The Indonesian Throughflow(ITF), which connects the tropical Pacific and Indian oceans, plays important roles in the inter-ocean water exchange and regional or even global climate variability. The Makassar Strait is t...The Indonesian Throughflow(ITF), which connects the tropical Pacific and Indian oceans, plays important roles in the inter-ocean water exchange and regional or even global climate variability. The Makassar Strait is the main inflow passage of the ITF, carrying about 77% of the total ITF volume transport. In this study, we analyze the simulated ITF in the Makassar Strait in the Simple Ocean Data Assimilation version 3(SODA3) datasets. A total of nine ensemble members of the SODA3 datasets, of which are driven by different surface forcings and bulk formulas, and with or without data assimilation, are used in this study. The annual mean water transports(i.e.,volume, heat and freshwater) are related to the combination of surface forcing and bulk formula, as well as whether data assimilation is employed. The phases of the seasonal and interannual variability in water transports cross the Makassar Strait, are basically consistent with each other among the SODA3 ensemble members. The interannual variability in Makassar Strait volume and heat transports are significantly correlated with El Ni?oSouthern Oscillation(ENSO) at time lags of-6 to 7 months. There is no statistically significant correlation between the freshwater transport and the ENSO. The Makassar Strait water transports are not significantly correlated with the Indian Ocean Dipole(IOD), which may attribute to model deficiency in simulating the propagation of semiannual Kelvin waves from the Indian Ocean to the Makassar Strait.展开更多
High soda content in fine alumina trihydrate（ATH） limits its application and increases the soda consumption. The variation of soda content in the fine ATH by seeded precipitation was determined by detection of elect...High soda content in fine alumina trihydrate（ATH） limits its application and increases the soda consumption. The variation of soda content in the fine ATH by seeded precipitation was determined by detection of electric conductivity of solution, soda content in ATH, measurement of particle size distribution and microscopic analysis. The results show that high concentration of sodium aluminate solution, ground circulative seed, low temperature or fast initial precipitation rate increases the soda content in ATH. Soda mainly exists in lattice soda and less soda in desilication product （DSP） exists in the fine ATH precipitated from sodium aluminate solution with concentration of Al2O3 （ρAl2O3） more than 160 g/L and mass ratio of alumina to silica （μSiO2） of 400, and lattice soda decreases with increasing initial precipitation temperature, aging seed, and low precipitation rate and precipitation time. Results also imply that -＋ 4）Na Al（OH ion-pair influences lattice soda content in ATH on the basis of electric conductivity variation.展开更多
In recent years,some reports,mainly from Chinese research,show that there has been an increasing trend in the use of ammonia-soda residue(ASR)(or called ammonia-soda white mud) as a soil conditioner in farmlands.Up to...In recent years,some reports,mainly from Chinese research,show that there has been an increasing trend in the use of ammonia-soda residue(ASR)(or called ammonia-soda white mud) as a soil conditioner in farmlands.Up to now,the studies on ASR have focused on its utilization for acid soil amendment in agriculture,but few studies have assessed its environmental risk.ASR contains pollutant elements such as mercury(Hg),cadmium(Cd),copper(Cu) and fluorine(F) and the purpose of this study was to review research on the environmental impacts of ASR application in agriculture.Observations obtained from 23 research reports indicate that the concentrations of Hg,Cd,Cu,F and Cl(0-170,0.01-2.8,4.5-200,2000-24700 and 1 600-188 000 mg kg^-1,respectively) in ASR may exceed the limits(≤0.5,≤0.3 and ≤50 mg kg^-1 for Hg,Cd and Cu,respectively) of Chinese Risk Screening Values for Soil Contamination of Agricultural Land(GB 15618-2018 2018) or the refereed critical value(≤800 and ≤200 mg kg^-1 for F and Cl,respectively) based on Chinese research.The concentrations of the elements Hg,Cd,Cu,F and Cl in the leachate of ASR detected by the extraction tests also exceed the limits(Class IV-V) of the Chinese Standard for Groundwater Quality(GB/T 14848-2017 2017).Based on the above results,it is suggested that ASR without any pretreatment for reducing harmful pollutants should not be used for soil remediation or conditioning of farmlands,to ensure soil health,food safety and environmental quality.展开更多
为了改进水文建模过程中的不确定性处理,采用一种融合全局优化和数据同化(Simultaneous Optimization and Data Assimilation,SODA)的混合框架,对Hy MOD模型进行了不确定性分析,并与经典SCEM-UA方法进行了比较。SODA方法具有如下特点:(1...为了改进水文建模过程中的不确定性处理,采用一种融合全局优化和数据同化(Simultaneous Optimization and Data Assimilation,SODA)的混合框架,对Hy MOD模型进行了不确定性分析,并与经典SCEM-UA方法进行了比较。SODA方法具有如下特点:(1)具备较高的参数搜索效率和寻优能力;(2)明确考虑包括输入、输出、参数以及模型结构在内的重要不确定性来源。SODA方法在渭河流域的实例应用结果表明:与SCEM-UA方法相比,SODA方法不仅显著提高了预报精度,而且推求出了性质更为优良的预报区间。SODA方法的成功应用,有助于模型概念的改进及对水文系统功能的理解。展开更多
The effects of oxidant dosage,oxidation temperature and time on the degradation of soda lignin by hydrogen peroxide with and without the presence of microwave irradiation were investigated.It is found that the oxidati...The effects of oxidant dosage,oxidation temperature and time on the degradation of soda lignin by hydrogen peroxide with and without the presence of microwave irradiation were investigated.It is found that the oxidative degradation of lignin includes the cleavage of ether bond inβ-O-4 structure,the partial destruction of aromatic ring,and the re-condensation of the degraded lignin.Compared to the conventionally heated oxidation of lignin,the microwave irradiation efficiently facilitates the degradation of the lignin with high molecular weight and the re-condensation of that with low molecular weight at a low oxidant dosage,low oxidation temperature,or a short oxidation time,which leads to the formation of the degraded lignin with narrower molecular weight distribution and lower molecular weight.Additionally,the lignin degraded in the presence of microwave irradiation has the characteristics of higher content of phenolic hydroxyl group,lower content of methoxyl group,and lower degree of condensation,which enhances the reactivity of lignin.Therefore,the oxidative degradation of lignin assisted by microwave irradiation may be a new pretreatment approach for efficiently utilizing the soda lignin.展开更多
Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusio...Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusion of the resulting leaching residues with caustic soda. The experimental results show that the extraction of zinc is heavily dependent on the contents of iron in the dusts. The higher iron content, the lower extraction of zinc is obtained. 53% and 38% of zinc can be extracted when both dusts were directly contacted with 5mol·L^-1 NaOH solution for 42h. The remaining zinc left in the leaching residues, which supposed to be present as zinc ferrites, can be further leached when the residues were fused with caustic soda. Quantitative extraction of zinc can be obtained from the leaching residue of Sample A while only 85% from Sample B. The extractability of zinc from dusts wit hvarious contents of iron is compared. The production flowsheet for zinc from the dusts using the process proposed is discussed.展开更多
By desilication treatment,the Al2O3/SiO2 molar ratio of coal fly ash could be improved to the range of 1.63-2.0.The desilicated coal fly ash(DSCFA)was enriched in alumina extraction.A processing technology was develop...By desilication treatment,the Al2O3/SiO2 molar ratio of coal fly ash could be improved to the range of 1.63-2.0.The desilicated coal fly ash(DSCFA)was enriched in alumina extraction.A processing technology was developed for alumina extraction from the DSCFA with the lime sintering process.Ca/(SiO2+TiO2)molar ratio,and NaO/Al2O3 molar ratio,sintering time,and temperature were the most significant parameters impacting on the aluminum extraction efficiency.The optima aluminum extraction efficiency was obtained under conditions of Ca/(SiO2+TiO2)molar ratio of 2.0,NaO/Al2O3 molar ratio of 0.98,and sintering at 1 200 ℃for 60 min.Astandard industrial dissolution method was used under conditions of caustic ratio(αk=n(NaO)/n(Al2O3)of 2.0,Al2O3 concentration of 50 g/L,sodium hydroxide concentration(Nk)of 60.78 g/L,Na2CO3 concentration of 10 g/L,temperature of 85℃, and dissolution duration of 10 min.The final aluminum extraction efficiency was 90%.展开更多
A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue soda residue and an industrial wasteliquor.Adding 3%-6% of the agent int...A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue soda residue and an industrial wasteliquor.Adding 3%-6% of the agent into Portland cement enables a shrinkage compensating concrete to be prepared.Mortar and concrete containing this expansion agent have better shrinkage compensating and mechanical properties.The raw materials component,production process,technical properties,micro analysis of mortar made with this expansion agent,mechanism of expansion and research results are described in this article.The experimental results show that the new type of concrete expansion agent accords with the standard and its main mineral component is xCaO ySO 3 zAl 2O 3.展开更多
基金The Fund of Laoshan Laboratory under contract No. LSKJ202202700the National Natural Science Foundation of China under contract Nos 42076023, 42076024 and 41876027the Global Change and Air-Sea Interaction Ⅱ Project under contract No.GASI-01-AIP-STwin。
文摘The Indonesian Throughflow(ITF), which connects the tropical Pacific and Indian oceans, plays important roles in the inter-ocean water exchange and regional or even global climate variability. The Makassar Strait is the main inflow passage of the ITF, carrying about 77% of the total ITF volume transport. In this study, we analyze the simulated ITF in the Makassar Strait in the Simple Ocean Data Assimilation version 3(SODA3) datasets. A total of nine ensemble members of the SODA3 datasets, of which are driven by different surface forcings and bulk formulas, and with or without data assimilation, are used in this study. The annual mean water transports(i.e.,volume, heat and freshwater) are related to the combination of surface forcing and bulk formula, as well as whether data assimilation is employed. The phases of the seasonal and interannual variability in water transports cross the Makassar Strait, are basically consistent with each other among the SODA3 ensemble members. The interannual variability in Makassar Strait volume and heat transports are significantly correlated with El Ni?oSouthern Oscillation(ENSO) at time lags of-6 to 7 months. There is no statistically significant correlation between the freshwater transport and the ENSO. The Makassar Strait water transports are not significantly correlated with the Indian Ocean Dipole(IOD), which may attribute to model deficiency in simulating the propagation of semiannual Kelvin waves from the Indian Ocean to the Makassar Strait.
基金Project(51274242)supported by the National Natural Science Foundation of China
文摘High soda content in fine alumina trihydrate（ATH） limits its application and increases the soda consumption. The variation of soda content in the fine ATH by seeded precipitation was determined by detection of electric conductivity of solution, soda content in ATH, measurement of particle size distribution and microscopic analysis. The results show that high concentration of sodium aluminate solution, ground circulative seed, low temperature or fast initial precipitation rate increases the soda content in ATH. Soda mainly exists in lattice soda and less soda in desilication product （DSP） exists in the fine ATH precipitated from sodium aluminate solution with concentration of Al2O3 （ρAl2O3） more than 160 g/L and mass ratio of alumina to silica （μSiO2） of 400, and lattice soda decreases with increasing initial precipitation temperature, aging seed, and low precipitation rate and precipitation time. Results also imply that -＋ 4）Na Al（OH ion-pair influences lattice soda content in ATH on the basis of electric conductivity variation.
基金supported by the Special Program for Fertilizer Registration of Ministry of Agriculture and Rural Affairs of China(2130112)
文摘In recent years,some reports,mainly from Chinese research,show that there has been an increasing trend in the use of ammonia-soda residue(ASR)(or called ammonia-soda white mud) as a soil conditioner in farmlands.Up to now,the studies on ASR have focused on its utilization for acid soil amendment in agriculture,but few studies have assessed its environmental risk.ASR contains pollutant elements such as mercury(Hg),cadmium(Cd),copper(Cu) and fluorine(F) and the purpose of this study was to review research on the environmental impacts of ASR application in agriculture.Observations obtained from 23 research reports indicate that the concentrations of Hg,Cd,Cu,F and Cl(0-170,0.01-2.8,4.5-200,2000-24700 and 1 600-188 000 mg kg^-1,respectively) in ASR may exceed the limits(≤0.5,≤0.3 and ≤50 mg kg^-1 for Hg,Cd and Cu,respectively) of Chinese Risk Screening Values for Soil Contamination of Agricultural Land(GB 15618-2018 2018) or the refereed critical value(≤800 and ≤200 mg kg^-1 for F and Cl,respectively) based on Chinese research.The concentrations of the elements Hg,Cd,Cu,F and Cl in the leachate of ASR detected by the extraction tests also exceed the limits(Class IV-V) of the Chinese Standard for Groundwater Quality(GB/T 14848-2017 2017).Based on the above results,it is suggested that ASR without any pretreatment for reducing harmful pollutants should not be used for soil remediation or conditioning of farmlands,to ensure soil health,food safety and environmental quality.
文摘为了改进水文建模过程中的不确定性处理,采用一种融合全局优化和数据同化(Simultaneous Optimization and Data Assimilation,SODA)的混合框架,对Hy MOD模型进行了不确定性分析,并与经典SCEM-UA方法进行了比较。SODA方法具有如下特点:(1)具备较高的参数搜索效率和寻优能力;(2)明确考虑包括输入、输出、参数以及模型结构在内的重要不确定性来源。SODA方法在渭河流域的实例应用结果表明:与SCEM-UA方法相比,SODA方法不仅显著提高了预报精度,而且推求出了性质更为优良的预报区间。SODA方法的成功应用,有助于模型概念的改进及对水文系统功能的理解。
基金Supported by the National Natural Science Foundation of China（20876064） the Natural Science Foundation of Guangdong Province（9151064101000082） the Guangdong Provincial International Cooperation Fund（2008B05010006）
文摘The effects of oxidant dosage,oxidation temperature and time on the degradation of soda lignin by hydrogen peroxide with and without the presence of microwave irradiation were investigated.It is found that the oxidative degradation of lignin includes the cleavage of ether bond inβ-O-4 structure,the partial destruction of aromatic ring,and the re-condensation of the degraded lignin.Compared to the conventionally heated oxidation of lignin,the microwave irradiation efficiently facilitates the degradation of the lignin with high molecular weight and the re-condensation of that with low molecular weight at a low oxidant dosage,low oxidation temperature,or a short oxidation time,which leads to the formation of the degraded lignin with narrower molecular weight distribution and lower molecular weight.Additionally,the lignin degraded in the presence of microwave irradiation has the characteristics of higher content of phenolic hydroxyl group,lower content of methoxyl group,and lower degree of condensation,which enhances the reactivity of lignin.Therefore,the oxidative degradation of lignin assisted by microwave irradiation may be a new pretreatment approach for efficiently utilizing the soda lignin.
文摘Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusion of the resulting leaching residues with caustic soda. The experimental results show that the extraction of zinc is heavily dependent on the contents of iron in the dusts. The higher iron content, the lower extraction of zinc is obtained. 53% and 38% of zinc can be extracted when both dusts were directly contacted with 5mol·L^-1 NaOH solution for 42h. The remaining zinc left in the leaching residues, which supposed to be present as zinc ferrites, can be further leached when the residues were fused with caustic soda. Quantitative extraction of zinc can be obtained from the leaching residue of Sample A while only 85% from Sample B. The extractability of zinc from dusts wit hvarious contents of iron is compared. The production flowsheet for zinc from the dusts using the process proposed is discussed.
基金Project(YFZX(0804))supported by Science Foundation of the Pingshuo Coal Industry Company,China
文摘By desilication treatment,the Al2O3/SiO2 molar ratio of coal fly ash could be improved to the range of 1.63-2.0.The desilicated coal fly ash(DSCFA)was enriched in alumina extraction.A processing technology was developed for alumina extraction from the DSCFA with the lime sintering process.Ca/(SiO2+TiO2)molar ratio,and NaO/Al2O3 molar ratio,sintering time,and temperature were the most significant parameters impacting on the aluminum extraction efficiency.The optima aluminum extraction efficiency was obtained under conditions of Ca/(SiO2+TiO2)molar ratio of 2.0,NaO/Al2O3 molar ratio of 0.98,and sintering at 1 200 ℃for 60 min.Astandard industrial dissolution method was used under conditions of caustic ratio(αk=n(NaO)/n(Al2O3)of 2.0,Al2O3 concentration of 50 g/L,sodium hydroxide concentration(Nk)of 60.78 g/L,Na2CO3 concentration of 10 g/L,temperature of 85℃, and dissolution duration of 10 min.The final aluminum extraction efficiency was 90%.
文摘A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue soda residue and an industrial wasteliquor.Adding 3%-6% of the agent into Portland cement enables a shrinkage compensating concrete to be prepared.Mortar and concrete containing this expansion agent have better shrinkage compensating and mechanical properties.The raw materials component,production process,technical properties,micro analysis of mortar made with this expansion agent,mechanism of expansion and research results are described in this article.The experimental results show that the new type of concrete expansion agent accords with the standard and its main mineral component is xCaO ySO 3 zAl 2O 3.
