To reduce the production cost of titanium,a new method for direct preparation of low-oxygen titanium powder by the magnesiothermic reduction of TiO_(2) with the assistance of a MgCl_(2)−HoCl_(3) molten salt was propos...To reduce the production cost of titanium,a new method for direct preparation of low-oxygen titanium powder by the magnesiothermic reduction of TiO_(2) with the assistance of a MgCl_(2)−HoCl_(3) molten salt was proposed.Thermodynamic calculations showed that the magnesiothermic reduction of TiO_(2) was feasible.However,hindrance of the reduction reaction by the reduction by-product of MgO resulted in a considerably high O concentration in the titanium powder.The addition of HoCl_(3) to the system significantly reduces the activity of MgO to produce low-oxygen titanium powder.Thermochemical deoxidation and reduction experiments were conducted with MgCl_(2)−HoCl_(3) molten salt in the temperature range of 1023−1273 K.The results showed that titanium powder with oxygen concentration(mass fraction)below 5.00×10^(-4) can be prepared at the Mg−MgCl_(2)−HoOCl−HoCl_(3) equilibrium.展开更多
The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable po...The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable pollutants such as methyl orange which make their degradation difficult. It is therefore necessary to find new, more effective techniques for the treatment of these discharges. Among the different solutions proposed to deal with this problem, we find advanced oxidation processes (POAs) which are clean and promising technologies in the field of wastewater depollution. In this regard, heterogeneous photocatalysis was used in an aqueous suspension of titanium oxide (TiO2) using a ultraviolet (UV) lamp as artificial radiation. The objective of this work is to study the influence of some operating parameters such as: the catalyst mass, the initial pollutant concentration, the volume of the solution and the pH of the solution, were examined. The results obtained showed that this photocatalyst made it possible to degrade 99.85% of the initial concentration of methyl orange (10 ppm), after 240 min of irradiation with an optimal mass of 0.50 g of TiO2 for a volume of 200 mL of methyl orange solution at pH = 3.0.展开更多
Flexible polymer-based dye-sensitized solar cells (DSSCs) offer promising potential for lightweight, cost-effective and versatile photovoltaic applications. However, the critical challenge in their widespread applicat...Flexible polymer-based dye-sensitized solar cells (DSSCs) offer promising potential for lightweight, cost-effective and versatile photovoltaic applications. However, the critical challenge in their widespread applications is the weak thermal stability of most polymeric substrates, which can only withstand a maximum temperature processing of 150˚C. In this study, a facile and low-cost strategy is proposed to develop at low temperature DSSC flexible photoanode based on a polymeric matrix. Highly porous nanocomposites fibrous mats composed of polyethylene terephthalate (PET) and titanium dioxide (TiO2) nanobars were prepared through an electrospinning process using different configurations (uniaxial electrospinning, coaxial electrospinning, and electrospray-assisted electrospinning). These techniques enabled precise control of the microstructure and the positioning of TiO2 within the composite nanofibers. Therefore, the as-produced photoanodes were loaded with N719 dye and tested in DSSC prototype using iodide-triiodide electrolyte and platinum (Pt) coated counter electrode. The results show that incorporating TiO2 on the fiber surface through the electrospray-assisted electrospinning enhanced the performance of the nanofiber composite, leading to improved dye loading capacity, electron transfer efficiency and photovoltaic performance.展开更多
This study used a Polyindole in combination with TiO2 nanocatalyst as an efficient heterogeneous catalyst to carry out a multi-component Hantzsch reaction involving different aromatic aldehydes with methyl acetoacetat...This study used a Polyindole in combination with TiO2 nanocatalyst as an efficient heterogeneous catalyst to carry out a multi-component Hantzsch reaction involving different aromatic aldehydes with methyl acetoacetate, and aqueous ammonium to create 1,4-dihydropyridine derivatives under solvent free condition at ambient temperature. A broad range of aldehydes and methyl acetoacetates, ranging from heteroaromatic to polyaromatic one, with high level of functional group tolerance can be used to provide the desired products possessing relevant medicinal moiety in high yields. This technology has prospective advantages over current protocols, including the utilization of a cheap, stable, recyclable, and safe catalyst, quicker reaction times with higher yields and simple product isolation.展开更多
The simulation by the Monte Carlo method executed by the software PyPENELOPE proved effective to specify the particle propagation characteristics by calculating the absorption fractions, backscattering and transmissio...The simulation by the Monte Carlo method executed by the software PyPENELOPE proved effective to specify the particle propagation characteristics by calculating the absorption fractions, backscattering and transmission of electrons and secondary photons under the incidence of 0.5 to 20 KeV range of primary electrons. More than 99.9% of the primary electrons were transmitted in the 125 nm thick MgO/TiO<sub>2</sub> material at 20 KeV. This occurred because several interactions took place in the transmitted primary irradiation such as characteristic, fluorescence, and bremsstrahlung produced when of the occupation of the KL3, KL2, KM3, and KM2 shell and sub-shell of titanium and magnesium which are the elements with a high atomic number in the material. The transmission particle characteristic of this material is therefore an indicator capable of improving the electrical performance and properties of the sensor.展开更多
基金financially supported by the National Natural Science Foundation of China (No.21968013)。
文摘To reduce the production cost of titanium,a new method for direct preparation of low-oxygen titanium powder by the magnesiothermic reduction of TiO_(2) with the assistance of a MgCl_(2)−HoCl_(3) molten salt was proposed.Thermodynamic calculations showed that the magnesiothermic reduction of TiO_(2) was feasible.However,hindrance of the reduction reaction by the reduction by-product of MgO resulted in a considerably high O concentration in the titanium powder.The addition of HoCl_(3) to the system significantly reduces the activity of MgO to produce low-oxygen titanium powder.Thermochemical deoxidation and reduction experiments were conducted with MgCl_(2)−HoCl_(3) molten salt in the temperature range of 1023−1273 K.The results showed that titanium powder with oxygen concentration(mass fraction)below 5.00×10^(-4) can be prepared at the Mg−MgCl_(2)−HoOCl−HoCl_(3) equilibrium.
文摘The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable pollutants such as methyl orange which make their degradation difficult. It is therefore necessary to find new, more effective techniques for the treatment of these discharges. Among the different solutions proposed to deal with this problem, we find advanced oxidation processes (POAs) which are clean and promising technologies in the field of wastewater depollution. In this regard, heterogeneous photocatalysis was used in an aqueous suspension of titanium oxide (TiO2) using a ultraviolet (UV) lamp as artificial radiation. The objective of this work is to study the influence of some operating parameters such as: the catalyst mass, the initial pollutant concentration, the volume of the solution and the pH of the solution, were examined. The results obtained showed that this photocatalyst made it possible to degrade 99.85% of the initial concentration of methyl orange (10 ppm), after 240 min of irradiation with an optimal mass of 0.50 g of TiO2 for a volume of 200 mL of methyl orange solution at pH = 3.0.
文摘Flexible polymer-based dye-sensitized solar cells (DSSCs) offer promising potential for lightweight, cost-effective and versatile photovoltaic applications. However, the critical challenge in their widespread applications is the weak thermal stability of most polymeric substrates, which can only withstand a maximum temperature processing of 150˚C. In this study, a facile and low-cost strategy is proposed to develop at low temperature DSSC flexible photoanode based on a polymeric matrix. Highly porous nanocomposites fibrous mats composed of polyethylene terephthalate (PET) and titanium dioxide (TiO2) nanobars were prepared through an electrospinning process using different configurations (uniaxial electrospinning, coaxial electrospinning, and electrospray-assisted electrospinning). These techniques enabled precise control of the microstructure and the positioning of TiO2 within the composite nanofibers. Therefore, the as-produced photoanodes were loaded with N719 dye and tested in DSSC prototype using iodide-triiodide electrolyte and platinum (Pt) coated counter electrode. The results show that incorporating TiO2 on the fiber surface through the electrospray-assisted electrospinning enhanced the performance of the nanofiber composite, leading to improved dye loading capacity, electron transfer efficiency and photovoltaic performance.
文摘This study used a Polyindole in combination with TiO2 nanocatalyst as an efficient heterogeneous catalyst to carry out a multi-component Hantzsch reaction involving different aromatic aldehydes with methyl acetoacetate, and aqueous ammonium to create 1,4-dihydropyridine derivatives under solvent free condition at ambient temperature. A broad range of aldehydes and methyl acetoacetates, ranging from heteroaromatic to polyaromatic one, with high level of functional group tolerance can be used to provide the desired products possessing relevant medicinal moiety in high yields. This technology has prospective advantages over current protocols, including the utilization of a cheap, stable, recyclable, and safe catalyst, quicker reaction times with higher yields and simple product isolation.
文摘The simulation by the Monte Carlo method executed by the software PyPENELOPE proved effective to specify the particle propagation characteristics by calculating the absorption fractions, backscattering and transmission of electrons and secondary photons under the incidence of 0.5 to 20 KeV range of primary electrons. More than 99.9% of the primary electrons were transmitted in the 125 nm thick MgO/TiO<sub>2</sub> material at 20 KeV. This occurred because several interactions took place in the transmitted primary irradiation such as characteristic, fluorescence, and bremsstrahlung produced when of the occupation of the KL3, KL2, KM3, and KM2 shell and sub-shell of titanium and magnesium which are the elements with a high atomic number in the material. The transmission particle characteristic of this material is therefore an indicator capable of improving the electrical performance and properties of the sensor.
