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电弧喷涂Zn-Al伪合金涂层耐腐蚀性能研究进展
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作者 张敏 丁玉萍 +1 位作者 王淞 刘施峰 《表面技术》 EI CAS CSCD 北大核心 2024年第10期1-15,共15页
通过在钢基体表面制备涂层可以很好地延长钢铁材料的服役时间,减少因腐蚀造成的重大事故和人员伤亡。相较于传统的纯Zn涂层、纯Al涂层以及Zn-Al合金涂层,Zn-Al伪合金涂层能够为基体材料提供长久有效的腐蚀防护,在钢铁材料的腐蚀防护中... 通过在钢基体表面制备涂层可以很好地延长钢铁材料的服役时间,减少因腐蚀造成的重大事故和人员伤亡。相较于传统的纯Zn涂层、纯Al涂层以及Zn-Al合金涂层,Zn-Al伪合金涂层能够为基体材料提供长久有效的腐蚀防护,在钢铁材料的腐蚀防护中具有巨大的应用潜力。简述了Zn-Al伪合金涂层电弧喷涂制备工艺的特点;介绍了Zn、Al、Zn-Al合金及Zn-Al伪合金涂层在模拟海洋环境下的腐蚀防护原理;在此基础上从组分、喷涂工艺参数(喷涂距离、喷涂电流和喷涂电压)、元素掺杂(Mg、Si及Re)及后处理工艺(封孔、激光重熔)等角度,论述了其对Zn-Al伪合金涂层耐蚀性的影响;讨论了Zn-Al伪合金涂层防腐体系在桥梁、海洋钢结构件、地下运输管道中的应用现状;最后总结了目前研究工作中存在的挑战,提出了电弧喷涂Zn-Al伪合金涂层尚需深入研究的重点问题,为提高钢铁材料使用寿命提供了参考。 展开更多
关键词 zn-al伪合金 电弧喷涂 涂层 耐蚀性
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烧结NdFeB磁体表面Zn-Al/T8超疏水复合涂层的显微组织及耐蚀性
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作者 张晓虎 罗军明 +4 位作者 徐吉林 陈金 黄俊 马永存 薛名山 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第5期1606-1617,共12页
为提升烧结NdFeB磁体的耐蚀性,采用旋涂法和等离子体增强化学气相沉积技术在其表面制备Zn-Al/T8(2-全氟辛基乙基丙烯酸酯)超疏水复合涂层。结果表明,Zn-Al涂层主要由片层状的Zn和Al相组成,厚度大约为28μm。Zn-Al/T8复合涂层的接触角达... 为提升烧结NdFeB磁体的耐蚀性,采用旋涂法和等离子体增强化学气相沉积技术在其表面制备Zn-Al/T8(2-全氟辛基乙基丙烯酸酯)超疏水复合涂层。结果表明,Zn-Al涂层主要由片层状的Zn和Al相组成,厚度大约为28μm。Zn-Al/T8复合涂层的接触角达到151.78°,而滚动角仅为5.13°,说明Zn-Al/T8复合涂层可提供一个超疏水表面。Zn-Al涂层和Zn-Al/T8复合涂层对烧结NdFeB的磁性能均无显著影响。Zn-Al涂层通过牺牲阳极来提高NdFeB磁体的耐蚀性,而Zn-Al/T8复合涂层通过超疏水表面进一步提升耐蚀性。Zn-Al/T8复合涂层较Zn-Al涂层具有更好的耐盐雾性能。Zn-Al/T8超疏水复合涂层是一种非常有前途的烧结NdFeB磁体保护涂层。 展开更多
关键词 显微组织 耐蚀性 烧结NDFEB磁体 zn-al涂层 超疏水表面 旋涂法 等离子体增强化学气相沉积
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A comprehensive review of radiation effects on solder alloys and solder joints
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作者 Norliza Ismail Wan Yusmawati Wan Yusoff +3 位作者 Nor Azlian Abdul Manaf Azuraida Amat Nurazlin Ahmad Emee Marina Salleh 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期86-102,共17页
In the realm of military and defence applications, exposure to radiation significantly challenges the performance and reliability of solder alloys and joints in electronic systems. This comprehensive review examines r... In the realm of military and defence applications, exposure to radiation significantly challenges the performance and reliability of solder alloys and joints in electronic systems. This comprehensive review examines radiation-induced effects on solder alloys and solder joints in terms of microstructure and mechanical properties. In this paper, we evaluate the existing literature, including experimental studies and fundamental theory, to provide a comprehensive overview of the behavior of solder materials under radiation. A review of the literature highlights key mechanisms that contribute to radiation-induced changes in the microstructure, such as the formation of intermetallic compounds, grain growth,micro-voids and micro-cracks. Radiation is explored as a factor influencing solder alloy hardness,strength, fatigue and ductility. Moreover, the review addresses the challenges and limitations inherent in studying the effects of radiation on solder materials and offers recommendations for future research. It is crucial to understand radiation-induced effects on solder performance to design robust and radiationresistant electronic systems. A review of radiation effects on solder materials and their applications in electronics serves as a valuable resource for researchers, engineers, and practitioners in that field. 展开更多
关键词 Defence technology solder alloy solder joints Radiation-induced effect MICROSTRUCTURE Mechanical properties
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A review of extreme condition effects on solder joint reliability:Understanding failure mechanisms
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作者 Norliza Ismail Wan Yusmawati Wan Yusoff +2 位作者 Azuraida Amat Nor Azlian Abdul Manaf Nurazlin Ahmad 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第11期134-158,共25页
Solder joint,crucial component in electronic systems,face significant challenges when exposed to extreme conditions during applications.The solder joint reliability involving microstructure and mechanical properties w... Solder joint,crucial component in electronic systems,face significant challenges when exposed to extreme conditions during applications.The solder joint reliability involving microstructure and mechanical properties will be affected by extreme conditions.Understanding the behaviour of solder joints under extreme conditions is vital to determine the durability and reliability of solder joint.This review paper aims to comprehensively explore the underlying failure mechanism affecting solder joint reliability under extreme conditions.This study covers an in-depth analysis of effect extreme temperature,mechanical stress,and radiation conditions towards solder joint.Impact of each condition to the microstructure including solder matrix and intermetallic compound layer,and mechanical properties such as fatigue,shear strength,creep,and hardness was thoroughly discussed.The failure mechanisms were illustrated in graphical diagrams to ensure clarity and understanding.Furthermore,the paper highlighted mitigation strategies that enhancing solder joint reliability under challenging operating conditions.The findings offer valuable guidance for researchers,engineers,and practitioners involved in electronics,engineering,and related fields,fostering advancements in solder joint reliability and performance. 展开更多
关键词 solder joint Extreme condition Failure mechanism Defence and military RELIABILITY
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Preventing formation of intermetallic compounds in ultrasonic-assisted Sn soldering of Mg/Al alloys through pre-plating a Ni coating layer on the Mg substrate
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作者 Yingzong Liu Yuanxing Li +1 位作者 Hui Chen Zongtao Zhu 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第2期726-741,共16页
Magnesium and aluminum alloys are widely used in various industries because of their excellent properties,and their reliable connection may increase application of materials.Intermetallic compounds(IMCs)affect the joi... Magnesium and aluminum alloys are widely used in various industries because of their excellent properties,and their reliable connection may increase application of materials.Intermetallic compounds(IMCs)affect the joint performance of Mg/Al.In this study,AZ31 Mg alloy with/without a nickel(Ni)coating layer and 6061 Al alloy were joined by ultrasonic-assisted soldering with Sn-3.0Ag-0.5Cu(SAC)filler.The effects of the Ni coating layer on the microstructure and mechanical properties of Mg/Al joints were systematically investigated.The Ni coating layer had a significant effect on formation of the Mg_(2)Sn IMC and the mechanical properties of Mg/Al joints.The blocky Mg_(2)Sn IMC formed in the Mg/SAC/Al joints without a Ni coating layer.The content of the Mg_(2)Sn IMC increased with increasing soldering temperature,but the joint strength decreased.The joint without a Ni coating layer fractured at the blocky Mg_(2)Sn IMC in the solder,and the maximum shear strength was 32.2 MPa.By pre-plating Ni on the Mg substrate,formation of the blocky Mg_(2)Sn IMC was inhibited in the soldering temperature range 240–280℃and the joint strength increased.However,when the soldering temperature increased to 310℃,the blocky Mg_(2)Sn IMC precipitated again in the solder.Transmission electron microscopy showed that some nano-sized Mg_(2)Sn IMC and the(Cu,Ni)_(6)Sn_(5)phase formed in the Mg(Ni)/SAC/Al joint soldered at 280℃,indicating that the Ni coating layer could no longer prevent diffusion of Mg into the solder when the soldering temperature was higher than 280℃.The maximum shear strength of the Mg(Ni)/SAC/Al joint was 58.2 MPa for a soldering temperature of 280℃,which was 80.7%higher than that of the Mg/SAC/Al joint,and the joint was broken at the Mg(Ni)/SAC interface.Pre-plating Ni is a feasible way to inhibit formation of IMCs when joining dissimilar metals. 展开更多
关键词 Ultrasonic-assisted soldering Mg_(2)Sn Ni coating layer Shear strength
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Industrial Fusion Cascade Detection of Solder Joint
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作者 Chunyuan Li Peng Zhang +2 位作者 Shuangming Wang Lie Liu Mingquan Shi 《Computers, Materials & Continua》 SCIE EI 2024年第10期1197-1214,共18页
With the remarkable advancements in machine vision research and its ever-expanding applications,scholars have increasingly focused on harnessing various vision methodologies within the industrial realm.Specifically,de... With the remarkable advancements in machine vision research and its ever-expanding applications,scholars have increasingly focused on harnessing various vision methodologies within the industrial realm.Specifically,detecting vehicle floor welding points poses unique challenges,including high operational costs and limited portability in practical settings.To address these challenges,this paper innovatively integrates template matching and the Faster RCNN algorithm,presenting an industrial fusion cascaded solder joint detection algorithm that seamlessly blends template matching with deep learning techniques.This algorithm meticulously weights and fuses the optimized features of both methodologies,enhancing the overall detection capabilities.Furthermore,it introduces an optimized multi-scale and multi-template matching approach,leveraging a diverse array of templates and image pyramid algorithms to bolster the accuracy and resilience of object detection.By integrating deep learning algorithms with this multi-scale and multi-template matching strategy,the cascaded target matching algorithm effectively accurately identifies solder joint types and positions.A comprehensive welding point dataset,labeled by experts specifically for vehicle detection,was constructed based on images from authentic industrial environments to validate the algorithm’s performance.Experiments demonstrate the algorithm’s compelling performance in industrial scenarios,outperforming the single-template matching algorithm by 21.3%,the multi-scale and multitemplate matching algorithm by 3.4%,the Faster RCNN algorithm by 19.7%,and the YOLOv9 algorithm by 17.3%in terms of solder joint detection accuracy.This optimized algorithm exhibits remarkable robustness and portability,ideally suited for detecting solder joints across diverse vehicle workpieces.Notably,this study’s dataset and feature fusion approach can be a valuable resource for other algorithms seeking to enhance their solder joint detection capabilities.This work thus not only presents a novel and effective solution for industrial solder joint detection but lays the groundwork for future advancements in this critical area. 展开更多
关键词 Cascade object detection deep learning feature fusion multi-scale and multi-template matching solder joint dataset
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火焰喷涂纯锌和Zn-Al合金涂层的耐腐蚀性能
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作者 刘畅 高名传 +2 位作者 袁振南 余斯亮 陈同舟 《机械工程材料》 CAS CSCD 北大核心 2024年第8期9-17,共9页
在6061-T6铝合金表面制备了火焰喷涂纯锌、Zn-15Al合金和Zn-30Al合金涂层,研究了不同涂层的微观形貌、耐中性盐雾腐蚀性能和电化学性能。结果表明:纯锌、Zn-15Al合金和Zn-30Al合金涂层截面结构致密,孔隙率依次降低,与基体呈机械结合;经... 在6061-T6铝合金表面制备了火焰喷涂纯锌、Zn-15Al合金和Zn-30Al合金涂层,研究了不同涂层的微观形貌、耐中性盐雾腐蚀性能和电化学性能。结果表明:纯锌、Zn-15Al合金和Zn-30Al合金涂层截面结构致密,孔隙率依次降低,与基体呈机械结合;经中性盐雾腐蚀后,纯锌、Zn-15Al合金与Zn-30Al合金涂层的腐蚀质量增加和腐蚀速率依次减小,Zn-30Al合金涂层表现出最好的耐中性盐雾腐蚀性;在人工海水溶液中,3种涂层的开路电位均低于铝合金基体,可以对基体进行牺牲阳极保护;相比纯锌涂层,Zn-15Al合金和Zn-30Al合金涂层的自腐蚀电流密度更小,自腐蚀电位更高,腐蚀速率更小,腐蚀倾向更低;随着浸泡腐蚀时间延长,Zn-15Al合金涂层的耐腐蚀性能无显著变化,Zn-30Al合金涂层的耐腐蚀性能逐渐增强。Zn-30Al合金涂层表现出最好的耐电化学腐蚀性。 展开更多
关键词 火焰喷涂 纯锌涂层 zn-al合金涂层 盐雾试验 电化学 耐蚀性
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Effect of Mo and ZrO_(2)nanoparticles addition on interfacial properties and shear strength of Sn58Bi/Cu solder joint
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作者 Amares SINGH Hui Leng CHOO +1 位作者 Wei Hong TAN Rajkumar DURAIRAJ 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2619-2628,共10页
The influence of Mo and ZrO_(2)nanoparticles addition on the interfacial properties and shear strength of Sn58Bi solder joint was investigated.The interfacial microstructures of Sn58Bi/Cu,Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(... The influence of Mo and ZrO_(2)nanoparticles addition on the interfacial properties and shear strength of Sn58Bi solder joint was investigated.The interfacial microstructures of Sn58Bi/Cu,Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints were analysed using a scanning electron microscope(SEM)coupled with energy dispersive X-ray(EDX)and the X-ray diffraction(XRD).Intermetallic compounds(IMCs)of MoSn_(2)are detected in the Sn58Bi+Mo/Cu solder joint,while SnZr,Zr_(5)Sn_(3),ZrCu and ZrSn_(2)are detected in Sn58Bi+ZrO_(2)/Cu solder joint.IMC layers for both composite solders comprise of Cu_(6)Sn_(5) and Cu_(3)Sn.The SEM images of these layers were used to measure the IMC layer’s thickness.The average IMC layer’s thickness is 1.4431μm for Sn58Bi+Mo/Cu and 0.9112μm for Sn58Bi+ZrO_(2)/Cu solder joints.Shear strength of the solder joints was investigated via the single shear lap test method.The average maximum load and shear stress of the Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints are increased by 33%and 69%,respectively,as compared to those of the Sn58Bi/Cu solder joint.By comparing both composite solder joints,the latter prevails better as adding smaller sized ZrO_(2)nanoparticles improves the interfacial properties granting a stronger solder joint. 展开更多
关键词 lead-free solder interfacial microstructure IMC layer thickness shear strength dislocation density ZrO_(2)nanoparticles Mo nanoparticles
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Zn-Al共掺杂和形貌调控制备LiMn_(2)O_(4)正极材料及其电化学性能
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作者 朱琴 马姣 +3 位作者 钱志慧 李萌 郭昱娇 郭俊明 《精细化工》 EI CAS CSCD 北大核心 2024年第6期1246-1253,1269,共9页
采用固相燃烧法在不同焙烧温度(600、650、700和750℃)下制备了LiZn_(0.05)Al_(0.03)Mn_(1.92)O_(4)正极材料,采用XRD、SEM、XPS对其进行了表征,通过循环伏安(CV)和电化学阻抗(EIS)测试了其电化学性能。结果表明,Zn-Al共掺杂和焙烧温度... 采用固相燃烧法在不同焙烧温度(600、650、700和750℃)下制备了LiZn_(0.05)Al_(0.03)Mn_(1.92)O_(4)正极材料,采用XRD、SEM、XPS对其进行了表征,通过循环伏安(CV)和电化学阻抗(EIS)测试了其电化学性能。结果表明,Zn-Al共掺杂和焙烧温度未改变LiMn_(2)O_(4)的晶体结构,正极材料的结晶性随焙烧温度(<750℃)的升高而增加,650℃及以上时形成了较多包含高暴露(111)晶面、小面积(110)、(100)晶面的截断八面体形貌晶粒,但750℃时正极材料发生部分分解。焙烧温度650℃的样品(LZAMO-650)表现出最佳的电化学性能,在5 C和10 C倍率下,初始放电比容量分别为101.3、99.9 mA·h/g,循环1000圈后容量保持率分别为81.5%、74.3%;LZAMO-650样品极化作用较小,有较好的循环可逆性,具有较低的电荷转移阻抗(R_(ct)=132.14Ω)和较大的锂离子扩散系数(DLi^(+)=3.65×10^(–16)cm^(2)/s)。Zn-Al共掺杂和形貌调控改性LiMn_(2)O_(4)正极材料有效抑制了Jahn-Teller效应,形成的截断八面体颗粒形貌降低了Mn的溶解,同时提供了更多的Li^(+)迁移三维通道,从而改善了材料的电化学性能。 展开更多
关键词 固相燃烧法 尖晶石LiMn_(2)O_(4) zn-al共掺 形貌调控 焙烧温度 JAHN-TELLER效应 Mn溶解 功能材料
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机械镀Zn-Al合金镀层的耐腐蚀性能研究 被引量:3
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作者 赵庆虚 王胜民 +2 位作者 赵晓军 赵凯 张国亮 《材料科学与工艺》 CAS CSCD 北大核心 2023年第1期27-34,共8页
为了增强机械镀镀层的耐腐蚀性能,采用机械镀方法,以含铝5%(质量分数)的Zn-Al合金粉为原料,在Q235钢材基体表面制备了Zn-Al合金镀层。利用扫描电镜(SEM)表征了合金镀层的截面和断面形貌;采用极化曲线、电化学阻抗谱(EIS)分析了合金镀层... 为了增强机械镀镀层的耐腐蚀性能,采用机械镀方法,以含铝5%(质量分数)的Zn-Al合金粉为原料,在Q235钢材基体表面制备了Zn-Al合金镀层。利用扫描电镜(SEM)表征了合金镀层的截面和断面形貌;采用极化曲线、电化学阻抗谱(EIS)分析了合金镀层在3.5%NaCl溶液中的电化学行为;通过中性盐雾腐蚀实验分析了合金镀层的耐蚀性,并采用XRD分析了镀层的盐雾腐蚀产物。结果表明,Zn-Al合金镀层由葫芦状的Zn-Al合金颗粒交错互嵌堆积而成,镀层颗粒之间以类似隼接的连接方式搭接“卡锁”;与机械镀Zn层相比,Zn-Al合金镀层的腐蚀电位正移了209 mV,腐蚀电流密度仅为纯Zn镀层的7.1%左右,极化电阻为纯Zn镀层的14倍;Zn-Al合金镀层的容抗弧半径明显大于纯Zn镀层的弧半径,且Q_(dl)较纯锌层减小;纯Zn镀层出现白锈和红锈的时间分别为24和362 h,而Zn-Al合金镀层出现白锈和红锈的时间为48和504 h。Zn-Al合金镀层的耐中性盐雾腐蚀性能明显优于纯Zn镀层,合金镀层对电荷转移具有更好的抑制作用,且Zn-Al合金镀层的腐蚀产物结构致密,可增强物理屏蔽功能。 展开更多
关键词 zn-al合金镀层 zn-al机械镀 zn-al合金 耐蚀性 沉积
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合成气制低碳烯烃串联反应中Zn-Al氧化物的制备及性能 被引量:2
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作者 李保珍 孟凡会 +1 位作者 王丽娜 李忠 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2023年第1期111-119,共9页
以工业拟薄水铝石为铝源,通过微波辅助蒸发诱导自组装(M-EISA)法制备了一系列不同Zn/Al原子比的Zn-Al氧化物,并与SAPO-18分子筛物理混合后考察其催化合成气制低碳烯烃(C_(2)^(=)-C_(4)^(=))反应性能。采用X射线衍射(XRD)、透射电镜(TEM)... 以工业拟薄水铝石为铝源,通过微波辅助蒸发诱导自组装(M-EISA)法制备了一系列不同Zn/Al原子比的Zn-Al氧化物,并与SAPO-18分子筛物理混合后考察其催化合成气制低碳烯烃(C_(2)^(=)-C_(4)^(=))反应性能。采用X射线衍射(XRD)、透射电镜(TEM)、N_(2)吸附-脱附、CO和H_(2)程序升温脱附(CO-TPD、H_(2)-TPD)、X射线光电子能谱(XPS)等进行表征。M-EISA法制备的Zn-Al氧化物随Zn/Al原子比的增加,比表面积和孔容逐渐下降,平均孔径先增大后降低。与浸渍(IP)法制备的ZnAl-IP相比,Zn/Al原子比为1∶2的ZnAl_(2)O_(x)样品中Zn分散度高,形成的ZnAl_(2)O_(4)尖晶石结构产生了更多的氧空位。催化结果表明,M-EISA法制备的Zn-Al样品活性随Zn/Al原子比的增加而先增加后减小,(C_(2)^(=)-C_(4)^(=))选择性逐渐降低。ZnAl_(2)O_(x)样品的CO转化率最高(34.8%),且反应50 h未见明显失活,催化性能明显优于ZnAl-IP样品。 展开更多
关键词 合成气转化 低碳烯烃 zn-al氧化物 双功能催化剂 微波辅助蒸发诱导自组装法
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Zn-Al冷喷涂复合涂层耐3.5 wt.%NaCl溶液腐蚀行为 被引量:3
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作者 孙永江 张金玲 +2 位作者 翟海民 王海鹏 李文生 《兰州理工大学学报》 CAS 北大核心 2023年第2期17-23,共7页
利用低压冷喷涂技术在Q235普通碳素钢基体表面沉积不同Al质量分数Zn-Al复合涂层,采用开路电位和极化曲线电化学测试方法,分析了Zn-Al复合涂层在3.5 wt.%NaCl溶液中浸泡的腐蚀电位,阻抗值以及腐蚀电流密度;利用附带能谱仪的扫描电子显微... 利用低压冷喷涂技术在Q235普通碳素钢基体表面沉积不同Al质量分数Zn-Al复合涂层,采用开路电位和极化曲线电化学测试方法,分析了Zn-Al复合涂层在3.5 wt.%NaCl溶液中浸泡的腐蚀电位,阻抗值以及腐蚀电流密度;利用附带能谱仪的扫描电子显微镜和X射线衍射仪分析了其在3.5 wt.%NaCl溶液浸泡1440 h后的涂层组织形貌、特定区域元素分布以及物相变化.研究表明:在3.5 wt.%NaCl溶液中,随着Al质量分数的增加,涂层耐腐蚀性能提高,当Al质量分数大于35%时,涂层耐腐蚀性能更加优越.因为腐蚀过程中Zn元素优先发生腐蚀,易形成稳定性较好的氧化膜,且Al抑制了Zn的活性从而减缓了腐蚀速率,Al质量分数越高,抑制效果越好.Zn-Al复合涂层在3.5 wt.%NaCl溶液的腐蚀机制为均匀腐蚀、点蚀、局部点蚀以及腐蚀产物的自我封闭. 展开更多
关键词 冷喷涂 zn-al复合涂层 Al质量分数 耐腐蚀性 腐蚀行为
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Zn-Al系钎焊材料的研究进展 被引量:1
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作者 陈晨 张亮 +1 位作者 王曦 李木兰 《材料导报》 CSCD 北大核心 2023年第22期138-150,共13页
Cu因其优良的力学性能、延展性能等而被广泛用于电子、机械等领域。但Cu同样作为世界性稀缺资源,尤其是我国十分依赖进口。为降低制造成本,寻找其他金属代替Cu成为当今的研究热潮。我国Al资源较为丰富,以Al代Cu能显著减少构件质量和成... Cu因其优良的力学性能、延展性能等而被广泛用于电子、机械等领域。但Cu同样作为世界性稀缺资源,尤其是我国十分依赖进口。为降低制造成本,寻找其他金属代替Cu成为当今的研究热潮。我国Al资源较为丰富,以Al代Cu能显著减少构件质量和成本消耗。然而,由于二者物理性能差异较大,在结合界面处易产生较大残余应力,影响连接件的可靠性。而传统的焊接方法温度较高,易导致Al侧软化和变形。诸多行业面临着Al连接困难的问题。因此,研究者们注意到一种具有很大应用潜能的钎料——Zn-Al钎料,通过改变Al含量,能控制其熔化温度,较为灵活地满足不同情况下的焊接需求,十分契合Cu/Al等金属的连接。本文针对Zn-Al钎料的研究现状,综合评述了其合金化方面的研究进展及发展趋势,主要从显微组织、力学性能等方面对现有研究成果进行分析总结,同时指出所存在的问题,并针对今后研究工作进行分析和展望,期望Zn-Al钎料能早日解决Cu/Al等连接的问题,以达到缓解Cu资源紧张、节省生产成本的目的。 展开更多
关键词 Cu资源稀缺 zn-al钎料 金属连接 显微组织 力学性能
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Zn-Al混合氧化物催化尿素醇解合成碳酸乙烯酯的研究
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作者 陈小朋 刘世钰 +1 位作者 沈卫华 方云进 《现代化工》 CAS CSCD 北大核心 2023年第10期101-104,110,共5页
采用共沉淀法制备了Zn-Al类水滑石前体,考察了不同煅烧温度下制备的Zn/Al复合氧化物催化剂对尿素和乙二醇合成碳酸乙烯酯(EC)收率的影响。结果表明,873 K温度下煅烧的催化剂在反应中表现出最高的催化活性,EC收率为91.1%,催化剂重复使用... 采用共沉淀法制备了Zn-Al类水滑石前体,考察了不同煅烧温度下制备的Zn/Al复合氧化物催化剂对尿素和乙二醇合成碳酸乙烯酯(EC)收率的影响。结果表明,873 K温度下煅烧的催化剂在反应中表现出最高的催化活性,EC收率为91.1%,催化剂重复使用4次活性没有降低。通过TG、XRD对催化剂进行了表征,并采用ICP测定了该复合氧化物中Zn、Al在反应体系中的化学溶解量,考察了溶解情况和收率之间的关系,结果发现适当Al的溶解能够与Zn起到很好的协同作用,从而促进EC的合成。 展开更多
关键词 zn-al氧化物催化剂 尿素 乙二醇 碳酸乙烯酯 溶解量
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NdFeB磁体表面环保型Zn-Al涂层的盐雾腐蚀行为
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作者 胡娜 谢发勤 +4 位作者 吴向清 李淑良 黄科超 贺栋栋 鲁闯 《装备环境工程》 CAS 2023年第4期86-95,共10页
目的 研究NdFeB磁体表面环保型Zn-Al涂层在盐雾环境中的腐蚀行为。方法 采用SEM、XRD、EDS、拉曼光谱、傅里叶变换红外光谱等对Zn-Al涂层的形貌、物相、成分结构进行分析。通过电化学曲线探究Zn-Al涂层在盐雾环境中的腐蚀机理。结果 在N... 目的 研究NdFeB磁体表面环保型Zn-Al涂层在盐雾环境中的腐蚀行为。方法 采用SEM、XRD、EDS、拉曼光谱、傅里叶变换红外光谱等对Zn-Al涂层的形貌、物相、成分结构进行分析。通过电化学曲线探究Zn-Al涂层在盐雾环境中的腐蚀机理。结果 在NdFeB磁体表面制备的环保型Zn-Al涂层的耐盐雾腐蚀时间不少于1 000 h。在盐雾腐蚀环境中,Zn-Al涂层表面逐渐被白锈覆盖,失去金属光泽,腐蚀至1 126 h时,Zn-Al涂层表面出现红色锈点,涂层微观组织呈蜂窝状结构,并出现微裂纹。腐蚀产物由Zn_(5)(OH)_(8)Cl_(2)·H_(2)O、Al_(9)SiAl_(12)(OH)_(18)(AlO_(4))(Si_(5)O_(16))Cl、Fe_(2)O_(3)和极少量的Zn、Al组成。腐蚀前期,Zn-Al涂层表面的钝化膜、硅烷膜起保护作用;随腐蚀进行,膜层破坏暴露出片状金属粉,金属粉活化,涂层发挥牺牲阳极保护作用;腐蚀后期,腐蚀介质通过涂层微裂纹穿透涂层至磁体,涂层牺牲阳极的保护作用和物理屏蔽保护作用显著减弱,直至失效。结论 环保型Zn-Al涂层可显著提高NdFeB磁体的耐中性盐雾腐蚀性能。 展开更多
关键词 zn-al涂层 NDFEB磁体 盐雾腐蚀 腐蚀机理 自腐蚀电位 电化学 物理屏蔽作用
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热喷涂Zn-Al涂层的耐蚀性能研究 被引量:2
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作者 贾恒琼 王涛 +4 位作者 吴韶亮 史懿 魏曌 石振平 袁磊 《高速铁路新材料》 2023年第2期22-27,共6页
选取了4种不同Al含量的热喷涂Zn-Al合金丝材,研究了Zn-Al涂层的厚度、微观结构、电化学腐蚀、耐盐雾腐蚀、附着力等性能。结果表明:涂层中Zn和Al微观分布与合金丝材的成分组成基本一致,说明2种元素的沉积效率基本接近100%;随着涂层中Al... 选取了4种不同Al含量的热喷涂Zn-Al合金丝材,研究了Zn-Al涂层的厚度、微观结构、电化学腐蚀、耐盐雾腐蚀、附着力等性能。结果表明:涂层中Zn和Al微观分布与合金丝材的成分组成基本一致,说明2种元素的沉积效率基本接近100%;随着涂层中Al含量的增加,涂层耐腐蚀性能大幅增加;热喷涂Zn-Al涂层的附着力优于钢结构防腐涂料的附着力。研究结果可以为热喷涂Zn-Al涂层的应用提供参考。 展开更多
关键词 热喷涂 zn-al涂层 耐腐蚀性能 附着力
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A review of soldering by localized heating
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作者 崔鹏 杨婉春 +3 位作者 彭飞 祝温博 杨帆 李明雨 《China Welding》 CAS 2023年第2期1-15,共15页
In recent years,the rapid development of the new energy industry has driven continuous upgrading of high-density and high-power devices.In the packaging and assembly process,the problem of differentiation of the therm... In recent years,the rapid development of the new energy industry has driven continuous upgrading of high-density and high-power devices.In the packaging and assembly process,the problem of differentiation of the thermal needs of different modules has become increasingly prominent,especially for small-size solder joints with high heat dissipation in high-power devices.Localized soldering is con-sidered a suitable choice to selectively heat the desired target while not affecting other heat-sensitive chips.This paper reviews several local-ized soldering processes,focusing on the size of solder joints,soldering materials,and current state of the technique.Each localized solder-ing process was discovered to have unique characteristics.The requirements for small-size solder joints are met by laser soldering,microres-istance soldering,and self-propagating soldering;however,laser soldering has difficulty meeting the requirements for large heat dissipation,microresistance soldering requires the application of pressure to joints,and self-propagating soldering requires ignition materials.However,for small-size solder junctions,selective wave soldering,microwave soldering,and ultrasonic soldering are not appropriate.Because the magnetic field can be focused on a tiny area and the output energy of induction heating is large,induction soldering can be employed as a significant trend in future research. 展开更多
关键词 localized soldering high heat dissipation small size induction soldering focused heating
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Interfacial reaction behavior and mechanical properties of 5A06 Al alloy soldered with Sn-1Ti-xGa solders at a low temperature
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作者 宋立志 肖勇 +2 位作者 奚邦富 李佳琪 张建 《China Welding》 CAS 2023年第2期23-31,共9页
Active soldering of 5A06 Al alloy was performed at 300 ℃ by using Sn-1Ti and Sn-1Ti-0.3Ga active solders, respectively. Theeffects of soldering time on the microstructure and mechanical properties of the joints were ... Active soldering of 5A06 Al alloy was performed at 300 ℃ by using Sn-1Ti and Sn-1Ti-0.3Ga active solders, respectively. Theeffects of soldering time on the microstructure and mechanical properties of the joints were investigated. The results showed that the Sn-1Tisolder broke the oxide film on the surface of the Al substrate and induced intergranular diffusion in the Al substrate. When Ga was added tothe solder, severe dissolution pits appeared in the Al substrate due to the action of Sn-1Ti-0.3Ga solder, and many Al particles were flakedfrom the matrix into the solder seam. Under thermal stress and the Ti adsorption effect, the oxide film cracked. With increasing solderingtime, the shear strength of 5A06 Al alloy joints soldered with Sn-1Ti and Sn-1Ti-0.3Ga active solders increased. When soldered for 90 min,the joint soldered with Sn-1Ti-0.3Ga solder had a higher shear strength of 22.12 MPa when compared to Sn-1Ti solder. 展开更多
关键词 5A06-Al alloy Sn-Ti-Ga solder low-temperature soldering interfacial reaction mechanical properties
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Research Progress on the Solder Joint Reliability of Electronics Using in Deep Space Exploration
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作者 Qilong Guan Chunjin Hang +4 位作者 Shengli Li Dan Yu Ying Ding Xiuli Wang Yanhong Tian 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第2期16-28,共13页
The spacecraft for deep space exploration missions will face extreme environments,including cryogenic temperature,intense radiation,wide-range temperature variations and even the combination of conditions mentioned ab... The spacecraft for deep space exploration missions will face extreme environments,including cryogenic temperature,intense radiation,wide-range temperature variations and even the combination of conditions mentioned above.Harsh environments will lead to solder joints degradation or even failure,resulting in damage to onboard electronics.The research activities on high reliability solder joints using in extreme environments can not only reduce the use of onboard protection devices,but effectively improve the overall reliability of spacecraft,which is of great significance to the aviation industry.In this paper,we review the reliability research on SnPb solder alloys,Sn-based lead-free solder alloys and In-based solder alloys in extreme environments,and try to provide some suggestions for the follow-up studies,which focus on solder joint reliability under extreme environments. 展开更多
关键词 Deep space exploration Extreme environments solder joints MICROSTRUCTURE ELECTRONICS RELIABILITY
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Effect of Strain Rate on Tensile Behavior of Sn-9Zn-xAg-ySb;{(x, y) = (0.2, 0.6), (0.2, 0.8), (0.6, 0.2), (0.8, 0.2)} Lead-Free Solder Alloys
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作者 Shihab Uddin Md. Abdul Gafur Mohammad Obaidur Rahman 《Materials Sciences and Applications》 CAS 2023年第4期273-283,共11页
The tensile properties of Sn-9Zn-xAg-ySb;{(x, y) = (0.2, 0.6), (0.2, 0.8), (0.6, 0.2), (0.8, 0.2)} lead-free solders were investigated. All the test samples were annealed at 150°C for 1 hour. The tests are carrie... The tensile properties of Sn-9Zn-xAg-ySb;{(x, y) = (0.2, 0.6), (0.2, 0.8), (0.6, 0.2), (0.8, 0.2)} lead-free solders were investigated. All the test samples were annealed at 150°C for 1 hour. The tests are carried out at room temperature at the strain rate of 4.17 × 10<sup>-3</sup> s<sup>-1</sup>, 20.85 × 10<sup>-3</sup> s<sup>-1</sup>, and 208.5 × 10<sup>-3</sup> s<sup>-1</sup>. It is seen that the tensile strength increases and the ductility decrease with increasing the strain rate over the investigated range. From the strain rate change test results, the strain sensitivity values are found in the range of 0.0831 to 0.1455 due to the addition of different alloying elements. 展开更多
关键词 Lead-Free solder Strain Rate Strain Sensitivity DUCTILITY Tensile Properties
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