-atom catalysts
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Subsoil tillage enhances wheat productivity,soil organic carbon and available nutrient status in dryland fields 被引量:1
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作者 Qiuyan Yan Linjia Wu +6 位作者 Fei Dong Shuangdui Yan Feng Li Yaqin Jia Jiancheng Zhang Ruifu Zhang Xiao Huang 《Journal of Integrative Agriculture》 SCIE CSCD 2024年第1期251-266,共16页
Tillage practices during the fallow period benefit water storage and yield in dryland wheat crops.However,there is currently no clarity on the responses of soil organic carbon(SOC),total nitrogen(TN),and available nut... Tillage practices during the fallow period benefit water storage and yield in dryland wheat crops.However,there is currently no clarity on the responses of soil organic carbon(SOC),total nitrogen(TN),and available nutrients to tillage practices within the growing season.This study evaluated the effects of three tillage practices(NT,no tillage;SS,subsoil tillage;DT,deep tillage)over five years on soil physicochemical properties.Soil samples at harvest stage from the fifth year were analyzed to determine the soil aggregate and aggregate-associated C and N fractions.The results indicated that SS and DT improved grain yield,straw biomass and straw carbon return of wheat compared with NT.In contrast to DT and NT,SS favored SOC and TN concentrations and stocks by increasing the soil organic carbon sequestration rate(SOCSR)and soil nitrogen sequestration rate(TNSR)in the 0-40 cm layer.Higher SOC levels under SS and NT were associated with greater aggregate-associated C fractions,while TN was positively associated with soluble organic nitrogen(SON).Compared with DT,the NT and SS treatments improved soil available nutrients in the 0-20 cm layer.These findings suggest that SS is an excellent practice for increasing soil carbon,nitrogen and nutrient availability in dryland wheat fields in North China. 展开更多
关键词 TILLAGE dryland wheat fields soil aggregate size soil nutrients soil carbon and nitrogen fractions
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Composition Engineering Opens an Avenue Toward Efficient and Sustainable Nitrogen Fixation 被引量:1
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作者 Xiaolin Wang Liming Yang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第1期313-325,共13页
In this work,we open an avenue toward rational design of potential efficient catalysts for sustainable ammonia synthesis through composition engineering strategy by exploiting the synergistic effects among the active ... In this work,we open an avenue toward rational design of potential efficient catalysts for sustainable ammonia synthesis through composition engineering strategy by exploiting the synergistic effects among the active sites as exemplified by diatomic metals anchored graphdiyne via the combination of hierarchical high-throughput screening,first-principles calculations,and molecular dynamics simulations.Totally 43 highly efficient catalysts feature ultralow onset potentials(|U_(onset)|≤0.40 V)with Rh-Hf and Rh-Ta showing negligible onset potentials of 0 and-0.04 V,respectively.Extremely high catalytic activities of Rh-Hf and Rh-Ta can be ascribed to the synergistic effects.When forming heteronuclears,the combinations of relatively weak(such as Rh)and relatively strong(such as Hf or Ta)components usually lead to the optimal strengths of adsorption Gibbs free energies of reaction intermediates.The origin can be ascribed to the mediate d-band centers of Rh-Hf and Rh-Ta,which lead to the optimal adsorption strengths of intermediates,thereby bringing the high catalytic activities.Our work provides a new and general strategy toward the architecture of highly efficient catalysts not only for electrocatalytic nitrogen reduction reaction(eNRR)but also for other important reactions.We expect that our work will boost both experimental and theoretical efforts in this direction. 展开更多
关键词 composition engineering strategy diatomic catalysts electrocatalytic nitrogen reduction reaction first-principles calculations graphdiyne hierarchical high-throughput screening synergistic effects
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Identification of the lysine and histidine transporter family in Camellia sinensis and the characterizations in nitrogen utilization 被引量:1
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作者 Wei Huang Danni Ma +9 位作者 Fawad Zaman Xulei Hao Li Xia E Zhang Pu Wang Mingle Wang Fei Guo Yu Wang Dejiang Ni Hua Zhao 《Horticultural Plant Journal》 SCIE CAS CSCD 2024年第1期273-287,共15页
In plants,the lysine and histidine transporter(LHT)family represent a class of proteins that mediate the uptake,translocation,and utilization of amino acids.The tea plant(Camellia sinensis)is a perennial evergreen wit... In plants,the lysine and histidine transporter(LHT)family represent a class of proteins that mediate the uptake,translocation,and utilization of amino acids.The tea plant(Camellia sinensis)is a perennial evergreen with a relatively high level of amino acids.However,systematic identification and molecular characterization of the LHT gene family has rarely been reported in tea plants.In this study,22 CsLHTs were identified from the‘Shuchazao’genome and classified into two groups.The modeled three-dimensional structure and the conserved domains presented a high similarity among the LHTs proteins.Moreover,it was predicted that a few genes were conserved through the analysis of the physiochemical characters,structures and cis-elements in promoters.The expression patterns in tea plants revealed that CsLHT7 was mainly expressed in the roots,and CsLHT4 and CsLHT11 exhibited relatively high expression in both the roots and leaves.Moreover,the expression of all three genes could be induced by organic nitrogen.Additionally,heterogeneous expression of CsLHT4,CsLHT7 and CsLHT11 in Arabidopsis thaliana decreased the aerial parts biomass compared with that in WT plants while significantly increased the rosette biomass only for CsLHT11transgenic plants versus WT plants.Overall,our results provide fundamental information about CsLHTs and potential genes in N utilization for further analysis in tea plants. 展开更多
关键词 Camellia sinensis Nitrogen Lysine and histidine transporter(LHT)family
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Carbonaceous and nitrogenous disinfection by-product formation in the surface and ground water treatment plants using Yellow River as water source 被引量:7
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作者 Yukun Hou Wenhai Chu Meng Ma 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2012年第7期1204-1209,共6页
This work investigated the formation of carbonaceous and nitrogenous disinfection by-products (C-DBPs, N-DBPs) upon chlorination of water samples collected from a surface water and a ground water treatment plant (S... This work investigated the formation of carbonaceous and nitrogenous disinfection by-products (C-DBPs, N-DBPs) upon chlorination of water samples collected from a surface water and a ground water treatment plant (SWTP and GWTP) where the conventional treatment processes, i.e., coagulation, sedimentation, and filtration were employed. Twenty DBPs, including four trihalomethanes, nine haloacetic acids, seven N-DBPs (dichloroacetamide, trichloroacetamide, dichloroacetonitrile, trichloroacetonitrile, bromochloroace- tonitrile, dibromoacetonitrile and trichloronitromethane), and eight volatile chlorinated compounds (dichloromethane (DCM), 1,2-dichloroethane, tetrachloroethylene, chlorobenzene, 1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,2,3-trichlorobenzene and 1,2,4- trichlorobenzene) were detected in the two WTPs. The concentrations of these contaminants were all below their corresponding maximum contamination levels (MCLs) regulated by the Standards for Drinking Water Quality of China (GB5749-2006) except for DCM (17.1 ~tg/L detected vs. 20 μg/L MCL). The SWTP had much higher concentrations of DBPs detected in the treated water as well as the DBP formation potentials tested in the filtered water than the GWTP, probably because more precursors (e.g., dissolved organic carbon, dissolved organic nitrogen) were present in the water source of the SWTE 展开更多
关键词 carbonaceous disinfection by-products nitrogenous disinfection by-products formation potential free chlorine watertreatment plant
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Co/CoO heterojunction rich in oxygen vacancies introduced by O_(2) plasma embedded in mesoporous walls of carbon nanoboxes covered with carbon nanotubes for rechargeable zinc-air battery 被引量:1
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作者 Leijun Ye Weiheng Chen +1 位作者 Zhong-Jie Jiang Zhongqing Jiang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第7期14-25,共12页
Herein,Co/CoO heterojunction nanoparticles(NPs)rich in oxygen vacancies embedded in mesoporous walls of nitrogen-doped hollow carbon nanoboxes coupled with nitrogen-doped carbon nanotubes(P-Co/CoOV@NHCNB@NCNT)are well... Herein,Co/CoO heterojunction nanoparticles(NPs)rich in oxygen vacancies embedded in mesoporous walls of nitrogen-doped hollow carbon nanoboxes coupled with nitrogen-doped carbon nanotubes(P-Co/CoOV@NHCNB@NCNT)are well designed through zeolite-imidazole framework(ZIF-67)carbonization,chemical vapor deposition,and O_(2) plasma treatment.As a result,the threedimensional NHCNBs coupled with NCNTs and unique heterojunction with rich oxygen vacancies reduce the charge transport resistance and accelerate the catalytic reaction rate of the P-Co/CoOV@NHCNB@NCNT,and they display exceedingly good electrocatalytic performance for oxygen reduction reaction(ORR,halfwave potential[EORR,1/2=0.855 V vs.reversible hydrogen electrode])and oxygen evolution reaction(OER,overpotential(η_(OER,10)=377mV@10mA cm^(−2)),which exceeds that of the commercial Pt/C+RuO_(2) and most of the formerly reported electrocatalysts.Impressively,both the aqueous and flexible foldable all-solid-state rechargeable zinc-air batteries(ZABs)assembled with the P-Co/CoOV@NHCNB@NCNT catalyst reveal a large maximum power density and outstanding long-term cycling stability.First-principles density functional theory calculations show that the formation of heterojunctions and oxygen vacancies enhances conductivity,reduces reaction energy barriers,and accelerates reaction kinetics rates.This work opens up a new avenue for the facile construction of highly active,structurally stable,and cost-effective bifunctional catalysts for ZABs. 展开更多
关键词 HETEROJUNCTION oxygen evolution/reduction reaction oxygen vacancies rechargeable zinc–air battery three‐dimensional nitrogen‐doped hollow carbon nanoboxes
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Solid state reactions of nitrogenous heterocyclic compounds (Ⅱ)——Solid state reactions of indole with carbonyl compounds 被引量:1
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作者 李晓陆 王永梅 +3 位作者 杜大明 文忠 熊国祥 孟继本 《Science China Chemistry》 SCIE EI CAS 1997年第3期270-277,共8页
<正> Solid state Michael addition reaction of indole with α,β-unsaturaled carbonyl compounds was carried out,by which a series of compounds containing three different heterocyclic groups binding to one carbon ... <正> Solid state Michael addition reaction of indole with α,β-unsaturaled carbonyl compounds was carried out,by which a series of compounds containing three different heterocyclic groups binding to one carbon atom were obtained.In the presence of Lewis acid,indole could undergo the solid state condensation reaction with aromatic ketones and aldehydes or quinones.The solid state reaction showed higher selectivity and yield than solution reaction The structures of products were identified by IR,1H NMR,MS,elemental analysis and X-ray crystal analysis.The reaction mechanism was also proposed. 展开更多
关键词 solid state REACTION nitrogenous COMPOUND INDOLE MICHAEL ADDITION REACTION
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