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L-shell x-ray fluorescence relative intensities for elements with 62≤Z≤83 at 18 keV and 23 keV by synchrotron radiation
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作者 M Alqadi S AL-Humaidi +1 位作者 H Alkhateeb F Alzoubi 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第8期270-273,共4页
The relative intensities of L-subshell x-ray fluorescence(XRF)for elements with atomic numbers 62≤Z≤83 were measured at two excitation energies,18 keV and 23 keV,using a synchrotron radiation source at a beamline of... The relative intensities of L-subshell x-ray fluorescence(XRF)for elements with atomic numbers 62≤Z≤83 were measured at two excitation energies,18 keV and 23 keV,using a synchrotron radiation source at a beamline of the Synchrotron Light Center for Experimental Science and Applications in the Middle East(SESAME),Jordan.The experimentally measured results of the relative intensities were compared with the calculated results using the subshell fluorescence yield and the Coster-Kronig transition probabilities recommended by Campbell and the values based on the Dirac-Hartree-Slater model by Puri.The experimental and theoretical results are in agreement.In this work,L XRF relative intensities for the elements Sm,Gd,Tb,Er,Ta,W,Re,Hg,Pb and Bi at energies of 18 keV and 23 keV were measured. 展开更多
关键词 L shell x-ray fluorescence(XRF) relative intensities synchrotron radiation
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Glancing incidence x-ray fluorescence spectrometry based on a single-bounce parabolic capillary
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作者 邵尚坤 李惠泉 +4 位作者 袁天语 孙学鹏 华路 刘志国 孙天希 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第8期247-250,共4页
Glancing incidence x-ray fluorescence spectrometry using a single-bounce parabolic capillary is proposed for the analysis of layered samples.The divergence of the x-ray beam was 0.33 mrad.In this paper,we used this in... Glancing incidence x-ray fluorescence spectrometry using a single-bounce parabolic capillary is proposed for the analysis of layered samples.The divergence of the x-ray beam was 0.33 mrad.In this paper,we used this instrumental setup to analyze a Si single crystal and a 50 nm HfO_(2) single-layer film deposited on a Si substrate. 展开更多
关键词 single-bounce parabolic capillary glancing incident x-ray fluorescence(GIXRF) atomic layer deposition film analysis
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Accuracy analysis of iron content of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum
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作者 WANG Jingjing CHEN Yanfei 《Baosteel Technical Research》 CAS 2023年第4期35-40,共6页
The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectro... The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectrometry, sometimes it exceeds the quality control limit.Influences, such as current, voltage, equipment(internal circulating water, 10%CH4+90%Ar, and vacuum) checking, instrument monitoring, sample cleaning, and oper-ators, were investigated by means of 6-sigma and lean operations to improve accuracy. 展开更多
关键词 x-ray fluorescence spectrometer Lspectrum galvanized coating iron content
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Elemental composition x-ray fluorescence analysis with a TES-based high-resolution x-ray spectrometer
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作者 吴秉骏 夏经铠 +4 位作者 张硕 傅强 章辉 谢晓明 刘志 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期67-73,共7页
The accurate analysis of the elemental composition plays a crucial role in the research of functional materials.The emitting characteristic x-ray fluorescence(XRF)photons can be used for precisely discriminating the s... The accurate analysis of the elemental composition plays a crucial role in the research of functional materials.The emitting characteristic x-ray fluorescence(XRF)photons can be used for precisely discriminating the specified element.The detection accuracy of conventional XRF methodology using semiconductor detector is limited by the energy resolution,thus posing a challenge in accurately scaling the actual energy of each XRF photon.We adopt a novel high-resolution x-ray spectrometer based on the superconducting transition-edge sensor(TES)for the XRF spectroscopy measurement of different elements.Properties including high energy resolution,high detection efficiency and precise linearity of the new spectrometer will bring significant benefits in analyzing elemental composition via XRF.In this paper,we study the Ledge emission line profiles of three adjacent rare earth elements with the evenly mixed sample of their oxide components:terbium,dysprosium and holmium.Two orders of magnitude better energy resolution are obtained compared to a commercial silicon drift detector.With this TES-based spectrometer,the spectral lines overlapped or interfered by background can be clearly distinguished,thus making the chemical component analysis more accurate and quantitative.A database of coefficient values for the line strength of the spectrum can then be constructed thereafter.Equipped with the novel XRF spectrometer and an established coefficient database,a direct analysis of the composition proportion of a certain element in an unknown sample can be achieved with high accuracy. 展开更多
关键词 x-ray emission spectra and fluorescence superconducting transition-edge sensor rare earth elements chemical composition analysis
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Potential Applications of X-ray Fluorescence Core Scanner in Elemental Analyses of the Muddy Sediments on the Coastal Shelves of China and in Ecological Study 被引量:2
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作者 ZHOU Xin SUN Liguang +1 位作者 LIU Yi WANG Yuhong 《Journal of Ocean University of China》 SCIE CAS 2013年第4期619-623,共5页
Large areas of muddy sediments on the coastal shelves of China provide important samples for studying climate and ecological changes. Analysis of a large number of such samples, which is essential for systematic study... Large areas of muddy sediments on the coastal shelves of China provide important samples for studying climate and ecological changes. Analysis of a large number of such samples, which is essential for systematic study on environmental information recorded in mud areas because of complicated sedimentary environment and variable sedimentary rate, requires a fast and economical method. In this study, we investigated the potential of X-ray fluorescence core scanner (XRFS), a fast analytical instrument for measuring the elemental concentrations of muddy sediments, and observed a significant correlation between the element concentrations of muddy sediments determined by regular X-ray fluorescence spectrometer (XRF) and XRFS, respectively. The correlations are mainly determined by excitation energy of elements, but also influenced by solubility of element ions. Furthermore, we found a striking link between A1 concentrations and marine-originated organic carbon (MOC), a proxy of marine primary productivity. This indicates that MOC is partly controlled by sedimentary characteristics. Therefore, XRFS method has a good potential in fast analysis of a large number of muddy sediment samples, and it can also be used to calibrate MOC in ecological study of coastal seas. 展开更多
关键词 x-ray fluorescence core scanner x-ray fluorescence spectrometer muddy sediment marine-originated organic carbon ecological study
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Geochemical analysis of marine sediments using fused glass disc by X-ray fluorescence spectrometry 被引量:8
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作者 夏宁 张勤 +1 位作者 姚德 李国会 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2008年第4期475-479,共5页
A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sedim... A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard (for the trace elements). The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% (n=12). 展开更多
关键词 marine sediment x-ray fluorescence spectrometry geochemical analysis multi-element analysis
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Elemental and proximate analysis of coal by x-ray fluorescence assisted laser-induced breakdown spectroscopy 被引量:5
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作者 Zhihui TIAN Xiaolin LI +9 位作者 Gang WANG Lei ZHANG Jiaxuan LI Shuqing WANG Yu BAI Wanfei ZHANG Han YUE Xiaofei MA Wangbao YIN Suotang JIA 《Plasma Science and Technology》 SCIE EI CAS CSCD 2022年第8期55-63,共9页
Although laser-induced breakdown spectroscopy(LIBS),as a fast on-line analysis technology,has great potential and competitiveness in the analysis of chemical composition and proximate analysis results of coal in therm... Although laser-induced breakdown spectroscopy(LIBS),as a fast on-line analysis technology,has great potential and competitiveness in the analysis of chemical composition and proximate analysis results of coal in thermal power plants,the measurement repeatability of LIBS needs to be further improved due to the difficulty in controlling the stability of the generated plasmas at present.In this paper,we propose a novel x-ray fluorescence(XRF) assisted LIBS method for high repeatability analysis of coal quality,which not only inherits the ability of LIBS to directly analyze organic elements such as C and H in coal,but also uses XRF to make up for the lack of stability of LIBS in determining other inorganic ash-forming elements.With the combination of elemental lines in LIBS and XRF spectra,the principal component analysis and the partial least squares are used to establish the prediction model and perform multi-elemental and proximate analysis of coal.Quantitative analysis results show that the relative standard deviation(RSD) of C is 0.15%,the RSDs of other elements are less than 4%,and the standard deviations of calorific value,ash content,sulfur content and volatile matter are 0.11 MJ kg,0.17%,0.79% and 0.41%respectively,indicating that the method has good repeatability in determination of coal quality.This work is helpful to accelerate the development of LIBS in the field of rapid measurement of coal entering the power plant and on-line monitoring of coal entering the furnace. 展开更多
关键词 laser-induced breakdown spectroscopy(LIBS) x-ray fluorescence spectrometry(XRF) high repeatability measurement spectral calibration instability analysis
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Use of portable X-ray fluorescence in the analysis of surficial sediments in the exploration of hydrothermal vents on the Southwest Indian Ridge 被引量:5
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作者 LIAO Shili TAO Chunhui +3 位作者 LI Huaiming ZHANG Guoyin LIANG Jin YANG Weifang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2017年第7期66-76,共11页
Hydrothermal plumes released from the eruption of sea floor hydrothermal fluids contain large amounts of oreforming materials. They precipitate within certain distances from the hydrothermal vent. Six surficial sedime... Hydrothermal plumes released from the eruption of sea floor hydrothermal fluids contain large amounts of oreforming materials. They precipitate within certain distances from the hydrothermal vent. Six surficial sediment samples from the Southwest Indian Ridge(SWIR) were analyzed by a portable X-ray fluorescence(PXRF) analyzer on board to find a favorable method fast and efficient enough for sea floor sulfide sediment geochemical exploration. These sediments were sampled near, at a moderate distance from, or far away from hydrothermal vents. The results demonstrate that the PXRF is effective in determining the enrichment characteristics of the oreforming elements in the calcareous sediments from the mid-ocean ridge. Sediment samples(〉40 mesh) have high levels of elemental copper, zinc, iron, and manganese, and levels of these elements in sediments finer than 40 mesh are lower and relatively stable. This may be due to relatively high levels of basalt debris/glass in the coarse sediments, which are consistent with the results obtained by microscopic observation. The results also show clear zoning of elements copper, zinc, arsenic, iron, and manganese in the surficial sediments around the hydrothermal vent. Sediments near the vent show relatively high content of the ore-forming elements and either high ratios of copper to iron content and zinc to iron content or high ratios of copper to manganese content and zinc to manganese content. These findings show that the content of the ore-forming elements in the sediments around hydrothermal vents are mainly influenced by the distance of sediments to the vent, rather than grain size. In this way, the PXRF analysis of surface sediment geochemistry is found to satisfy the requirements of recognition geochemical anomaly in mid-ocean ridge sediments. Sediments with diameters finer than 40 mesh should be used as analytical samples in the geochemical exploration for hydrothermal vents on mid-oceanic ridges. The results concerning copper, zinc, arsenic, iron, and manganese and their ratio features can be used as indicators in sediment geochemical exploration of seafloor sulfides. 展开更多
关键词 mid-ocean ridge sediments hydrothermal activity portable x-ray fluorescence geochemical exploration
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Simulation Study of Quantitative X-Ray Fluorescence Analysis of Ore Slurry Using Partial Least-Squares Regression 被引量:1
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作者 林才寿 毛莉 +1 位作者 黄宁 安竹 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第5期427-430,共4页
X-ray fluorescence (XRF) in combination with partial least-squares (PLS) regression was employed to analyze the ore slurry grade. Using the Monte Carlo simulation code PENELOPE, X-ray fluorescence spectra of ore s... X-ray fluorescence (XRF) in combination with partial least-squares (PLS) regression was employed to analyze the ore slurry grade. Using the Monte Carlo simulation code PENELOPE, X-ray fluorescence spectra of ore samples were obtained. Good accuracy was achieved when this method was used to analyze elements with concentrations of several percent or above. It was demonstrated that the more the number of X-ray fluorescence spectra used to calibrate, the better the obtained accuracy. In this method detector resolution was found to have little or no effect on the results of quantitative analysis. The effect of the concentration of water was investigated as well, and it was found to have little influence on the results. 展开更多
关键词 x-ray fluorescence PLS ore slurry grade Monte Carlo simulation
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Spatial resolution and image processing for pinhole camera-based X-ray fluorescence imaging: a simulation study 被引量:1
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作者 Ze He Ning Huang +2 位作者 Peng Wang Zi-Han Chen Bo Peng 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2022年第5期135-153,共19页
Spatial resolution and image-processing methods for full-field X-ray fluorescence(FF-XRF)imaging using X-ray pinhole cameras were studied using Geant4simulations with different geometries and algorithms for image reco... Spatial resolution and image-processing methods for full-field X-ray fluorescence(FF-XRF)imaging using X-ray pinhole cameras were studied using Geant4simulations with different geometries and algorithms for image reconstruction.The main objectives were:(1)calculating the quantum efficiency curves of specific cameras,(2)studying the relationships between the spatial resolution and the pinhole diameter,magnification,and camera binning value,and(3)comparing image-processing methods for pinhole camera systems.Several results were obtained using a point and plane source as the X-ray fluorescence emitter and an array of 100×100 silicon pixel detectors as the X-ray camera.The quantum efficiency of a back-illuminated deep depletion(BI-DD)structure was above 30%for the XRF energies in the 0.8–9 keV range,with the maximum of 93.7%at 4 keV.The best spatial resolution of the pinhole camera was 24.7μm and 31.3 lp/mm when measured using the profile function of the point source,with the diameter of 20μm,magnification of 3.16,and camera bin of 1.A blind deconvolution algorithm with Gaussian filtering performed better than the Wiener filter and Richardson iterative methods on FF-XRF images,with the signal-to-noise ratio of 7.81 dB and improved signalto-noise ratio of 7.24 dB at the diameter of 120μm,magnification of 1.0,and camera bin of 1. 展开更多
关键词 Full-field x-ray fluorescence(FF-XRF) x-ray pinhole camera Spatial resolution Image processing
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Preliminary determination of calcium,phosphorus,and the calcium/phosphorus ratio in cortical bone of Chinstrap penguin using synchrotron X-ray fluorescence analysis 被引量:1
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作者 谢周清 程帮波 +3 位作者 孙立广 黄玉营 何伟 赵三平 《Chinese Journal of Polar Science》 2006年第1期48-54,共7页
Synchrotron radiation X-ray fluorescence (SR-XRF) approach was applied to analyzing of Chinstrap penguin ( Pygoscelis Antarctica) cortical bone. The method enabled the in situ determination of Ca and P concentrati... Synchrotron radiation X-ray fluorescence (SR-XRF) approach was applied to analyzing of Chinstrap penguin ( Pygoscelis Antarctica) cortical bone. The method enabled the in situ determination of Ca and P concentrations and the Ca/P ratio in cortical bone. The preliminary results show that : ( 1 ) there is the bone site-related difference for Ca and P concentrations. The mean values for the investigated parameters ( on a dry-weight basis) are: 30.7% (Ca) and 14.9% (P) for the femoral cortical bone, 21.4% (Ca) and 11.5% (P) for wing cortical bone. (2) The variation for the Ca/P ratio in cortical bone is lower than those for Ca and P separately. This is in agreement with the previous report that the specificity of the Ca/P ratio is better than that of Ca and P concentrations and is more reliable for the diagnosis of bone disorders. The authors suggest that further studies be conducted to establish norreal values of Ca, P and Ca/P ratio for polar animals and provide a basis for the diagnosis of bone disorders. 展开更多
关键词 synchrontron radiation x-ray fluorescence (SR-XRF) PENGUIN bone Ca P and Ca/P ratio.
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Determination of Element Levels of Lagoon from Townships near Cocody City Abidjan Côte D’Ivoire Using Energy Dispersive X-Ray Fluorescence 被引量:1
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作者 Alfred Djoman Djama Agbo Koudou Djagouri +1 位作者 Jean-Claude Olkalé Brigui Konin Pierre-Claver Kakou 《World Journal of Nuclear Science and Technology》 2021年第2期109-118,共10页
Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, ... Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water. 展开更多
关键词 Ebrie Lagoon POLLUTION Heavy Metals Energy Dispersive x-ray fluorescence
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X-ray fluorescence spectrometry determination of open-hearth furnace slag by pressed powder briquetting
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作者 ZHANG Qiao TIAN Yi-Guang GUO Wu-Xue 《China Foundry》 SCIE CAS 2006年第1期36-40,共5页
A rapid analysis method of determining content of eight compounds of open-hearth furnace slag was developed using X-ray fluorescence spectrometry and pressed powder briquettes. Matrix effect was corrected using theore... A rapid analysis method of determining content of eight compounds of open-hearth furnace slag was developed using X-ray fluorescence spectrometry and pressed powder briquettes. Matrix effect was corrected using theoretical alpha coefficient. Grains-size effect was eliminated by optimized sample preparation technique parameters. Mineral effect was corrected with standard curve of specially made standard samples. The analysis results of TiO2, TFe, SiO2, MgO, Al2O3, CaO, MnO and P2O5 in slag samples showed that both precision and accuracy are comparable with that of chemical method. 展开更多
关键词 x-ray fluorescence spectrometry SLAG powder briquetting
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X-RAY FLUORESCENCE SPECTRA ANALYSIS ON THE STRUCTURE AROUND Ti^(4+) OF BaO-SiO_2-B_2O_3-TiO_2 SYSTEM GLASSES
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作者 宋晓岚 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2000年第4期43-47,共5页
The structure around Ti^(4+) in Bao-SiO_2 -B_2O_3-TiO_2 had been studied by X-ray fluorescence spectra. The results show that the Ti^(4+) mainly exists in the [TiO_4] and enters the network of [SiO_4]. [TiO_4] has the... The structure around Ti^(4+) in Bao-SiO_2 -B_2O_3-TiO_2 had been studied by X-ray fluorescence spectra. The results show that the Ti^(4+) mainly exists in the [TiO_4] and enters the network of [SiO_4]. [TiO_4] has the tendency to change to [TiO_6] with the increase of TiO_2 con-tent. When the TiO_2 content increases to about 20mol% the tendency reaches its maximum. 展开更多
关键词 titanium barium boronsilicate glasses Ti^(4+) structural state x-ray fluorescence spectra analysis (XRF)
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SMONTE CARLO CALCULATION FOR CALIBRATION FUNCTIONS IN TOTAL REFLECTION X-RAY FLUORESCENCE SPECTROMETRY
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作者 范钦敏 刘亚雯 魏成连 《Nuclear Science and Techniques》 SCIE CAS CSCD 1995年第1期14-17,共4页
Simulation approach includes such processes as photon emissions from X-ray tube with a spectral distribution, total reflection on the sample support, photoelectric effect in thin layer sample, as well as characteristi... Simulation approach includes such processes as photon emissions from X-ray tube with a spectral distribution, total reflection on the sample support, photoelectric effect in thin layer sample, as well as characteristic line absorption and detection. The calculation results are in agreement with experimental ones. 展开更多
关键词 Total reflection x-ray fluorescence analysis Calibration function Monte Carlo simulation
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Apply X-Ray Fluorescence and γ-Ray Spectroscopy to Analyze Igneous and Sedimentary Environmental Samples of Al-Atawilah (Al-Baha), Saudi Arabia
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作者 Bashayer M. Al-Zahrani Haifa S. Alqannas Safia H. Hamidalddin 《Journal of Geoscience and Environment Protection》 2020年第11期139-149,共11页
Igneous and sedimentary rocks contain an amount of natural radioactivity (NORM). U-238, Th-232 and their decay products, and K-40 are important sources of gamma-radiation. Knowledge of the radionuclide content of rock... Igneous and sedimentary rocks contain an amount of natural radioactivity (NORM). U-238, Th-232 and their decay products, and K-40 are important sources of gamma-radiation. Knowledge of the radionuclide content of rocks is necessary to estimate the exposure of the population to the radiation. Many types of rocks are used in building and industries, thus the radiation detection is important, it provides a baseline map of levels of the radioactivity in the study region. The purpose of this study is to evaluate the activity concentrations of the natural radionuclides (U-238 (Ra-226), Th-232 and K-40) and the fallout nuclide (Cs-137) (if found) in thirty samples of igneous and sedimentary rocks of Al-Atawilah (Al-Baha). The samples were collected and prepared during 2018/2019, and analyzed with a good experimental instrument (High energy resolution γ-ray spectroscopy with HPGe detector), also these rock samples were analyzed with X-ray fluorescence to subdivided these rocks based on the major oxides proportions contained of each sample. The mean activity concentrations of naturally radionuclides were found in the igneous rock samples varied depending on the type of the igneous rock. For sedimentary rock samples, the activity concentrations were found high for quartz sandstone sample, which may be due to its high proportion of SiO<sub>2</sub> and K<sub>2</sub>O. The estimated mean values of absorbed dose rate are within the permissible limit value. The findings indicate high dose level values in granite (rhyolite) and most of diorite (andesite) igneous rock samples while gabbro (basalt) igneous rock samples (except for one sample) record low levels of dose rate. All sedimentary rock samples have low dose rate (except for the quartz sand-stone sample). 展开更多
关键词 Classification of Igneous and Sedimentary Rocks x-ray fluorescence Spectroscopy Gamma-Ray Spectroscopy Activity Concentration Absorbed Dose Rate
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Chemical Composition Assessment by Wavelength Dispersive X-Ray Fluorescence of Agricultural Soils in the Mining Town of Moanda, Gabon
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作者 Albert Novy Messi Me Ndong Adam Bouraïma +2 位作者 Crislain Bissielou Jean-Jacques Anguile Thomas Makani 《Journal of Agricultural Chemistry and Environment》 2021年第3期345-358,共14页
This work focuses on the analysis of the chemical composition of soils dedicated to agriculture in order to assess the impacts of manganese mining activity in the city of Moanda in South-East Gabon. The result of the ... This work focuses on the analysis of the chemical composition of soils dedicated to agriculture in order to assess the impacts of manganese mining activity in the city of Moanda in South-East Gabon. The result of the analysis obtained using wavelength dispersive X-ray fluorescence revealed the presence of twenty-seven elements in the seventeen soil samples collected namely: Na, K, Rb, Mg, Ca, Sr, Ba, Ti, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Cr, Mn, Al, O, C, P, S, Si, I, Ac and Th. Iron (Fe), aluminum (Al) and manganese (Mn) were respectively higher. The practice of agriculture near mining sites is not without risks for the quality of agricultural products and the health of the population. 展开更多
关键词 Metallic Trace Elements x-ray fluorescence Agricultural Soils
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Quantitative energy-dispersive X-ray fluorescence analysis for unknown samples using full-spectrum least-squares regression 被引量:6
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作者 Yong-Li Liu Qing-Xian Zhang +2 位作者 Jian Zhang Hai-Tao Bai Liang-Quan Ge 《Nuclear Science and Techniques》 SCIE CAS CSCD 2019年第3期149-159,共11页
The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectr... The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectrum evaluation method is able to obtain the background-corrected and interference-free net peaks, which is significant for quantization analyses. A variety of analytical parameters and functions to describe the features of the fluorescence spectra of pure elements are used and established, such as the mass absorption coefficient, the Gi factor, and fundamental fluorescence formulas. The FSLS iterative program was compiled in the C language. The content of each component should reach the convergence criterion at the end of the calculations. After a basic theory analysis and experimental preparation, 13 national standard soil samples were detected using a spectrometer to test the feasibility of using the algorithm. The results show that the calculated contents of Ti, Fe, Ni, Cu, and Zn have the same changing tendency as the corresponding standard content in the 13 reference samples. Accuracies of 0.35% and 14.03% are obtained, respectively, for Fe and Ti, whose standard concentrations are 8.82% and 0.578%, respectively. However, the calculated results of trace elements (only tens of lg/g) deviate from the standard values. This may be because of measurement accuracy and mutual effects between the elements. 展开更多
关键词 Energy-dispersive x-ray fluorescence analysis Full-spectrum LEAST-SQUARES METHOD Effective atomic number Mass attenuation coefficient Fundamental parameter METHOD
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Impact of Different Grinding Aids on Standard Deviation in X-Ray Fluorescence Analysis of Cement Raw Meal 被引量:3
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作者 Andrew Aondoaver Tyopine Aondo Joseph Wangum Edwin Ameh Idoko 《American Journal of Analytical Chemistry》 2015年第5期492-494,共3页
X-ray fluorescence (XRF) analysis utilizes particle size which is resulted from milling of a material. The milling ensures uniform and fine grained powder. The finer and more uniform the particle size is, the better t... X-ray fluorescence (XRF) analysis utilizes particle size which is resulted from milling of a material. The milling ensures uniform and fine grained powder. The finer and more uniform the particle size is, the better the result and easier it is for material quality control. To ensure uniformity in particle size and finer powder, a comparative analysis was conducted with different grinding aids and pressed pellet method was used in obtaining analysis results. Pressed pellets of cement raw meal sample milled with different grinding aids (graphite, aspirin and lithium borate) were subjected to XRF. Graphite produced better particle size uniformity with a corresponding standard deviation that made quality control of raw meal easier and better than aspirin and lithium borate. 展开更多
关键词 x-ray fluorescence Pressed PELLETS Standard Deviation GRINDING AID Particle Size UNIFORMITY Comparative Analysis Cement RAW MEAL Quality Control
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Analysis of Heavy Metals in Human Scalp Hair Using Energy Dispersive X-Ray Fluorescence Technique 被引量:1
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作者 Peter O. Onuwa Lami A. Nnamonu +1 位作者 Ishaq S. Eneji Rufus Sha’Ato 《Journal of Analytical Sciences, Methods and Instrumentation》 2012年第4期187-193,共7页
Analysis of six heavy metals (Cr, Mn, Ni, Cu, Zn and Mo) in human scalp hair was carried out among various occupational distributions to ascertain their heavy metal burden, using energy dispersive x-ray fluorescence t... Analysis of six heavy metals (Cr, Mn, Ni, Cu, Zn and Mo) in human scalp hair was carried out among various occupational distributions to ascertain their heavy metal burden, using energy dispersive x-ray fluorescence technique (ED-XRF). The result of the analysis shows that mean concentrations (mg/kg) of heavy metals obtained were as follows: Cr = 17.1 ± 12.7;Mn = 3.11 ± 0.50;Ni = 11.3 ± 9.3;Zn = 451 ± 128;Cu = 83.3 ± 35.8 and Mo is 9.16 ± 9.1.While the mean concentrations of Cr, Cu, and Mo were higher in the females, that of Mn, Ni and Zn were more in the males. Statistical analysis of the results for both genders at 0.05 probably shows significant difference for Ni, Zn and Mo while Cr, Mn and Cu showed no significant difference. The relationships between age, body mass, height, and heavy metal concentrations were also investigated. Statistical analysis of the results indicates that there was no correlation between the body mass (R2 ≤ 0.048), height (R2 ≤ 0.002) and heavy metal concentration in hair. Zn showed the highest deviation among other elements in the individual samples for both genders which reflect the individual variation in the concentration of Zn. 展开更多
关键词 HUMAN HAIR HEAVY METALS x-ray fluorescence Risk Assessment
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