Visco-elastic Properties of VES Diverting Acid for Carbonate Reservoirs

Storage modulus and loss modulus is the main performance index of visco-elastic properties.In this paper the storage modulus and loss modulus of a new diverting acid and their influencing factors were systematically investigated.Besides,the constitutive equations of the diverting acid at different temperatures were elicited from shearing experiments,which show that the visco-elastic surfactant(VES)acid system is a non-Newtonian power law fluid at low temperature and a Newtonian fluid at high temperature.The storage modulus and loss modulus at different temperatures,pH,and VES content in the acid are critical for the design of acid stimulation for oil well,especially when the VES acid is used in this field only on trial and the basic data are in urgent needed for the design and construction of the acidification stimulation.

Molecular simulation study of the microstructures and properties of pyridinium ionic liquid[HPy][BF_(4)]mixed with acetonitrile

The microstructures and thermodynamic properties of mixed systems comprising pyridinium ionic liquid[HPy][BF_(4)]and acetonitrile at different mole fractions were studied using molecular dynamics simulation in this work.The following properties were determined:density,self-diffusion coefficient,excess molar volume,and radial distribution function.The results show that with an increase in the mole fraction of[HPy][BF_(4)],the self-diffusion coefficient decreases.Additionally,the excess molar volume initially decreases,reaches a minimum,and then increases.The rules of radial distribution functions(RDFs)of characteristic atoms are different.With increasing the mole fraction of[HPy][BF_(4)],the first peak of the RDFs of HA1-F decreases,while that of CT6-CT6 rises at first and then decreases.This indicates that the solvent molecules affect the polar and non-polar regions of[HPy][BF_(4)]differently.

Research on the Construction of Intellectual Property System and Optimization of Business Environment in China

With the rapid development of globalization and information technology,intellectual property has been one of the key drivers of economic growth,and the construction of intellectual property system has become an important criterion for measuring the quality of business environment.This article is intended to explore the current status of intellectual property system construction in China,the challenges,and its relationship with the business environment,to propose the corresponding countermeasures and suggestions.The study finds that the legal system of intellectual property in China is gradually improving,and judicial and administrative protection are continuously strengthened.However,the challenges still remain such as frequent infringements,rights hard to protect and insufficient international cooperation.These issues not only affect the legitimate rights and interests of innovation entities,but also for the market fairness and the level of the business environment.Therefore,this article proposes that strengthening the perfection of the intellectual property legal system,enhancing intellectual property services and support capabilities,strengthening international cooperation and exchanges,and accelerating the cultivation of composite talents.It aims to provide theoretical references for the construction of intellectual property system and the optimization of the business environment,promote the high-quality development of economy and enhance the global competitiveness of the country.

谐和与有界噪声联合参激作用下的Visco-Elastic系统

研究了带visco＿elastic项的非线性系统,在谐和与有界噪声联合参激作用下的响应和稳定性问题· 用多尺度法分离了系统的快变项,并求出了系统的最大Liapunov指数和稳态概率密度函数,根据最大Liapunov指数可得系统解稳定的充分必要条件· 讨论了系统的visco＿elastic项对系统阻尼项和刚度项的贡献。

One-dimensional consolidation of visco-elastic aquitard due to withdrawal of deep-groundwater

One-dimensional consolidation of visco-elastic aquitard due to withdrawal of deep-groundwater was studied.Merchant model was used to simulate visco-elastic characteristic of aquitard.General solutions of the governing equation were obtained by applying Laplace transform with respect to time,and then the pore-pressure,strain and deformation of the aquitard could be calculated by Laplace inversion.A case was analyzed to validate the correctness of the present method.Finally,some consolidation properties of the problem were analyzed.Comparison of the average degree of consolidation defined by pore pressure with that defined by settlement shows that they are different and the maximum difference is 22.8%.The influences of parameters of Merchant model and the rate of the water level on the consolidation are great.The smaller the viscosity coefficient is,the later the rate of consolidation decreases.The rate of consolidation is decreased with the decrease of the rate of the water level fall.Therefore,the lagged effect of land subsidence should be considered in the actual project.

Heat and Mass Transfer in MHD Visco-Elastic Fluid Flow through a Porous Medium over a Stretching Sheet with Chemical Reaction

This paper presents the study of convective heat and mass transfer characteristics of an incompressible MHD visco-elastic fluid flow immersed in a porous medium over a stretching sheet with chemical reaction and thermal stratification effects. The resultant governing boundary layer equations are highly non-linear and coupled form of partial differential equations, and they have been solved by using fourth order Runge-Kutta integration scheme with Newton Raphson shooting method. Numerical computations are carried out for the non-dimensional physical parameters. Here a numerical has been carried out to study the effect of different physical parameters such as visco-elasticity, permeability of the porous medium, magnetic field, Grashof number, Schmidt number, heat source parameter and chemical reaction parameter on the flow, heat and mass transfer characteristics.

Vibration of Visco-Elastic Parallelogram Plate with Parabolic Thickness Variation

The main objective of the present investigation is to study the vibration of visco-elastic parallelogram plate whose thickness varies parabolically. It is assumed that the plate is clamped on all the four edges and that the thickness varies parabolically in one direction i.e. along length of the plate. Rayleigh-Ritz technique has been used to determine the frequency equation. A two terms deflection function has been used as a solution. For visco-elastic, the basic elastic and viscous elements are combined. We have taken Kelvin model for visco-elasticity that is the combination of the elastic and viscous elements in parallel. Here the elastic element means the spring and the viscous element means the dashpot. The assumption of small deflection and linear visco-elastic properties of “Kelvin” type are taken. We have calculated time period and deflection at various points for different values of skew angles, aspect ratio and taper constant, for the first two modes of vibration. Results are supported by tables. Alloy “Duralumin” is considered for all the material constants used in numerical

Effect of Non-Homogeneity on Thermally Induced Vibration of Orthotropic Visco-Elastic Rectangular Plate of Linearly Varying Thickness

The analysis presented here is to study the effect of non-homogeneity on thermally induced vibration of orthotropic visco-elastic rectangular plate of linearly varying thickness. Thermal vibrational behavior of non-homogeneous rectangular plates of variable thickness having clamped boundary conditions on all the four edges is studied. For non–homogeneity of the plate material, density is assumed to vary linearly in one direction. Using the method of separation of variables, the governing differential equation is solved. An approximate but quite convenient frequency equation is derived by using Rayleigh-Ritz technique with a two-term deflection function. Time period and deflection at different points for the first two modes of vibration are calculated for various values of temperature gradients, non- homogeneity constant, taper constant and aspect ratio. Comparison studies have been carried out with non-homogeneous visco-elastic rectangular plate to establish the accuracy and versatility.

ONE-DIMENSIONAL CONSOLIDATION OF LAYERED AND VISCO-ELASTIC SOILS UNDER ARBITRARY LOADING

Based on the layered visco-elastic soil model, according to the Terzaghi's one dimensional consolidation theory, by the method of Laplace transform and matrix transfer technique, the problems about the consolidation of layered and saturated visco-elastic soils under arbitrary loading were solved. Through deductions, the general solution, in the terms of layer thickness, the modulus and the coefficients of permeability and Laplacian transform's parameters was obtained. The strain and deformation of the layered and saturated visco-elastic soils under arbitrary loading can be calculated by Laplace inversion. According to the results of several numerical examples, the consolidation of visco-elastic soils logs behind that of elastic soils. The development of effective stress and the displacement is vibrant process under cyclic loading. Finally, an engineering case is studied and the results prove that the methods are very effective.

An analytic solution describing the visco-elastic deformation of coal pillars in room and pillar mine

Coal pillar deformation is typically nonlinear and time-dependent. The accurate prediction of this defor- mation has a vital importance for the successful implementation of mining techniques. These methods have proven very important as a way to excavate coal resources from under buildings, railways, or water bodies. Elastic and visco-elastic theory are employed with a Maxwell model to formulate an analytic solution for displacement of coal pillars in room and pillar mine. These results show that the visco-elastic solution adequately predicts the coal pillar deformation over time. We conclude that the visco-elastic solution can predict the coal pillar and roadway displacement from the measured geological parameters of the conditions in situ. Furthermore, this method would be useful for mine design, coal pillar support optimization, ground subsidence prediction, and coal pillar stability analysis.

Rheological Behaviour for Polymer Melts and Concentrated Solutions Part Ⅰ:A New Multiple Reptation Model to Predict the Nonlinear Visco-elasticity with Nagai Chain Constraints in Entangled Polymer Melts

An approach of stochastically statistical mechanics and a unified molecular theory of nonlinear viscoelasticity with constraints of Nagai chain entanglement for polymer melts have been proposed. A multimode model structure for a single polymer chain with n tail segments and N reversible entanglement sites on the test polymer chain is developed. Based on the above model structure and the mechanism of molecular flow by the dynamical reorganization of entanglement sites, the probability distribution function of the end-to-end vectr for a single polymer chain at entangled state and the viscoelastic free energy of deformation for polymer melts are calculated by using the method of the stochastically statistical mechanics. The four types of stress-strain relation and the memory function are derived from this thery. The above theoretical relations are verified by the experimentaf data for various polymer melts. These relations are found to be in good agreement with the experimental results

Properties and Characteristics of Regolith-Based Materials for Extraterrestrial Construction

The construction of extraterrestrial bases has become a new goal in the active exploration of deep space.Among the construction techniques,in situ resource-based construction is one of the most promising because of its good sustainability and acceptable economic cost,triggering the development of various types of extraterrestrial construction materials.A comprehensive survey and comparison of materials from the perspective of performance was conducted to provide suggestions for material selection and optimization.Thirteen types of typical construction materials are discussed in terms of their reliability and applicability in extreme extraterrestrial environment.Mechanical,thermal and optical,and radiation-shielding properties are considered.The influencing factors and optimization methods for these properties are analyzed.From the perspective of material properties,the existing challenges lie in the comprehensive,long-term,and real characterization of regolith-based construction materials.Correspondingly,the suggested future directions include the application of high-throughput characterization methods,accelerated durability tests,and conducting extraterrestrial experiments.

Physical,mechanical and thermal properties of vacuum sintered HUST-1 lunar regolith simulant

Establishing a base on the Moon is one of the new goals of human lunar exploration in recent years.Sintered lunar regolith is one of the most potential building materials for lunar bases.The physical,mechanical and thermal properties of sintered lunar regolith are vital performance indices for the structural design of a lunar base and analysis of many critical mechanical and thermal issues.In this study,the HUST-1 lunar regolith simulant(HLRS)was sintered at 1030,1040,1050,1060,1070,and 1080℃.The effect of sintering temperature on the compressive strength was investigated,and the exact value of the optimum vacuum sintering temperature was determined between 1040 and 1060℃.Then,the microstructure and material composition of vacuum sintered HLRS at different temperatures were characterized.It was found that the sintering temperature has no significant effect on the mineral composition in the temperature range of 1030-1080℃.Besides,the heat capacity,thermal conductivity,and coefficient of thermal expansion(CTE)of vacuum sintered HLRS at different temperatures were investigated.Specific heat capacity of sintered samples increases with the increase of test temperature within the temperature range from-75 to 145℃.Besides,the thermal conductivity of the sintered sample is proportional to density.Finally,the two temperatures of 1040 and 1050℃were selected for a more detailed study of mechanical properties.The results showed that compressive strength of sintered sample is much higher than tensile strength.This study reveals the effects of sintering temperature on the physical,mechanical and thermal properties of vacuum sintered HLRS,and these material parameters will provide support for the construction of future lunar bases.

Rayleigh-type wave propagation in incompressible visco-elastic media under initial stress

Propagation of Rayleigh-type surface waves in an incompressible visco-elastic material over incompressible visco-elastic semi-infinite media under the effect of initial stresses is discussed. The dispersion equation is determined to study the effect of differ- ent types of parameters such as inhomogeneity, initial stress, wave number, phase velocity, damping factor, visco-elasticity, and incompressibility on the Rayleigh-type wave prop- agation. It is found that the affecting parameters have a significant effect on the wave propagation. Cardano＇s and Ferrari＇s methods are deployed to estimate the roots of dif- ferential equations associated with layer and semi-infinite media. The MATHEMATICA software is applied to explicate the effect of these parameters graphically.

Visco-elastic fluid flow past an infinite vertical porous plate in the presence of first-order chemical reaction

An analysis has been developed to study the unsteady free convection flow of an incompressible visco-elastic fluid on a continuously moving vertical porous plate in the presence of a first-order chemical reaction. The governing equations are solved numerically using an implicit finite difference technique. The obtained numerical solutions are compared with the analytical solutions. The velocity profiles are presented. A parametric analysis is performed to illustrate the influences of the visco-elastic parameter, the dimensionless chemical reaction parameter, and the plate moving velocity on the steady state velocity profiles, the time dependent friction coefficient, the Nusselt number, and the Sherwood number.

Experimental study on visco-elastic constitutive relationship and its parameters for geogrids

Geogrids are used as reinforcement materials widely in geotechnical and civil engineering fields. In this paper, a series of comparative tests on creep behavior of specific geoOgrids are conducted in the laboratory under different combinations of loading levels and environmental temperature. Based on the test results,comparative analyses are made to study long-term behaviors of isochronous load-strain curves, creep curves and relaxation curves for the specified geogrids. Furthermore, a constitutive model based on theory of visco-elasticity and tests results is proposed for geogrids and a rational procedure is presented in detail for determining the relevant parameters of the proposed model. Finally, the effect of tests temperature on model parameter values is investigated.

HEMORRHEOLOGY, VISCO-ELASTICITY AND THIXOTROPY IN CEREBRAL THROMBOSIS

In this study, we used blood rheometer type HT-I to determine blood viscosity, plasma viscosity, hematocrit, blood red cell visco-elasticity and thixotropy in 70 cases with cerebral thrombosis, compared with normal control group in order to study the relationship between their alteration and cerebral thrombosis blood and plasma viscosity were higher in the patients than in normal control. Hysteresis loop analysis showed that the red blood cell’s visco-elasticity, thixotropy and deformity decrease.

High-throughput calculations combining machine learning to investigate the corrosion properties of binary Mg alloys

Magnesium(Mg)alloys have shown great prospects as both structural and biomedical materials,while poor corrosion resistance limits their further application.In this work,to avoid the time-consuming and laborious experiment trial,a high-throughput computational strategy based on first-principles calculations is designed for screening corrosion-resistant binary Mg alloy with intermetallics,from both the thermodynamic and kinetic perspectives.The stable binary Mg intermetallics with low equilibrium potential difference with respect to the Mg matrix are firstly identified.Then,the hydrogen adsorption energies on the surfaces of these Mg intermetallics are calculated,and the corrosion exchange current density is further calculated by a hydrogen evolution reaction(HER)kinetic model.Several intermetallics,e.g.Y_(3)Mg,Y_(2)Mg and La_(5)Mg,are identified to be promising intermetallics which might effectively hinder the cathodic HER.Furthermore,machine learning(ML)models are developed to predict Mg intermetallics with proper hydrogen adsorption energy employing work function(W_(f))and weighted first ionization energy(WFIE).The generalization of the ML models is tested on five new binary Mg intermetallics with the average root mean square error(RMSE)of 0.11 eV.This study not only predicts some promising binary Mg intermetallics which may suppress the galvanic corrosion,but also provides a high-throughput screening strategy and ML models for the design of corrosion-resistant alloy,which can be extended to ternary Mg alloys or other alloy systems.

Thermal Effect on Free Vibration of Non-Homogeneous Orthotropic Visco-Elastic Rectangular Plate of Parabolically Varying Thickness

A simple model presented here is to study the thermal effect on vibration of non-homogeneous orthotropic visco-elastic rectangular plate of parabolically varying thickness having clamped boundary conditions on all the four edges. For non-homogeneity of the plate material, density is assumed to vary linearly in one direction. Using the separation of variables method, the governing differential equation has been solved for vibration of non-homogeneous orthotropic viscoelastic rectangular plate. An approximate frequency equation is derived by using Rayleigh-Ritz technique with a two-term deflection function. Results are calculated for time period and deflection at different points, for the first two modes of vibration, for various values of temperature gradients, non-homogeneity constant, taper constant and aspect ratio and shown by graphs.

A review on the multi-scaled structures and mechanical/thermal properties of tool steels fabricated by laser powder bed fusion additive manufacturing

The laser powder bed fusion(LPBF) process can integrally form geometrically complex and high-performance metallic parts that have attracted much interest,especially in the molds industry.The appearance of the LPBF makes it possible to design and produce complex conformal cooling channel systems in molds.Thus,LPBF-processed tool steels have attracted more and more attention.The complex thermal history in the LPBF process makes the microstructural characteristics and properties different from those of conventional manufactured tool steels.This paper provides an overview of LPBF-processed tool steels by describing the physical phenomena,the microstructural characteristics,and the mechanical/thermal properties,including tensile properties,wear resistance,and thermal properties.The microstructural characteristics are presented through a multiscale perspective,ranging from densification,meso-structure,microstructure,substructure in grains,to nanoprecipitates.Finally,a summary of tool steels and their challenges and outlooks are introduced.