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A virtual thermometer for ultrahigh-temperature-pressure experiments in a large-volume press
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作者 Bingtao Feng Longjian Xie +8 位作者 Xuyuan Hou Shucheng Liu Luyao Chen Xinyu Zhao Chenyi Li Qiang Zhou Kuo Hu Zhaodong Liu Bingbing Liu 《Matter and Radiation at Extremes》 SCIE EI CSCD 2024年第4期98-110,共13页
Ultrahigh-temperature-pressure experiments are crucial for understanding the physical and chemical properties of matter.The recent development of boron-doped diamond(BDD)heaters has made such melting experiments possi... Ultrahigh-temperature-pressure experiments are crucial for understanding the physical and chemical properties of matter.The recent development of boron-doped diamond(BDD)heaters has made such melting experiments possible in large-volume presses.However,estimates of temperatures above 2600 K and of the temperature distributions inside BDD heaters are not well constrained,owing to the lack of a suitable thermometer.Here,we establish a three-dimensional finite element model as a virtual thermometer to estimate the temperature and temperature field above 2600 K.The advantage of this virtual thermometer over those proposed in previous studies is that it considers both alternating and direct current heating modes,the actual sizes of cell assemblies after compression,the effects of the electrode,thermocouple and anvil,and the heat dissipation by the pressure-transmitting medium.The virtual thermometer reproduces the power-temperature relationships of ultrahigh-temperature-pressure experiments below 2600 K at press loads of 2.8-7.9 MN(~19 to 28 GPa)within experimental uncertainties.The temperatures above 2600 K predicted by our virtual thermometer are within the uncertainty of those extrapolated from power-temperature relationships below 2600 K.Furthermore,our model shows that the temperature distribution inside a BDD heater(19-26 K/mm along the radial direction and<83 K/mm along the longitudinal direction)is more homogeneous than those inside conventional heaters such as graphite or LaCrO_(3) heaters(100-200 K/mm).Our study thus provides a reliable virtual thermometer for ultrahigh-temperature experiments using BDD heaters in Earth and material sciences. 展开更多
关键词 VIRTUAL ultrahigh SIZES
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Amorphous Iridium Oxide-Integrated Anode Electrodes with Ultrahigh Material Utilization for Hydrogen Production at Industrial Current Densities
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作者 Lei Ding Kui Li +10 位作者 Weitian Wang Zhiqiang Xie Shule Yu Haoran Yu David ACullen Alex Keane Kathy Ayers Christopher BCapuano Fangyuan Liu Pu-Xian Gao Feng-Yuan Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期225-239,共15页
Herein,ionomer-free amorphous iridium oxide(IrO_(x))thin electrodes are first developed as highly active anodes for proton exchange membrane electrolyzer cells(PEMECs)via low-cost,environmentally friendly,and easily s... Herein,ionomer-free amorphous iridium oxide(IrO_(x))thin electrodes are first developed as highly active anodes for proton exchange membrane electrolyzer cells(PEMECs)via low-cost,environmentally friendly,and easily scalable electrodeposition at room temperature.Combined with a Nafion 117 membrane,the IrO_(x)-integrated electrode with an ultralow loading of 0.075 mg cm^(-2)delivers a high cell efficiency of about 90%,achieving more than 96%catalyst savings and 42-fold higher catalyst utilization compared to commercial catalyst-coated membrane(2 mg cm^(-2)).Additionally,the IrO_(x)electrode demonstrates superior performance,higher catalyst utilization and significantly simplified fabrication with easy scalability compared with the most previously reported anodes.Notably,the remarkable performance could be mainly due to the amorphous phase property,sufficient Ir^(3+)content,and rich surface hydroxide groups in catalysts.Overall,due to the high activity,high cell efficiency,an economical,greatly simplified and easily scalable fabrication process,and ultrahigh material utilization,the IrO_(x)electrode shows great potential to be applied in industry and accelerates the commercialization of PEMECs and renewable energy evolution. 展开更多
关键词 Ionomer-free Amorphous IrOx electrodes ultrahigh material utilization Scalable electrodeposition Hydrogen production
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Health diagnosis of ultrahigh arch dam performance using heterogeneous spatial panel vector model
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作者 Er-feng Zhao Xin Li Chong-shi Gu 《Water Science and Engineering》 EI CAS CSCD 2024年第2期177-186,共10页
Currently,more than ten ultrahigh arch dams have been constructed or are being constructed in China.Safety control is essential to long-term operation of these dams.This study employed the flexibility coefficient and ... Currently,more than ten ultrahigh arch dams have been constructed or are being constructed in China.Safety control is essential to long-term operation of these dams.This study employed the flexibility coefficient and plastic complementary energy norm to assess the structural safety of arch dams.A comprehensive analysis was conducted,focusing on differences among conventional methods in characterizing the structural behavior of the Xiaowan arch dam in China.Subsequently,the spatiotemporal characteristics of the measured performance of the Xiaowan dam were explored,including periodicity,convergence,and time-effect characteristics.These findings revealed the governing mechanism of main factors.Furthermore,a heterogeneous spatial panel vector model was developed,considering both common factors and specific factors affecting the safety and performance of arch dams.This model aims to comprehensively illustrate spatial heterogeneity between the entire structure and local regions,introducing a specific effect quantity to characterize local deformation differences.Ultimately,the proposed model was applied to the Xiaowan arch dam,accurately quantifying the spatiotemporal heterogeneity of dam performance.Additionally,the spatiotemporal distri-bution characteristics of environmental load effects on different parts of the dam were reasonably interpreted.Validation of the model prediction enhances its credibility,leading to the formulation of health diagnosis criteria for future long-term operation of the Xiaowan dam.The findings not only enhance the predictive ability and timely control of ultrahigh arch dams'performance but also provide a crucial basis for assessing the effectiveness of engineering treatment measures. 展开更多
关键词 ultrahigh arch dam Structural performance Deformation behavior Diagnosis criterion Panel data model
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Ultrahigh spatiotemporal resolution beam signal reconstruction with bunch phase compensation
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作者 You-Ming Deng Yong-Bin Leng +2 位作者 Xing-Yi Xu Jian Chen Yi-Mei Zhou 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期99-108,共10页
Various electromagnetic signals are excited by the beam in the acceleration and beam-diagnostic elements of a particle accelerator.It is important to obtain time-domain waveforms of these signals with high temporal re... Various electromagnetic signals are excited by the beam in the acceleration and beam-diagnostic elements of a particle accelerator.It is important to obtain time-domain waveforms of these signals with high temporal resolution for research,such as the study of beam–cavity interactions and bunch-by-bunch parameter measurements.Therefore,a signal reconstruction algorithm with ultrahigh spatiotemporal resolution and bunch phase compensation based on equivalent sampling is proposed in this paper.Compared with traditional equivalent sampling,the use of phase compensation and setting the bunch signal zero-crossing point as the time reference can construct a more accurate reconstructed signal.The basic principles of the method,simulation,and experimental comparison are also introduced.Based on the beam test platform of the Shanghai Synchrotron Radiation Facility(SSRF)and the method of experimental verification,the factors that affect the reconstructed signal quality are analyzed and discussed,including the depth of the sampled data,quantization noise of analog-to-digital converter,beam transverse oscillation,and longitudinal oscillation.The results of the beam experiments show that under the user operation conditions of the SSRF,a beam excitation signal with an amplitude uncertainty of 2%can be reconstructed. 展开更多
关键词 Turn-by-turn bunch phase compensation technique Equivalent sampling Signal reconstruction algorithm ultrahigh spatiotemporal resolution SSRF
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Topological Structure-Modulated Collagen Carbon as Two-in-One Energy Storage Configuration toward Ultrahigh Power and Energy Density
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作者 Li Yuan Wenlong Cai +4 位作者 Yunhong Wei Yiran Pu Can Liu Yun Zhang Hao Wu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期18-29,共12页
Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the susta... Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the sustainable development of energy and the environment.Herein,a facile collagen microstructure modulation strategy is proposed to construct a nitrogen/oxygen dual-doped hierarchically porous carbon fiber with ultrahigh specific surface area(2788 m^(2)g^(-1))and large pore volume(4.56 cm^(3)g^(-1))via local microfibrous breakage/disassembly of natural structured proteins.Combining operando spectroscopy and density functional theory unveil that the dual-heteroatom doping could effectively regulate the electronic structure of carbon atom framework with enhanced electric conductivity and electronegativity as well as decreased diffusion resistance in favor of rapid pseudocapacitive-dominated Li^(+)-storage(353 mAh g^(-1)at 10 A g^(-1)).Theoretical calculations reveal that the tailored micro-/mesoporous structures favor the rapid charge transfer and ion storage,synergistically realizing high capacity and superior rate performance for NPCF-H cathode(75.0 mAh g^(-1)at 30 A g^(-1)).The assembled device with NPCF-H as both anode and cathode achieves extremely high energy density(200 Wh kg^(-1))with maximum power density(42600 W kg^(-1))and ultralong lifespan(80%capacity retention over 10000 cycles). 展开更多
关键词 collagen carbon energy storage device theoretical calculations topological structure modulation ultrahigh power and energy density
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Role of extrusion rate on the microstructure and tensile properties evolution of ultrahigh-strength low-alloy Mg-1.0Al-1.0Ca-0.4Mn(wt.%)alloy 被引量:6
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作者 X.Q.Liu X.G.Qiao +3 位作者 R.S.Pei Y.Q.Chi L.Yuan M.Y.Zheng 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第2期553-561,共9页
Mg-1.0Al-1.0Ca-0.4Mn(AXM1104, wt.%) low alloy was extruded at 200 ℃ with an extrusion ratio of 25 and different ram speeds from 1.0 to 7.0 mm/s. The influence of extrusion rate on microstructure and mechanical proper... Mg-1.0Al-1.0Ca-0.4Mn(AXM1104, wt.%) low alloy was extruded at 200 ℃ with an extrusion ratio of 25 and different ram speeds from 1.0 to 7.0 mm/s. The influence of extrusion rate on microstructure and mechanical properties of the AXM1104 alloy was systematically studied. With the increasing of extrusion rate, the mean dynamically recrystallized(DRXed) grain size of the low alloy and average particles diameter of precipitate second phases were increased, while the degree of grain boundary segregation and the intensity of the basal fiber texture were decreased. With the rising of extrusion rate from 1.0 to 7.0 mm/s, the tensile yield strength(TYS) of the as-extruded AXM1104 alloy was decreased from 445 MPa to 249 MPa, while the elongation to failure(EL) was increased from 5.0% to 17.6%. The TYS, ultimate tensile strength(UTS) and EL of the AXM1104 alloy extruded at the ram speed of 1.5 mm/s was 412 MPa, 419 MPa and 12.0%, respectively,exhibiting comprehensive tensile mechanical properties with ultra-high strength and excellent plasticity. The ultra-high TYS of 412 MPa was mainly due to the strengthening from ultra-fine DRXed grains with segregation of solute atoms at grain boundaries. The strain hardening rate is increase slightly with increasing extrusion speed, which may be ascribed to the increasing mean DRXed grain size with rising extrusion speed. The higher strain hardening rate contributes to the higher EL of these AXM1104 samples extruded at higher ram speed. 展开更多
关键词 Mg-Al-Ca-Mn alloy Ultrafine grain Extrusion rate Grain boundary segregation MICROSTRUCTURE ultrahigh strength
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Effects of phonon bandgap on phonon-phonon scattering in ultrahigh thermal conductivityθ-phase TaN
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作者 吴超 刘晨晗 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第4期543-548,共6页
Phonon bandgap typically has a significant effect on phonon-phonon scattering process.In this work,the effects of mass modified phonon bandgap inθ-phase Ta N are systemically investigated by the means of first-princi... Phonon bandgap typically has a significant effect on phonon-phonon scattering process.In this work,the effects of mass modified phonon bandgap inθ-phase Ta N are systemically investigated by the means of first-principles calculations with linearized Boltzmann transport equation.Through detailed calculations,we find that phonon bandgap has a significant effect on three-phonon process while exhibits a much weaker effect on four-phonon process.The reason for the ultrahigh thermal conductivity ofθ-phase Ta N is the long lifetime of phonons including both three-phonon and four-phonon processes,which originates from the weak phonon anharmonicity and large phonon bandgap-induced small phonon-phonon scattering phase space.This work advances the understanding of phonon bandgap effects on phonon transport. 展开更多
关键词 ultrahigh thermal conductivity phonon-phonon scattering phase space first-principles calculation phonon bandgap
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Solid-state NMR spectroscopy at ultrahigh resolution for structural and dynamical studies of MOFs
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作者 Qing Wang Min Peng +4 位作者 Cong-Cong Liang Jing Tan Sophia Zhang Yue-Biao Zhang Haiming Liu 《Magnetic Resonance Letters》 2023年第2期175-186,I0005,共13页
To characterize the structure and dynamics of metal--organic frameworks(MOFs)indepth at the molecular level,it is necessary to pursue high-resolution solid-state magic angle spinning(MAS)nuclear magnetic resonance(NMR... To characterize the structure and dynamics of metal--organic frameworks(MOFs)indepth at the molecular level,it is necessary to pursue high-resolution solid-state magic angle spinning(MAS)nuclear magnetic resonance(NMR)spectroscopy.Spectral resolution is usually affected by the quality of materials and various experimental conditions,of which magic angle(MA)accuracy is a crucial determinant.The current industrial criteria for MA calibration based on the common standard of KBr were found insufficient in guaranteeing optimal resolution MAS NMR for highly ordered MOFs.To drive towards higher-resolution MAS NMR spectroscopy,we propose_a calibration protocol for more accurate MA with a higher-precision criterion based on 79Br MAS NMR of KBr,where the linewidth ratio of the fifth-order spinning sideband to the central band of KBr should be less than 1.00.As a result,ultrahigh-resolution 13C cross-polarization(CP)MAS NMR of MOF-5 is achieved with minimal linewidths as low as 4 Hz,and therefore MOF-5 can be used as a new standard convenient for verifying MA accuracy and also optimizing 13c CP conditions.Maintaining high-precision MA under variable temperature(VT)was found challenging on certain commercial MAS NMR probes,as was systematically investigated by VT NMR using KBr and MOF-5.Nevertheless,ultrahigh-resolution MAS NMR spectroscopy with stable MA under VT is employed to reveal fine structures and linker dynamics of a series of Zn-based MOFs with highly regulated structures.The ultrahigh-resolution NMR methodcan be generally applied to study a broad range of MOFs and other materials. 展开更多
关键词 Solid-state NMR ultrahigh resolution MOFS Structure and dynamics Magic angle calibration
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Model-Free Feature Screening via Maximal Information Coefficient (MIC) for Ultrahigh-Dimensional Multiclass Classification
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作者 Tingting Chen Guangming Deng 《Open Journal of Statistics》 2023年第6期917-940,共24页
It is common for datasets to contain both categorical and continuous variables. However, many feature screening methods designed for high-dimensional classification assume that the variables are continuous. This limit... It is common for datasets to contain both categorical and continuous variables. However, many feature screening methods designed for high-dimensional classification assume that the variables are continuous. This limits the applicability of existing methods in handling this complex scenario. To address this issue, we propose a model-free feature screening approach for ultra-high-dimensional multi-classification that can handle both categorical and continuous variables. Our proposed feature screening method utilizes the Maximal Information Coefficient to assess the predictive power of the variables. By satisfying certain regularity conditions, we have proven that our screening procedure possesses the sure screening property and ranking consistency properties. To validate the effectiveness of our approach, we conduct simulation studies and provide real data analysis examples to demonstrate its performance in finite samples. In summary, our proposed method offers a solution for effectively screening features in ultra-high-dimensional datasets with a mixture of categorical and continuous covariates. 展开更多
关键词 ultrahigh-Dimensional Feature Screening MODEL-FREE Maximal Information Coefficient (MIC) Multiclass Classification
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Application of pre-alloyed powders for diamond tools by ultrahigh pressure water atomization 被引量:2
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作者 储志强 郭学益 +3 位作者 刘东华 谭彦显 李栋 田庆华 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第10期2665-2671,共7页
Copper, iron and cobalt based pre-alloyed powders for diamond tools were prepared by ultrahigh pressure water atomization(UPWA) process. Pre-alloyed powders prepared by different processes including UPWA, convention... Copper, iron and cobalt based pre-alloyed powders for diamond tools were prepared by ultrahigh pressure water atomization(UPWA) process. Pre-alloyed powders prepared by different processes including UPWA, conventional water atomization (CWA) and elemental metal mechanical mixing (EMMM) were sintered to segments and then compared in mechanical properties, holding force between matrix and diamond, fracture morphology of blank and sintering diamond section containing matrix. The results showed that the pre-alloyed powder prepared by UPWA exhibits the best mechanical properties including the relative density, the hardness and the bending strength of matrix sinteredsegment. Sintered segments fractography of UPWA pre-alloyed powder indicatesmechanical mosaic strength and chemical bonding force between the pre-alloyed powder and the diamond, leading to the great increase in the holding force between matrix and diamond. The mechanical performance andthe service life of diamond tools were greatly improved by UPWA pre-alloyed powders. 展开更多
关键词 ultrahigh pressure water atomization pre-alloyed powders diamond tools sintered segments
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Microstructure and microhardness of directionally solidified and heat-treated Nb-Ti-Si based ultrahigh temperature alloy 被引量:5
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作者 郭海生 郭喜平 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第6期1283-1290,共8页
Directionally solidified (DS) specimens of Nb-Ti-Si based ultrahigh temperature alloy were heat-treated at (1 500 ℃, 50 h) and (1 500 ℃, 50 h) + (1 100 ℃, 50 h), respectively. The results show that the mic... Directionally solidified (DS) specimens of Nb-Ti-Si based ultrahigh temperature alloy were heat-treated at (1 500 ℃, 50 h) and (1 500 ℃, 50 h) + (1 100 ℃, 50 h), respectively. The results show that the microstructures become uniform, the long and big primary (Nb,X)sSi3 (X represents Ti and Hf elements) plates in the DS specimens are broken into small ones, and the eutectic cells lose their lamellar morphology and their interfaces become blurry after heat-treatment. Meanwhile, the (Nb,X)sSi3 slices in the eutectic cells of the DS specimens coarsen obviously after heat-treatment. Homogenizing and aging treatments could effectively eliminate elemental microsegregation, and the segregation ratios of all elements in niobium solid solution (Nbss) in different regions tend to 1. After heat-treatment, the microhardness of retained eutectic cells increases evidently, and the maximum value reaches HV1 404.57 for the specimen directionally solidified with a withdrawing rate of 100 μm/s and then heat-treated at (1 500 ℃, 50 h) + (1 100 ℃, 50 h), which is 72.8 % higher than that under DS condition. 展开更多
关键词 Nb-Ti-Si based ultrahigh temperature alloy homogenizing treatment aging treatment microstructural evolution MICROHARDNESS
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Effect of high temperature treatments on microstructure of Nb-Ti-Cr-Si based ultrahigh temperature alloy 被引量:3
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作者 郭宝会 郭喜平 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第8期1710-1716,共7页
To investigate the effects of homogenizing and aging treatments on the microstructure of an Nb-Ti-Cr-Si based ultrahigh temperature alloy,coupons were homogenized at 1 200-1 500 °C for 24 h,and then aged at 1 000... To investigate the effects of homogenizing and aging treatments on the microstructure of an Nb-Ti-Cr-Si based ultrahigh temperature alloy,coupons were homogenized at 1 200-1 500 °C for 24 h,and then aged at 1 000 °C for 24 h.The results show that the heat-treated alloy is composed of Nb solid solution(Nbss),(Nb,X)5Si3 and Cr2Nb phases.With the increase of heat-treatment temperature,previous Nbss dendrites transformed into equiaxed grains,and petal-like Nbss/(Nb,X)5Si3 eutectic colonies gradually changed into small(Nb,X)5Si3 particles distributed in Nbss matrix.A drastic change occurred in the morphology of the Laves phase after homogenizing treatment.Previously coarse Cr2Nb blocks dissolved during homogenizing at temperature above 1 300 °C,and then much finer and crowded Cr2Nb flakes precipitated in the Nbss matrix in cooling.Aging treatment at 1 000 °C for 24 h led to further precipitation of fine particles of Laves phase in Nbss matrix and made the difference in concentrations of Ti,Hf and Al in Nbss,(Nb,X)5Si3 and Cr2Nb phases reduced. 展开更多
关键词 homogenizing treatment aging treatment Nb-Ti-Cr-Si based ultrahigh temperature alloy microstructural evolution
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Improvement of Toughness of Ultrahigh Strength Steel Aermet 100 被引量:16
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作者 Liuding WANG Laizhu JIANG +2 位作者 Ming ZHU Xiao LIU Wangmin ZHOU 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2005年第5期710-714,共5页
The influence of double aging on the microstructure and mechanical properties of ultrahigh strength steel Aermet 100 was analyzed. Under the double aging, there is no apparent decrease in the strength of steel. Howeve... The influence of double aging on the microstructure and mechanical properties of ultrahigh strength steel Aermet 100 was analyzed. Under the double aging, there is no apparent decrease in the strength of steel. However, the impact fatigue life can be prolonged by 35.5% and dynamic fracture toughness be raised by 22.6% respectively, as compared with the normal aging. Based on the observation of microscopic structure, the physical mechanism of the prolongation of impact fatigue life and the enhancement of stability of the reverted austenite, AR, is analyzed further. The results show that this new technique is a breakthrough of combination optimization between strength and toughness for Aermet 100 steel. In the light of the current understanding on this subject, the volume fracture of soften and tough AR formed in process of heat preservation at higher temperature of double aging increases drastically. Moreover, during the treatment of lower temperature of double aging, the carbon separating from the martensitic ferrite will diffuse into AR, resulting that the martensitic brittleness decreases and the stability of AR increases. 展开更多
关键词 ultrahigh strength steel Aging treatment Impact fatigue life Dynamic fracture toughness
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Effects of Si on the stability of retained austenite and temper embrittlement of ultrahigh strength steels 被引量:9
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作者 Li-jun Wang Qing-wu Cai Hui-bin Wu Wei Yu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2011年第5期543-550,共8页
Effects of silicon (Si) content on the stability of retained austenite and temper embrittlement of ultrahigh strength steels were investigated using X-ray diffraction (XRD),transmission electron microscopy (TEM)... Effects of silicon (Si) content on the stability of retained austenite and temper embrittlement of ultrahigh strength steels were investigated using X-ray diffraction (XRD),transmission electron microscopy (TEM),and other experimental methods.The results show that Si can suppress temper embrittlement,improve temper resistance,and hinder the decomposition of retained austenite.Reversed austenite appears gradually with the increase of Si content during tempering.Si has a significant effect on enhancing carbon (C) partitioning and improving the stability of retained austenite.Si and C atoms are mutually exclusive in lath bainite,while they attract each other in austenite.ε-carbides are found in 1.8wt% Si steel tempered at 250℃,and they get coarsened obviously when tempered at 400℃,leading to temper embrittlement.Not ε-carbides but acicular or lath carbides lead to temper embrittlement in 0.4wt% Si steel,which can be inferred as cementites and composite compounds.Temper embrittlement is closely related to the decomposition of retained austenite and the formation of reversed austenite. 展开更多
关键词 SILICON ultrahigh strength steel retained austenite temper embrittlement reversed austenite
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Extensional Tectonic Framework of Post High and Ultrahigh Pressure Metamorphism in Dabieshan,China 被引量:5
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作者 Zhong Zengqiu Suo Shutian You Zhendong Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 《Journal of Earth Science》 SCIE CAS CSCD 1998年第1期3-7,共5页
The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones ... The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones surrounding the core of the Luotian dome, and the separation of the UHP, HP and epidote blueschist units by the detachment zones, which form the vertically stacking sheet like slices of the HP and UHP metamorphic rocks. From the core outwards, exist the HP and UHP rock barren Dabie complex, UHP unit, HP unit and epidote blueschist unit. The extension tectonics of post HP and UHP metamorphic event constrain the distribution and present configuration of the HP and UHP metamorphic rocks, and the extensional tectonic framework bears some similarities to the Cordillera metamorphic core complex. It is suggested that partial melting happened in the Dabie gneiss complex (DGC) and UHP unit contemporaneously with the extrusion of UHP metamorphic rocks into the lower-middle crust. The formation and emplacement of the migmatite and granites are the response to the change in thermal state, facilitating the transfer from the compressive regime to extensional regime in the crust. The large scale crustal extension and uplift and the accompanying anatexis in Dabieshan are probably related to the delamination and magmatic underplating in the mantle and the lower crust. 展开更多
关键词 high and ultrahigh pressure metamorphic rocks post collision extension tectonics Dabieshan.
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NORTH QAIDAM ULTRAHIGH PRESSURE METAMORPHIC (UHPM) BELT ON THE NORTHEASTERN QINGHAI-TIBET PLATEAU AND ITS EASTWARD EXTENSION 被引量:3
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作者 Yang Jingsui 1, Song Suguang 1, Wu Cailai 1, Shi Rendeng 1, Marc Jalivet 2(1 Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037, China 2 Department of Geology, University of Montpellier II, Montpellier, France) 《地学前缘》 EI CAS CSCD 2000年第S1期241-242,共2页
Eclogite was firstly discovered at the Da Qaidam region (Yang,et al., 1998), and then in the Xitieshan and Dulan regions in 1999, constituting an over 350km long high\|pressure metamorphic belt in the northeastern Qin... Eclogite was firstly discovered at the Da Qaidam region (Yang,et al., 1998), and then in the Xitieshan and Dulan regions in 1999, constituting an over 350km long high\|pressure metamorphic belt in the northeastern Qinghai—Tibet plateau. Eclogites occur as pods in the garnet\|muscovite gneiss of the Dakendaban Group (or called Shaliuhe Group in Dulan) of Upper Proterozoic age. In general, the pods of eclogite vary in size; most of them are less than 20m×10m, some large ones up to about 100m×50m. The eclogite\|hosted gneiss is pale\|gray in color, consisting mainly plagioclase and quartz, and minor muscovite (5%~10% in vol.) and garnet (1%~2%). Some of the country rocks of eclogite are mica\|quartz\|(feldspar) schist, quartzite, and ultramafic rocks, the latter also occur in blocks.Over 50 pods were found in a belt of 10km×3km in the Da Qaidam region (No.1 location). Only a few pods of eclogite were found in the Xitieshan region in 1999 field expedition (No.2 location). Eclogite in Dulan occurs in the Proterozoic strata of Shaliuhe Group (same as the Dakendaban Group but with a different name). The eclogites in the Dulan region (No.3 location) expose about 10km wide in SN and an unknown length in EW, and can be subdivided into two belts, the North Eclogite Belt of Dulan (NEBD) and the South Eclogite Belt of Dulan (SEBD). 展开更多
关键词 ECLOGITE UHP ultrahigh pressure METAMORPHISM COESITE dulan Da Qaidam QINGHAI Tibet
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Microstructural evolution and mechanical properties of an ultrahighstrength Al-Zn-Mg-Cu alloy via powder metallurgy and hot extrusion 被引量:8
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作者 CHEN Cun-guang HAN Wei-hao +5 位作者 QI Miao DONG Shi-peng LI Pei YANG Fang HAO Jun-jie GUO Zhi-meng 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第4期1195-1205,共11页
In this work,a novel ultrahigh-strength Al-10Zn-3.5Mg-1.5Cu alloy was fabricated by powder metallurgy followed by hot extrusion.Investigations on microstructural evolution and mechanical properties of the fabricated s... In this work,a novel ultrahigh-strength Al-10Zn-3.5Mg-1.5Cu alloy was fabricated by powder metallurgy followed by hot extrusion.Investigations on microstructural evolution and mechanical properties of the fabricated samples were carried out.The results show that the grain size of sintered samples matches with the powder particles after ball milling.The relative densities of sintered and hot extruded samples reach 99.1%and 100%,respectively.Owing to the comprehensive mechanism of grain refinement,aging and dispersion strengthening,the ultimate tensile strength,yield strength and elongation of the Al-10Zn-3.5Mg-1.5Cu alloy after hot extrusion and subsequent heat treatment achieve 810 MPa,770 MPa and 8%,respectively. 展开更多
关键词 powder metallurgy Al-Zn-Mg-Cu alloy ultrahigh strength hot extrusion
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Intercalating Ultrathin MoO_3 Nanobelts into MXene Film with Ultrahigh Volumetric Capacitance and Excellent Deformation for High-Energy-Density Devices 被引量:5
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作者 Yuanming Wang Xue Wang +5 位作者 Xiaolong Li Rong Liu Yang Bai Huanhao Xiao Yang Liu Guohui Yuan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2020年第9期109-122,共14页
The restacking hindrance of MXene films restricts their development for high volumetric energy density of flexible supercapacitors toward applications in miniature,portable,wearable or implantable electronic devices.A... The restacking hindrance of MXene films restricts their development for high volumetric energy density of flexible supercapacitors toward applications in miniature,portable,wearable or implantable electronic devices.A valid solution is construction of rational heterojunction to achieve a synergistic property enhancement.The introduction of spacers such as graphene,CNTs,cellulose and the like demonstrates limited enhancement in rate capability.The combination of currently reported pseudocapacitive materials and MXene tends to express the potential capacitance of pseudocapacitive materials rather than MXene,leading to low volumetric capacitance.Therefore,it is necessary to exploit more ideal candidate materials to couple with MXene for fully expressing both potentials.Herein,for the first time,high electrochemically active materials of ultrathin MoO3 nanobelts are intercalated into MXene films.In the composites,MoO3 nanobelts not only act as pillaring components to prevent restacking of MXene nanosheets for fully expressing the MXene pseudocapacitance in acidic environment but also provide considerable pseudocapacitive contribution.As a result,the optimal M/MoO3 electrode not only achieves a breakthrough in volumetric capacitance(1817 F cm-3 and 545 F g-1),but also maintains good rate capability and excellent flexibility.Moreover,the corresponding symmetric supercapacitor likewise shows a remarkable energy density of 44.6 Wh L-1(13.4 Wh kg-1),rendering the flexible electrode a promising candidate for application in high-energy-density energy storage devices. 展开更多
关键词 MXene MoO3 nanobelts Hybrid film ultrahigh volumetric capacitance Supercapacitors
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^(40)Ar/^(39)Ar Dating of Deformation Events and Reconstruction of Exhumation of Ultrahigh-Pressure Metamorphic Rocks in Donghai, East China 被引量:17
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作者 LI Jinyi, YANG Tiannan, CHEN Wen and ZHANG Sihong Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037E-mail: jyli@cags.net.cn 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2003年第2期155-168,共14页
Recent investigations reveal that the ultrahigh-pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile-brittle structural events during their exhumation. The e... Recent investigations reveal that the ultrahigh-pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile-brittle structural events during their exhumation. The earlier ductile deformation took place under the condition of amphibolite facies and the later transitional ductile-brittle deformation under the condition of greenschist facies. The hanging walls moved southeastward during both of these two events. The 40Ar/39Ar dating of muscovites from muscovite-plagioclase schists in the Haizhou phosphorous mine, which are structurally overlain by UHPM rocks, yields a plateau age of 218.0±2.9 Ma and isochron age of 219.8Ma, indicating that the earlier event of the ampibolite-facies deformation probably took place about 220 Ma ago. The 40Ar/39Ar dating of oriented amphiboles parallel to the movement direction of the hanging wall on a decollement plane yields a plateau age of 213.1±0.3 Ma and isochron age of 213.4±4.1 Ma, probably representing the age of the later event. The dating of pegmatitic biotites and K-feldspars near the decollement plane from the eastern Fangshan area yield plateau ages of 203.4±0.3 Ma, 203.6±0.4 Ma and 204.8±2.2 Ma, and isochron ages of 204.0±2.0 Ma, 200.6±3.1 Ma and 204.0±5.0 Ma, respectively, implying that the rocks in the studied area had not been cooled down to closing temperature of the dated biotites and K-feldspars until the beginning of the Jurassic (about 204 Ma). The integration of these data with previous chronological ages on the ultrahigh-pressure metamorphism lead to a new inference on the exhumation of the UHPM rocks. The UHPM rocks in the area were exhumed at the rate of 3-4 km/Ma from the mantle (about 80-100 km below the earth's surface at about 240 Ma) to the lower crust (at the depth of about 20-30km at 220 Ma), and at the rate of 1-2 km/Ma to the middle crust (at the depth of about 15 km at 213 Ma), and then at the rate of less than 1 km/Ma to the upper crust about 10 km deep at about 204 Ma. 展开更多
关键词 ultrahigh-pressure metamorphic rocks structural deformation 40Ar/39Ar dating EXHUMATION Donghai East China
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High- and Ultrahigh-pressure Metamorphism and Retrogressive Textures of Gneiss in the Donghai Area——Evidence from gneisses in drillhole ZK2304 被引量:12
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作者 LIU Fulai, XU Zhiqin, XU Huifen and YANG Jingsui Institute of Geology, CAGS, 26 Baiwanzhuang Rd., Beijing 100037 Zhu Xiling 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1999年第3期300-315,370,共17页
In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamo... In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamorphic reactions. In addition to garnet, jadeititic-clinopyroxene and rutile, other peak stage (M2) minerals in some gneisses include phengite, aragonite and coesite or quartz pseudomorphs after coesite. The typical peak-stage mineral assemblages in gneisses are characterized by garnet + jadeitic-clinopyroxene + rutile + coesite, garnet + jadeitic-clinopyroxene + phengite + rutile ± coesite and garnet + jadeitic-clinopyroxene + aragonite + rutile ± coesite. The grossular content (Gro) in garnet is high and may reach 50. 1 mol%. The SiO2 content of phengite ranges from 54.37% to 54.84% with 3.54-3.57 p.f.u. Quartz pseudomorphs after coesite occur as inclusions in garnet.The gneisses of the Donghai area have been subjected to multistage recrystallization and exhibit a closewise P-T evolutional path characterized by the near-isothermal decompression. The inclusion assemblage (Hb+Ep+Bi+Pl+Qz) within garnet and other minerals has recorded a pre-peak stage (Mi) epidote amphibole fades metamorphic event. High- and ultrahigh-pressure peak metamorphism (M2) took place at T=750-860℃ and P>2.7 GPa. The symplectitic assemblages after garnet, jadeitic-clinopyroxene and rutile imply a near-isothermal decompression metamorphism (M3, M4) during the rapid exhumation. Several lines of evidence of petrography and metamorphic reactions indicate that both gneisses and eclogites have experienced ultrahigh-pressure metamorphism in the Donghai area. This research may be of great significance for an in-depth study of the metamorphism and tectonic evolution in the Su-Lu ultrahigh-pressure metamorphic belt. 展开更多
关键词 GNEISS high- and ultrahigh-pressure metamorphism retrogressive texture drillhole Donghai area
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