Near-infrared (NIR) spectroscopy combined with chemometrics methods was applied to the rapid and reagent-free analysis of serum urea nitrogen (SUN). The mul-partitions modeling was performed to achieve parameter stabi...Near-infrared (NIR) spectroscopy combined with chemometrics methods was applied to the rapid and reagent-free analysis of serum urea nitrogen (SUN). The mul-partitions modeling was performed to achieve parameter stability. A large-scale parameter cyclic and global optimization platform for Norris derivative filter (NDF) of three parameters (the derivative order: d, the number of smoothing points: s and the number of differential gaps: g) was developed with PLS regression. Meantime, the parameters’ adaptive analysis of NDF algorithm was also given, and achieved a significantly better modeling effect than one without spectral pre-processing. After eliminating the interference wavebands of saturated absorption, the modeling performance was further improved. In validation, the root mean square error (SEP), correlation coefficient (RP) for prediction and the ratio of performance to deviation (RPD) were 1.66 mmol?L-1, 0.966 and 4.7, respectively. The results showed that the high-precision analysis of SUN was feasibility based on NIR spectroscopy and Norris-PLS. The global optimization method of NDF is also expected to be applied to other analysis objects.展开更多
分别以Nicolet Antaris、Spectrum One NTS近红外光谱仪为源机和目标机,采集153个具有代表性的初烤烟叶样品光谱,应用Karl Norris导数滤波器对其中的120个烟叶样品的光谱进行预处理,筛选谱区,同时结合主成分分析验证源机与目标机光谱的...分别以Nicolet Antaris、Spectrum One NTS近红外光谱仪为源机和目标机,采集153个具有代表性的初烤烟叶样品光谱,应用Karl Norris导数滤波器对其中的120个烟叶样品的光谱进行预处理,筛选谱区,同时结合主成分分析验证源机与目标机光谱的一致性,将获取的有关光谱预处理参数应用于源机模型的转移运算得到目标机的转移模型,应用源机模型和目标机转移模型对另外的33个烟叶样品的总糖、还原糖、总氮和烟碱进行预测,并对预测结果进行配对t-检验。结果显示,在P>0.05时,二者的预测结果无显著性差异。展开更多
Frank Norris is a famous American naturalist writer.His novel McTeague is known as the“Declaration of American Naturalism”and its publication establishes him as“the father of American naturalism”.However,few schol...Frank Norris is a famous American naturalist writer.His novel McTeague is known as the“Declaration of American Naturalism”and its publication establishes him as“the father of American naturalism”.However,few scholars had given a detailed literature review on the current studies of Frank Norris and his novel McTeague.Through the literature search of online databases such as CNKI,EBSCO,ProQuest,and the downloading of data from 1348 libraries,it is obvious that domestic researches concerning Norris’s works are not large while foreign researches are rich in number and deep in level.Studies related to Norris’s Mc⁃Teague both at home and abroad mainly focus on naturalism,character,image,plot,money worship,comic and comparative study,which still can be further explored from different angles like the perspectives of economy,consumption or contemporary narrative.It arouses people’s attention to Frank Norris’s and other American naturalists’works while sheds light on the future studies of McTeague.展开更多
We applied near-infrared(NIR)spectroscopy with chemometrics for the rapid and reagent-fee analysis of serum urea nitrogen(SUN).The modeling is based on the average effect of multiple sample partitions to achieve param...We applied near-infrared(NIR)spectroscopy with chemometrics for the rapid and reagent-fee analysis of serum urea nitrogen(SUN).The modeling is based on the average effect of multiple sample partitions to achieve parameter selection with stability.A multiparameter optimization platform with Norris derivative filter-partial least squares(Norris-PLS)was developed to select the most suitable mode(d=2,s=33,g=15).Using equidistant combination PLS(EC-PLS)with four parameters(initial wavelength I,number of wavelengths N,number of wavelength gaps G and latent variables LV),we performed wavelength screening after eliminating high-absorption wavebands.The optimal EC-PLS parameters were I=1228 nm,N=26,G=16 and LV=12.The root-mean square error(SEP),correlation coefficient(R_(p))for prediction and ratio of performance-to-deviation(RPD)for validation were 1.03 mmol L^(-1),0.992 and 7.6,respectively.We proposed the wavelength step-by-step phase-out PLS(WSP-PLS)to remove redun-dant wavelengths in the top 100 EC-PLS models with improved prediction performance.The combination of 19 wavelengths was identifed as the optimal model for SUN.The SEP,Rp and RPD in validation were 1.01 mmol L^(-1),0.992 and 7.7,respectively.The prediction effect and wavelength complexity were better than those of EC-PIS.Our results showed that NIR spectroscopy combined with the EC-PLS and WSP-PLS methods enabled the high-precision analysis ofSUN.WSP-PLS is a secondary optimization method that can further optimize any wavelength moc odel obtained through other continuous or discrete strategies to establish a simple and better model.展开更多
Many reviewers have contributed their expertise and time to the peer review, a critical process to ensure the quality of World Journal of Biological Chemistry. The editors and authors of the articles submitted to the ...Many reviewers have contributed their expertise and time to the peer review, a critical process to ensure the quality of World Journal of Biological Chemistry. The editors and authors of the articles submitted to the journal are grateful to the following reviewers展开更多
Many reviewers have contributed their expertise and time to the peer review, a critical process to ensure the quality of World Journal of Biological Chemistry. The editors and
文摘Near-infrared (NIR) spectroscopy combined with chemometrics methods was applied to the rapid and reagent-free analysis of serum urea nitrogen (SUN). The mul-partitions modeling was performed to achieve parameter stability. A large-scale parameter cyclic and global optimization platform for Norris derivative filter (NDF) of three parameters (the derivative order: d, the number of smoothing points: s and the number of differential gaps: g) was developed with PLS regression. Meantime, the parameters’ adaptive analysis of NDF algorithm was also given, and achieved a significantly better modeling effect than one without spectral pre-processing. After eliminating the interference wavebands of saturated absorption, the modeling performance was further improved. In validation, the root mean square error (SEP), correlation coefficient (RP) for prediction and the ratio of performance to deviation (RPD) were 1.66 mmol?L-1, 0.966 and 4.7, respectively. The results showed that the high-precision analysis of SUN was feasibility based on NIR spectroscopy and Norris-PLS. The global optimization method of NDF is also expected to be applied to other analysis objects.
文摘分别以Nicolet Antaris、Spectrum One NTS近红外光谱仪为源机和目标机,采集153个具有代表性的初烤烟叶样品光谱,应用Karl Norris导数滤波器对其中的120个烟叶样品的光谱进行预处理,筛选谱区,同时结合主成分分析验证源机与目标机光谱的一致性,将获取的有关光谱预处理参数应用于源机模型的转移运算得到目标机的转移模型,应用源机模型和目标机转移模型对另外的33个烟叶样品的总糖、还原糖、总氮和烟碱进行预测,并对预测结果进行配对t-检验。结果显示,在P>0.05时,二者的预测结果无显著性差异。
文摘Frank Norris is a famous American naturalist writer.His novel McTeague is known as the“Declaration of American Naturalism”and its publication establishes him as“the father of American naturalism”.However,few scholars had given a detailed literature review on the current studies of Frank Norris and his novel McTeague.Through the literature search of online databases such as CNKI,EBSCO,ProQuest,and the downloading of data from 1348 libraries,it is obvious that domestic researches concerning Norris’s works are not large while foreign researches are rich in number and deep in level.Studies related to Norris’s Mc⁃Teague both at home and abroad mainly focus on naturalism,character,image,plot,money worship,comic and comparative study,which still can be further explored from different angles like the perspectives of economy,consumption or contemporary narrative.It arouses people’s attention to Frank Norris’s and other American naturalists’works while sheds light on the future studies of McTeague.
基金supported by the Science and Technology Project of Guangdong Province of China(Nos.2014A020213016,2014A020212445)the University-enterprise Joint Research Project"Intelligent detection network technology joint research centre"(No.40115031).
文摘We applied near-infrared(NIR)spectroscopy with chemometrics for the rapid and reagent-fee analysis of serum urea nitrogen(SUN).The modeling is based on the average effect of multiple sample partitions to achieve parameter selection with stability.A multiparameter optimization platform with Norris derivative filter-partial least squares(Norris-PLS)was developed to select the most suitable mode(d=2,s=33,g=15).Using equidistant combination PLS(EC-PLS)with four parameters(initial wavelength I,number of wavelengths N,number of wavelength gaps G and latent variables LV),we performed wavelength screening after eliminating high-absorption wavebands.The optimal EC-PLS parameters were I=1228 nm,N=26,G=16 and LV=12.The root-mean square error(SEP),correlation coefficient(R_(p))for prediction and ratio of performance-to-deviation(RPD)for validation were 1.03 mmol L^(-1),0.992 and 7.6,respectively.We proposed the wavelength step-by-step phase-out PLS(WSP-PLS)to remove redun-dant wavelengths in the top 100 EC-PLS models with improved prediction performance.The combination of 19 wavelengths was identifed as the optimal model for SUN.The SEP,Rp and RPD in validation were 1.01 mmol L^(-1),0.992 and 7.7,respectively.The prediction effect and wavelength complexity were better than those of EC-PIS.Our results showed that NIR spectroscopy combined with the EC-PLS and WSP-PLS methods enabled the high-precision analysis ofSUN.WSP-PLS is a secondary optimization method that can further optimize any wavelength moc odel obtained through other continuous or discrete strategies to establish a simple and better model.
文摘Many reviewers have contributed their expertise and time to the peer review, a critical process to ensure the quality of World Journal of Biological Chemistry. The editors and authors of the articles submitted to the journal are grateful to the following reviewers
文摘Many reviewers have contributed their expertise and time to the peer review, a critical process to ensure the quality of World Journal of Biological Chemistry. The editors and
