Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-se...Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-sence of electrolyte. The effects of the characteristics of the cationic agent and the pretreatment conditions on dye-ability of reactive dye were investigated. The results showed that the fixation and K/S values of the reactive dyes on the cationic cotton were improved compared with those on the untreated one in the presence of salt. Tests on fast-ness properties of the dyed cotton and fabric quality of the pretreated cotton were carried out and the results showed that wash and rub fastness of the salt-free dyeing were both satisfactory. And anti-crease property,tensile and tear strength,and handling of the cationic cotton were also good compared with that of the untreated one.展开更多
Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride ...Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection(FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction(XRD), tensile strength and whiteness and yellowness index,were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyes were tested, and the results presented that dye fixation on the cationic fabrics in the absence of salt was improved with satisfactory light fastness property and applicable wash and rub fastnesses.展开更多
The practical energy density of solid-state batteries remains limited,partly because of the lack of a general method to fabricate thin membranes for solid-state electrolytes with high ionic conductivity and low area-s...The practical energy density of solid-state batteries remains limited,partly because of the lack of a general method to fabricate thin membranes for solid-state electrolytes with high ionic conductivity and low area-specific resistance(ASR).Herein,we use an ultrahigh concentration of a ceramic ion conductor(Na_(3)SbS_(4))to build an ionconduction“highway”,and a polymer(polyethylene oxide,2 wt%)as a flexible host to prepare a polymer-inceramic ion-conducting membrane of approximately 40μm.Without the use of any salt(e.g.,NaPF_(6)),the resulting membrane exhibits a threefold increase in electronic ASR and a twofold decrease in ionic ASR compared with a pure ceramic counterpart.The activation energy for sodium-ion transport is only 190 meV in the membrane,similar to that in pure ceramic,suggesting ion transport predominantly occurs through a percolated network of ion-conducting ceramic particles.The salt-free design also provides an opportunity to suppress dendritic metal electrodeposits,according to a recently refined chemomechanical model of metal deposition.Our work suggests that salt is not always necessary in composite solid-state electrolytes,which broadens the choice of polymers to allow the optimization of other desired attributes,such as mechanical strength,chemical/electrochemical stability,and cost.展开更多
Cationic base surfactant, tetradecyltrimethylammonium hydroxide (TTAOH), can be obtained through anion exchange from tetradecyltrimethylammonium bromide (TTABr). Salt-free cationic and anionic (catanionic) surfactant ...Cationic base surfactant, tetradecyltrimethylammonium hydroxide (TTAOH), can be obtained through anion exchange from tetradecyltrimethylammonium bromide (TTABr). Salt-free cationic and anionic (catanionic) surfactant mixtures were studied by mixing TTAOH with oleic acid (OA) or stearic acid (SA) in water. The phase behavior of TTAOH/OA/H2O is compared with that of TTAOH/SA/H2O. It was found that the phase behavior of TTAOH/OA/H2O and TTAOH/SA/H2O system differs from each other due to the existence of the unsaturated double carbon bond (C=C) in OA. At fixed total surfactant concentration (25 mg/mL) of TTAOH/OA/H2O system at 25℃, one can observe an isotropic L1 phase, and a L1/Lα two-phase region with increasing OA content. The volume of top turbid Lα phase increases while the bottom phase changes gradually from transparently clear to a bit turbid until a single Lα-phase is reached. Finally at high OA concentration, excess OA is separated from the bulk aqueous solutions. TTAOH/SA/H2O system usually forms white precipitating at 25℃ due to the high chain melting temperature of SA. When heated to 60℃, however, the state of samples changes. At fixed total surfactant concentration of 25 mg/mL, an isotropic L1 phase and a milk-white or bluish Lα-phase are observed with increasing SA concentration. Transparent thin layers which are strongly birefringent form at the tops of some samples within the Lα-phase region. Finally, at high SA concentration, excess SA is separated from the bulk aqueous solutions. In addition to phase behavior study, we also measured the conductivity of TTAOH/OA/H2O system at 25℃ and TTAOH/SA/H2O system at 60℃, respectively. Surface tension and rheological measurements were also performed on typical samples.展开更多
Researches on the construction, structure, and formation of vesicles formed from surfactants have attracted great attention from colloid and interface chemists. The vesicles formed from salt-free cationic-anionic surf...Researches on the construction, structure, and formation of vesicles formed from surfactants have attracted great attention from colloid and interface chemists. The vesicles formed from salt-free cationic-anionic surfactant systems are very different from those with excess salts, having many particular properties. In this paper, we introduce the properties of vesicles prepared from salt-free surfactant systems, according to our own results, especially the vesicles formed from surfactants with divalent metal ions as counterions in aqueous solutions and room temperature ionic liquids. Moreover, the primary results on template effect of the metal-ligand vesicles have also been summarized.展开更多
为解决Lyocell织物活性染料染色无机盐用量大、纤维原纤化等问题,分析了Lyocell织物的连续式无盐轧染染色技术,探讨了焙烘温度、焙烘时间、浸轧次数、碱剂及尿素用量对染色性能的影响,并与传统浸染工艺进行了比较。结果表明:Lyocell织...为解决Lyocell织物活性染料染色无机盐用量大、纤维原纤化等问题,分析了Lyocell织物的连续式无盐轧染染色技术,探讨了焙烘温度、焙烘时间、浸轧次数、碱剂及尿素用量对染色性能的影响,并与传统浸染工艺进行了比较。结果表明:Lyocell织物活性染料轧-烘-焙最佳的染色配方和工艺为碱剂25 g L,尿素60 g L,二浸二轧,160℃下焙烘2 min。相比传统浸染工艺,连续式无盐轧染染色可获得更高的染色深度,且改善了原纤化程度。展开更多
基金Supported by the National Science Foundation for Distinguished Young Scholar of China（20525620） the National Natural Science Foundation of China（20806013） the Program for Changjiang Scholar and Innovative Research Team in University（IRT 0711）
文摘Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-sence of electrolyte. The effects of the characteristics of the cationic agent and the pretreatment conditions on dye-ability of reactive dye were investigated. The results showed that the fixation and K/S values of the reactive dyes on the cationic cotton were improved compared with those on the untreated one in the presence of salt. Tests on fast-ness properties of the dyed cotton and fabric quality of the pretreated cotton were carried out and the results showed that wash and rub fastness of the salt-free dyeing were both satisfactory. And anti-crease property,tensile and tear strength,and handling of the cationic cotton were also good compared with that of the untreated one.
基金Supported by the National Natural Science Foundation of China(2137604221421005)+2 种基金the National Key Technology R&D Program(2013BAF08B06)Innovative Research Team of Ministry of Education of the People's Republic of China(IRT-13R06)Dalian University of Technology(DUT2013TB07)
文摘Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection(FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction(XRD), tensile strength and whiteness and yellowness index,were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyes were tested, and the results presented that dye fixation on the cationic fabrics in the absence of salt was improved with satisfactory light fastness property and applicable wash and rub fastnesses.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.51902201,51527801).The authors would also like to thank Dr.Chunjie Cao from Carl Zeiss(Shanghai)Co.,Ltd.for the XRM figure processing,and Ms.Yirong Gao for constructive suggestions and comments regarding the manuscript.
文摘The practical energy density of solid-state batteries remains limited,partly because of the lack of a general method to fabricate thin membranes for solid-state electrolytes with high ionic conductivity and low area-specific resistance(ASR).Herein,we use an ultrahigh concentration of a ceramic ion conductor(Na_(3)SbS_(4))to build an ionconduction“highway”,and a polymer(polyethylene oxide,2 wt%)as a flexible host to prepare a polymer-inceramic ion-conducting membrane of approximately 40μm.Without the use of any salt(e.g.,NaPF_(6)),the resulting membrane exhibits a threefold increase in electronic ASR and a twofold decrease in ionic ASR compared with a pure ceramic counterpart.The activation energy for sodium-ion transport is only 190 meV in the membrane,similar to that in pure ceramic,suggesting ion transport predominantly occurs through a percolated network of ion-conducting ceramic particles.The salt-free design also provides an opportunity to suppress dendritic metal electrodeposits,according to a recently refined chemomechanical model of metal deposition.Our work suggests that salt is not always necessary in composite solid-state electrolytes,which broadens the choice of polymers to allow the optimization of other desired attributes,such as mechanical strength,chemical/electrochemical stability,and cost.
基金Supported by the National Natural Science Foundation of China (Grant No. 20803045)National Basic Research Program of China) (Grant No. 2009CB 930103)New Teacher’s Foundation of Ministry of Education (Grant No. 200804221008)
文摘Cationic base surfactant, tetradecyltrimethylammonium hydroxide (TTAOH), can be obtained through anion exchange from tetradecyltrimethylammonium bromide (TTABr). Salt-free cationic and anionic (catanionic) surfactant mixtures were studied by mixing TTAOH with oleic acid (OA) or stearic acid (SA) in water. The phase behavior of TTAOH/OA/H2O is compared with that of TTAOH/SA/H2O. It was found that the phase behavior of TTAOH/OA/H2O and TTAOH/SA/H2O system differs from each other due to the existence of the unsaturated double carbon bond (C=C) in OA. At fixed total surfactant concentration (25 mg/mL) of TTAOH/OA/H2O system at 25℃, one can observe an isotropic L1 phase, and a L1/Lα two-phase region with increasing OA content. The volume of top turbid Lα phase increases while the bottom phase changes gradually from transparently clear to a bit turbid until a single Lα-phase is reached. Finally at high OA concentration, excess OA is separated from the bulk aqueous solutions. TTAOH/SA/H2O system usually forms white precipitating at 25℃ due to the high chain melting temperature of SA. When heated to 60℃, however, the state of samples changes. At fixed total surfactant concentration of 25 mg/mL, an isotropic L1 phase and a milk-white or bluish Lα-phase are observed with increasing SA concentration. Transparent thin layers which are strongly birefringent form at the tops of some samples within the Lα-phase region. Finally, at high SA concentration, excess SA is separated from the bulk aqueous solutions. In addition to phase behavior study, we also measured the conductivity of TTAOH/OA/H2O system at 25℃ and TTAOH/SA/H2O system at 60℃, respectively. Surface tension and rheological measurements were also performed on typical samples.
基金the National Natural Science Foundation of China (Grant Nos. 20625307, 20533050 and 20473049)
文摘Researches on the construction, structure, and formation of vesicles formed from surfactants have attracted great attention from colloid and interface chemists. The vesicles formed from salt-free cationic-anionic surfactant systems are very different from those with excess salts, having many particular properties. In this paper, we introduce the properties of vesicles prepared from salt-free surfactant systems, according to our own results, especially the vesicles formed from surfactants with divalent metal ions as counterions in aqueous solutions and room temperature ionic liquids. Moreover, the primary results on template effect of the metal-ligand vesicles have also been summarized.
文摘为解决Lyocell织物活性染料染色无机盐用量大、纤维原纤化等问题,分析了Lyocell织物的连续式无盐轧染染色技术,探讨了焙烘温度、焙烘时间、浸轧次数、碱剂及尿素用量对染色性能的影响,并与传统浸染工艺进行了比较。结果表明:Lyocell织物活性染料轧-烘-焙最佳的染色配方和工艺为碱剂25 g L,尿素60 g L,二浸二轧,160℃下焙烘2 min。相比传统浸染工艺,连续式无盐轧染染色可获得更高的染色深度,且改善了原纤化程度。
